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公开(公告)号：US06794477B2
公开(公告)日：2004-09-21
申请号：US10217372
申请日：2002-08-13
IPC分类号： C08G7720
CPC分类号： B32B17/10761 , C08F8/42 , Y10T428/2995 , Y10T428/31612 , Y10T428/31663 , C08F18/08
摘要： Silane-modified polyvinyl acetals are obtained by copolymerizing a) vinyl esters of C1-15 alkylcarboxylic acids having from 1 to 15 carbon atoms, and optionally (meth)acrylates C1-15 of alcohols, olefins, dienes, vinylaromatics, or vinyl halides, with b) from 0.02 to 20.0 % by weight of an ethylenically unsaturated, hydrolyzable silicon compounds or hydrolyzable mercaptosilanes; hydrolyzing the resulting vinyl ester copolymers to 50 mol % or more of vinyl alcohol units; and acetalizing vinyl alcohol units with a C1-15 aliphatic or aromatic aldehydes, wherein from 5 to 50 % by weight of a mixture of comonomers a) and silane comonomers b), based on the total weight of comonomers a) and b), is used as an initial charge, and the remainder is metered in during polymerization, such that the ratio between the comonomers a) and silane comonomers b) remains constant throughout the polymerization, resulting in a homogeneous polymer.
摘要翻译： 硅烷改性的聚乙烯醇缩醛通过以下方法获得：a）将具有1至15个碳原子的C1-15烷基羧酸的乙烯基酯和任选的醇，烯烃，二烯，乙烯基芳族化合物或乙烯基卤化物的（甲基）丙烯酸酯C1-15与 b）0.02至20.0重量％的烯属不饱和的可水解的硅化合物或可水解的巯基硅烷; 将得到的乙烯基酯共聚物水解成50摩尔％以上的乙烯醇单元; 和用C1-15脂族或芳族醛缩醛化乙烯醇单元，其中基于共聚单体a）和b）的总重量，5至50重量％的共聚单体a）和硅烷共聚单体b）的混合物是 用作初始电荷，其余部分在聚合期间计量，使得共聚单体a）和硅烷共聚单体b）之间的比例在整个聚合过程中保持恒定，从而产生均匀的聚合物。
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公开(公告)号：US06756442B2
公开(公告)日：2004-06-29
申请号：US10217558
申请日：2002-08-13
申请人： Kurt Stark , Thomas Kornek , Bernhard Glaser , Karl-Heinz Eichel
发明人： Kurt Stark , Thomas Kornek , Bernhard Glaser , Karl-Heinz Eichel
IPC分类号： C08F828
CPC分类号： B32B17/10761 , C08F8/42 , C08F16/06
摘要： The invention relates to silane-modified polyvinyl acetals obtained by acetalizing partially hydrolyzed or fully hydrolyzed vinyl ester polymers having at least 50 mol % of vinyl alcohol units with one or more aldehydes, optionally in the form of their hemiacetals or their acetals, where at least one aldehyde contains hydrolyzable silane groups.
摘要翻译： 本发明涉及通过将部分水解或完全水解的具有至少50mol％乙烯醇单元与一种或多种醛的乙烯基酯聚合物任选以其半缩醛形式或其缩醛形式缩醛得到的硅烷改性聚乙烯醇缩醛，其中至少 一个醛含有可水解的硅烷基团。
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公开(公告)号：US20050171280A1
公开(公告)日：2005-08-04
申请号：US10513691
申请日：2003-09-04
CPC分类号： C08F8/28 , Y10T428/31833 , C08F8/48 , C08F16/06
摘要： The invention relates to a method for producing polyvinylacetals that can be obtained by saponifying a vinylester polymer and subsequently acetalizing the polyvinyl alcohol, which is obtained therewith, with one or more aldehydes selected from the group consisting of aliphatic and aromatic aldehydes having 1 to 15 C atoms, whereby: a) the polyvinyl alcohol is present in an aqueous medium; b) a pH value of
摘要翻译： 本发明涉及一种生产聚乙烯醇缩乙醛的方法，该方法可以通过将乙烯基酯聚合物皂化并随后用其中一种或多种醛选自具有1至15个碳原子的脂族和芳族醛， 原子，其中：a）聚乙烯醇存在于水介质中; b）pH值<1的任选地通过加入酸来设定; c）通过加入醛成分引发缩醛化， d）通过过滤将沉淀的聚乙烯醇缩乙醛与滤液分离。 本发明的方法的特征在于，10至100重量％的水性介质由先前制备的滤液组成，并且在d）中产生的滤液任选地再次用于另一种制剂。
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公开(公告)号：US07351765B2
公开(公告)日：2008-04-01
申请号：US10513691
申请日：2003-09-04
IPC分类号： C08F8/00
CPC分类号： C08F8/28 , Y10T428/31833 , C08F8/48 , C08F16/06
摘要： Polyvinyl acetals are obtained in a cost-effective and environmentally advantageous manner by employing as at least a portion of the aqueous acetalization medium, the mother liquor from a previous acetalization reaction.
