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20 条记录 (耗时 0.014 秒)

    Process for the manufacture of fluorinated alkanols and esters thereof
    1.
    发明授权
    Process for the manufacture of fluorinated alkanols and esters thereof 失效
    制备氟化链烷醇及其酯的方法

    公开(公告)号：US4613681A

    公开(公告)日：1986-09-23

    申请号：US163978

    申请日：1980-06-30

    申请人： Louis Foulletier ,  Andre Lantz

    发明人： Louis Foulletier ,  Andre Lantz

    IPC分类号： C07C27/00 ,  C07C29/124 ,  C07C31/38 ,  C07C67/00 ,  C07C69/62 ,  C07C69/003 ,  C07C29/58

    CPC分类号： C07C29/124 ,  C07C67/00

    摘要： This invention relates to a process for the preparation of a fluorinated compound of the general formulaR.sub.F C.sub.2 H.sub.4 ORcomprising reacting an iodide of the general formula R.sub.F C.sub.2 H.sub.4 I with a percarboxylic acid of the general formula R.sup.1 CO.sub.3 H at a temperature and for a time sufficient to form said fluorinated compound; in said formulae R.sub.F is a straight or branched chain perfluorinated radical containing 1 to 20 C atoms, R is a hydrogen atom or --COR.sup.1, and R.sup.1 is a hydrogen atom or an aliphatic or aromatic hydrocarbon radical.

    摘要翻译： 本发明涉及制备通式为RFC2H4OR的含氟化合物的方法，包括使通式为RFC2H4I的碘化物与通式为R 1 CO 3 H的过羧酸在足以形成所述氟化化合物的温度和时间下反应; 在所述式中，RF是含有1至20个C原子的直链或支链全氟化基团，R是氢原子或-COR 1，R 1是氢原子或脂族或芳族烃基。

    Process for gaseous phase fluorination of aliphatic chlorinated or chlorofluorinated hydrocarbons
    5.
    发明授权
    Process for gaseous phase fluorination of aliphatic chlorinated or chlorofluorinated hydrocarbons 失效
    脂肪族氯化或氯氟化烃的气相氟化方法

    公开(公告)号：US4876406A

    公开(公告)日：1989-10-24

    申请号：US669404

    申请日：1984-11-08

    申请人： Louis Foulletier

    发明人： Louis Foulletier

    IPC分类号： B01J23/26 ,  B01J27/18 ,  B01J27/188 ,  B01J35/10 ,  C07B61/00 ,  C07C17/00 ,  C07C17/20 ,  C07C19/08 ,  C07C19/10 ,  C07C19/12 ,  C07C67/00

    CPC分类号： B01J27/18 ,  B01J23/26 ,  B01J35/0026 ,  B01J35/1019 ,  B01J35/1061 ,  B01J35/108 ,  C07C17/206

    摘要： This invention relates to improved catalysts for gaseous phase fluoridation of aliphatic chlorinated and chlorofluorinated hydrocarbons by hydrofluoric acid. The catalysts comprise chromium salts or oxides complexed with aluminum phosphate and are characterized by a total specific surface area greater than about 200 m.sup.2 /g, but less than about 1000 m.sup.2 /g a surface area of pores of 40 to 50 .ANG. in radius above about 5 m.sup.2 /g, but less than about 150 m.sup.2 /g, a surface area of pores greater than or equal to 250 .ANG. in radius above about 2 m.sup.2 /g. but less than about 60 m.sup.2 /g. This invention also relates to gaseous phase fluoridation processes for chlorinated or chlorofluorinated derivatives utilizing these catalysts in fluidized bed reactors.

