ALKALI METAL SILICATE, ALKALI TRANSITION METAL SILICATE, AND METHOD FOR SYNTHESIZING SILICATE
    1.
    发明申请
    ALKALI METAL SILICATE, ALKALI TRANSITION METAL SILICATE, AND METHOD FOR SYNTHESIZING SILICATE 有权
    碱金属硅酸盐,碱金属过渡金属硅酸盐和合成硅酸盐的方法

    公开(公告)号:US20130059208A1

    公开(公告)日:2013-03-07

    申请号:US13595000

    申请日:2012-08-27

    IPC分类号: C01B33/32 H01M4/58 B32B5/00

    摘要: A method for synthesizing alkali metal silicate which can be easily microparticulated, a method for synthesizing, with the use of the alkali metal silicate, alkali transition metal silicate, and alkali metal silicate and alkali transition metal silicate which are synthesized by the synthesis methods are disclosed. The alkali metal silicate is synthesized by the following steps: forming a basic solution including an alkali metal salt; mixing the basic solution including the alkali metal salt with silicon particles to form a basic solution including the alkali metal silicate; and adding the basic solution including the alkali metal silicate to a poor solvent for the alkali metal silicate to precipitate the alkali metal silicate. Further, the alkali metal silicate is mixed with a microparticulated compound including a transition metal to form a mixture, and the mixture is subjected to heat treatment, whereby the alkali transition metal silicate is generated.

    摘要翻译: 公开了一种可以容易地微粒化的碱金属硅酸盐的合成方法,使用通过合成方法合成的碱金属硅酸盐,碱金属过渡金属硅酸盐,碱金属硅酸盐和碱金属过渡金属硅酸盐进行合成的方法 。 通过以下步骤合成碱金属硅酸盐:形成碱金属盐的碱溶液; 将包括碱金属盐的碱性溶液与硅颗粒混合以形成包含碱金属硅酸盐的碱性溶液; 并将碱金属硅酸盐的碱性溶液加入到碱金属硅酸盐的不良溶剂中以沉淀碱金属硅酸盐。 此外,将碱金属硅酸盐与包含过渡金属的微粒化合物混合以形成混合物,并对该混合物进行热处理,从而产生碱金属过渡金属硅酸盐。

    Alkali metal silicate, alkali transition metal silicate, and method for synthesizing silicate
    2.
    发明授权
    Alkali metal silicate, alkali transition metal silicate, and method for synthesizing silicate 有权
    碱金属硅酸盐,碱金属过渡金属硅酸盐,以及合成硅酸盐的方法

    公开(公告)号:US09472805B2

    公开(公告)日:2016-10-18

    申请号:US13595000

    申请日:2012-08-27

    IPC分类号: H01M4/58 C01B33/32

    摘要: A method for synthesizing alkali metal silicate which can be easily microparticulated, a method for synthesizing, with the use of the alkali metal silicate, alkali transition metal silicate, and alkali metal silicate and alkali transition metal silicate which are synthesized by the synthesis methods are disclosed. The alkali metal silicate is synthesized by the following steps: forming a basic solution including an alkali metal salt; mixing the basic solution including the alkali metal salt with silicon particles to form a basic solution including the alkali metal silicate; and adding the basic solution including the alkali metal silicate to a poor solvent for the alkali metal silicate to precipitate the alkali metal silicate. Further, the alkali metal silicate is mixed with a microparticulated compound including a transition metal to form a mixture, and the mixture is subjected to heat treatment, whereby the alkali transition metal silicate is generated.