摘要翻译： 通过采用至少一部分水性缩醛化介质，来自先前的缩醛化反应的母液，以成本有效和环境有利的方式获得聚乙烯醇缩醛。
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公开(公告)号：US06870009B2
公开(公告)日：2005-03-22
申请号：US10218135
申请日：2002-08-13
申请人： Kurt Stark , Bernhard Glaser , Werner Bauer , Peter Tschirner
发明人： Kurt Stark , Bernhard Glaser , Werner Bauer , Peter Tschirner
IPC分类号： C09D5/02 , C08F8/12 , C08F8/28 , C08F16/38 , C08F18/04 , C09D5/03 , C09D11/10 , C09D129/14 , C08K5/07
CPC分类号： C08F8/28 , C08F8/48 , C08F216/06 , C08F218/08
摘要： Low molecular weight polyvinyl acetals have a solution viscosity of from 2 to 12 mPas and a degree of polymerization Pw less than 200, and are obtained by hydrolyzing a vinyl ester polymer having a solution viscosity of from 1.0 to 1.6 mPas until the content of vinyl alcohol units is ≧50 mol %, to produce a polyvinyl alcohol whose solution viscosity is from 1.0 to 2.0 mPas, and then acetalizing the resultant polyvinyl alcohol. The products may be used as binders and films of increased adhesion to substrates.
摘要翻译： 低分子量聚乙烯醇缩醛的溶液粘度为2〜12mPa·s，聚合度Pw小于200，通过将溶液粘度为1.0〜1.6mPa·s的乙烯基酯系聚合物水解，直至乙烯醇含量 单位为> 50摩尔％，得到溶液粘度为1.0〜2.0mPa·s的聚乙烯醇，然后使所得聚乙烯醇缩醛化。 该产品可以用作粘合剂和增加对基材的粘附性的膜。
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公开(公告)号：US07776962B2
公开(公告)日：2010-08-17
申请号：US11719040
申请日：2005-11-03
申请人： Kurt Stark
发明人： Kurt Stark
IPC分类号： C08F8/00
CPC分类号： C09D129/14 , C08F8/48 , C08F8/28 , C08F16/06
摘要： Low shear-thinning polyvinyl acetals having a solution viscosity in 30% strength by weight solution in methyl ethyl ketone which changes by not more than 10% in a shear rate range from 1 to 100 s−1. The preparation of the low shear-thinning polyvinyl acetals involves acetalation of partly hydrolyzed or completely hydrolyzed vinyl ester polymers comprising ≧50 mol % of vinyl alcohol units with one or more aldehydes, optionally in the form of the hydrates, hemiacetals or full acetals, wherein from 0 to 60% by weight of the aldehyde, based on the total amount of the aldehyde, is initially introduced over the course of the first one to ten minutes of the acetalation and is prereacted over the course of from 1 to 30 minutes, and the remaining proportion is then metered in continuously over the course of at least 20 minutes.
摘要翻译： 低剪切稀化的聚乙烯醇缩醛，其溶液粘度在甲基乙基酮中的30重量％强度重量溶液中，在1至100s -1的剪切速率范围内变化不超过10％。 低剪切稀化聚乙烯醇缩醛的制备涉及部分水解或完全水解的乙烯基酯聚合物的缩醛化，其包含≥50mol％乙烯醇单元与一种或多种醛，任选呈水合物，半缩醛或全缩醛的形式，其中 基于醛的总量，醛的0至60重量％最初在缩醛的第一个1至10分钟的过程中引入，并且在1至30分钟的时间内预反应，并且 然后在至少20分钟的时间内连续计量剩余的比例。
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公开(公告)号：US20080161500A1
公开(公告)日：2008-07-03
申请号：US11914686
申请日：2006-05-11
申请人： Kurt Stark , Christian Ochs
发明人： Kurt Stark , Christian Ochs
IPC分类号： C08F8/42
CPC分类号： C08K5/5419 , C08F2/38 , C08L83/06
摘要： A process for preparing silicone-containing polymers comprises free-radical polymerization of one or more ethylenically unsaturated organic monomers in the presence of copper-free free-radical initiator and one or more polymerization regulators, wherein a polymerization regulator is a silicone which contains at least one aldehyde group.
