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公开(公告)号:US5932685A
公开(公告)日:1999-08-03
申请号:US918387
申请日:1997-08-26
申请人: Kuniharu Mori , Norimi Tabota , Koji Yamada , Shigeji Konagaya , Tsutomu Oko , Hiroaki Esaki , Seizo Takabayashi , Shinichiro Okumura , Tsutomu Isaka
发明人: Kuniharu Mori , Norimi Tabota , Koji Yamada , Shigeji Konagaya , Tsutomu Oko , Hiroaki Esaki , Seizo Takabayashi , Shinichiro Okumura , Tsutomu Isaka
CPC分类号: C08J5/18 , B29D7/01 , B29K2067/00 , B29K2995/0049 , C08J2367/02 , Y10T428/2817 , Y10T428/2826
摘要: Heat-shrinkable polyester films having a heat shrinkability of 30% or more, preferably 40% or more, in the direction of major shrinkage after treatment in hot water at 80.degree. C. for 30 seconds, the ratio of heat shrinkability in the direction of major shrinkage after treatment in hot water at 80.degree. C. for 5 seconds to heat shrinkability in the direction of major shrinkage after treatment in hot water at 80.degree. C. for 30 seconds being 0.8 or less, preferably 0.7 or less. The heat-shrinkable polyester films are suitable for label applications because of their particular heat-shrinkable properties such that not only do they scarcely cause longitudinal sinking when shrunk but also they have very few wrinkles, shrinkage spots and strains remaining after shrinkage.
摘要翻译: 在80℃下在热水中处理30秒后,在热收缩率为30%以上,优选为40%以上的热收缩性聚酯膜的热收缩率为 在80℃的热水中处理后,在80℃的热水中处理后的主收缩方向的热收缩率为80以下,优选为0.7以下,在80℃的热水中处理后的收缩率大。 热收缩聚酯薄膜由于具有特定的热收缩特性而适用于标签用途,因此不仅在收缩时几乎不引起纵向下沉,而且在收缩后残留的褶皱,收缩点和应变也很少。
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公开(公告)号:US5985387A
公开(公告)日:1999-11-16
申请号:US240024
申请日:1999-01-29
申请人: Kuniharu Mori , Mitsuo Inoue , Shinichiro Okumura , Tsutomu Oko , Norimi Tabota , Masatoshi Hashimoto , Hideki Ito , Seizo Takabayashi , Tsutomu Isaka
发明人: Kuniharu Mori , Mitsuo Inoue , Shinichiro Okumura , Tsutomu Oko , Norimi Tabota , Masatoshi Hashimoto , Hideki Ito , Seizo Takabayashi , Tsutomu Isaka
CPC分类号: C08J5/18 , B29C61/003 , B29C61/0608 , B29C63/42 , B29C63/423 , B29K2067/00 , C08J2367/02 , Y10T428/1328 , Y10T428/26 , Y10T428/269
摘要: In a thermo-shrinkable polyester film, the thermal shrinkage ratio in a main shrinking direction is about 20% or more after being treated in water of about 70.degree. C. for about seconds, about 35 to about 55% after treated in water of about 75.degree. C. for about 5 seconds, and about 50 to about 60% after being treated in water of about 80.degree. C. for about 5 seconds. After the film is shrunk by about 5% by treatment in water of about 75.degree. C. for about 10 seconds, the probability of the elongation at rupture of the film in the direction perpendicular to the main shrinking direction being about 20% or less, is about 10% or less. The ratio of .tau..sub.1 /.tau..sub.2 is about 0.05 to about 0.45, where .tau..sub.2 is the stress of shrinkage in a main shrinking direction of the film at about 90.degree. C., and .tau..sub.1 is the stress of shrinkage in a direction perpendicular to the main shrinking direction of the film at about 90.degree. C. The sealing strength of the film is about 1.2 kg/15 mm of width or more.
