公开(公告)号：US4997874A

公开(公告)日：1991-03-05

申请号：US169499

申请日：1988-03-17

申请人： Makoto Asano ,  Kiyoharu Hasegawa ,  Masatoshi Takagi ,  Akihiro Yamaguchi ,  Keizaburo Yamaguchi ,  Yoshimitsu Tanabe ,  Hiroyuki Akahori

发明人： Makoto Asano ,  Kiyoharu Hasegawa ,  Masatoshi Takagi ,  Akihiro Yamaguchi ,  Keizaburo Yamaguchi ,  Yoshimitsu Tanabe ,  Hiroyuki Akahori

IPC分类号： B41M5/155

CPC分类号： B41M5/155

摘要： An aqueous suspension of a multivalent-metal-modified salicylic acid resin, which is suitable for use in the production of color-developing sheets for pressure-sensitive recording paper sheets, contains a specific multivalent-metal-modified salicylic acid resin at the first-mentioned resin. Fine particles of the specific multivalent-metal-modified salicylic acid is dispersed in an aqueous solution of a dispersant composed of at least one compound selected from the group consisting of:(a) water-soluble anionic high-molecular compounds composed of polyvinyl alcohol derivatives containing sulfonic acid groups in their molecules, and salts thereof,(b) acrylamide-modified polyvinyl alcohols, and(c) water-soluble anionic high-molecular compounds composed of polymers or copolymers comprising particular styrenesulfonic acid derivatives as their essential components.The aqueous dispersion is prepared by finely grinding the specific multivalent-metal-modified salicylic acid in the aqueous solution of the dispersant.

公开(公告)号：US5260403A

公开(公告)日：1993-11-09

申请号：US906887

申请日：1992-07-02

申请人： Keizaburo Yamaguchi ,  Yoshimitsu Tanabe ,  Kiyoharu Hasegawa ,  Akihiro Yamaguchi

发明人： Keizaburo Yamaguchi ,  Yoshimitsu Tanabe ,  Kiyoharu Hasegawa ,  Akihiro Yamaguchi

IPC分类号： B41M5/155 ,  B41M5/333 ,  C08G61/02 ,  C08G83/00 ,  B41M5/16

CPC分类号： B41M5/155 ,  Y10S428/913 ,  Y10S428/914 ,  Y10T428/256 ,  Y10T428/277

摘要： A color-developing sheet for pressure-sensitive copying paper sheets is obtained using an aqueous suspension of a color-developing composition containing a multivalent metal salt of a salicylic acid resin obtained from a salicylic acid ester and a mixture of styrenes which include a styrene dimer, which aqueous suspension is obtained by finely wet-grinding the color-developing composition in the presence of at least one anionic, water-soluble, high-molecular weight substance selected from (a) polyvinyl alcohol derivatives containing at least one sulfonic acid group thereof and salts thereof and (b) polymers and copolymers containing as an essential component a styrenesulfonic acid salt.

公开(公告)号：US5447901A

公开(公告)日：1995-09-05

申请号：US297525

申请日：1994-08-26

申请人： Keizaburo Yamaguchi ,  Yoshimitsu Tanabe ,  Kiyoharu Hasegawa ,  Akihiro Yamaguchi

发明人： Keizaburo Yamaguchi ,  Yoshimitsu Tanabe ,  Kiyoharu Hasegawa ,  Akihiro Yamaguchi

IPC分类号： B41M5/155 ,  B41M5/333 ,  B41M5/035 ,  B41M5/38

CPC分类号： B41M5/155 ,  B41M5/3331 ,  C08G2261/312

摘要： A color-developing composition comprises a multi-valent-metal-modified salicylic acid resin (Resin A) and a polycondensation resin (resin B) at a weight ratio of 90-30 to 10-70. Resin A is composed of 5-35 mole % of a structural unit (I) and 65-95 mole % of at least one structural unit (II) or 65-95 mole % of a coupled structural unit of at least one unit (II) and at least one unit (III) and has a weight-average molecular weight of 350-5,000. Resin B is composed of the unit (II) and/or the unit (III) and has a weight-average molecular weight of 350-5,000. ##STR1## wherein Z represents M/m, M being a metal ion of m valence and m being an integer; R.sub.1 and R.sub.2 represent H or a C.sub.1-12 alkyl, aralkyl, aryl or cycloalkyl group; R.sub.3 and R.sub.6 represent H or a C.sub.1-4 alkyl group; and R.sub.4 and R.sub.5 represent H or CH.sub.3.

