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公开(公告)号:US4849432A
公开(公告)日:1989-07-18
申请号:US17641
申请日:1987-02-24
申请人: Kozo Shiokawa , Shinichi Tsuboi , Shinzo Kagabu , Shoko Sasaki , Koichi Moriya , Yumi Hattori
发明人: Kozo Shiokawa , Shinichi Tsuboi , Shinzo Kagabu , Shoko Sasaki , Koichi Moriya , Yumi Hattori
IPC分类号: C07D237/00 , A01N43/50 , A01N43/54 , A01N43/60 , A01N43/78 , A01N43/86 , A01N47/40 , C07D277/20 , C07D277/28 , C07D277/32 , C07D277/38 , C07D401/06 , C07D403/06 , C07D413/06 , C07D417/06
CPC分类号: C07D401/06 , A01N47/40 , C07D277/28 , C07D403/06 , C07D413/06 , C07D417/06
摘要: Novel heterocyclic compounds of the formula ##STR1## wherein, R.sup.1 represents a hydrogen atom or an alkyl group, A represents an ethylene group which may be substituted by alkyl or a trimethylene group which may be substituted by alkyl, X represents an oxygen or sulfur atom or the group ##STR2## in which R.sup.2 represents a hydrogen atom of an optionally substituted alkyl, an alkenyl, an alkynyl or an acyl group, and R.sup.3 represents a hydrogen atom or an alkyl group, and Z represents an optionally sibstituted 5- or 6-membered heterocyclic group which contains at least two hetero atoms selected from oxygen, sulfur and nitrogen atoms, or an optionally substituted 3- or 4-pyridyl group.The above defined novel heterocyclic compounds of formula (I) exhibit powerful insecticidal properties.
摘要翻译: 式(I)的新型杂环化合物其中,R1表示氢原子或烷基,A表示可以被可被烷基取代的烷基或三亚甲基取代的亚乙基,X表示氧 或硫原子或其中R 2表示任选取代的烷基,烯基,炔基或酰基的氢原子的基团,且R 3表示氢原子或烷基,Z表示任选取代的5 - 或6元杂环基,或含有至少两个选自氧,硫和氮原子的杂原子,或任选取代的3-或4-吡啶基。 上述定义的式(I)新颖杂环化合物具有强大的杀虫性能。
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公开(公告)号:US4806553A
公开(公告)日:1989-02-21
申请号:US64267
申请日:1987-06-18
申请人: Kozo Shiokawa , Shinichi Tsuboi , Shinzo Kagabu , Shoko Sasaki , Koichi Moriya , Yumi Hattori
发明人: Kozo Shiokawa , Shinichi Tsuboi , Shinzo Kagabu , Shoko Sasaki , Koichi Moriya , Yumi Hattori
IPC分类号: C07D213/36 , A01N43/40 , A01N43/54 , A01N43/56 , A01N43/58 , A01N43/60 , A01N43/74 , A01N43/76 , A01N43/78 , A01N43/80 , A01N43/824 , A01N43/828 , A01N43/832 , A01N47/42 , C07D213/38 , C07D213/61 , C07D213/64 , C07D213/70 , C07D231/12 , C07D237/08 , C07D237/12 , C07D239/26 , C07D239/28 , C07D239/30 , C07D241/12 , C07D261/08 , C07D263/32 , C07D271/10 , C07D275/02 , C07D277/20 , C07D277/28 , C07D277/32 , C07D285/04 , C07D285/06 , C07D285/10 , C07D521/00 , A61K31/44 , C07D213/26
CPC分类号: C07D213/64 , A01N43/40 , A01N43/74 , A01N43/80 , A01N47/42 , C07D213/38 , C07D213/61 , C07D213/70 , C07D231/12 , C07D237/08 , C07D237/12 , C07D239/26 , C07D239/30 , C07D241/12 , C07D261/08 , C07D263/32 , C07D271/10 , C07D275/02 , C07D277/32 , C07D285/06 , C07D285/10
摘要: There are provided insecticidally active alkylenediamines of the formula ##STR1## wherein W.sup.1 stands for a 5- or 6-membered heterocyclic group which may be substituted, containing at least one hetero atom selected from, O, S and N, R.sup.1, R.sup.2 and R.sup.3 are hydrogen or alkyl and R.sup.4, X, Y and Z have the meanings as given in the specification.The new alkylenediamines can be prepared according to different preparation methods and exhibit a strong insecticidal activity.
