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1.发明授权
公开(公告)号：US4981887A
公开(公告)日：1991-01-01
申请号：US457409
申请日：1989-12-28
申请人： Philip J. Ruhoff , Rodney W. Stockstad , James A. Prevost , Larry B. Brandenburger , Robert B. Edenborg
发明人： Philip J. Ruhoff , Rodney W. Stockstad , James A. Prevost , Larry B. Brandenburger , Robert B. Edenborg
IPC分类号： C09D5/44 , C09D167/08
CPC分类号： C09D167/08 , C09D5/4423 , Y10S524/901
摘要： To improve chip resistance of an alkyd-type electro-depositable coating composition, there may be added to the composition an ethylenically unsaturated, addition-polymerizable monomer or oligomer having a substantially linear backbone, having a molecular weight of at least about 150, and being reactive with fatty acid unsaturation of the alkyd.
摘要翻译： 为了提高醇酸型可电沉积涂料组合物的耐芯片电阻，可以向组合物中加入具有至少约150的分子量的具有基本线性主链的烯属不饱和的可加成聚合的单体或低聚物， 与醇酸的脂肪酸不饱和度反应。
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公开(公告)号：US5082922A
公开(公告)日：1992-01-21
申请号：US256614
申请日：1988-10-12
CPC分类号： C09D4/00 , C08F2/02 , C08F8/00 , C09D161/20
摘要： A method is provided for producing a modified addition polymer from an ethylenically unsaturated monomer composition that includes at least one monomer having hydroxyl or carboxyl functionality. The ethylenically unsaturated monomer composition, and a free radical initiator therefor, is dissolved in a solvent-free molten composition maintained at an addition polymerization temperature, the molten composition comprising a cyclic compound reactive via ring-opening with the hydroxyl or carboxyl functionality. The resulting material is useful in the manufacture of paints in liquid or powder form.
摘要翻译： 提供了一种从包含至少一种具有羟基或羧基官能团的单体的烯属不饱和单体组合物制备改性加成聚合物的方法。 将烯属不饱和单体组合物及其自由基引发剂溶解在保持加成聚合温度的无溶剂的熔融组合物中，熔融组合物包含通过开环与羟基或羧基官能团反应的环状化合物。 所得材料可用于制造液体或粉末形式的油漆。
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3.发明授权Modified alkyd cationic electrodeposition compositions for producing chip-resistant films 失效用于生产耐芯片膜的改性醇酸阳离子电沉积组合物
公开(公告)号：US4914139A
公开(公告)日：1990-04-03
申请号：US234471
申请日：1988-08-19
申请人： Philip J. Ruhoff , Rodney W. Stockstad , James A. Prevost , Larry B. Brandenburger , Robert B. Edenborg
发明人： Philip J. Ruhoff , Rodney W. Stockstad , James A. Prevost , Larry B. Brandenburger , Robert B. Edenborg
CPC分类号： C09D5/4423 , C08G63/46 , Y10T428/31696 , Y10T428/31699
摘要： An alkyd-type electrodepositable coating composition derived from the reaction of a base alkyd with ethylenically unsaturated monomers including an amine-functional monomer is provided with improved resistance to chipping by chemically incorporating in it by covalent bonding one or more chemical agents selected from the group of:(a) preformed elastomers having functional groups reactive with carboxyl or hydroxyl groups of acid and polyol alkyl precursors, and(b) an addition polymerizable monomer having primary and secondary ethylenic unsaturation.
摘要翻译： 由碱性醇酸树脂与包含胺官能单体的烯属不饱和单体的反应得到的醇酸型可电沉积涂料组合物通过化学结合在一起而具有改进的耐碎裂性，通过共价键合一种或多种选自以下的化学试剂： （a）具有与酸和多元醇烷基前体的羧基或羟基反应的官能团的预成型弹性体，和（b）具有伯和仲烯属不饱和键的加成聚合单体。
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公开(公告)号：US4511692A
公开(公告)日：1985-04-16
申请号：US559385
申请日：1983-12-08
CPC分类号： C09D5/4423 , C08G63/48 , C09D167/08 , Y10S524/901
摘要： A cationic electrodeposition composition comprising the reaction product of one or more base alkyds, containing unsaturation of the fatty acid chains to provide oxidative curing and one or more ethylenically unsaturated monomers, and one or more amine functional monomers, which are added to the base alkyd and polymerized. This composition provides a vehicle which is hydrolytically stable. Paints are prepared by the addition of conventional driers, pigments and solvents to the vehicle composition.
