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公开(公告)号:US20220407063A1
公开(公告)日:2022-12-22
申请号:US17779244
申请日:2021-03-22
Applicant: LG Chem, Ltd.
Inventor: Hyun Uk Kim , Eung Ju Lee , Woo Hyun Kim , Sang Soon Choi , Jun Gil Kim , Gyeong Il Yoo
Abstract: A positive electrode active material precursor, a method of preparing the same, and a positive electrode active material, a positive electrode, and a lithium secondary battery prepared from the same. In some embodiments, a positive electrode active material precursor includes nickel, cobalt, and manganese, wherein the positive electrode active material precursor satisfies: Equation 1 (2.5≤C(100)/C(001)≤5.0) and Equation 2 (1.0≤C(101)/C(001)≤3.0), where C(001) is a crystalline size in a (001) plane, C(100) is a crystalline size in a (100) plane, and C(101) is a crystalline size in a (101) plane. The positive electrode active material precursor has particle growth of a (001) plane that is suppressed.
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公开(公告)号:US20220102731A1
公开(公告)日:2022-03-31
申请号:US17422583
申请日:2020-01-16
Applicant: LG Chem, Ltd.
Inventor: Min Kyu You , Kyung Lok Lee , Ji A Shin , Sang Soon Choi
IPC: H01M4/66 , H01M10/0525 , H01M4/04 , H01M4/02
Abstract: A lithium secondary battery is disclosed herein. In some embodiments, a lithium secondary battery includes: a battery case having an interior region, a separator, wherein the separator divides the interior region into a first region and a second region, a positive electrode formed in the first region and including a positive electrode active material and positive electrode current collector particles; and a negative electrode formed in the second region and including a negative electrode active material and negative electrode current collector particles.
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公开(公告)号:US10700352B2
公开(公告)日:2020-06-30
申请号:US16070049
申请日:2017-03-03
Applicant: LG Chem, Ltd.
Inventor: Myung Gi Jeong , Sang Won Woo , Seung Beom Cho , Sang Soon Choi
Abstract: The present disclosure relates to a precursor of a positive electrode active material for a secondary battery including a single layer-structured secondary particle in which pillar-shaped primary particles radially oriented in a surface direction from the particle center are aggregated, wherein the secondary particle has a shell shape, and the primary particle includes a composite metal hydroxide of Ni—Co—Mn of the following Chemical Formula 1, and a positive electrode active material prepared using the same: Ni1−(x+y+z)CoxMyMnz(OH)2 [Chemical Formula 1] In Chemical Formula 1, M, x, y and z have the same definitions as in the specification.
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公开(公告)号:US12080886B2
公开(公告)日:2024-09-03
申请号:US17050919
申请日:2019-05-07
Applicant: LG Chem, Ltd.
Inventor: Won Sig Jung , Sang Soon Choi , Hyun Ah Park
CPC classification number: H01M4/525 , B08B3/08 , C01G53/50 , H01M4/366 , H01M4/505 , H01M10/0525 , C01P2004/80 , C01P2006/40 , H01M2004/028
Abstract: A method of washing a positive electrode active material includes (1) preparing a lithium composite transition metal oxide which contains Ni, Co and Mn, and has the Ni content of 60 mol % or more; (2) putting the lithium composite transition metal oxide into water; and (3) adding a weak acid to water to which the lithium composite transition metal oxide is added to adjust the pH to 7 to 10, wherein the acid is a weak acid.
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公开(公告)号:US20230307629A1
公开(公告)日:2023-09-28
申请号:US18018616
申请日:2021-08-06
Applicant: LG Chem, Ltd.
Inventor: Na Ri Kim , Young Su Park , Woo Hyun Kim , Sang Soon Choi , Hwa Seok Chae , Hyun Uk Kim , Dong Jin Kim , Dong Ryoung Kang
CPC classification number: H01M4/525 , H01M4/505 , H01M4/485 , H01M4/0471 , H01M2004/028
Abstract: A positive electrode active material precursor and method of preparing the same are disclosed herein. In some embodiments, a positive electrode active material precursor includes a particle having a first region, a second region, and a third region, a composition of the particle is represented by the following Formula 1 or Formula 2:
[M1aM2bM3cM4d](OH)2 [Formula 1]
[M1aM2bM3cM4d]O·OH [Formula 2]
M1, M2, and M3 are different from each other and independently selected from the group consisting of Ni, Co, and Mn, M4 is at least one selected from the group consisting of B, Mg, Ca, Al, Ti, V, Cr, Fe, Zn, Ga, Y, Zr, Nb, Mo, Ta, and W, and 0-
公开(公告)号:US20210234164A1
公开(公告)日:2021-07-29
申请号:US17050919
申请日:2019-05-07
Applicant: LG Chem, Ltd.
