摘要:
A film roll of a heat-shrinkable polyester film characterized in that the heat-shrinkable polyester film meets the following requirements (1) and (2). (1) When samples are cut off therefrom at an almost equal interval along the longitudinal direction, and immersed in hot water at 85° C. for 10 seconds, subsequently in water at 25° C. and withdrawn, heat-shrinkage percentages in the maximum shrinkage direction of all the samples are 20% or more. (2) When raw polymers used for production of the film above comprises of a major constitutional unit and one or more sub constitutional units different therefrom; and the content of the primary sub constitutional unit is determined, the content of the primary sub constitutional unit in each sample is more than 7 mole % in 100% of all constitutional units, and when an average of the contents of the primary sub constitutional unit is calculated, the contents thereof of all the samples fall within a range of ±2 mole % relative to the average.
摘要:
A film roll of a heat-shrinkable polyester film characterized in that the heat-shrinkable polyester film meets the following requirements (1) and (2). (1) When samples are cut off therefrom at an almost equal interval along the longitudinal direction, and immersed in hot water at 85° C. for 10 seconds, subsequently in water at 25° C. and withdrawn, heat-shrinkage percentages in the maximum shrinkage direction of all the samples are 20% or more. (2) When raw polymers used for production of the film above comprises of a major constitutional unit and one or more sub constitutional units different therefrom; and the content of the primary sub constitutional unit is determined, the content of the primary sub constitutional unit in each sample is more than 7 mole % in 100% of all constitutional units, and when an average of the contents of the primary sub constitutional unit is calculated, the contents thereof of all the samples fall within a range of ±2 mole % relative to the average.
摘要:
A film roll of a heat-shrinkable polyester film characterized in that the heat-shrinkable polyester film meets the following requirements (1) and (2).(1) When samples are cut off therefrom at an almost equal interval along the longitudinal direction, and immersed in hot water at 85° C. for 10 seconds, subsequently in water at 25° C. and withdrawn, heat-shrinkage percentages in the maximum shrinkage direction of all the samples are 20% or more.(2) When raw polymers used for production of the film above comprises of a major constitutional unit and one or more sub constitutional units different therefrom; and the content of the primary sub constitutional unit is determined, the content of the primary sub constitutional unit in each sample is more than 7 mole % in 100% of all constitutional units, and when an average of the contents of the primary sub constitutional unit is calculated, the contents thereof of all the samples fall within a range of ±2 mole % relative to the average.
摘要:
The heat-shrinkable polyester film rolls according to the present invention is characterized in that the film rolls have (1) a heat shrinkage percentage at 85° C. in the maximum shrinkage direction of 20% or more; (2) a melt resistivity at a temperature of 275° C. of 0.70×108 Ω·cm or less; (3) when samples thereof are cut off at an interval of about 100 m and the fluctuation in thickness in the maximum shrinkage direction is measured, a thickness distribution width represented by the following formula of respective samples of 7% or less. Thickness distribution width=(Maximum thickness−Minimum thickness)/Average thickness×100 Container-wrapping films excellent in processability and printability can be produced from the heat-shrinkable polyester film rolls in high yield.
摘要:
A film roll of a heat-shrinkable polyester film meeting the following requirements: (1) when samples are cut off therefrom at an almost equal interval along the longitudinal direction, and immersed in hot water at 85° C. for 10 seconds, subsequently in water at 25° C. and withdrawn, heat-shrinkage percentages in the maximum shrinkage direction of all the samples are 20% or more; and (2) when raw polymers used for production of the film above comprises of a major constitutional unit and one or more sub constitutional units different therefrom, and the content of the primary sub constitutional unit in each sample is more than 7 mole % in 100% of all constitutional units, and the contents of the primary sub constitutional unit of all the samples fall within a range of ±2 mole % relative to the average.
摘要:
Disclosed is a heat-shrinkable polyester film having a specific composition. A heat shrinkage factor of a 10 cm square sample of the film in a maximal shrinkage direction of the film is not less than 20% under the condition that the sample is immersed in hot water of 85° C. for 10 seconds, and then in water of 25° C. for 10 seconds. The number of test pieces of the film having a rupture ratio of not more than 5% is not more than 10% to the total number of the test pieces under the condition that a tensile test of drawing the film in a direction orthogonal to the maximal shrinkage direction of the film is conducted with a distance between corresponding chucks of 100 mm, each test piece having 15 mm in width, a temperature of 23° C., and a drawing rate of 200 mm/min.
摘要:
In heat-shrinkable polyester films, the content of 1,4-cyclohexane dimethanol is 10 to 50% by mole based on the polyhydric alcohol component and that the heat shrinkage factors of a 10 cm square sample of the films in (A) hot water of 75° C., (B) hot water of 85° C., and (C) hot water of 95° C. are 30 to 40%, 50 to 60%, and 65 to 77%, respectively. The films can be produced by drawing under specified conditions.
摘要:
A film roll comprising a heat-shrinkable polystyrene based resin film wound into a roll, characterized in that, each of the samples taken out from the roll exhibits, in a heat shrinkage test under the condition of the immersion in a hot water at 85° C. for 10 sec, a heat shrinkage rate in the main shrinking direction of within ±5% relative to an average rate of the total samples; a heat-shrinkable polystyrene based resin film taken from the roll; a heat-shrinkable label comprising the film; a method for producing the heat-shrinkable polystyrene based resin film roll which comprises using raw material chips having a specific form, or using a hopper having a specific shape for feeding raw material chips to an extruder, or limiting the variation of the surface temperature of a film in a specific production step to a specific range.
摘要:
A polyamide based resin film roll is provided. The polyamide based resin film roll comprising: a first sample cutout portion within 2 m from the winding end of film; and a final cutout portion within 2 m from the winding start of film, wherein when a sample cutout portion is set up in approximately every 100 m from the first sample cutout portion, in all samples cut out from each of the cutout portions, mechanical properties such as boiling water shrinkage percentage and refraction index in the thickness direction are adjusted within a given range of variation width.
摘要:
A polyamide based resin film roll is provided. The polyamide based resin film roll comprising: a first sample cutout portion within 2 m from the winding end of film; and a final cutout portion within 2 m from the winding start of film, wherein when a sample cutout portion is set up in approximately every 100 m from the first sample cutout portion, in all samples cut out from each of the cutout portions, mechanical properties such as boiling water shrinkage percentage and refraction index in the thickness direction are adjusted within a given range of variation width.