摘要翻译: 提供了具有下式的杀虫活性亚烷基二胺:其中W1代表可被取代的含有至少一个选自O,S和N,R 1,R 2和R 3的杂原子的5或6元杂环基 是氢或烷基,R4,X,Y和Z具有说明书中给出的含义。 新的亚烷基二胺可以根据不同的制备方法制备,具有很强的杀虫活性。
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公开(公告)号:US4876263A
公开(公告)日:1989-10-24
申请号:US208421
申请日:1988-06-17
申请人: Kozo Shiokawa , Shinichi Tsuboi , Shoko Sasaki , Koichi Moriya , Yumi Hattori , Katsuhiko Shibuya
发明人: Kozo Shiokawa , Shinichi Tsuboi , Shoko Sasaki , Koichi Moriya , Yumi Hattori , Katsuhiko Shibuya
IPC分类号: A01N43/90 , A01N47/12 , A01N47/18 , C07D471/04 , C07D487/04 , C07D498/04 , C07D513/04
CPC分类号: C07D471/04 , A01N43/90 , A01N47/18 , C07D487/04 , C07D513/04
摘要: Nitro-subsliluted heterocyclic compounds of the formula (I) ##STR1## wherein R is hydrogen or alkyl, Z is an optionally substituted aryl or optionally subtituted heterocyclic groun containing at least one atom selected from N, O and S,A is optionally substituted ethylene or optionally substituted trimethylene, andB stands for 2 or 3 members of a heterocyclic ring which is formed, together with the adjacent C-atom and N-aom and at least one of said members may represent a hetero atom and may be optionally substituted, provided that when B stands for 3 members, two of which are carbon atoms and the other one is a nitrogen atom which is located in the middle of the three members, then at least one of said two carbon atoms must be substituted by a keto group. Such compounds being useful as insecticides.
摘要翻译: 硝基亚稀释的式(I)的杂环化合物其中R是氢或烷基,Z是任选取代的芳基或含有至少一个选自N,O和S的原子的任选取代的杂环化合物,A是 任选取代的乙烯或任选取代的三亚甲基,B代表杂环的2或3个成员,其与相邻的C原子和N-aom一起形成,并且所述成员中的至少一个可以表示杂原子,并且可以是 任选取代,条件是当B代表3个成员时,其中两个是碳原子,另一个是位于三个成员中间的氮原子,则所述两个碳原子中的至少一个必须被 一个酮基。 这些化合物可用作杀虫剂。
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公开(公告)号:US5472960A
公开(公告)日:1995-12-05
申请号:US291236
申请日:1994-08-16
申请人: Kozo Shiokawa , Shinichi Tsuboi , Shoko Sasaki , Koichi Moriya , Yumi Hattori , Katsuhiko Shibuya
发明人: Kozo Shiokawa , Shinichi Tsuboi , Shoko Sasaki , Koichi Moriya , Yumi Hattori , Katsuhiko Shibuya
IPC分类号: A01N43/90 , A01N47/12 , A01N47/18 , C07D471/04 , C07D487/04 , C07D498/04 , C07D513/04 , A01N33/18 , A01N43/86
CPC分类号: C07D471/04 , A01N43/90 , A01N47/18 , C07D487/04 , C07D513/04
摘要: Nitro-substituted heterocyclic compounds of the formula (I) ##STR1## wherein R is hydrogen or alkyl,Z is an optionally substituted aryl or optionally substituted heterocyclic group containing at least one atom selected from N, O and S,A is optionally substituted ethylene or optionally substituted trimethylene, andB stands for 2 or 3 members of a heterocyclic ring which is formed, together with the adjacent C-atom and N-atom and at least one of said members may represent a hetero atom and may be optionally substituted, provided that when B stands for 3 members, two of which are carbon atoms and the other one is a nitrogen atom which is located in the middle of the three members, then at least one of said two carbon atoms must be substituted by a keto group. Such compounds being useful as insecticides.