摘要翻译： 显色组合物包含重量比为90-30至10-70的多价金属改性水杨酸树脂（树脂A）和缩聚树脂（树脂B）。 树脂A由5-35摩尔％的结构单元（I）和65-95摩尔％的至少一种结构单元（II）或65-95摩尔％的至少一个单元（II）的偶联结构单元组成 ）和至少一种单元（I​​II），并且其重均分子量为350-5,000。 树脂B由单元（II）和/或单元（III）组成，重均分子量为350-5,000。 （III）其中Z表示M / m，M是m价金属离子，m为整数; R1和R2表示H或C1-12烷基，芳烷基，芳基或环烷基; R3和R6表示H或C1-4烷基; R4和R5代表H或CH3。

公开(公告)号：US5376615A

公开(公告)日：1994-12-27

申请号：US915175

申请日：1992-07-20

申请人： Keizaburo Yamaguchi ,  Yoshimitsu Tanabe ,  Kiyoharu Hasegawa ,  Akihiro Yamaguchi

发明人： Keizaburo Yamaguchi ,  Yoshimitsu Tanabe ,  Kiyoharu Hasegawa ,  Akihiro Yamaguchi

IPC分类号： B41M5/155 ,  B41M5/333 ,  B41M5/20

CPC分类号： B41M5/155 ,  B41M5/3331 ,  C08G2261/312

摘要： A color-developing composition comprises a multi-valent-metal-modified salicylic acid resin (Resin A) and a polycondensation resin (resin B) at a weight ratio of 90-30 to 10-70. Resin A is composed of 5-35 mole % of a structural unit (I) and 65-95 mole % of at least one structural unit (II) or 65-95 mole % of a coupled structural unit of at least one unit (II) and at least one unit (III) and has a weight-average molecular weight of 350-5,000. Resin B is composed of the unit (II) and/or the unit (III) and has a weight-average molecular weight of 350-5,000. ##STR1## wherein Z represents M/m, M being a metal ion of m valence and m being an integer; R.sub.1 and R.sub.2 represent H or a C.sub.1-12 alkyl, aralkyl, aryl or cycloalkyl group; R.sub.3 and R.sub.6 represent H or a C.sub.1-4 alkyl group; and R.sub.4 and R.sub.5 represent H or CH.sub.3.

摘要翻译： 显色组合物包含重量比为90-30至10-70的多价金属改性水杨酸树脂（树脂A）和缩聚树脂（树脂B）。 树脂A由5-35摩尔％的结构单元（I）和65-95摩尔％的至少一种结构单元（II）或65-95摩尔％的至少一个单元（II）的偶联结构单元组成 ）和至少一种单元（I​​II），并且其重均分子量为350-5,000。 树脂B由单元（II）和/或单元（III）组成，重均分子量为350-5,000。 （III）其中Z表示M / m，M是m价金属离子，m为整数; R1和R2表示H或C1-12烷基，芳烷基，芳基或环烷基; R3和R6表示H或C1-4烷基; R4和R5代表H或CH3。

公开(公告)号：US5391806A

公开(公告)日：1995-02-21

申请号：US131549

申请日：1993-10-05

申请人： Atsuo Otsuji ,  Toshihiro Motoshima ,  Yoshimitsu Tanabe ,  Kiyoharu Hasegawa ,  Kazuyoshi Kikkawa ,  Masakatsu Nakatsuka ,  Akihiro Yamaguchi

