Alpha-alumina in the form of spherical non-aggregated particles having a
narrow size distribution and sizes below 2 microns and process for
preparing same
    5.
    发明授权
    Alpha-alumina in the form of spherical non-aggregated particles having a narrow size distribution and sizes below 2 microns and process for preparing same 失效
    具有窄尺寸分布和尺寸低于2微米的球形非聚集颗粒形式的α-氧化铝及其制备方法

    公开(公告)号:US4818515A

    公开(公告)日:1989-04-04

    申请号:US102295

    申请日:1987-09-25

    IPC分类号: C01F7/02 B01J21/04 C01F7/44

    摘要: Alpha-alumina consisting essentially of solid, spherical, non-aggregated particles, having a diameter from 0.06 to 2 .mu.m, a polydispersion index below 2.0, a total porosity below 0.3 cc/g, a specific surface area from 0.7 to 80 m.sup.2 /g, and an apparent density of the particles from 3.20 to 3.94 g/cm.sup.3. The alpha-alumina is prepared by a process consisting, in that an alpha-alumina precursor, having a water content from 2 to 33% by weight, at starting temperatures ranging from room temperature to 850.degree. C., and consisting essentially of solid spherical, non-aggregated particles, having a particle diameter from 0.07 to 2.3 .mu.m and a polydispersion index of .ltoreq.2.0, is subjected to a heat-treatment at temperatures ranging from 1130.degree. to 1700.degree. C., said precursor being instantaneously brought from the starting temperature to the treatment temperature, and by carrying out the treatment during times, as generally indicated in the accompanying FIG. 1 between straight lines (a) and (b), which are sufficient to convert the precursor to phase alpha, but not such as to cause breakages and/or aggregations; the resulting product being then brought again to room temperature by means of a non-instantaneous cooling of the order of at least 10 seconds.

    摘要翻译: 基本上由固体,球形,非凝集颗粒组成的α-氧化铝,其直径为0.06至2μm,多分散指数低于2.0,总孔隙率低于0.3cc / g,比表面积为0.7至80m2 / g,颗粒的表观密度为3.20〜3.94g / cm 3。 α-氧化铝通过以下方法制备:α-氧化铝前体,其水含量为2-33重量%,起始温度为室温至850℃,基本上由固体球形 ,粒径为0.07〜2.3μm,分散指数为2.0的非凝集粒子在1130〜1700℃的温度下进行热处理,所述前体即时带入 从起始温度到处理温度,并且通过在时间期间进行处理,如附图中通常所示。 在直线(a)和(b)之间的直线(1),其足以将前体转化为α相,但不会导致断裂和/或聚集; 然后通过至少10秒的次数的非瞬时冷却将所得产物再次升至室温。