Method for preparing modified conjugate diene polymer

    公开(公告)号:US10730968B2

    公开(公告)日:2020-08-04

    申请号:US15741596

    申请日:2016-12-16

    申请人: LG Chem, Ltd.

    摘要: The present invention relates to a method of preparing a modified conjugated diene-based polymer, and more particularly, to a method of preparing a modified conjugated diene-based polymer, including: (S1) preparing an active polymer with an organic metal bonded thereto by polymerizing a conjugated diene-based monomer in a hydrocarbon solvent in the presence of an organometallic compound; and (S2) mixing the active polymer prepared according to process S1 with a modifier, wherein the mixing of process S2 is performed at a Reynolds number of 20 or less for 1 minute or more, the Reynolds number being maintained within a range of ±5 of a Reynolds number when the modifier is added (wherein the range is between greater than 0 to 20 or less).

    Method For Preparing Modified Polymerization Initiator And Apparatus For Preparing Modified Polymerization Initiator

    公开(公告)号:US20190083949A1

    公开(公告)日:2019-03-21

    申请号:US16079345

    申请日:2017-11-30

    申请人: LG Chem, Ltd.

    IPC分类号: B01J14/00 B01J19/00 C08F2/38

    摘要: The present invention relates to a method for producing a modified polymerization initiator, and more particularly, to a method for preparing a modified polymerization initiator, wherein the method includes the steps of: (S1) introducing a first fluid and a second fluid into a reactor, and reacting the compounds included in the fluids, and (S2) obtaining the modified polymerization initiator prepared by the reaction of the step (S1) through an outlet of the reactor, wherein the step (S1) and step (S2) are continuously performed, wherein in the step (S1), the flow amount of the first fluid and the second fluid is maintained constant at the time when the first fluid and the second fluid are mixed, and the flow rate of the first fluid is increased. Also, the present invention provides an apparatus for producing a modified polymerization initiator for performing the same.

    Method For Preparing Modification Initiator And Apparatus For Preparing The Same

    公开(公告)号:US20220213239A1

    公开(公告)日:2022-07-07

    申请号:US17441433

    申请日:2020-10-12

    申请人: LG Chem, Ltd.

    摘要: The present invention relates to a method for preparing a modification initiator, the method capable of reducing side reactions to the minimum and obtaining the modification initiator with a high conversion rate, and an apparatus for performing the same, wherein the method includes (S1) reacting a first fluid including a modification functional group-containing compound and a conjugated diene-based monomer and a second fluid including a polymerization initiation functional group-containing compound, and (S2) obtaining a third fluid including a modification initiator prepared by the reaction of Step S1, wherein the modification functional group-containing compound is used in a ratio of greater than 1 mole based on 1 mole of the polymerization initiation functional group-containing compound, the conjugated diene-based monomer is used in a ratio of 1 mole to 4 moles based on 1 mole of the modification functional group-containing compound, and Step S1 and Step S2 are continuously performed.