摘要翻译: 在热收缩性聚酯膜中,在约70℃的水中处理约秒之后,主要收缩方向的热收缩率为约20%或更多,约35至约55%在约 在约80℃的水中处理约5秒钟,约75℃至约5秒,约50至约60%。 通过在约75℃的水中处理约5%的膜约10秒后,膜在垂直于主收缩方向的方向上的断裂伸长的概率为约20%以下, 约为10%以下。 tau 1 / tau 2的比例为约0.05至约0.45,其中τ2是在约90℃的膜的主收缩方向上的收缩应力,τ1是在垂直方向上的收缩应力 到约90℃的膜的主收缩方向。膜的密封强度为约1.2kg / 15mm的宽度或更大。
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公开(公告)号:US06663929B1
公开(公告)日:2003-12-16
申请号:US09216095
申请日:1998-12-18
申请人: Norimi Tabota , Tsutomu Oko , Teruo Kurosawa , Kuniharu Mori , Katsuhiko Nose , Hiroshi Shibano
发明人: Norimi Tabota , Tsutomu Oko , Teruo Kurosawa , Kuniharu Mori , Katsuhiko Nose , Hiroshi Shibano
IPC分类号: B65D2308
CPC分类号: B29B17/02 , B29B17/0036 , B29B2017/0234 , B29B2017/0244 , B29B2017/0289 , B29B2017/0296 , B29K2067/00 , B29K2105/065 , B29L2031/7158 , B29L2031/744 , B65D23/08 , G09F3/04 , Y02W30/524 , Y02W30/62 , Y02W30/622 , Y02W30/807 , Y10T428/1352 , Y10T428/24901 , Y10T428/2813 , Y10T428/31786
摘要: A label having a thermoplastic polymer film and an ink layer formed on at least one surface thereof, the ink layer being removable in alkaline hot water, can easily be recycled after separated or without being separated from the bottle into polymer pellets with improved purity. The recycled polymer pellets are extremely suitable for the effective use of resources because they contain substantially no ink and can therefore find various applications.
摘要翻译: 具有热塑性聚合物膜的标签和在其至少一个表面上形成的油墨层,油墨层可在碱性热水中除去,可以容易地在分离或不与瓶分离成循环,成为具有改进的纯度的聚合物颗粒。 回收的聚合物颗粒非常适合于有效利用资源,因为它们基本上不含油墨,因此可以发现各种应用。
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公开(公告)号:US06447925B1
公开(公告)日:2002-09-10
申请号:US09678384
申请日:2000-10-03
IPC分类号: B32B2736
CPC分类号: C08J5/18 , B29D7/01 , B29K2067/00 , B29K2995/0049 , C08J2367/02 , Y10S428/91 , Y10T428/1328 , Y10T428/31786
摘要: A heat-shrinkable polyester film having a shrinkability in hot water (hereinafter referred to as a hot-water shrinkability) at 95° C. for 10 seconds ranging from 30% to 50% in at least one direction (hereinafter referred to as direction (A)) and ranging from 25% to 45% in a direction (hereinafter referred to as direction (B)) perpendicular to said at least one direction, wherein a difference &Dgr;HS between the hot-water shrinkability in direction (A) and the hot-water shrinkability in direction (B) (ie., &Dgr;HS=|hot-water shrinkability in direction (A)—hot-water shrinkability in direction (B)|) is 10% or smaller, is useful as a wrapping material, mainly as a covering material for the openings of vessels used for packing noodles, puddings, salads, and other foods.
摘要翻译: 在95℃下在至少一个方向上在30%至50%范围内(以下称为方向(以下称为方向性(以下称为热收缩性) (A)),并且在垂直于所述至少一个方向的方向(以下称为方向(B))为25%至45%,其中方向(A)的热水收缩率与热 方向(B)(即DELTAHS = |方向(A) - 热收缩方向(B)|的热水收缩率)方向(B)的水收缩率为10%以下,主要用作包装材料 作为用于包装面条,布丁,沙拉和其他食品的容器开口的覆盖材料。
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公开(公告)号:US20050196563A1
公开(公告)日:2005-09-08
申请号:US11035074
申请日:2005-01-14
CPC分类号: C08J5/18 , C08J2367/02 , Y10T428/13
摘要: A heat shrinkable polyester film of the present invention has a transverse tear defect percentage of about 20% or less as determined in the following vibration test: the film is rolled into a tubular shape, two of its opposite edges bonded together, and then the tubular film is placed around a vertical stack (total weight: 660 g) of three food container cans each having a diameter of 72 mm and a height of 55 mm; the can stack with the tubular film placed therearound is passed through a shrink tunnel to shrink the tubular film onto the can stack; a total of 18 packs of such can stacks are placed into a cardboard box having a length of 455 mm, a width of 230 mm and a height of 165 mm (6 packs in the length direction by 3 packs in the width direction), and the cardboard box is sealed; the cardboard box is vibrated along the width direction for 30 min by a stroke of 50 mm and at a vibration rate of 180 reciprocations/min, after which the transverse tearage of the tubular film is visually observed; and the transverse tear defect percentage (%) is determined based on the number of defective packs per 18 packs, wherein the defective pack is any pack having a tear flaw of 30 mm or longer along a can periphery. The heat shrinkable polyester film of the present invention has a good shock resistance during shipping especially under low temperatures, with a good finish after shrinkage and a sufficient solvent adhesiveness. Thus, the heat shrinkable polyester film of the present invention is suitable for use in a multi-packaging label for packaging, inter alia, a stack of cans.
