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    Pyrazde herbicides
    2.
    发明授权
    Pyrazde herbicides 失效
    吡唑除草剂

    公开(公告)号：US06339046B1

    公开(公告)日：2002-01-15

    申请号：US08959437

    申请日：1997-10-28

    申请人： Kurt Nebel ,  Juraj Tuleja ,  Georg Pissiotas ,  Hans-Georg Brunner

    发明人： Kurt Nebel ,  Juraj Tuleja ,  Georg Pissiotas ,  Hans-Georg Brunner

    IPC分类号： A01N4356

    CPC分类号： A01N43/56 ,  C07D231/14

    摘要： Compounds of the formula I in which R1 is C1-C4alkyl; R2 is cyano or NH2C(S)—; R3 is hydrogen, C1-C4alkyl, C1-C4haloalkyl, C3- or C4alkenyl, C3- or C4alkynyl, C3-C8haloalkenyl, NC—CH2—, HOC(O)—CH2— or C1-C4alkoxy-C(O)—CH2—; W is a group  and R4 to R6, R60, R61, R70, X1, X2, n1 and A1—B1 are as defined in claim 1, and the pyrazole N-oxide, agronomically acceptable salts and stereomers of these compounds of the formula I, with the exclusion of the compound of the formula  have good selective herbicidal properties when used pre- and post-emergence. The preparation of these compounds and their use as herbicidally active ingredients are described.

    摘要翻译： R1为C1-C4烷基的式Iin化合物; R2为氰基或NH2C（S） - ; R3为氢，C1-C4烷基，C1-C4卤代烷基，C3-或C4-烯基，C3-或C4-炔基，C3-C8卤代烯基，NC-CH2 - ，HOC（O）-CH 2 - 或C 1 -C 4烷氧基-C（O）-CH 2 - ; W是基团，R 4 -R 6，R 60，R 61，R 70，X 1，X 2，n 1和A 1 -B 1如权利要求 1和吡唑N-氧化物，这些式I化合物的农学上可接受的盐和立体异构体，排除下式化合物在出苗前和出苗后使用时具有良好的选择性除草性质。 描述了这些化合物的制备及其作为除草活性成分的用途。

    Pyrazole herbicides
    3.
    发明授权
    Pyrazole herbicides 失效
    吡唑除草剂

    公开(公告)号：US5731267A

    公开(公告)日：1998-03-24

    申请号：US820758

    申请日：1997-03-19

    申请人： Georg Pissiotas ,  Kurt Nebel ,  Hans-Georg Brunner

    发明人： Georg Pissiotas ,  Kurt Nebel ,  Hans-Georg Brunner

    IPC分类号： A01N43/56 ,  C07D231/12 ,  C07D231/14 ,  C07D231/16 ,  C07D231/18 ,  C07D307/79 ,  C07D307/85 ,  C07D405/04 ,  C07D405/02

