公开(公告)号：US08445381B2

公开(公告)日：2013-05-21

申请号：US11961750

申请日：2007-12-20

Applicant: Krishnaswamy Ramkumar ,  Sundar Narayanan

Inventor： Krishnaswamy Ramkumar ,  Sundar Narayanan

IPC: H01L21/02

CPC classification number: H01L21/022 ,  H01L21/0217 ,  H01L21/02233 ,  H01L21/02337 ,  H01L21/28044 ,  H01L21/3144 ,  H01L29/4941 ,  H01L29/78

Abstract: A method of making a semiconductor structure comprises forming an oxide layer on a substrate; forming a silicon nitride layer on the oxide layer; annealing the layers in NO; and annealing the layers in ammonia. The equivalent oxide thickness of the oxide layer and the silicon nitride layer together is at most 25 Angstroms.

Abstract translation: 制造半导体结构的方法包括在衬底上形成氧化物层; 在氧化物层上形成氮化硅层; 在NO中退火层; 并在氨中退火层。 氧化物层和氮化硅层的等效氧化物厚度在一起为至多25埃。

公开(公告)号：US06905893B1

公开(公告)日：2005-06-14

申请号：US10289020

申请日：2002-11-05

Applicant: Sundar Narayanan ,  Krishnaswamy Ramkumar

Inventor： Sundar Narayanan ,  Krishnaswamy Ramkumar

IPC: G01N1/32 ,  G01N19/06 ,  H01L21/66 ,  H01L23/544

CPC classification number: H01L22/20 ,  G01N1/32 ,  G01N19/06 ,  H01L22/34

Abstract: A method is provided for determining a concentration profile of an impurity within a layer of a semiconductor topography. The method may include exposing the layer and an underlying layer to oxidizing conditions. In addition, the method may include comparing thickness measurements of total dielectric above the underlying layer taken before and after exposing the topography to oxidizing conditions . In some cases, the comparison may include plotting pre-oxidation thickness measurements versus post-oxidation measurements. In other embodiments, the comparison may include determining differences between the pre-oxidation and post-oxidation thickness measurements and correlating the differences to concentrations of the impurity. In some cases, such a correlation may include subtracting a concentration of the impurity at a first location along the semiconductor topography from a concentration of the impurity at a second location along the semiconductor topography.

Abstract translation: 提供了一种用于确定半导体形貌层内的杂质的浓度分布的方法。 该方法可以包括将层和下层暴露于氧化条件。 此外，该方法可以包括将暴露于地形之前和之后的所述下层的总电介质的厚度测量值与氧化条件进行比较。 在某些情况下，比较可能包括绘制预氧化厚度测量值与氧化后测量值。 在其他实施例中，比较可以包括确定预氧化和后氧化厚度测量之间的差异并将差异与杂质的浓度相关联。 在一些情况下，这种相关可以包括沿着半导体形貌从第二位置处的杂质浓度减去沿着半导体形貌的第一位置处的杂质的浓度。

公开(公告)号：US20050067663A1

公开(公告)日：2005-03-31

申请号：US10950332

申请日：2004-09-24

Applicant: Krishnaswamy Ramkumar ,  Sundar Narayanan

Inventor： Krishnaswamy Ramkumar ,  Sundar Narayanan

IPC: H01L21/28 ,  H01L21/314 ,  H01L29/49 ,  H01L29/78 ,  H01L21/20

CPC classification number: H01L21/022 ,  H01L21/0217 ,  H01L21/02233 ,  H01L21/02337 ,  H01L21/28044 ,  H01L21/3144 ,  H01L29/4941 ,  H01L29/78

Abstract: A method of making a semiconductor structure comprises forming an oxide layer on a substrate; forming a silicon nitride layer on the oxide layer; annealing the layers in NO; and annealing the layers in ammonia. The equivalent oxide thickness of the oxide layer and the silicon nitride layer together is at most 25 Angstroms.

Abstract translation: 制造半导体结构的方法包括在衬底上形成氧化物层; 在氧化物层上形成氮化硅层; 在NO中退火层; 并在氨中退火层。 氧化物层和氮化硅层的等效氧化物厚度在一起为至多25埃。

公开(公告)号：US06803321B1

公开(公告)日：2004-10-12

申请号：US10313049

申请日：2002-12-06

Applicant: Alain Blosse ,  Krishnaswamy Ramkumar ,  Sundar Narayanan

Inventor： Alain Blosse ,  Krishnaswamy Ramkumar ,  Sundar Narayanan

IPC: H01I21302

CPC classification number: H01L21/76897 ,  H01L21/28247 ,  H01L21/31116 ,  H01L21/3185

Abstract: A method of forming a semiconductor structure comprises forming a nitride layer on a stack, and etching the nitride layer to form spacers in contact with sides of the stack. The stack is on a semiconductor substrate, the stack comprises (i) a gate layer, comprising silicon, (ii) a metallic layer, on the gate layer, and (iii) an etch-stop layer, on the metallic layer. The forming is by CVD with a gas comprising SixL2x, L is an amino group, and X is 1 or 2.