    摘要翻译: 公开了一种可以容易地微粒化的碱金属硅酸盐的合成方法,使用通过合成方法合成的碱金属硅酸盐,碱金属过渡金属硅酸盐,碱金属硅酸盐和碱金属过渡金属硅酸盐进行合成的方法 。 通过以下步骤合成碱金属硅酸盐:形成碱金属盐的碱溶液; 将包括碱金属盐的碱性溶液与硅颗粒混合以形成包含碱金属硅酸盐的碱性溶液; 并将碱金属硅酸盐的碱性溶液加入到碱金属硅酸盐的不良溶剂中以沉淀碱金属硅酸盐。 此外,将碱金属硅酸盐与包含过渡金属的微粒化合物混合以形成混合物,并对该混合物进行热处理,从而产生碱金属过渡金属硅酸盐。

    Method for manufacturing positive electrode active material for energy storage device and energy storage device
    3.
    发明授权
    Method for manufacturing positive electrode active material for energy storage device and energy storage device 有权
    储能装置用正极活性物质及储能装置的制造方法

    公开(公告)号:US09490474B2

    公开(公告)日:2016-11-08

    申请号:US13248700

    申请日:2011-09-29

    摘要: An energy storage device having high capacity per weight or volume and a positive electrode active material for the energy storage device are manufactured. A surface of a main material included in the positive electrode active material for the energy storage device is coated with two-dimensional carbon. The main material included in the positive electrode active material is coated with a highly conductive material which has a structure expanding two-dimensionally and whose thickness is ignorable, whereby the amount of carbon coating can be reduced and an energy storage device having capacity close to theoretical capacity can be obtained even when a conduction auxiliary agent is not used or the amount of the conduction auxiliary agent is extremely small. Accordingly, the amount of carbon coating in a positive electrode and the volume of the conduction auxiliary agent can be reduced; consequently, the volume of the positive electrode can be reduced.

    摘要翻译: 制造具有高容量/重量或体积的储能装置和用于储能装置的正极活性物质。 包含在能量储存装置的正极活性物质中的主要材料的表面涂覆有二维碳。 包含在正极活性物质中的主要材料涂覆有具有二维膨胀并且其厚度可忽略的结构的高导电性材料,由此可以减少碳涂层的量,并且具有接近理论的容量的储能装置 即使不使用导电助剂或导电助剂的量极少,也可以获得容量。 因此,可以减少正极中的碳涂覆量和导电助剂的体积; 因此,可以减小正极的体积。

    Power storage device
    5.
    发明授权
    Power storage device 有权
    蓄电装置

    公开(公告)号:US08728653B2

    公开(公告)日:2014-05-20

    申请号:US13045667

    申请日:2011-03-11

    IPC分类号: H01M4/131

    摘要: An object is to increase the amount of ions capable of entering and leaving a positive electrode active material in an ion battery so that the capacity of the battery is increased. When a solid solution including alkali metal oxide having electrical conductivity less than or equal to 10−10 S/cm and including alkali metal with a valence of 2 or more, and alkali metal oxide having electrical conductivity greater than or equal to 1×10−6 S/cm and less than or equal to 3×10−6 S/cm is used as a positive electrode active material in an ion battery, the amount of ions capable of entering and leaving the positive electrode active material is increased, so that the capacity of the battery is increased.

    摘要翻译: 目的是增加能够在离子电池中进入和离开正极活性物质的离子的量,使得电池的容量增加。 当包含导电率小于或等于10-10S / cm的碱金属氧化物并且包含2价以上的碱金属的固溶体,以及导电率大于或等于1×10 -5的碱金属氧化物时, 作为离子电池中的正极活性物质,使用6S / cm且小于等于3×10 -6 S / cm的离子,能够进出正极活性物质的离子的量增加, 电池的容量增加。

    Power storage device
    6.
    发明授权
    Power storage device 有权
    蓄电装置

    公开(公告)号:US08597830B2

    公开(公告)日:2013-12-03

    申请号:US13113189

    申请日:2011-05-23

    IPC分类号: H01M4/13

    摘要: An object is to provide a power storage device with high discharge capacity and high energy density. The power storage device includes a positive electrode in which a positive electrode active material is formed over a positive electrode current collector; and a negative electrode which faces the positive electrode with an electrolyte interposed therebetween. The positive electrode active material includes a film-form first region which includes a compound containing lithium and nickel; and a film-form second region which includes a compound containing lithium and one or more of iron, manganese, and cobalt, but not containing nickel. The first region is covered with the second region. Since a superficial portion of the positive electrode active material does not contain nickel, nickel is not in contact with an electrolyte solution; thus, generation of a catalyst effect of nickel can be suppressed, and a high discharge potential of nickel can be utilized.