    CPC分类号： C07D405/04 ,  A01N43/56 ,  C07D231/14 ,  C07D231/16 ,  C07D231/18 ,  C07D307/79 ,  C07D307/85

    摘要： Compounds of the formula I ##STR1## in which R is hydrogen, fluorine or chlorine; R.sub.1 is hydrogen, halogen, trifluoromethyl, C.sub.1 -C.sub.4 haloalkoxy, cyano, nitro or amino; A-B is a group ##STR2## in which the 2 carbon atom is bonded to the oxygen atom; W is a group ##STR3## R.sub.2 is hydrogen or C.sub.1 -C.sub.6 -alkyl; R.sub.3 is C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 haloalkyl, cyano-C.sub.1 -C.sub.4 alkyl, hydroxy-C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkoxy-C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.6 alkenyloxy-C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.6 alkynyloxy-C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.6 alkylcarbonyloxy-C.sub.1 -C.sub.6 alkyl, carboxyl, C.sub.1 -C.sub.6 alkoxycarbonyl, C.sub.1 -C.sub.6 haloalkoxycarbonyl, C.sub.3 -C.sub.6 alkenyloxycarbonyl, C.sub.3 -C.sub.6 alkynyloxycarbonyl, C.sub.3 -C.sub.6 cycloalkoxycarbonyl, C.sub.1 -C.sub.4 alkoxy-C.sub.1 -C.sub.4 alkoxycarbonyl, C.sub.1 -C.sub.4 alkylaminocarbonyl, di-C.sub.1 -C.sub.4 alkylaminocarbonyl, aminocarbonyl, benzyloxycarbonyl, phenyloxycarbonyl, C.sub.1 -C.sub.4 alkyl-SO.sub.2 NHC(O)--, C.sub.1 -C.sub.6 alkyl -ON.dbd.CH--, C.sub.1 -C.sub.6 alkoxycarbonyl-C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.3 alkylcarbonyl, ClC(O)--, NH.sub.2 C(S)--, OHC-- or cyano;R.sub.4 is hydrogen, fluorine, chlorine or bromine; R.sub.5 is carboxyl, C.sub.1 -C.sub.6 alkoxycarbonyl, NH.sub.2 C(O)--, NH.sub.2 C(S)--, HON.dbd.CH--, OHC-- or cyano; R.sub.6 is hydrogen or C.sub.1 -C.sub.4 alkyl; n is 0, 1 or 2, with the proviso that n is 0 if R.sub.6 is hydrogen; and R.sub.7 is hydrogen or C.sub.1 -C.sub.4 alkyl, and agronomically acceptable salts and stereoisomers of these compounds are suitable as herbicides.

    摘要翻译： 式I的化合物（I）其中R是氢，氟或氯; R1是氢，卤素，三氟甲基，C1-C4卤代烷氧基，氰基，硝基或氨基; A-B是其中2个碳原子键合到氧原子上的组 （W1）或（IMA）（W2）R2是氢或C1-C6-烷基; R 3是C 1 -C 6烷基，C 1 -C 6卤代烷基，氰基-C 1 -C 4烷基，羟基-C 1 -C 6烷基，C 1 -C 6烷氧基-C 1 -C 6烷基，C 3 -C 6烯氧基-C 1 -C 4烷基，C 3 -C 6炔氧基-C 1 -C 4烷基， C 1 -C 4烷基羰基氧基-C 1 -C 6烷基，羧基，C 1 -C 6烷氧基羰基，C 1 -C 6卤代烷氧基羰基，C 3 -C 6烯氧基羰基，C 3 -C 6炔氧基羰基，C 3 -C 6环烷氧基羰基，C 1 -C 4烷氧基-C 1 -C 4烷氧基羰基，C 1 -C 4烷基氨基羰基，二-C 1 -C 4烷基氨基羰基，氨基羰基，苄氧基羰基， 苯氧基羰基，C 1 -C 4烷基-SO 2 NHC（O） - ，C 1 -C 6烷基-ON = CH-，C 1 -C 6烷氧基羰基-C 1 -C 4烷基，C 1 -C 3烷基羰基，ClC（O） - ，NH 2 C（S） - ，OHC-或氰基; R4是氢，氟，氯或溴; R5是羧基，C1-C6烷氧基羰基，NH2C（O） - ，NH2C（S） - ，HON = CH-，OHC-或氰基; R6是氢或C1-C4烷基; n为0,1或2，条件是如果R6为氢，n为0; 并且R 7是氢或C 1 -C 4烷基，并且这些化合物的农学上可接受的盐和立体异构体适合作为除草剂。

    Novel herbicidally active n-phenyl-azoles
    5.
    发明授权
    Novel herbicidally active n-phenyl-azoles 失效
    新型除草活性的n-苯基 - 唑类

    公开(公告)号：US5049181A

    公开(公告)日：1991-09-17

    申请号：US440007

    申请日：1989-11-21

    申请人： Georg Pissiotas ,  Hans Moser ,  Hans-Georg Brunner

    发明人： Georg Pissiotas ,  Hans Moser ,  Hans-Georg Brunner

    IPC分类号： A01N43/90 ,  C07D231/12 ,  C07D231/22 ,  C07D231/56 ,  C07D401/12 ,  C07D403/12 ,  C07D405/12 ,  C07D409/12 ,  C07D417/12 ,  C07D471/04 ,  C07D487/04 ,  C07D521/00

