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公开(公告)号：US4997874A
公开(公告)日：1991-03-05
申请号：US169499
申请日：1988-03-17
申请人： Makoto Asano , Kiyoharu Hasegawa , Masatoshi Takagi , Akihiro Yamaguchi , Keizaburo Yamaguchi , Yoshimitsu Tanabe , Hiroyuki Akahori
发明人： Makoto Asano , Kiyoharu Hasegawa , Masatoshi Takagi , Akihiro Yamaguchi , Keizaburo Yamaguchi , Yoshimitsu Tanabe , Hiroyuki Akahori
IPC分类号： B41M5/155
CPC分类号： B41M5/155
摘要： An aqueous suspension of a multivalent-metal-modified salicylic acid resin, which is suitable for use in the production of color-developing sheets for pressure-sensitive recording paper sheets, contains a specific multivalent-metal-modified salicylic acid resin at the first-mentioned resin. Fine particles of the specific multivalent-metal-modified salicylic acid is dispersed in an aqueous solution of a dispersant composed of at least one compound selected from the group consisting of:(a) water-soluble anionic high-molecular compounds composed of polyvinyl alcohol derivatives containing sulfonic acid groups in their molecules, and salts thereof,(b) acrylamide-modified polyvinyl alcohols, and(c) water-soluble anionic high-molecular compounds composed of polymers or copolymers comprising particular styrenesulfonic acid derivatives as their essential components.The aqueous dispersion is prepared by finely grinding the specific multivalent-metal-modified salicylic acid in the aqueous solution of the dispersant.
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2.发明授权
公开(公告)号：US5260403A
公开(公告)日：1993-11-09
申请号：US906887
申请日：1992-07-02
CPC分类号： B41M5/155 , Y10S428/913 , Y10S428/914 , Y10T428/256 , Y10T428/277
摘要： A color-developing sheet for pressure-sensitive copying paper sheets is obtained using an aqueous suspension of a color-developing composition containing a multivalent metal salt of a salicylic acid resin obtained from a salicylic acid ester and a mixture of styrenes which include a styrene dimer, which aqueous suspension is obtained by finely wet-grinding the color-developing composition in the presence of at least one anionic, water-soluble, high-molecular weight substance selected from (a) polyvinyl alcohol derivatives containing at least one sulfonic acid group thereof and salts thereof and (b) polymers and copolymers containing as an essential component a styrenesulfonic acid salt.
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公开(公告)号：US5447901A
公开(公告)日：1995-09-05
申请号：US297525
申请日：1994-08-26
CPC分类号： B41M5/155 , B41M5/3331 , C08G2261/312
摘要： A color-developing composition comprises a multi-valent-metal-modified salicylic acid resin (Resin A) and a polycondensation resin (resin B) at a weight ratio of 90-30 to 10-70. Resin A is composed of 5-35 mole % of a structural unit (I) and 65-95 mole % of at least one structural unit (II) or 65-95 mole % of a coupled structural unit of at least one unit (II) and at least one unit (III) and has a weight-average molecular weight of 350-5,000. Resin B is composed of the unit (II) and/or the unit (III) and has a weight-average molecular weight of 350-5,000. ##STR1## wherein Z represents M/m, M being a metal ion of m valence and m being an integer; R.sub.1 and R.sub.2 represent H or a C.sub.1-12 alkyl, aralkyl, aryl or cycloalkyl group; R.sub.3 and R.sub.6 represent H or a C.sub.1-4 alkyl group; and R.sub.4 and R.sub.5 represent H or CH.sub.3.
摘要翻译： 显色组合物包含重量比为90-30至10-70的多价金属改性水杨酸树脂（树脂A）和缩聚树脂（树脂B）。 树脂A由5-35摩尔％的结构单元（I）和65-95摩尔％的至少一种结构单元（II）或65-95摩尔％的至少一个单元（II）的偶联结构单元组成 ）和至少一种单元（III），并且其重均分子量为350-5,000。 树脂B由单元（II）和/或单元（III）组成，重均分子量为350-5,000。 （III）其中Z表示M / m，M是m价金属离子，m为整数; R1和R2表示H或C1-12烷基，芳烷基，芳基或环烷基; R3和R6表示H或C1-4烷基; R4和R5代表H或CH3。
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公开(公告)号：US5376615A
公开(公告)日：1994-12-27
申请号：US915175
申请日：1992-07-20
CPC分类号： B41M5/155 , B41M5/3331 , C08G2261/312
摘要： A color-developing composition comprises a multi-valent-metal-modified salicylic acid resin (Resin A) and a polycondensation resin (resin B) at a weight ratio of 90-30 to 10-70. Resin A is composed of 5-35 mole % of a structural unit (I) and 65-95 mole % of at least one structural unit (II) or 65-95 mole % of a coupled structural unit of at least one unit (II) and at least one unit (III) and has a weight-average molecular weight of 350-5,000. Resin B is composed of the unit (II) and/or the unit (III) and has a weight-average molecular weight of 350-5,000. ##STR1## wherein Z represents M/m, M being a metal ion of m valence and m being an integer; R.sub.1 and R.sub.2 represent H or a C.sub.1-12 alkyl, aralkyl, aryl or cycloalkyl group; R.sub.3 and R.sub.6 represent H or a C.sub.1-4 alkyl group; and R.sub.4 and R.sub.5 represent H or CH.sub.3.