摘要翻译: 本发明的热收缩聚酯薄膜在以下振动试验中确定的横向撕裂缺陷率为约20%以下:将薄膜卷成管状,将其两个相对的边缘粘合在一起,然后将管状 将薄膜放置在直径为72mm,高度为55mm的三个食物容器罐的垂直叠层(总重量:660g)周围; 将放置在其周围的管状膜的堆叠通过收缩通道将管状膜收缩到罐叠上; 将总共18个这样的罐堆叠放置在长度为455mm,宽度为230mm,高度为165mm的纸板箱(沿长度方向6个宽度方向上包装3个包装)的纸板箱中,以及 纸箱被密封; 纸板箱沿宽度方向振动30分钟,行程为50毫米,振动速度为180次/分钟,此后目视观察到管状薄膜的横向撕裂; 横向撕裂缺陷百分比(%)是根据每18包的缺陷包的数量确定的,其中,有缺陷的包装是沿罐周边具有30mm或更长的撕裂缺陷的任何包装。 本发明的热收缩性聚酯膜在运输时具有良好的抗冲击性,特别是在低温下,收缩后的良好的涂饰和充分的溶剂粘附性。 因此,本发明的热收缩聚酯薄膜特别适合用于多包装标签中,尤其是包装一叠罐。
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公开(公告)号:US06451445B1
公开(公告)日:2002-09-17
申请号:US09574881
申请日:2000-05-19
申请人: Hideki Ito , Norimi Tabota , Tsutomu Oko
发明人: Hideki Ito , Norimi Tabota , Tsutomu Oko
IPC分类号: B32B2706
CPC分类号: C08J5/18 , B29C55/143 , B29C61/003 , B29C63/423 , B29D7/01 , B29K2067/00 , B29K2995/0049 , B65C3/065 , C08J2367/02 , Y10T428/31786
摘要: The present invention provides a heat shrinkable polyester film whose hot water shrinkage along its main shrinkage direction is equal to or greater than 20% when the film is put in hot water of 70° C. for 5 sec; 35% to 55% when put in hot water of 75° C. for 5 sec; and 50% to 60% when put in hot water of 80° C. for 5 sec, wherein the compressive strength of the label formed by the film satisfies a following expression (1): Y>X2.2 (1) where y denotes compressive strength (mN) and x denotes film thickness (&mgr;m).
摘要翻译: 本发明提供一种热收缩聚酯薄膜,当将薄膜置于70℃的热水中5秒时,其主收缩方向的热水收缩率等于或大于20% 在75℃的热水中放置35%至55%5秒钟; 在80℃的热水中放置5〜60%,其中由膜形成的标签的抗压强度满足下式(1):其中y表示抗压强度(mN),x表示 膜厚(母)。
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公开(公告)号:USRE40274E1
公开(公告)日:2008-04-29
申请号:US10943255
申请日:2004-09-17
申请人: Hideki Ito , Norimi Tabota , Tsutomu Oko
发明人: Hideki Ito , Norimi Tabota , Tsutomu Oko
CPC分类号: C08J5/18 , B29C55/143 , B29C61/003 , B29C63/423 , B29D7/01 , B29K2067/00 , B29K2995/0049 , B65C3/065 , C08J2367/02 , Y10T428/31786
摘要: The present invention provides a heat shrinkable polyester film whose hot water shrinkage along its main shrinkage direction is equal to or greater than 20% when the film is put in hot water of 70° C. for 5 sec; 35% to 55% when put in hot water of 75° C. for 5 sec; and 50% to 60% when put in hot water of 80° C. for 5 sec, wherein the compressive strength of the label formed by the film satisfies a following expression (1): Y>X2.2 (1) where y denotes compressive strength (mN) and x denotes film thickness (μm).