摘要翻译: 式(I)的硝基取代的杂环化合物其中R是氢或烷基,Z是任选取代的芳基或含有至少一个选自N,O和S的原子的任选取代的杂环基,A是 任选取代的乙烯或任选取代的三亚甲基,B代表与相邻C原子和N-原子一起形成的杂环的2或3个成员,并且所述成员中的至少一个可以表示杂原子,并且可以是 任选取代,条件是当B代表3个成员时,其中两个是碳原子,另一个是位于三个成员中间的氮原子,则所述两个碳原子中的至少一个必须被 一个酮基。 这些化合物可用作杀虫剂。
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公开(公告)号:US5366976A
公开(公告)日:1994-11-22
申请号:US126950
申请日:1993-09-27
申请人: Kozo Shiokawa , Shinichi Tsuboi , Shoko Sasaki , Koichi Moriya , Yumi Hattori , Katsuhiko Shibuya
发明人: Kozo Shiokawa , Shinichi Tsuboi , Shoko Sasaki , Koichi Moriya , Yumi Hattori , Katsuhiko Shibuya
IPC分类号: A01N43/90 , A01N47/12 , A01N47/18 , C07D471/04 , C07D487/04 , C07D498/04 , C07D513/04
CPC分类号: C07D471/04 , A01N43/90 , A01N47/18 , C07D487/04 , C07D513/04
摘要: Nitro-substituted heterocyclic compounds of the formula (I) ##STR1## wherein R is hydrogen or alkyl,Z is an optionally substituted aryl or optionally substituted heterocyclic group containing at least one atom selected from N, O and S,A is optionally substituted ethylene or optionally substituted trimethylene, andB stands for 2 or 3 members of a heterocyclic ring which is formed, together with the adjacent C-atom and N-atom and at least one of said members may represent a hetero atom and may be optionally substituted, provided that when B stands for 3 members, two of which are carbon atoms and the other one is a nitrogen atom which is located in the middle of the three members, then at least one of said two carbon atoms must be substituted by a keto group. Such compounds being useful as insecticides.
摘要翻译: 式(I)的硝基取代的杂环化合物其中R是氢或烷基,Z是任选取代的芳基或含有至少一个选自N,O和S的原子的任选取代的杂环基,A是 任选取代的乙烯或任选取代的三亚甲基,B代表与相邻C原子和N-原子一起形成的杂环的2或3个成员,并且所述成员中的至少一个可以表示杂原子,并且可以是 任选取代,条件是当B代表3个成员时,其中两个是碳原子,另一个是位于三个成员中间的氮原子,则所述两个碳原子中的至少一个必须被 一个酮基。 这些化合物可用作杀虫剂。
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公开(公告)号:US5231098A
公开(公告)日:1993-07-27
申请号:US823240
申请日:1992-01-21
申请人: Kozo Shiokawa , Shinichi Tsuboi , Shoko Sasaki , Koichi Moriya , Yumi Hattori , Katsuhiko Shibuya
发明人: Kozo Shiokawa , Shinichi Tsuboi , Shoko Sasaki , Koichi Moriya , Yumi Hattori , Katsuhiko Shibuya
IPC分类号: A01N43/90 , A01N47/18 , C07D471/04 , C07D487/04 , C07D498/04 , C07D513/04
CPC分类号: C07D471/04 , A01N43/90 , A01N47/18 , C07D487/04 , C07D513/04
摘要: Nitro-substituted heterocyclic compounds of the formula (I) ##STR1## wherein R is hydrogen or alkyl, Z is an optionally substituted aryl or optionally substituted heterocyclic groun containing at least one atom selected from N, O and S,A is optionally substituted ethylene or optionally substituted trimethylene, andB stands for 2 or 3 members of a heterocyclic ring which is formed, together with the adjacent C-atom and N-atom and at least one of said members may represent a hetero atom and may be optionally substituted, provided that when B stands for 3 members, two of which are carbon atoms and the other one is a nitrogen atom which is located in the middle of the three members, then at least one of said two carbon atoms must be substituted by a keto group. Such compounds being useful as insecticides.