摘要翻译： 制备含硅聚合物的方法包括在无铜自由基引发剂和一种或多种聚合调节剂存在下，一种或多种烯属不饱和有机单体的自由基聚合，其中聚合调节剂是至少含有 一个醛基。
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8.发明授权公开(公告)号：US07288592B2
公开(公告)日：2007-10-30
申请号：US10507241
申请日：2003-04-03
申请人： Kurt Stark , Robert Singer
发明人： Kurt Stark , Robert Singer
IPC分类号： C08F30/08
CPC分类号： C09D183/10 , C08F283/12 , C08F218/02
摘要： Organosilicone and vinyl ester copolymers free from phase separation are prepared by copolymerizing at least one vinyl ester monomer with organosilicones containing difunctional silicone monomers and optionally a minor amount of monofunctional silicone monomers, in a non-aqueous solvent mixture containing at least one solvent with a transfer coefficient greater than 20·10−4 relative to vinyl acetate.
摘要翻译： 通过在至少一种含有至少一种溶剂的非水溶剂混合物中将至少一种乙烯基酯单体与含有双官能硅酮单体和任选的少量单官能有机硅单体的有机硅共聚合来制备无相分离的有机硅氧烷和乙烯基酯共聚物 系数相对于乙酸乙烯酯为大于20.10±0.4。
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公开(公告)号：US20070179245A1
公开(公告)日：2007-08-02
申请号：US10598650
申请日：2005-03-03
申请人： Kurt Stark , Christian Hogl
发明人： Kurt Stark , Christian Hogl
IPC分类号： C08F230/08
CPC分类号： C08F283/12
摘要： Polymer dispersions of polymers derived from silicone macromers and ethylenically unsaturated monomers are capable of incorporating large amounts of chemically bonded macromer, when the silicone macromer and part of the unsaturated monomer are polymerized in aqueous medium as an initial charge with an oil soluble initiator, and the remaining monomers are fed in and polymerized using a water soluble initiator. The dispersions may be dried to form water redispersible polymer powders.
摘要翻译： 衍生自硅氧烷大分子单体和烯属不饱和单体的聚合物的聚合物分散体能够掺入大量的化学键合的大分子单体，当硅氧烷大分子单体和部分不饱和单体在含水介质中作为起始电荷与油溶性引发剂聚合时， 剩余的单体进料并使用水溶性引发剂进行聚合。 可以将分散体干燥以形成水可再分散的聚合物粉末。
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10.发明授权Thermoplastic silicone block copolymers, the production thereof and the use of the same 失效热塑性硅酮嵌段共聚物，其生产方法及其用途公开(公告)号：US06824881B2
公开(公告)日：2004-11-30
申请号：US10451594
申请日：2003-06-23
申请人： Hans Lautenschlager , Jochen Dauth , Wolfgang Keller , Theo Mayer , Kurt Stark
发明人： Hans Lautenschlager , Jochen Dauth , Wolfgang Keller , Theo Mayer , Kurt Stark
IPC分类号： B32B2732
CPC分类号： C08G77/52 , C08G77/38 , C08G77/442 , C09D183/10 , Y10T428/31663 , Y10T428/31855
摘要： Thermoplastic silicon block copolymers containing (A) a hard segment polymer constituent prepared from styrene, methylmethacrylate, butylacrylate, acrylonitrile, vinyl monomers, or mixtures therefore, and (B) a soft segment polymer constituent of general formula (I) G-[(SiR2O)mSiR2—X—]n(SiR2O)mSiR2-G wherein R is an optionally halogenated monovalent C1-18 hydrocarbon radical and X is a specific aryl group-containing, silicon bonded radical, and each G may be a radical (A)-Z-(Si) or Z′-(Si) wherein -Z- represents an aryl group-containing bivalent radical and Z′- represents a monovalent aryl group-containing radical, provided that there is, at most, one radical G and one radical Z′- in formula (I). In formula (I), m represents a whole number between 1 and 1000 and n represents 0 or a whole number between 1 and 20, provided that when n does not equal 0, 4≦n·m≦1000.
摘要翻译： 含有（A）由苯乙烯，甲基丙烯酸甲酯，丙烯酸丁酯，丙烯腈，乙烯基单体或其混合物制备的硬链段聚合物组分的热塑性硅嵌段共聚物，和（B）通式（I）的软链段聚合物组分G - [（SiR 2 O ）mSiR 2 -X-n（SiR 2 O）m SiR 2 -G其中R是任选卤代的一价C 1-18烃基，X是特定的含芳基的硅键合基团，并且每个G可以是基团（A） - Z-（Si）或Z' - （Si）其中-Z-表示含芳基的二价基团，Z'表示含单价芳基的基团，条件是至多存在一个基团G和一个 式（I）中的基团Z'-。 在式（I）中，m表示1与1000之间的整数，n表示0或1至20之间的整数，条件是当n不等于0时，4 <= n.m <= 1000。
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