Abstract translation: 形成半导体结构的方法包括在叠层上形成氮化物层，并蚀刻氮化物层以形成与堆叠的侧面接触的间隔物。 叠层在半导体衬底上，堆叠包括（i）栅极层，包括硅，（ii）栅极层上的金属层，和（iii）金属层上的蚀刻停止层。 通过CVD形成气体，其中包含SixL2x的气体，L是氨基，X是1或2。

公开(公告)号：US06773975B1

公开(公告)日：2004-08-10

申请号：US10326707

申请日：2002-12-20

Applicant: Krishnaswamy Ramkumar ,  Sundar Narayanan ,  Shahin Sharifzadeh

Inventor： Krishnaswamy Ramkumar ,  Sundar Narayanan ,  Shahin Sharifzadeh

IPC: H01L218238

CPC classification number: H01L21/823481 ,  H01L21/76229

Abstract: In one embodiment, a transistor is fabricated by forming gate materials, such as a gate oxide layer and a gate polysilicon layer, prior to forming a shallow trench isolation (STI) structure. Forming the gate materials early in the process minimizes exposure of the STI structure to processing steps that may expose its corners. Also, to minimize cross-diffusion of dopants and to help lower gate resistance, a metal stack comprising a barrier layer and a metal layer may be employed as a conductive line between gates. In one embodiment, the metal stack comprises a barrier layer of tungsten-nitride and a metal layer of tungsten.

Abstract translation: 在一个实施例中，在形成浅沟槽隔离（STI）结构之前，通过形成栅极材料，例如栅极氧化物层和栅极多晶硅层来制造晶体管。 在此过程早期形成栅极材料可最大限度地减少STI结构暴露其角落的处理步骤。 此外，为了最小化掺杂剂的交叉扩散并有助于降低栅极电阻，可以使用包括阻挡层和金属层的金属堆叠作为栅极之间的导电线。 在一个实施例中，金属堆叠包括氮化钨的阻挡层和钨的金属层。

公开(公告)号：US07371637B2

公开(公告)日：2008-05-13

申请号：US10950332

申请日：2004-09-24

Applicant: Krishnaswamy Ramkumar ,  Sundar Narayanan

Inventor： Krishnaswamy Ramkumar ,  Sundar Narayanan

IPC: H01L21/20

CPC classification number: H01L21/022 ,  H01L21/0217 ,  H01L21/02233 ,  H01L21/02337 ,  H01L21/28044 ,  H01L21/3144 ,  H01L29/4941 ,  H01L29/78

Abstract: A method of making a semiconductor structure comprises forming an oxide layer on a substrate; forming a silicon nitride layer on the oxide layer; annealing the layers in NO; and annealing the layers in ammonia. The equivalent oxide thickness of the oxide layer and the silicon nitride layer together is at most 25 Angstroms.

Abstract translation: 制造半导体结构的方法包括在衬底上形成氧化物层; 在氧化物层上形成氮化硅层; 在NO中退火层; 并在氨中退火层。 氧化物层和氮化硅层的等效氧化物厚度在一起为至多25埃。

公开(公告)号：US06803330B2

公开(公告)日：2004-10-12

申请号：US09975256

申请日：2001-10-12

Applicant: Krishnaswamy Ramkumar ,  Sundar Narayanan

Inventor： Krishnaswamy Ramkumar ,  Sundar Narayanan

IPC: H01L2131

CPC classification number: H01L21/28185 ,  H01L21/28202 ,  H01L29/518

Abstract: A method of nitriding a gate oxide layer by annealing a preformed oxide layer with nitric oxide (NO) gas is disclosed. The nitridation process can be carried out at lower temperatures and pressures than a conventional nitrous oxide anneal while still achieving acceptable levels of nitridation. The nitridation process can be conducted at atmospheric or sub-atmospheric pressures. As a result, the nitridation process can be used to form nitrided gate oxide layers in-situ in a CVD furnace. The nitrided gate oxide layer can optionally be reoxidized in a second oxidation step after the nitridation step. A gate electrode layer (e.g., boron doped polysilicon) can then be deposited on top of the nitrided gate oxide layer or on top of the reoxidized and nitrided gate oxide layer.