摘要翻译： 一种阳离子电沉积组合物，其包含一种或多种碱性醇酸树脂的反应产物，其含有脂肪酸链的不饱和键以提供氧化固化和一种或多种烯属不饱和单体，以及一种或多种胺官能单体，其加入到碱性醇酸树脂和 聚合。 该组合物提供水解稳定的载体。 通过向车辆组合物中加入常规的干燥剂，颜料和溶剂来制备油漆。
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公开(公告)号：US20120329972A1
公开(公告)日：2012-12-27
申请号：US13605366
申请日：2012-09-06
IPC分类号： C08F220/26
CPC分类号： C08G63/47 , C08F290/061 , C08G63/48 , C08G63/912 , C08G63/916 , C09D151/08 , C09D167/07 , C08F220/02
摘要： Resins derived significantly from renewable or recyclable starting materials may be formed from the reaction product of a monomer blend that includes an ethylenically unsaturated macromonomer and at least one other ethylenically unsaturated monomer, which may be acid functional. The ethylenically unsaturated macromonomer may be derived from the reaction of an acid functional intermediate, which may be the acidolysis reaction product of an engineered polyester and an acid or anhydride functional material with an hydroxyl-functional, amine-functional, or epoxy functional reactant, optionally in the presence of a polyacid, to yield a resin intermediate, which may subsequently be reacted with an ethylenically unsaturated coupling agent to yield the macromonomer. The resins described herein are useful in generating low VOC acrylic alkyd coatings. Methods of producing water reducible resins are also described.
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公开(公告)号：US20120329971A1
公开(公告)日：2012-12-27
申请号：US13605319
申请日：2012-09-06
IPC分类号： C08F20/18
CPC分类号： C08G63/47 , C08F290/061 , C08G63/48 , C08G63/912 , C08G63/916 , C09D151/08 , C09D167/07 , C08F220/02
摘要： Resins derived significantly from renewable or recyclable starting materials may be formed from the reaction product of a monomer blend that includes an ethylenically unsaturated macromonomer and at least one other ethylenically unsaturated monomer, which may be acid functional. The ethylenically unsaturated macromonomer may be derived from the reaction of an acid functional intermediate, which may be the acidolysis reaction product of an engineered polyester and an acid or anhydride functional material with an hydroxyl-functional, amine-functional, or epoxy functional reactant, optionally in the presence of a polyacid, to yield a resin intermediate, which may subsequently be reacted with an ethylenically unsaturated coupling agent to yield the macromonomer. The resins described herein are useful in generating low VOC acrylic alkyd coatings. Methods of producing water reducible resins are also described.
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公开(公告)号：US20120322952A1
公开(公告)日：2012-12-20
申请号：US13605406
申请日：2012-09-06
IPC分类号： C08G63/91
CPC分类号： C08G63/47 , C08F290/061 , C08G63/48 , C08G63/912 , C08G63/916 , C09D151/08 , C09D167/07 , C08F220/02
摘要： Resins derived significantly from renewable or recyclable starting materials may be formed from the reaction product of a monomer blend that includes an ethylenically unsaturated macromonomer and at least one other ethylenically unsaturated monomer, which may be acid functional. The ethylenically unsaturated macromonomer may be derived from the reaction of an acid functional intermediate, which may be the acidolysis reaction product of an engineered polyester and an acid or anhydride functional material with an hydroxyl-functional, amine-functional, or epoxy functional reactant, optionally in the presence of a polyacid, to yield a resin intermediate, which may subsequently be reacted with an ethylenically unsaturated coupling agent to yield the macromonomer. The resins described herein are useful in generating low VOC acrylic alkyd coatings. Methods of producing water reducible resins are also described.