    摘要翻译： 本发明涉及通过氢氟酸进行脂族氯化和氯氟化烃气相氟化改进的催化剂。 催化剂包括与磷酸铝络合的铬盐或氧化物，其特征在于总共比表面积大于约200m 2 / g，但小于约1000m 2 / ga的孔的表面积为40至50，半径大于约5 m 2 / g，但小于约150m 2 / g，大于或等于250的孔的表面积大约在2m 2 / g以上。 但小于约60m2 / g。 本发明还涉及在流化床反应器中利用这些催化剂的氯化或氯氟化衍生物的气相氟化方法。

    Catalysts for gaseous phase fluorination of aliphatic chlorinated and chlorofluorinated hydrocarbons
    6.
    发明授权
    Catalysts for gaseous phase fluorination of aliphatic chlorinated and chlorofluorinated hydrocarbons 失效
    用于脂族氯化和氯氟化烃气相氟化的催化剂

    公开(公告)号：US4474895A

    公开(公告)日：1984-10-02

    申请号：US324414

    申请日：1981-11-24

    申请人： Louis Foulletier

    发明人： Louis Foulletier

    IPC分类号： B01J21/18 ,  B01J23/26 ,  B01J35/10 ,  B01J37/26 ,  C07B61/00 ,  C07C17/00 ,  C07C17/20 ,  C07C19/08 ,  C07C19/10 ,  C07C19/12 ,  C07C45/63 ,  C07C67/00 ,  B01J27/12

    CPC分类号： B01J35/10 ,  B01J21/18 ,  B01J23/26 ,  C07C17/206 ,  C07C45/63 ,  B01J35/1028 ,  B01J35/1061

    摘要： This invention relates to improved catalysts for gaseous phase fluorination of aliphatic chlorinated and chlorofluorinated hydrocarbons by hydrofluoric acid. The catalysts are characterized by an active carbon support having a total specific surface area greater than about 1000 m.sup.2 /g but less than about 2000 m.sup.2 /g, a surface area of pores of 40 to 50 .ANG. in radius above about 5 m.sup.2 /g but less than about 15 m.sup.2 /g, a surface area of pores greater than or equal to 250 .ANG. in radius above about 2 m.sup.2 /g but less than about 6 m.sup.2 /g, which has been impregnated with an aqueous chromium trioxide solution and dried. This invention also relates to gaseous phase fluorination processes for chlorinated or chlorofluorinated derivatives utilizing these catalysts in fluidized bed reactors.

    摘要翻译： 本发明涉及通过氢氟酸进行脂族氯化和氯氟化烃气相氟化改进的催化剂。 催化剂的特征在于具有大于约1000m 2 / g但小于约2000m 2 / g的总比表面积的活性炭载体，半径在约5m 2 / g以上的孔的表面积为40至50，但是 小于约15m 2 / g，大于或等于250的孔的表面积大于约2m 2 / g但小于约6m 2 / g，其已用三氧化铬水溶液浸渍并干燥。 本发明还涉及在流化床反应器中利用这些催化剂的氯化或氯氟化衍生物的气相氟化方法。

    Polyfluorinated sulphonic acids and their derivatives
    8.
    发明授权
    Polyfluorinated sulphonic acids and their derivatives 失效
    多氟磺酸及其衍生物

    公开(公告)号：US4610829A

    公开(公告)日：1986-09-09

    申请号：US966508

    申请日：1978-12-04

    申请人： Jean-Pierre Lalu ,  Louis Foulletier

    发明人： Jean-Pierre Lalu ,  Louis Foulletier

    IPC分类号： C07B45/02 ,  C07C309/06 ,  C11D1/00 ,  C23F11/16 ,  C07C143/70

    CPC分类号： C07C309/06 ,  C07B45/02 ,  C11D1/004 ,  C23F11/16 ,  Y10S516/03

    摘要： New products and compositions of matter complying with the general formula:[C.sub.n F.sub.2n+1 --CH.sub.2 --.sub.b SO.sub.2 --Z].sub.d Mwherein: C.sub.n F.sub.2n+1 represents a straight or ramified branched perfluorinated chain: n represents a whole number between 1 and 20, b is a whole number between 2 and 20, preferably equal to 2 or 4, Z represents a chlorine, bromine or an oxygen atom (when Z is a chlorine or a bromine atom, M is nothing and d is equal to 1), when Z is an oxygen atom: M is a hydrogen atom in which case, d is equal to 1, M is a metal of the Groups I.sub.A, II.sub.A, I.sub.B, II.sub.B, VIII of the periodic table, the ammonium radical, the aluminum or the lead radical, and in which case d represents the valence of this metal and methods for preparing new products as illustrated by the following representative reactions.