发明人： Atsuo Otsuji ,  Toshihiro Motoshima ,  Yoshimitsu Tanabe ,  Kiyoharu Hasegawa ,  Kazuyoshi Kikkawa ,  Masakatsu Nakatsuka ,  Akihiro Yamaguchi

IPC分类号： B41M5/337 ,  B41M5/30 ,  B41M5/333 ,  C07C39/00 ,  C07C271/28 ,  C07C271/58 ,  C07C317/22 ,  C07C317/42 ,  C07C323/20 ,  C07C323/43 ,  C07C333/08 ,  C09B11/28 ,  C09K9/00

CPC分类号： C07C333/08 ,  B41M5/3335 ,  C07C271/28 ,  C07C271/58 ,  C07C317/22 ,  C07C323/20 ,  C07C323/43 ,  B41M5/3333 ,  B41M5/3336 ,  C07C2101/14

摘要： Heat-sensitive recording materials contain an electron-donating chromogenic compound and an electron-attracting compound. The recording materials also contain at least one compound represented by the following formula: ##STR1## wherein R.sub.1 and R.sub.3 mean a hydrogen atom or an alkyl, aralkyl or aryl group, R.sub.2 and R.sub.4 denote an alkyl, alkenyl, aralkyl or aryl group, X.sub.1, X.sub.2, Y.sub.1 and Y.sub.2 stand for an oxygen or a sulfur atom, and --Z.sub.1 -- and --Z.sub.2 -- are a specific aromatic group. Also provided are phenol compounds represented by the following formula: ##STR2## wherein R.sub.1, R.sub.2, X.sub.1 and Y.sub.1 have the same meanings as defined above; R.sub.5 and R.sub.6 are a hydrogen or halogen atom or an alkyl, alkoxy, aralkyl, aryl or hydroxyl group; p and q stand for an integer of 1-4; R.sub.5 and R.sub.6 may be either the same or different when p and q represent an integer of 2 or greater; and --Z.sub.3 -- means a specific divalent group.

摘要翻译： 热敏记录材料含有给电子显色化合物和吸电子化合物。 记录材料还含有至少一种由下式表示的化合物：其中R 1和R 3表示氢原子或烷基，芳烷基或芳基，R 2和R 4表示烷基，烯基，芳烷基或芳基，X 1 ，X2，Y1和Y2表示氧或硫原子，-Z1和-Z2-是特定的芳族基团。 还提供了由下式表示的酚化合物：其中R1，R2，X1和Y1具有与上述相同的含义; R5和R6是氢或卤素原子或烷基，烷氧基，芳烷基，芳基或羟基; p和q代表1-4的整数; 当p和q表示2或更大的整数时，R 5和R 6可以相同或不同; 和-Z 3 - 表示特定的二价基团。

公开(公告)号：US5306688A

公开(公告)日：1994-04-26

申请号：US946694

申请日：1992-09-18

申请人： Yoshimitsu Tanabe ,  Yuki Kobayashi ,  Atsuo Otsuji ,  Masakatsu Nakatsuka ,  Kiyoharu Hasegawa ,  Kazuyoshi Kikkawa ,  Akihiro Yamaguchi ,  Naomasa Koike ,  Fumio Okumura

发明人： Yoshimitsu Tanabe ,  Yuki Kobayashi ,  Atsuo Otsuji ,  Masakatsu Nakatsuka ,  Kiyoharu Hasegawa ,  Kazuyoshi Kikkawa ,  Akihiro Yamaguchi ,  Naomasa Koike ,  Fumio Okumura

IPC分类号： B41M5/30 ,  B41M5/333 ,  C07C271/28 ,  C07C271/58 ,  C07C333/08 ,  C07C333/24 ,  B41M5/32

CPC分类号： C07C333/24 ,  B41M5/3335 ,  C07C271/28 ,  C07C271/58 ,  C07C333/08 ,  B41M5/3336

摘要： A heat-sensitive recording material comprising a color forming, electron donating compound and a salicylic acid derivative represented by the formula (1): ##STR1## wherein X.sub.1 and X.sub.2 are a hydrogen atom, an alkyl group, an alkoxy group, an aralkyl group, an aryl group or a halogen atom, Y.sub.1 and Y.sub.2 are an oxygen atom or a sulfur atom, R.sub.1 is a hydrogen atom, an alkyl group, an aralkyl group or an aryl group , and R.sub.2 is an alkyl group, an alkenyl group, an aralkyl group or an aryl group, and/or a metal salt of the salicylic acid derivative as an electron accepting compound, is disclosed.