摘要翻译： 显色组合物包含重量比为90-30至10-70的多价金属改性水杨酸树脂（树脂A）和缩聚树脂（树脂B）。 树脂A由5-35摩尔％的结构单元（I）和65-95摩尔％的至少一种结构单元（II）或65-95摩尔％的至少一个单元（II）的偶联结构单元组成 ）和至少一种单元（III），并且其重均分子量为350-5,000。 树脂B由单元（II）和/或单元（III）组成，重均分子量为350-5,000。 （III）其中Z表示M / m，M是m价金属离子，m为整数; R1和R2表示H或C1-12烷基，芳烷基，芳基或环烷基; R3和R6表示H或C1-4烷基; R4和R5代表H或CH3。
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5.发明授权
公开(公告)号：US5023366A
公开(公告)日：1991-06-11
申请号：US111763
申请日：1987-10-23
摘要： Disclosed herein are salicylic acid copolymers having a weight average molecular weight of 500-10,000 and obtained (a) by condensing salicylic acid (i) with a benzyl alcohol (ii) and/or benzyl ether (iii) or a benzyl halide (iv) in the presence of an acid catalyst or (b) by reacting a co-condensation resin of (i) and (ii) and/or (iii) with (iv) or (c) by reacting a co-condensation resin of (i) and (ii) and/or (iii) or (iv) with a styrene derivative in the presence of an acid catalyst; multivalent metal salts of the salicylic acid copolymers; color-developing agents comprising the multivalent metal salts; and color-developing sheets suited for pressure-sensitive copying paper and comprising the color-developing agents. Their production processes are also disclosed.
摘要翻译： 本文公开了重均分子量为500〜10,000的水杨酸共聚物，（a）通过将水杨酸（i）与苄醇（ⅱ）和/或苄基醚（ⅲ）或苄基卤（ⅳ） 在酸催化剂的存在下，或（b）通过使（i）和（ii）和/或（iii）的共缩合树脂与（iv）或（c）的共缩合树脂与 ）和（ii）和/或（iii）或（iv）与苯乙烯衍生物在酸催化剂存在下反应; 水杨酸共聚物的多价金属盐; 包含多价金属盐的显色剂; 以及适用于压敏复印纸并包含彩色显影剂的彩色显影纸。 他们的生产过程也被披露。
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6.发明授权Linear salicylic acid copolymers and their metal salts, production process thereof, color-developing agents comprising metal-resins of the copolymers 失效线性水杨酸共聚物及其金属盐，其制备方法，包含共聚物的金属 - 树脂的显色剂
公开(公告)号：US4783521A
公开(公告)日：1988-11-08
申请号：US4323
申请日：1987-01-16
摘要： Disclosed herein are novel linear copolymers having weight average molecular weight of 500-30,000 and comprising structural units represented by the following formulae (I), (II), (III) and (IV): ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 mean individually an alkyl group having 4 or fewer carbon atoms and R.sub.4 denotes an alkyl, cycloalkyl, aralkyl or phenyl group, and multivalent metal salts thereof in each of which the multivalent metal forms the multivalent metal salt between carboxyl groups within the same molecule of the copolymer or between different molecules of the copolymer; color-developing agents comprising multivalent metal-modified resins of the copolymers; and color-developing sheets obtained by coating the color-developing agents on their surfaces.
摘要翻译： 本文公开了重均分子量为500〜30,000的新型线性共聚物，其包含由下式（I），（II），（III）和（IV）表示的结构单元：（I） （III）其中R1，R2和R3分别表示具有4个或更少碳原子的烷基，R4表示烷基，环烷基，芳烷基或苯基，其多价金属盐在 其中的多价金属在共聚物的相同分子内或共聚物的不同分子之间的羧基之间形成多价金属盐; 包含共聚物的多价金属改性树脂的显色剂; 以及通过在其表面上涂布显色剂而获得的显色片。
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公开(公告)号：US5484948A
公开(公告)日：1996-01-16
申请号：US284103
申请日：1994-08-02
申请人： Keizaburo Yamaguchi , Tatsuhiro Urakami , Yoshimitsu Tanabe , Midori Yamazaki , Shoji Tamai , Norimasa Yamaya , Masahiro Ohta , Akihiro Yamaguchi
发明人： Keizaburo Yamaguchi , Tatsuhiro Urakami , Yoshimitsu Tanabe , Midori Yamazaki , Shoji Tamai , Norimasa Yamaya , Masahiro Ohta , Akihiro Yamaguchi
IPC分类号： C07C201/12 , C07C205/38 , C07C213/02 , C07C217/90 , C07D207/44 , C07D207/452 , C08G73/12 , C07D207/444
CPC分类号： C07D207/452 , C07C205/38 , C07C217/90 , C08G73/124
摘要： Disclosed is an aromatic diamine compound represented by the formula (I) ##STR1## wherein R is H or CH.sub.3. Also disclosed is a bismaleimide compound represented by the formula (IV) ##STR2## wherein R is H or CH.sub.3, A resin forming composition comprising these compounds is also disclosed. The compounds are useful as raw materials for resins, and the resin forming composition and the resin can provide excellent heat resistance and impact resistance and low hygroscopicity.