Abstract translation: 公开了通过用一氧化氮（NO）气体退火预形成的氧化物层来对栅极氧化物层进行氮化的方法。 氮化过程可以在比常规氧化亚氮退火更低的温度和压力下进行，同时仍然达到可接受的氮化水平。 氮化过程可以在大气压或低于大气压的压力下进行。 结果，可以使用氮化工艺在CVD炉中原位形成氮化的栅极氧化物层。 氮化栅氧化层可以在氮化步骤后的第二氧化步骤中任选地再氧化。 然后可以在氮化栅极氧化物层的顶部上或在再氧化和氮化的栅极氧化物层的顶部上沉积栅极电极层（例如，硼掺杂的多晶硅）。

公开(公告)号：US06664120B1

公开(公告)日：2003-12-16

申请号：US10023065

申请日：2001-12-17

Applicant: Sundar Narayanan ,  Krishnaswamy Ramkumar

Inventor： Sundar Narayanan ,  Krishnaswamy Ramkumar

IPC: H01L2166

CPC classification number: H01L22/20 ,  G01N1/32 ,  G01N19/06 ,  H01L22/34

Abstract: A method and a structure are provided for measuring a concentration of an impurity within a layer arranged upon a semiconductor substrate. The method may include exposing the layer and semiconductor substrate to oxidizing conditions and determining a difference in total dielectric thickness above the substrate from before to after exposing the layer and substrate. The difference may be correlated to a concentration of the impurity. In some cases, the method may include designating a plurality of measurement locations on the layer such that a concentration profile of the impurity within the layer may be determined. In some embodiments, exposing the layer and substrate may include forming an oxidized interface between the layer and the semiconductor substrate. Preferably, the oxidized interface is thicker underneath portions of the layer with a lower concentration of the impurity than underneath portions of the layer with a higher concentration of the impurity.

Abstract translation: 提供了一种测量布置在半导体衬底上的层内的杂质浓度的方法和结构。 该方法可以包括将层和半导体衬底暴露于氧化条件，并确定在暴露层和衬底之前至之后的衬底上的总电介质厚度的差异。 该差异可能与杂质的浓度相关。 在一些情况下，该方法可以包括指定层上的多个测量位置，使得可以确定该层内的杂质的浓度分布。 在一些实施例中，暴露层和衬底可以包括在层和半导体衬底之间形成氧化界面。 优选地，具有较低浓度的杂质的层的下部的氧化界面比具有较高浓度杂质的层的下部更厚。

公开(公告)号：US20080093680A1

公开(公告)日：2008-04-24

申请号：US11961750

申请日：2007-12-20

Applicant: Krishnaswamy Ramkumar ,  Sundar Narayanan

Inventor： Krishnaswamy Ramkumar ,  Sundar Narayanan

IPC: H01L29/78 ,  H01L21/31

CPC classification number: H01L21/022 ,  H01L21/0217 ,  H01L21/02233 ,  H01L21/02337 ,  H01L21/28044 ,  H01L21/3144 ,  H01L29/4941 ,  H01L29/78

Abstract: A method of making a semiconductor structure comprises forming an oxide layer on a substrate; forming a silicon nitride layer on the oxide layer; annealing the layers in NO; and annealing the layers in ammonia. The equivalent oxide thickness of the oxide layer and the silicon nitride layer together is at most 25 Angstroms.

Abstract translation: 制造半导体结构的方法包括在衬底上形成氧化物层; 在氧化物层上形成氮化硅层; 在NO中退火层; 并在氨中退火层。 氧化物层和氮化硅层的等效氧化物厚度在一起为至多25埃。

公开(公告)号：US07189652B1

公开(公告)日：2007-03-13

申请号：US10313048

申请日：2002-12-06

Applicant: Alain Blosse ,  Sundar Narayanan ,  Krishnaswamy Ramkumar

Inventor： Alain Blosse ,  Sundar Narayanan ,  Krishnaswamy Ramkumar

IPC: H01L21/302

CPC classification number: H01L21/28247 ,  H01L21/28061

Abstract: A method of forming a semiconductor structure comprises oxidizing a stack, to form sidewall oxide in contact with sides of the stack. The stack is on a semiconductor substrate, the stack includes a gate layer, comprising silicon; a metallic layer, on the gate layer; and an etch-stop layer, on the metallic layer. The sidewall oxide in contact with the metallic layer is thinner than the sidewall oxide in contact with the gate layer.

Abstract translation: 形成半导体结构的方法包括氧化堆叠，以形成与堆叠的侧面接触的侧壁氧化物。 堆叠在半导体衬底上，堆叠包括包含硅的栅极层; 栅极层上的金属层; 和金属层上的蚀刻停止层。 与金属层接触的侧壁氧化物比与栅极层接触的侧壁氧化物薄。