    CPC分类号： C07D249/08 ,  C07D231/12 ,  C07D231/56 ,  C07D233/56 ,  C07D401/12 ,  C07D403/12 ,  C07D405/12 ,  C07D409/12 ,  C07D417/12 ,  C07D471/04 ,  C07D487/04

    摘要： The invention relates to novel phenyl substituted pyrazoles, 4,5,6,7-tetrahydro-indazoles, 2,4,5,6-tetrahydro-cyclopenta[c]pyrazoles, octahydroimidazo[1,5-a]pyridin-1,3-diones, hexahydro-1H-pyrrolo[1,2-c]-imidazol-1,3-diones, hexahydro-1H-1,2,4-triazolo[1,2-a]pyridazin-1,3-diones and tetrahydro-1H,5H-pyrazolo[1,2-a][1,2,4]triazol-1,3-diones which have phenyl-substituted in the 2-position, herbicidal activity. It furthermore relates to agrochemical compositions, which contain these compounds, to their use for controlling undesirable plant-growth and for processes for the preparation of the compounds according to this invention.The novel N-Phenyl-azoles correspond to the formula I ##STR1## R.sup.1 is hydrogen or halogen; R.sup.2 is halogen;A is a straight-chain or branched C.sub.1 -C.sub.4 -alkylene chain;n is zero or 1;Q is --S(O).sub.m --R.sup.3 ; di-C.sub.1 -C.sub.4 -alkylamino; a 5- or 6-membered heterocyclus, that is bound via a carbon or nitrogen atom and which contains 1 to 3 hetero-atoms selected from the group consisting of N, O and S, which heterocycles can be fused to a benzene ring and mono- or disubstituted by halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.3 -haloalkyl, C.sub.1 -C.sub.3 -alkoxy, C.sub.1 -C.sub.3 -haloalkoxy, C.sub.1 -C.sub.3 -dialkylamino, hydroxy or carboxyl;R.sup.3 is C.sub.1 -C.sub.10 -alkyl; ##STR2## m is zero, 1 or 2; R.sup.4 is C.sub.1 -C.sub.4 -alkyl, halogen or C.sub.1 -C.sub.4 -alkoxy;p is zero 1, 2, or 3;X is hydrogen, halogen or C.sub.1 -C.sub.4 -alkyl;Y is C.sub.1 -C.sub.4 -alkyl; orX and Y form together a --(CH.sub.2).sub.q -chain, which is optionally mono- or disubstituted by methyl;q is three or four; andZ is halogen, methyl, C.sub.1 -C.sub.6 -alkoxy or C.sub.1 -C.sub.6 -alkylthio; under inclusion of the salts of these azoles with acids, bases and complex-building substances.

    摘要翻译： 本发明涉及新的苯基取代的吡唑，4,5,6,7-四氢 - 吲唑，2,4,5,6-四氢 - 环戊二烯并[c]吡唑，八氢咪唑并[1,5-a]吡啶-1,3 六氢-1H-吡咯并[1,2-c] - 咪唑-1,3-二酮，六氢-1H-1,2,4-三唑并[1,2-a]哒嗪-1,3-二酮和 四氢-1H，5H-吡唑并[1,2-a] [1,2,4]三唑-1,3-二酮，其具有2位的苯基取代，除草活性。 此外，它还涉及含有这些化合物的农药组合物，其用于控制​​不期望的植物生长和根据本发明的化合物的制备方法。 新型N-苯基 - 吡咯对应于式I（I）其中R1是氢或卤素; R2是卤素; A是直链或支链的C 1 -C 4 - 亚烷基链; n为零或1; Q是-S（O）m -R 3; 二-C 1 -C 4烷基氨基; 通过碳或氮原子结合并含有1至3个选自N，O和S的杂原子的5-或6-元杂环，该杂环可以与苯环稠合并且单 或被卤素，C 1 -C 4 - 烷基，C 1 -C 3 - 卤代烷基，C 1 -C 3 - 烷氧基，C 1 -C 3 - 卤代烷氧基，C 1 -C 3 - 二烷基氨基，羟基或羧基二取代; R3是C1-C10-烷基; m是零，1或2; R4是C1-C4-烷基，卤素或C1-C4-烷氧基; p为零1,2或3; X是氢，卤素或C 1 -C 4 - 烷基; Y是C 1 -C 4 - 烷基; 或X和Y一起形成 - （CH 2）q链，其任选被甲基单或二取代; q是三四个; Z为卤素，甲基，C 1 -C 6 - 烷氧基或C 1 -C 6 - 烷硫基; 在这些唑类的盐类与酸，碱和复合物构成物质之间。