摘要翻译： 一种热敏记录材料，其包含成色剂，给电子化合物和由式（1）表示的水杨酸衍生物：（*化学结构*）（I）其中X 1和X 2是氢原子，烷基， 烷氧基，芳烷基，芳基或卤素原子，Y1和Y2为氧原子或硫原子，R1为氢原子，烷基，芳烷基或芳基，R2为烷基 基团，烯基，芳烷基或芳基，和/或作为电子接受性化合物的水杨酸衍生物的金属盐。

公开(公告)号：US5281570A

公开(公告)日：1994-01-25

申请号：US916790

申请日：1992-07-22

申请人： Kiyoharu Hasegawa ,  Yoshimitsu Tanabe ,  Kazuyoshi Kikkawa ,  Masakatsu Nakatsuka ,  Akihiro Yamaguchi

发明人： Kiyoharu Hasegawa ,  Yoshimitsu Tanabe ,  Kazuyoshi Kikkawa ,  Masakatsu Nakatsuka ,  Akihiro Yamaguchi

IPC分类号： C09K9/02 ,  B41M5/28

CPC分类号： C09K9/02 ,  B41M5/305 ,  Y10T428/2984

摘要： A reversible thermochromic material, preferably in the form of a microcapsule, comprising:(a) an electron donative color former;(b) a sulfide, sulfoxide or sulfone containing a hydroxy phenyl radical; and(c) a chemical compound selected from alcohols, esters, ethers, ketones, carboxylic acids or acid amides,chromatizes very brightly and in a dense color, generates a change of chromic hue (colored - colorless) within a narrow temperature range and provides a stable thermochromatism on a long term basis.

摘要翻译： 一种可逆的热变色材料，优选为微胶囊形式，包括：（a）一种给电子着色剂; （b）含有羟基苯基的硫化物，亚砜或砜; 和（c）选自醇，酯，醚，酮，羧酸或酰胺的化合物，非常明亮和致密的着色，在窄的温度范围内产生铬色调（着色 - 无色）的变化，并提供 长期稳定的热色素。

公开(公告)号：US5270281A

公开(公告)日：1993-12-14

申请号：US901486

申请日：1992-06-22

申请人： Atsuo Otsuji ,  Toshihiro Motoshima ,  Yoshimitsu Tanabe ,  Kiyoharu Hasegawa ,  Kazuyoshi Kikkawa ,  Masakatsu Nakatsuka ,  Akihiro Yamaguchi

发明人： Atsuo Otsuji ,  Toshihiro Motoshima ,  Yoshimitsu Tanabe ,  Kiyoharu Hasegawa ,  Kazuyoshi Kikkawa ,  Masakatsu Nakatsuka ,  Akihiro Yamaguchi

IPC分类号： B41M5/337 ,  B41M5/30 ,  B41M5/333 ,  C07C39/00 ,  C07C271/28 ,  C07C271/58 ,  C07C317/22 ,  C07C317/42 ,  C07C323/20 ,  C07C323/43 ,  C07C333/08 ,  C09B11/28 ,  C09K9/00 ,  B41M5/18

CPC分类号： C07C333/08 ,  B41M5/3335 ,  C07C271/28 ,  C07C271/58 ,  C07C317/22 ,  C07C323/20 ,  C07C323/43 ,  B41M5/3333 ,  B41M5/3336 ,  C07C2101/14