摘要翻译: 本发明提供一种热收缩聚酯薄膜,当将薄膜置于70℃的热水中5秒时,其主收缩方向的热水收缩率等于或大于20% 在75℃的热水中放置35%至55%5秒钟; 在80℃的热水中放置5〜60%,其中,由膜形成的标签的抗压强度满足下式(1):&lt;&CenterDot;&CenterDot;&CenterDot;&CenterDot; 线公式“end =”lead“?> Y> X <2>(1)<?in-line-formula description =”In-line Formulas“end =”tail“?>其中y表示 抗压强度(mN),x表示膜厚度(mum)。
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公开(公告)号:US20060063008A1
公开(公告)日:2006-03-23
申请号:US10539478
申请日:2003-12-24
IPC分类号: B32B27/40
CPC分类号: C08J5/18 , B29C63/423 , B29K2067/00 , B29K2995/0049 , B32B27/36 , C08J7/04 , C08J7/047 , C08J2367/02 , C08J2467/00 , C08J2475/00 , Y10T428/31551 , Y10T428/31565 , Y10T428/31786
摘要: A heat-shrinkable polyester type film has a dynamic friction coefficient of at least one face with one face of another film of μd≦0.27 and range R≦0.05 and a weight loss of less than 0.24 g/m2 after 10 reciprocation times with 400 g load using a color fastness rubbing tester comprising a friction element bearing a sand paper with #1000 particle diameter.
摘要翻译: 热收缩聚酯型膜具有至少一个面的动摩擦系数,其中另一个泥浆膜的一面为<0.27,范围R <= 0.05,重量损失小于0.24g / m 2, / SUP>,使用具有#1000粒径的砂纸的摩擦元件的色牢度摩擦测试仪,使用400g负荷进行10次往复运动。
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公开(公告)号:US20060057346A1
公开(公告)日:2006-03-16
申请号:US10512412
申请日:2003-04-23
申请人: Hideki Ito , Norimi Tabota , Hiroshi Nagano
发明人: Hideki Ito , Norimi Tabota , Hiroshi Nagano
IPC分类号: B32B27/32
CPC分类号: C08J5/18 , B29C61/0608 , B29C63/423 , B29K2067/00 , B29K2995/0049 , B29L2031/723 , B29L2031/744 , C08J2367/02 , Y10T428/1328 , Y10T428/1331
摘要: A heat-shrinkable polyester film characterized in that: (A) the heat shrinkage percentages in the maximum shrinkage direction thereof is 10 to 50% in hot water at 70° C.; (B) the heat shrinkage percentages in the maximum shrinkage direction thereof is 70% or more and that in the direction orthogonal to the maximum shrinkage direction is 10% or less in hot water at 85° C.; and (C) when the heat shrinkage percentage in the maximum shrinkage direction in hot water at 95° C. is designated as X0 (%) and the heat shrinkage percentage in the maximum shrinkage direction of a film obtained by previously heat-shrinking said film to an extent of 10% in hot water at 95° C. is designated as X10 (%), the difference in heat shrinkage percentage Δ (%) calculated according to the following equation is 10 to 20%. Δ=X0−X10
摘要翻译: 一种热收缩性聚酯膜,其特征在于:(A)在70℃的热水中,其最大收缩方向的热收缩率为10〜50%。 (B)在85℃的热水中,其最大收缩方向的热收缩率为70%以上,与最大收缩方向正交的方向的热收缩率为10%以下。
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公开(公告)号:US20050236731A1
公开(公告)日:2005-10-27
申请号:US11159144
申请日:2005-06-23
申请人: Satoshi Hayakawa , Norimi Tabota , Yoshinori Takegawa , Katsuya Ito , Shigeru Komeda , Katsuhiko Nose
发明人: Satoshi Hayakawa , Norimi Tabota , Yoshinori Takegawa , Katsuya Ito , Shigeru Komeda , Katsuhiko Nose
IPC分类号: B29B7/60 , B29B7/30 , B29B7/58 , B29B11/00 , B29B13/10 , B29C47/10 , B29C55/00 , B29C55/02 , B29C61/00 , B29C61/02 , B29C61/06 , B29K67/00 , B29K105/02 , B29L7/00 , C08J5/18 , C08L67/02 , B29C47/00 , B29C47/88
CPC分类号: C08J5/18 , B29C55/00 , B29C61/003 , B29K2067/00 , C08J2367/02 , Y10S428/91 , Y10T428/1328 , Y10T428/1331 , Y10T428/24 , Y10T428/31786
摘要: A film roll of a heat-shrinkable polyester film characterized in that the heat-shrinkable polyester film meets the following requirements (1) and (2). (1) When samples are cut off therefrom at an almost equal interval along the longitudinal direction, and immersed in hot water at 85° C. for 10 seconds, subsequently in water at 25° C. and withdrawn, heat-shrinkage percentages in the maximum shrinkage direction of all the samples are 20% or more. (2) When raw polymers used for production of the film above comprises of a major constitutional unit and one or more sub constitutional units different therefrom; and the content of the primary sub constitutional unit is determined, the content of the primary sub constitutional unit in each sample is more than 7 mole % in 100% of all constitutional units, and when an average of the contents of the primary sub constitutional unit is calculated, the contents thereof of all the samples fall within a range of ±2 mole % relative to the average.
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