Silane-modified polyvinyl acetals
    2.
    发明授权
    Silane-modified polyvinyl acetals 失效
    硅烷改性的聚乙烯醇缩醛

    公开(公告)号:US06794477B2

    公开(公告)日:2004-09-21

    申请号:US10217372

    申请日:2002-08-13

    IPC分类号: C08G7720

    摘要: Silane-modified polyvinyl acetals are obtained by copolymerizing a) vinyl esters of C1-15 alkylcarboxylic acids having from 1 to 15 carbon atoms, and optionally (meth)acrylates C1-15 of alcohols, olefins, dienes, vinylaromatics, or vinyl halides, with b) from 0.02 to 20.0 % by weight of an ethylenically unsaturated, hydrolyzable silicon compounds or hydrolyzable mercaptosilanes; hydrolyzing the resulting vinyl ester copolymers to 50 mol % or more of vinyl alcohol units; and acetalizing vinyl alcohol units with a C1-15 aliphatic or aromatic aldehydes, wherein from 5 to 50 % by weight of a mixture of comonomers a) and silane comonomers b), based on the total weight of comonomers a) and b), is used as an initial charge, and the remainder is metered in during polymerization, such that the ratio between the comonomers a) and silane comonomers b) remains constant throughout the polymerization, resulting in a homogeneous polymer.

    摘要翻译: 硅烷改性的聚乙烯醇缩醛通过以下方法获得:a)将具有1至15个碳原子的C1-15烷基羧酸的乙烯基酯和任选的醇,烯烃,二烯,乙烯基芳族化合物或乙烯基卤化物的(甲基)丙烯酸酯C1-15与 b)0.02至20.0重量%的烯属不饱和的可水解的硅化合物或可水解的巯基硅烷; 将得到的乙烯基酯共聚物水解成50摩尔%以上的乙烯醇单元; 和用C1-15脂族或芳族醛缩醛化乙烯醇单元,其中基于共聚单体a)和b)的总重量,5至50重量%的共聚单体a)和硅烷共聚单体b)的混合物是 用作初始电荷,其余部分在聚合期间计量,使得共聚单体a)和硅烷共聚单体b)之间的比例在整个聚合过程中保持恒定,从而产生均匀的聚合物。

    Low cross-linking-density gel and process for producing the same
    4.
    发明授权
    Low cross-linking-density gel and process for producing the same 失效
    低交联密度凝胶及其制备方法

    公开(公告)号:US06797797B2

    公开(公告)日:2004-09-28

    申请号:US09367483

    申请日:1999-10-18

    IPC分类号: C08G7720

    摘要: A process for producing a low cross-linking-density gel capable of effectively inhibiting light scattering in joining the ends of optical fiber cores with each other. The process is characterized by involving the compounding step for adjusting a flexible silicone gal material to have a specified refractive index and the reaction step for cross-linking the flexible silicone gel material obtained in the above step in a binding region with a low cross-linking density, thus yielding a low cross-linking-density gel.

    摘要翻译: 一种生产低交联密度凝胶的方法,其能够有效地抑制将光纤芯的端部彼此接合的光散射。 该方法的特征在于包括用于调节柔性硅氧烷gal材料以具有特定折射率的配混步骤和将上述步骤中获得的柔性硅凝胶材料交联到具有低交联度的结合区域中的反应步骤 密度,从而产生低交联密度凝胶。

    Photocurable siloxane polymers
    7.
    发明授权
    Photocurable siloxane polymers 有权
    光固化硅氧烷聚合物

    公开(公告)号:US06399734B1

    公开(公告)日:2002-06-04

    申请号:US09416773

    申请日:1999-10-13

    IPC分类号: C08G7720

    摘要: The present invention relates to photocurable siloxane polymers having functional acryl groups, useful in the preparation of intraocular lenses (IOLs). The polymers are siloxane copolymers, wherein the siloxane can be selected from the group consisting of diphenyl siloxane, phenylalkyl siloxane, dialkyl siloxane, and trifluoroalkyl alkyl siloxane. The invention also relates to methods for producing the said siloxane polymers, as well as to producing accommodating lenses in vivo, which means that the tens is formed in the capsular bag of the eye.

    摘要翻译: 本发明涉及可用于制备眼内透镜(IOL)的具有功能性丙烯酰基的光固化硅氧烷聚合物。 聚合物是硅氧烷共聚物,其中硅氧烷可以选自二苯基硅氧烷,苯基烷基硅氧烷,二烷基硅氧烷和三氟烷基烷基硅氧烷。 本发明还涉及制备所述硅氧烷聚合物的方法,以及在体内生产容纳透镜,这意味着在眼囊的囊袋中形成十位。

    Hardenable mass with silane dendrimers
    8.
    发明授权
    Hardenable mass with silane dendrimers 有权
    具有硅烷树枝状大分子的可硬化质量

    公开(公告)号:US06335413B1

    公开(公告)日:2002-01-01

    申请号:US09485069

    申请日:2000-02-03

    IPC分类号: C08G7720

    摘要: The invention relates to curable materials containing (A) optionally organopolysiloxanes with at least two unsaturated groups in the molecule, (B) organohydrogenpolysiloxanes with at least 3 SiH groups in molecule, (C) optionally organopolysiloxanes without reactive groups (D) catalyst (E) optionally hydrophilizing agents, (F) fillers and (G) optionally conventional dental additives, adjuvants and colorants, and (H) at least one silane dendrimer with terminal alkenyl groups The materials are particularly suitable for dental materials and are characterized by a particularly good end hardness with excellent processing viscosity.

    摘要翻译: 本发明涉及含有(A)分子中具有至少两个不饱和基团的(A)任选的有机聚硅氧烷的可固化材料,(B)分子中具有至少3个SiH基团的有机氢聚硅氧烷,(C)任选地没有反应性基团的有机聚硅氧烷(D)催化剂(E) 任选的亲水剂,(F)填料和(G)任选的常规牙科添加剂,助剂和着色剂,和(H)至少一个具有末端烯基的硅烷树枝状聚合物。该材料特别适用于牙科材料,其特征在于特别好的终端硬度 具有优良的加工粘度。

    Acrylic functional organopolysiloxanes and radiation-curable compositions
    9.
    发明授权
    Acrylic functional organopolysiloxanes and radiation-curable compositions 失效
    丙烯酸官能有机聚硅氧烷和可辐射固化组合物

    公开(公告)号:US06239246B1

    公开(公告)日:2001-05-29

    申请号:US09361186

    申请日:1999-07-27

    IPC分类号: C08G7720

    摘要: A novel acrylic functional organopolysiloxane is obtained by effecting addition reaction between (A) an organopolysiloxane having acrylic functional groups and (B) an organopolysiloxane having a hydride group at either end to induce partial crosslinking. The acrylic functional organopolysiloxane forms a cured film ensuring light release and good retention of adhesion.

    摘要翻译: 通过实现(A)具有丙烯酸官能团的有机聚硅氧烷和(B)在任一端具有氢化物基团的有机聚硅氧烷以引起部分交联的加成反应,得到新的丙烯酸官能的有机聚硅氧烷。 丙烯酸官能的有机聚硅氧烷形成固化膜,确保光的释放和良好的粘合保持性。