    摘要翻译: 目的是提供具有高放电容量和高能量密度的蓄电装置。 蓄电装置包括在正极集电体上形成正极活性物质的正极, 以及负极,其正极与正极之间插入电解质。 正极活性物质包括含有锂和镍的化合物的膜状第一区域; 以及膜状第二区域,其包含含有锂和一种或多种铁,锰和钴但不含镍的化合物。 第一个地区覆盖着第二个地区。 由于正极活性物质的表面部分不含镍,所以镍不与电解液接触; 因此,可以抑制镍的催化剂效果的产生,并且可以利用镍的高放电电位。

    Power storage device
    9.
    发明授权
    Power storage device 有权
    蓄电装置

    公开(公告)号:US08927148B2

    公开(公告)日:2015-01-06

    申请号:US13113602

    申请日:2011-05-23

    申请人: Takahiro Kawakami

    发明人: Takahiro Kawakami

    摘要: A power storage device including a positive electrode in which a positive electrode active material is formed over a positive electrode current collector and a negative electrode which faces the positive electrode with an electrolyte interposed therebetween is provided. The positive electrode active material includes a first region which includes a compound containing lithium and one or more of manganese, cobalt, and nickel; and a second region which covers the first region and includes a compound containing lithium and iron. Since a superficial portion of the positive electrode active material includes the second region containing iron, an energy barrier when lithium is inserted into and extracted from the surface of the positive electrode active material can be decreased.

    摘要翻译: 提供一种蓄电装置,其包括在正极集电体上形成有正极活性物质的正极和在其间具有电解质的与正极相对的负极。 正极活性物质包括含有锂和锰,钴,镍中的一种以上的化合物的第一区域, 以及第二区域,其覆盖所述第一区域并且包括含有锂和铁的化合物。 由于正极活性物质的表面部分包括含有铁的第二区域,因此可以减少锂从正极活性物质的表面插入并从其中提取时的能量势垒。

    Power storage device having olivine type positive electrode active material with oriented crystal structure
    10.
    发明授权
    Power storage device having olivine type positive electrode active material with oriented crystal structure 有权
    具有定向晶体结构的橄榄石型正极活性物质的蓄电装置

    公开(公告)号:US08808917B2

    公开(公告)日:2014-08-19

    申请号:US12871974

    申请日:2010-08-31

    IPC分类号: H01M4/136

    摘要: An object is to increase the amount of ions capable of leaving and entering an active material so as to increase capacity of a secondary battery. The present invention relates to a manufacturing method of a power storage device including a positive electrode active material formed using a composite oxide containing at least alkali metal and transition metal. The method includes the steps of: forming a base layer over a support substrate; forming a layer of lithium iron phosphate or a layer of sodium iron phosphate over the base layer; and using a layer of single crystalline lithium iron phosphate having an olivine structure or a layer of single crystalline sodium iron phosphate having an olivine structure with crystal axes oriented in a direction as the positive electrode material by converting the layer of lithium iron phosphate or the layer of sodium iron phosphate by a heat treatment.

    摘要翻译: 目的是增加能够离开和进入活性物质的离子的量,以增加二次电池的容量。 本发明涉及一种蓄电装置的制造方法,其包括使用至少含有碱金属和过渡金属的复合氧化物形成的正极活性物质。 该方法包括以下步骤:在支撑衬底上形成基底层; 在基层上形成磷酸铁锂层或磷酸铁钠层; 并且使用具有橄榄石结构的单晶磷酸铁锂层或具有以<010方向取向的晶轴的橄榄石结构的单晶磷酸铁钠层作为正极材料的层,通过将磷酸铁锂层 或通过热处理的磷酸铁钠层。