    Herbicidally active thiadiazabicyclononanes and nonenes
    6.
    发明授权
    Herbicidally active thiadiazabicyclononanes and nonenes 失效

    公开(公告)号：US5180418A

    公开(公告)日：1993-01-19

    申请号：US732988

    申请日：1991-07-19

    申请人： Georg Pissiotas ,  Hans Moser ,  Hans-Georg Brunner ,  Eginhard Steiner

    发明人： Georg Pissiotas ,  Hans Moser ,  Hans-Georg Brunner ,  Eginhard Steiner

    IPC分类号： A01N37/32 ,  A01N37/38 ,  A01N43/38 ,  A01N43/40 ,  A01N43/824 ,  A01N43/90 ,  A01N53/00 ,  C07C323/35 ,  C07C323/40 ,  C07C331/28 ,  C07D207/40 ,  C07D207/404 ,  C07D207/408 ,  C07D207/44 ,  C07D207/452 ,  C07D209/48 ,  C07D211/88 ,  C07D265/24 ,  C07D265/26 ,  C07D471/04 ,  C07D487/04 ,  C07D513/04 ,  C07F7/08

    CPC分类号： C07D207/408 ,  A01N37/38 ,  A01N43/90 ,  A01N53/00 ,  C07C323/35 ,  C07C323/40 ,  C07C331/28 ,  C07D207/452 ,  C07D209/48 ,  C07D211/88 ,  C07D265/26 ,  C07D471/04 ,  C07D487/04 ,  C07D513/04 ,  C07F7/0812