Inventor: Won Sig Jung , Sang Soon Choi , Hyun Ah Park
Abstract: A method of washing a positive electrode active material includes (1) preparing a lithium composite transition metal oxide which contains Ni, Co and Mn, and has the Ni content of 60 mol % or more; (2) putting the lithium composite transition metal oxide into water; and (3) adding a weak acid to water to which the lithium composite transition metal oxide is added to adjust the pH to 7 to 10, wherein the acid is a weak acid.
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公开(公告)号:US20210036317A1
公开(公告)日:2021-02-04
申请号:US16628111
申请日:2018-07-13
Applicant: LG Chem, Ltd.
Inventor: Sang Soon Choi , Seung Beom Cho , Hyun Ah Park , Won Sig Jung
IPC: H01M4/525 , H01M4/505 , H01M10/0525 , C01G53/00
Abstract: A method of preparing a positive electrode active material which includes forming a pre-sintered mixture by adding a reaction mixture including a lithium raw material and a nickel-manganese-cobalt precursor to a first crucible and performing a primary heat treatment at a temperature of 500° C. to 800° C., and, after discharging the pre-sintered mixture from the first crucible, adding the pre-sintered mixture to a second crucible and performing a secondary heat treatment at a temperature of 700° C. to 1,000° C. to form a lithium nickel manganese cobalt-based positive electrode active material, wherein a volume of the pre-sintered mixture formed after the primary heat treatment is 20% to 50% of a volume of the reaction mixture added to the first crucible.
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公开(公告)号:US20190214628A1
公开(公告)日:2019-07-11
申请号:US16333378
申请日:2018-02-06
Applicant: LG Chem, Ltd.
Inventor: Sang Soon Choi , Hyun Ah Park , Won Sig Jung
IPC: H01M4/04 , H01M10/0525 , H01M4/505 , H01M4/525 , C01G53/00
CPC classification number: H01M4/0471 , C01G53/00 , C01P2006/40 , H01M4/505 , H01M4/525 , H01M10/0525 , H01M2004/028
Abstract: A method of preparing a positive electrode active material precursor for a lithium secondary battery by using a batch-type reactor, which includes the steps of 1) forming positive electrode active material precursor particles while continuously adding a transition metal-containing solution including a transition metal cation, an aqueous alkaline solution, and an ammonium ion-containing solution to a batch-type reactor, 2) sedimenting the positive electrode active material precursor particles formed; 3) discharging a supernatant formed after the sedimentation of the positive electrode active material precursor particles to an outside; 4) adjusting a pH to 10 to 12 by adding the ammonium ion-containing solution; and 5) growing the positive electrode active material precursor particles while continuously again adding the transition metal-containing solution to the batch-type reactor, and a method of preparing a positive electrode active material using the same.
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公开(公告)号:US12126019B2
公开(公告)日:2024-10-22
申请号:US17799752
申请日:2021-06-14
Applicant: LG Chem, Ltd.
Inventor: Ick Soon Kwak , Chang Wan Chae , Sang Soon Choi , Hwa Seok Chae
CPC classification number: H01M4/525 , C01G53/50 , H01M4/0471 , H01M4/505 , C01P2002/52 , C01P2004/84 , C01P2006/40 , H01M2004/028
Abstract: A method of preparing a positive electrode active material is disclosed herein. In some embodiments, the method includes firing a first mixture at 400° C. to 700° C. to prepare a primary firing product, wherein the first mixture has a positive electrode active material precursor having a specific composition, a first lithium-containing source material, and optionally, an aluminum-containing source material, and firing a second mixture at a temperature above the firing temperature of the first mixture to prepare a positive electrode active material, wherein the second mixture has the primary firing product, a second lithium-containing source material, and a specific doping element M1-containing source material. The method is capable of degrading the cake strength of a primary firing product and providing a positive electrode active material having excellent quality by dividing a firing process into two steps.
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公开(公告)号:US20230339772A1
公开(公告)日:2023-10-26
申请号:US18005274
申请日:2021-07-26
Applicant: LG Chem, Ltd.
Inventor: Na Ri Kim , Young Su Park , Woo Ram Lee , Sang Soon Choi , Hyun Ah Park , Hyun Uk Kim , Woo Hyun Kim , Hwan Young Choi
IPC: C01G53/04
CPC classification number: C01G53/04 , C01P2006/40 , C01P2004/61 , C01P2006/12 , C01P2006/11
Abstract: A positive electrode active material precursor includes: a first region formed in the center of a particle of the positive electrode active material precursor and having a composition represented by Chemical Formula 1 or 2; and a second region formed on the first region and having a composition represented by Chemical Formula 3 or 4. A method of preparing the positive electrode active material precursor is also provided.
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