摘要翻译： 公开了由式（I）表示的芳族二胺化合物，其中R是H或CH 3。 还公开了由式（IV）表示的双马来酰亚胺化合物。其中R是H或CH 3，包含这些化合物的树脂形成组合物也被公开。 这些化合物可用作树脂的原料，树脂形成组合物和树脂可以提供优异的耐热性和耐冲击性和低吸湿性。
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8.发明授权Aromatic diamine compounds, bismaleimide compounds, thermosetting resin forming compositions therefrom, resins therefrom, and methods for their preparation 失效芳族二胺化合物，双马来酰亚胺化合物，形成其组合物的热固性树脂，其树脂及其制备方法
公开(公告)号：US5206438A
公开(公告)日：1993-04-27
申请号：US601424
申请日：1990-10-23
申请人： Keizaburo Yamaguchi , Tatsuhiro Urakami , Yoshimitsu Tanabe , Midori Yamazaki , Shoji Tamai , Norimasa Yamaya , Masahiro Ohta , Akihiro Yamaguchi
发明人： Keizaburo Yamaguchi , Tatsuhiro Urakami , Yoshimitsu Tanabe , Midori Yamazaki , Shoji Tamai , Norimasa Yamaya , Masahiro Ohta , Akihiro Yamaguchi
IPC分类号： C07C201/12 , C07C205/38 , C07C213/02 , C07C217/90 , C07D207/44 , C07D207/452 , C08G73/12
CPC分类号： C07D207/452 , C07C205/38 , C07C217/90 , C08G73/124
摘要： Disclosed is an aromatic diamine compound represented by the formula (I) ##STR1## wherein R is H or CH.sub.3. Also disclosed is a bismaleimide compound represented by the formula (IV) ##STR2## wherein R is H or CH.sub.3, A resin forming composition comprising these compounds is also disclosed. The compounds are useful as raw materials for resins, and the resin forming composition and the resin can provide excellent heat resistance and impact resistance and low hygroscopicity.
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9.发明授权Epoxy resins containing imido rings, production process thereof and epoxy resin compositions containing the same 失效含有亚氨基环的环氧树脂及其制备方法和含有它的环氧树脂组合物
公开(公告)号：US4957994A
公开(公告)日：1990-09-18
申请号：US393798
申请日：1989-08-15
CPC分类号： C08G59/26 , C08G59/063
摘要： An opoxy resin is obtained by reacting an epihalohydrin with an imido-ring-containing diphenol represented by the following formula (I): ##STR1## wherein R represents an aliphatic group having at least two carbon atoms, an alicyclic group, a monocyclic aryl group, a fused polycyclic aromatic group, or a non-fused polycyclic aromatic group formed of aromatic groups coupled together directly or via a linking member and the two hydroxyl groups are each bonded to a meta position or the para position. In the epoxy resin, at least 50% of the hdroxyl groups of molecules of the diphenol have been opoxidized.
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公开(公告)号：US5145949A
公开(公告)日：1992-09-08
申请号：US823478
申请日：1992-01-22
申请人： Keizaburo Yamaguchi , Yoshimitsu Tanabe , Tatsuhiro Urakami , Akihiro Yamaguchi , Norimasa Yamaya , Masahiro Ohta
发明人： Keizaburo Yamaguchi , Yoshimitsu Tanabe , Tatsuhiro Urakami , Akihiro Yamaguchi , Norimasa Yamaya , Masahiro Ohta
IPC分类号： C07C211/50 , C08G73/12
CPC分类号： C08G73/121 , C07C211/50
摘要： Disclosed herein is an aromatic amine resin formed of a mixture of aromatic amine compounds represented by the following general formula (a): ##STR1## wherein A means a phenylene, alkyl-substituted phenylene, diphenylene, diphenyl ether or naphthylenyl group, R.sup.1 denotes a halogen atom or a hydroxyl, C.sub.1-4 alkoxy or C.sub.1-5 alkyl group, l stands for 1 or 2, m is an integer of 0-3, when m is 2 or 3, R.sup.1 s may be the same or different and two of R.sup.1 s may join together into a 5- to 6-membered alicyclic moiety which may optionally contain one or more side chains, and n stands for an integer of 0-300.
摘要翻译： 本文公开了由以下通式（a）表示的芳族胺化合物的混合物形成的芳香族胺树脂：其中A表示亚苯基，烷基取代的亚苯基，二亚苯基，二苯基醚或萘基， R1表示卤素原子或羟基，C1-4烷氧基或C1-5烷基，l表示1或2，m表示0-3的整数，当m为2或3时，R 1可以相同或不同 并且R 1中的两个可以连接在一起可以任选地含有一个或多个侧链的5-至6-元脂环部分，n表示0-300的整数。
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