    摘要： Cycloalkanecarboxylic acid derivatives of formula I ##STR1## wherein W is ##STR2## and A is CO--R.sub.3 or CN; R.sub.1 is hydrogen or fluorine; R.sub.2 is halogen or cyano; R.sub.3 is chlorine, X--R.sub.5, amino, C.sub.1 -C.sub.4 alkylamino, d-C.sub.1 -C.sub.4 alkylamino, C.sub.2 -C.sub.4 haloalkylamino, di-C.sub.2 -C.sub.4 haloalkylamino, C.sub.1 -C.sub.4 hydroxyalkylamino, di-C.sub.1 -C.sub.4 hydroxyalkylamino, C.sub.3 -C.sub.4 alkenylamino, diallylamino, --N-pyrrolidino, --N-piperidino, --N-morpholino, --N-thiomorpholino, --N-piperidazino, the group --O--N.dbd.C--(R.sub.9)R.sub.10 or the group --N--R.sub.6 (OR.sub.6); each of R.sub.4 and R.sub.14, independently of the other, is hydrogen, fluorine, chlorine, bromine, C.sub.1 -C.sub.4 alkyl or trifluoromethyl; R.sub.5 is hydrogen, C.sub.1 -C.sub.10 alkyl, C.sub.1 -C.sub.4 alkoxy-C.sub.1 -C.sub.4 alkyl, halo-C.sub.1 -C.sub.8 alkyl, C.sub.1 -C.sub.10 alkylthio-C.sub.1 -C.sub.4 alkyl, di-C.sub.1 -C.sub.4 alkylamino-C.sub.1 -C.sub.4 alkyl, cyano-C.sub.1 -C.sub.8 alkyl, C.sub.3 -C.sub.8 alkenyl, halo-C.sub.3 -C.sub. 8 alkenyl, C.sub.3 -C.sub.8 alkynyl, C.sub.3 -C.sub.7 cycloalkyl, C.sub.3 -C.sub.7 cycloalkyl-C.sub.1 -C.sub.4 alkyl or halo-C.sub.3 -C.sub.7 cycloalkyl, or benzyl which is unsubstituted or substituted at the phenyl ring by up to three identical or different substituents selected from halogen, C.sub.1 -C.sub.4 alkyl, halo-C.sub.1 -C.sub.4 alkyl, halo-C.sub.1 -C.sub.4 alkoxy or C.sub.1 -C.sub.4 alkoxy, or is an alkali metal ion, an alkaline earth metal ion or an ammonium ion, the group --[CHR.sub.6 --(CH.sub.2).sub.m ]--COOR.sub.7, or the group [CHR.sub.6 --(CH.sub.2).sub.t --Si(R.sub.8).sub.3 ]; R.sub.6 is hydrogen or C.sub.1 -C.sub.4 alkyl; R.sub.7 is hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.8 alkenyl, C.sub.3 -C.sub.8 alkynyl, C.sub.1 -C.sub.8 alkoxy-C.sub.2 -C.sub.8 alkyl, C.sub.1 -C.sub.8 alkylthio-C.sub.2 -C.sub.8 alkyl or C.sub.3 -C.sub.7 cycloalkyl; R.sub.8 is C.sub.1 - C.sub.4 alkyl; R.sub.9 is C.sub.1 -C.sub.4 alkyl; R.sub.10 is C.sub.1 -C.sub.4 alkyl or phenyl; or R.sub.9 and R.sub.10, together with the carbon atom to which they are bonded, form a cyclohexane ring; R.sub.11 is C.sub.1 -C.sub.8 alkyl; R.sub.12 is hydrogen or C.sub.1 -C.sub.8 alkyl; R.sub.13 is hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.7 cycloalkyl, C.sub.1 -C.sub.4 alkoxy-C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkylthio-C.sub.1 -C.sub.4 alkyl, halo-C.sub.1 -C.sub.7 alkyl, C.sub.3 -C.sub.7 alkenyl or C.sub.3 -C.sub.7 alkynyl; X, Y, Y.sub.1, Y.sub.2, Y.sub.3, Y.sub.4, Z.sub.1 and Z.sub.2 are each independently oxygen or sulfur; n is 0, 1, 2, 3 or 4; m is 0, 1, 2, 3 or 4; q is 1 or 2; and t is 0, 1, 2, 3 or 4, have good pre- and post-emergence selective herbicidal and growth regulating properties.

    Herbicidal thiadiazabicyclooctanes
    7.
    发明授权
    Herbicidal thiadiazabicyclooctanes 失效
    除草剂噻二唑二环辛烷

    公开(公告)号：US5416065A

    公开(公告)日：1995-05-16

    申请号：US154243

    申请日：1993-11-18

    申请人： Hans-Georg Brunner ,  Hans Moser ,  Georg Pissiotas

    发明人： Hans-Georg Brunner ,  Hans Moser ,  Georg Pissiotas

    IPC分类号： C07D513/04 ,  A01N43/90

    CPC分类号： C07D513/04

    摘要： Thiadiazabicyclooctanes of formula I ##STR1## wherein Z is oxygen or sulfur;R.sub.53 is hydrogen or C.sub.1 -C.sub.6 alkyl;R.sub.54 is C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkoxy, C.sub.3 -C.sub.6 alkenyloxy, C3-C6alkynyioxy, hydroxy or C.sub.1 -C.sub.6 haloalkoxy; orR.sub.53 and R.sub.54, together with the carbon atom to which they are bonded, form an unsubstituted 3-, 4-, 5- or 6-membered saturated ring;W is a group of formulae W.sub.1 to W.sub.10 ##STR2##

    摘要翻译： 式I的噻二唑二环辛烷其中Z是氧或硫; R53是氢或C1-C6烷基; R 54是C 1 -C 6烷基，C 1 -C 6烷氧基，C 3 -C 6烯氧基，C 3 -C 6炔氧基，羟基或C 1 -C 6卤代烷氧基; 或R 53和R 54与它们所键合的碳原子一起形成未取代的3-，4-，5-或6-元饱和环; （W1）（W2）（W3）（W4）（W5）（W6）（W7 ）（W8）（W9）或（W10）