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公开(公告)号：US20150087789A1
公开(公告)日：2015-03-26
申请号：US14560830
申请日：2014-12-04
Applicant: MITSUBISHI CHEMICAL CORPORATION , GENOMATICA, INC.
Inventor： Masaru UTSUNOMIYA , Yusuke IZAWA , Norikazu KONISHI , Kota TANAKA , Shinichiro MATSUZONO , Takayuki SUZUKI , Michael JAPS , Mark BURK , Warren CLARK
IPC: C08G18/42 , C08G63/183
CPC classification number: C08G18/4213 , C08G18/42 , C08G18/4238 , C08G18/664 , C08G63/16 , C08G63/183 , C12P7/18
Abstract: At the time of producing a polyester by using a dicarboxylic acid component and a biomass-resource-derived diol as raw materials, a polyester is efficiently produced with good color tone, as the raw material diol derived from biomass resources, a diol in which the content of a cyclic carbonyl compound having a carbon atom number of 5 or 6 is from 0.01 to 12 ppm by mass, is used, and by controlling the content of a cyclic carbonyl compound having a carbon atom number of 5 or 6 in the raw material diol to fall in a prescribed range, the color tone of the polyester is improved.
Abstract translation: 通过使用二羧酸成分和生物质源二醇作为原料制造聚酯时，可以有效地生产具有良好色调的聚酯作为源自生物质资源的原料二醇，其中， 使用碳原子数为5或6的环状羰基化合物的含量为0.01〜12质量ppm，通过控制原料中碳原子数为5或6的环状羰基化合物的含量 二醇落在规定范围内，聚酯的色调提高。
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公开(公告)号：US20150087038A1
公开(公告)日：2015-03-26
申请号：US14560714
申请日：2014-12-04
Applicant: MITSUBISHI CHEMICAL CORPORATION , GENOMATICA, INC.
Inventor： Masaru UTSUNOMIYA , Yusuke IZAWA , Norikazu KONISHI , Kota TANAKA , Shinichiro MATSUZONO , Takayuki SUZUKI , Michael JAPS , Mark BURK , Warren CLARK
Abstract: An object of the present invention is to provide high-quality 1,4BG capable of working out to a raw material of PBT with good color tone, by efficiently removing and refining impurities mixed when producing a biomass-derived 1,4BG on an industrial scale and the present invention relates to a production method of refined 1,4BG, where a crude 1,4BG-containing solution is obtained from refined raw material 1,4BG obtained by removing bacterial cells, salt contents and water from the fermentation culture medium, through a step of removing high-boiling-point components and/or low-boiling-point components by distillation and/or a step of converting an unsaturated compound to a hydride and the target product is obtained as a side stream in a further distillation step.
Abstract translation: 本发明的目的是提供一种能够通过在工业规模生产生物质衍生的1,4BG时有效地除去和精制混合的杂质来提供具有良好色调的PBT原料的高质量的1,4BG 本发明涉及精制的1,4BG的制造方法，其中，通过从发酵培养基中除去细菌细胞，盐含量和水，通过从精制原料1,4BG获得粗制的含1,4BG的溶液，通过 通过蒸馏除去高沸点组分和/或低沸点组分的步骤和/或将不饱和化合物转化为氢化物的步骤，并在另外的蒸馏步骤中作为副产物获得目标产物。
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公开(公告)号：US20150087034A1
公开(公告)日：2015-03-26
申请号：US14560800
申请日：2014-12-04
Applicant: MITSUBISHI CHEMICAL CORPORATION , GENOMATICA, INC.
Inventor： Masaru UTSUNOMIYA , Yusuke IZAWA , Norikazu KONISHI , Shinichiro MATSUZONO , Takayuki SUZUKI , Michael JAPS , Mark BURK , Warren CLARK
CPC classification number: C08G63/80 , C08G63/183 , C08G63/78 , C12N9/0006 , C12N9/0008 , C12N9/93 , C12P7/18 , C12Y101/01061 , C12Y102/01024 , C12Y102/04002 , C12Y602/01004 , Y02P20/52
Abstract: The present invention aims to provide a method for producing polybutylene terephthalate (PBT) with an excellent color using biomass-derived 1,4-butanediol (BG). The invention relates to a method for producing PBT comprising a step of subjecting a diol component containing raw material 1,4-BG having a nitrogen content of 0.01 to 50 ppm by mass and a dicarboxylic acid component to esterification or ester-exchange reaction, and a polycondensation reaction step for obtaining PBT from the reactant, wherein the content of gamma butyrolactone in the raw material 1,4-BG is 1 to 100 ppm by mass.
Abstract translation: 本发明的目的在于提供使用生物质衍生的1,4-丁二醇（BG）制造具有优异颜色的聚对苯二甲酸丁二醇酯（PBT）的方法。 本发明涉及一种制备PBT的方法，包括将含有0.01〜50质量ppm的氮含量的原料1,4-BG的二醇成分和二羧酸成分进行酯化或酯交换反应的工序，以及 用于从反应物中获得PBT的缩聚反应步骤，其中原料1,4-BG中的γ-丁内酯的含量为1〜100质量ppm。
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