摘要翻译： 从可再生或可再循环起始材料中显着衍生的树脂可以由包含烯属不饱和大分子单体和至少一种其它烯属不饱和单体的单体共混物的反应产物形成，其可以是酸官能的。 烯键式不饱和大分子单体可以衍生自酸官能中间体的反应，酸功能中间体可以是工程聚酯和酸或酸酐官能材料与羟基官能的胺官能或环氧官能的反应物的酸解反应产物，任选地 在多酸的存在下，产生树脂中间体，随后可与烯属不饱和偶联剂反应以产生大分子单体。 本文所述的树脂可用于产生低VOC丙烯酸醇酸涂料。 还描述了生产可水还原树脂的方法。
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公开(公告)号：US20100160586A1
公开(公告)日：2010-06-24
申请号：US12641418
申请日：2009-12-18
IPC分类号： C08F224/00 , C08F220/26 , C08F230/08
CPC分类号： C08G63/47 , C08F290/061 , C08G63/48 , C08G63/912 , C08G63/916 , C09D151/08 , C09D167/07 , C08F220/02
摘要： Resins derived significantly from renewable or recyclable starting materials may be formed from the reaction product of a monomer blend that includes an ethylenically unsaturated macromonomer and at least one other ethylenically unsaturated monomer, which may be acid functional. The ethylenically unsaturated macromonomer may be derived from the reaction of an acid functional intermediate, which may be the acidolysis reaction product of an engineered polyester and an acid or anhydride functional material with an hydroxyl-functional, amine-functional, or epoxy functional reactant, optionally in the presence of a polyacid, to yield a resin intermediate, which may subsequently be reacted with an ethylenically unsaturated coupling agent to yield the macromonomer. The resins described herein are useful in generating low VOC acrylic alkyd coatings. Methods of producing water reducible resins are also described.
摘要翻译： 从可再生或可再循环起始材料中显着衍生的树脂可以由包含烯属不饱和大分子单体和至少一种其它烯属不饱和单体的单体共混物的反应产物形成，其可以是酸官能的。 烯键式不饱和大分子单体可以衍生自酸官能中间体的反应，酸功能中间体可以是工程聚酯和酸或酸酐官能材料与羟基官能的胺官能或环氧官能的反应物的酸解反应产物，任选地 在多酸的存在下，产生树脂中间体，随后可与烯属不饱和偶联剂反应以产生大分子单体。 本文所述的树脂可用于产生低VOC丙烯酸醇酸涂料。 还描述了生产可水还原树脂的方法。
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公开(公告)号：US08637609B1
公开(公告)日：2014-01-28
申请号：US13326815
申请日：2011-12-15
申请人： Philip J. Ruhoff , Padmaja Perumal
CPC分类号： C08G18/44 , C08F283/006 , C08G18/4238 , C08G18/6659 , C08G18/7642 , C08L2201/54 , C09D143/04 , C09D175/04 , C08F2220/1825 , C08F212/08 , C08F220/14 , C08F220/36 , C08F220/06 , C08F2230/085 , C08G18/672 , C08G18/0823 , C08G18/12 , C08G18/3228 , C08L75/04
摘要： A waterborne coating composition contains a film forming binder dispersed in an aqueous carrier; wherein the binder is an admixture including (A) about 40-60% by weight of an acrylic silane polymer derived from a monomer blend including alkyl (meth)acrylate monomers and at least one silane containing alkyl (meth)acrylate monomer; and (B) about 60-40% by weight of a polyurethane/acrylic hybrid dispersion. The composition is useful for plastic and metal substrates.
摘要翻译： 水性涂料组合物含有分散在水性载体中的成膜粘合剂; 其中粘合剂是包含（A）约40-60重量％的衍生自包含（甲基）丙烯酸烷基酯单体和至少一种含（甲基）丙烯酸烷基酯（甲基）丙烯酸烷基酯单体的单体共混物的丙烯酸硅烷聚合物的混合物; 和（B）约60-40重量％的聚氨酯/丙烯酸混合分散体。 该组合物可用于塑料和金属基材。
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公开(公告)号：US20110021734A1
公开(公告)日：2011-01-27
申请号：US12835800
申请日：2010-07-14
IPC分类号： C08F251/02
CPC分类号： C08B31/00 , C08F2/22 , C08F251/00 , C08F285/00 , C08L3/04 , C09D151/02 , C08F218/08
摘要： Film forming polymers derived substantially from biorenewable polysaccharides may be formed as the emulsion polymerization products of a blend of hydrophobic polysaccharides and ethylenically unsaturated monomers. The hydrophobic polysaccharides may be prepared as the emulsion reaction product of a water soluble polysaccharide and a monomer mixture of hydrophilic ethylenically unsaturated monomers and hydrophobic ethylenically unsaturated monomer, in the presence of a water soluble chain transfer agent.
摘要翻译： 可以形成基本上由生物可再生多糖衍生的成膜聚合物作为疏水多糖和烯键式不饱和单体的共混物的乳液聚合产物。 疏水多糖可以在水溶性链转移剂的存在下制备为水溶性多糖和亲水性烯属不饱和单体和疏水性烯属不饱和单体的单体混合物的乳液反应产物。
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