    摘要翻译： 新产品和符合以下通式的物质组成：[CnF2n + 1-CH2-bSO2-Z] dM其中：CnF2n + 1表示直链或支链支化全氟链：n表示1〜20的整数，b表示 2〜20的整数，优选2或4，Z表示氯，溴或氧原子（当Z为氯或溴原子时，M为无，d为1），当Z为 氧原子：M是氢原子，在这种情况下，d等于1，M是元素周期表中IA，IIA，IB，IIB，VIII族的金属，铵基，铝或铅自由基 ，并且在这种情况下，d表示该金属的化合价和制备新产品的方法，如以下代表性反应所示。

    Fire extinguishing compositions containing fluorinated surfactants
    10.
    发明授权
    Fire extinguishing compositions containing fluorinated surfactants 失效
    含氟表面活性剂的灭火组合物

    公开(公告)号：US3941705A

    公开(公告)日：1976-03-02

    申请号：US559565

    申请日：1975-03-18

    申请人： Louis Foulletier ,  Rene Bertocchio

    发明人： Louis Foulletier ,  Rene Bertocchio

    IPC分类号： A62D1/02 ,  A62D1/00

    CPC分类号： A62D1/0085 ,  Y10S516/06

    摘要： A surface-active fluorinated composition characterized by the association therein of from 35% to about 60% of at least one surface-active ampholyte compound of the formula ##EQU1## wherein n is an integer between 1 and 20, a is a number between 2 and 10, R.sub.1 is an atom of hydrogen or an alkyl radical containing from 1 to 6 atoms of carbon, R.sub.2 and R.sub.3 are alkyl radicals containing from 1 to 3 atoms of carbon, at least one of which is the methyl radical and p and q are integers between 0 and 10; from about 20% to about 40% of at least one surface-active fluorinated non-ionic compound of the formulaC.sub.n F.sub.2n.sub.+1 -- (CH.sub.2).sub.a -- CO--O--(CH.sub.2 --CH.sub.2 --O).sub.m R.sub.4wherein n and a have the same meaning as above, m is an integer between 1 and 20 and R.sub.4 is an alkyl radical containing from 1 to 6 atoms of carbon; and from about 8% to about 40% of at least one amine salt compound of the formula ##EQU2## wherein X is the group CO or SO.sub.2 R.sub.1, R.sub.5 and R.sub.6 may be hydrogen atoms, alkyl radicals containing from 1 to 6 atoms of carbon, or the group ##EQU3## in which R.sub.2, R.sub.3, p and q have the values given above.

    摘要翻译： 一种表面活性氟化组合物，其特征在于其中含有35％至约60％的至少一种式R 2 C n F 2n + 1（CH 2）a-CON-（CH 2）p N +的表面活性两性电解质化合物 ---（CH2）qCOO - | R1R3其中n为1至20之间的整数，a为2至10之间的数，R1为氢原子或含有1至6个碳原子的烷基， R2和R3是含有1至3个碳原子的烷基，其中至少一个是甲基，p和q是0和10之间的整数; 约20％至约40％的至少一种式CnF2n + 1-（CH2）a-CO-O-（CH2-CH2-O）mR4的表面活性氟化非离子化合物，其中n和a具有 m为1〜20的整数，R 4为含有1〜6个碳原子的烷基; 和约8％至约40％的至少一种式R 1 C n F 2n + 1 - （CH 2）a -XO - HN - R 6 R 6的胺盐化合物，其中X为基团CO或SO 2 + L，R 1，R 5和R 6可以是氢原子，含有1至6个碳原子的烷基或基团R 2 - （CH 2）p N + - （CH 2）q -COOH - ，其中 R2，R3，p和q具有上面给出的值。