摘要翻译: 硝基取代的式(I)的杂环化合物其中R是氢或烷基,Z是任选取代的芳基或含有至少一个选自N,O和S的原子的任选取代的杂环化合物,A是 任选取代的乙烯或任选取代的三亚甲基,B代表与相邻C原子和N-原子一起形成的杂环的2或3个成员,并且所述成员中的至少一个可以表示杂原子,并且可以是 任选取代,条件是当B代表3个成员时,其中两个是碳原子,另一个是位于三个成员中间的氮原子,则所述两个碳原子中的至少一个必须被 一个酮基。 这些化合物可用作杀虫剂。
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公开(公告)号:US4960780A
公开(公告)日:1990-10-02
申请号:US353370
申请日:1989-05-17
申请人: Kozo Shiokawa , Shinichi Tsuboi , Shoko Sasaki , Koichi Moriya , Yumi Hattori , Katsuhiko Shibuya
发明人: Kozo Shiokawa , Shinichi Tsuboi , Shoko Sasaki , Koichi Moriya , Yumi Hattori , Katsuhiko Shibuya
IPC分类号: A01N43/90 , A01N47/12 , A01N47/18 , C07D471/04 , C07D487/04 , C07D498/04 , C07D513/04
CPC分类号: C07D471/04 , A01N43/90 , A01N47/18 , C07D487/04 , C07D513/04
摘要: Nitro-substituted heterocyclic compounds of the formula (I) ##STR1## wherein R is hydrogen or alkyl,Z is an optionally substituted aryl or optionally substituted heterocyclic groun containing at least one atom selected from N, O and S,A is optionally substituted ethylene or optionally substituted trimethylene, andB stands for 2 or 3 members of a heterocyclic ring which is formed, together with the adjacent C-atom and N-atom and at least one of said members may represent a hetero atom and may be optionally substituted, provided that when B stands for 3 members, two of which are carbon atoms and the other one is a nitrogen atom which is located in the middle of the three members, then at least one of said two carbon atoms must be substituted by a keto group. Such compounds being useful as insecticides.
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公开(公告)号:US5622956A
公开(公告)日:1997-04-22
申请号:US461903
申请日:1995-06-05
申请人: Kozo Shiokawa , Shinichi Tsuboi , Shoko Sasaki , Koichi Moriya , Yumi Hattori , Katsuhiko Shibuya
发明人: Kozo Shiokawa , Shinichi Tsuboi , Shoko Sasaki , Koichi Moriya , Yumi Hattori , Katsuhiko Shibuya
IPC分类号: A01N43/90 , A01N47/12 , A01N47/18 , C07D471/04 , C07D487/04 , C07D498/04 , C07D513/04 , A61K31/505
CPC分类号: C07D471/04 , A01N43/90 , A01N47/18 , C07D487/04 , C07D513/04
摘要: Nitro-substituted heterocyclic compounds of the formula (I) ##STR1## wherein R is hydrogen or alkyl,Z is an optionally substituted aryl or optionally substituted heterocyclic group containing at least one atom selected from N, O and S,A is optionally substituted ethylene or optionally substituted trimethylene, andB stands for 2 or 3 members of a heterocyclic ring which is formed, together with the adjacent C-atom and N-atom and at least one of said members may represent a hetero atom and may be optionally substituted, provided that when B stands for 3 members, two of which are carbon atoms and the other one is a nitrogen atom which is located in the middle of the three members, then at least one of said two carbon atoms must be substituted by a keto group. Such compounds being useful as insecticides.
摘要翻译: 式(I)的硝基取代的杂环化合物其中R是氢或烷基,Z是任选取代的芳基或含有至少一个选自N,O和S的原子的任选取代的杂环基,A是 任选取代的乙烯或任选取代的三亚甲基,B代表与相邻C原子和N-原子一起形成的杂环的2或3个成员,并且所述成员中的至少一个可以表示杂原子,并且可以是 任选取代,条件是当B代表3个成员时,其中两个是碳原子,另一个是位于三个成员中间的氮原子,则所述两个碳原子中的至少一个必须被 一个酮基。 这些化合物可用作杀虫剂。
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公开(公告)号:US4882344A
公开(公告)日:1989-11-21
申请号:US243545
申请日:1988-09-13
申请人: Kozo Shiokawa , Shinichi Tsuboi , Shoko Sasaki , Koichi Moriya , Yumi Hattori , Katsuhiko Shibuya
发明人: Kozo Shiokawa , Shinichi Tsuboi , Shoko Sasaki , Koichi Moriya , Yumi Hattori , Katsuhiko Shibuya
IPC分类号: A01N43/40 , A01N43/50 , A01N43/78 , A01N51/00 , C07D213/26 , C07D213/57 , C07D213/74 , C07D213/75 , C07D213/76 , C07D213/77 , C07D239/42 , C07D277/32 , C07D277/48 , C07D277/50 , C07D401/06 , C07D403/06 , C07D413/06 , C07D417/06 , A61K31/44
CPC分类号: C07D213/75 , A01N43/50 , A01N51/00 , C07D213/77 , C07D239/42 , C07D277/32 , C07D277/48 , C07D277/50 , C07D401/06 , C07D403/06 , C07D413/06 , C07D417/06
摘要: Novel insecticidally active heterocyclic compounds of the formula ##STR1## wherein W represents a substituted pyridyl group, or a 5- or 6-membered optionally substituted heterocyclic group containing at least two hetero atoms selected from oxygen, sulfur and nitrogen atoms,R represents a hydrogen atom or an alkyl group,Y represents .dbd.N-- or ##STR2## R' represents a hydrogen atom, an alkyl group, an aryl group, an acyl group, an alkoxycarbonyl group or a cyano group,Z represents a nitro group or a cyano group, andT represents 3 or 4 optionally substituted ring members of a 5- or 6-membered unsaturated heterocyclic ring which it forms together with the adjoining carbon atom and nitrogen atom, said 5- or 6-membered unsaturated heterocyclic ring containing 1 to 3 hetero atoms which are selected from oxygen, sulfur and nitrogen atoms and at least one of which is a nitrogen atom.
摘要翻译: 新颖的具有下式的杀虫活性杂环化合物,其中W代表取代的吡啶基,或含有至少两个选自氧,硫和氮原子的杂原子的5或6元任选取代的杂环基,R代表氢 原子或烷基,Y表示= N-或R'表示氢原子,烷基,芳基,酰基,烷氧基羰基或氰基,Z表示硝基或氰基 并且T表示与邻接的碳原子和氮原子一起形成的5或6元不饱和杂环的3或4个任选取代的环成员,所述5或6元不饱和杂环含有1至3个 杂原子,其选自氧,硫和氮原子,并且其中至少一个是氮原子。
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公开(公告)号:US5036082A
公开(公告)日:1991-07-30
申请号:US510509
申请日:1990-04-18
申请人: Kozo Shiokawa , Shinichi Tsuboi , Shoko Sasaki , Koichi Moriya , Yumi Hattori , Katsuhiko Shibuya
发明人: Kozo Shiokawa , Shinichi Tsuboi , Shoko Sasaki , Koichi Moriya , Yumi Hattori , Katsuhiko Shibuya
IPC分类号: A01N43/90 , A01N47/12 , A01N47/18 , C07D471/04 , C07D487/04 , C07D498/04 , C07D513/04
CPC分类号: C07D471/04 , A01N43/90 , A01N47/18 , C07D487/04 , C07D513/04
摘要: Nitro-substituted heterocyclic compounds of the formula (I) ##STR1## wherein R is hydrogen or alkyl, Z is an optionally substituted aryl or optionally substituted heterocyclic group containing at least one atom selected from N, O and S,A is optionally substituted ethylene or optionally substituted trimethylene, andB stands for 2 or 3 members of a heterocyclic ring which is formed, together with the adjacent C-atom and N-atom and at least one of said members may represent a hetero atom and may be optionally substituted, provided that when B stands for 3 members, two of which are carbon atoms and the other one is a nitrogen atom which is located in the middle of the three members, then at least one of said two carbon atoms must be substituted by a keto group. Such compounds being useful as insecticides.
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