摘要： Heat-sensitive recording materials contain an electron-donating chromogenic compound and an electron-attracting compound. The recording materials also contain at least one compound represented by the following formula: ##STR1## wherein R.sub.1 and R.sub.3 mean a hydrogen atom or an alkyl, aralkyl or aryl group, R.sub.2 and R.sub.4 denote an alkyl, alkenyl, aralkyl or aryl group, X.sub.1, X.sub.2, Y.sub.1 and Y.sub.2 stand for an oxygen or a sulfur atom, and --Z.sub.1 -- and --Z.sub.2 -- are a specific aromatic group. Also provided are phenol compounds represented by the following formula: ##STR2## wherein R.sub.1, R.sub.2, X.sub.1 and Y.sub.1 have the same meanings as defined above; R.sub.5 and R.sub.6 are a hydrogen or halogen atom or an alkyl, alkoxy, aralkyl, aryl or hydroxyl group; p and q stand for an integer of 1-4; R.sub.5 and R.sub.6 may be either the same or different when p and q represent an integer of 2 or greater; and --Z.sub.3 -- means a specific divalent group.

摘要翻译： 热敏记录材料含有给电子显色化合物和吸电子化合物。 记录材料还含有至少一种由下式表示的化合物：其中R 1和R 3表示氢原子或烷基，芳烷基或芳基，R 2和R 4表示烷基，烯基，芳烷基或芳基，X 1 ，X2，Y1和Y2表示氧或硫原子，-Z1和-Z2-是特定的芳族基团。 还提供了由下式表示的酚化合物：其中R1，R2，X1和Y1具有与上述相同的含义; R5和R6是氢或卤素原子或烷基，烷氧基，芳烷基，芳基或羟基; p和q代表1-4的整数; 当p和q表示2或更大的整数时，R 5和R 6可以相同或不同; 和-Z 3 - 表示特定的二价基团。

公开(公告)号：US4735744A

公开(公告)日：1988-04-05

申请号：US738348

申请日：1985-05-28

申请人： Michihiro Tsujimoto ,  Kiyoharu Hasegawa ,  Hiroyuki Akahori ,  Eishi Tanaka ,  Makoto Asano

发明人： Michihiro Tsujimoto ,  Kiyoharu Hasegawa ,  Hiroyuki Akahori ,  Eishi Tanaka ,  Makoto Asano

IPC分类号： B41M5/00 ,  B41M5/155 ,  C07C50/04 ,  C07C317/00

CPC分类号： B41M5/155 ,  C07C317/00

摘要： Disclosed herein is a novel benzoquinone derivative represented by the following general formula (I): ##STR1## wherein R.sub.1 means an alkyl or cycloalkyl group, R.sub.2 denotes an alkyl or cycloalkyl group, a phenyl group which may optionally contain one or more halogen atoms and/or alkyl, cycloalkyl, alkoxy, alkylene, phenoxy, phenyl and/or biphenylyl groups, or a benzyl or naphthyl group which may optionally contain one or more methyl groups. This compound is useful as an oxidative color-developing agent for recording materials.

摘要翻译： 本文公开了由以下通式（I）表示的新型苯醌衍生物：其中R 1表示烷基或环烷基，R 2表示烷基或环烷基，可任选地含有一个或多个 卤素原子和/或烷基，环烷基，烷氧基，亚烷基，苯氧基，苯基和/或联苯基，或可任意含有一个或多个甲基的苄基或萘基。 该化合物可用作记录材料的氧化显色剂。

公开(公告)号：US4632987A

公开(公告)日：1986-12-30

申请号：US562587

申请日：1983-12-02

申请人： Michihiro Tsujimoto ,  Hiroyuki Akahori ,  Kiyoharu Hasegawa ,  Makoto Asano

发明人： Michihiro Tsujimoto ,  Hiroyuki Akahori ,  Kiyoharu Hasegawa ,  Makoto Asano

IPC分类号： C07B61/00 ,  B01J27/00 ,  C07C67/00 ,  C07C209/00 ,  C07C209/68 ,  C07C209/78 ,  C07C211/44 ,  C07C211/50 ,  C07C213/00 ,  C07C217/80 ,  C09B11/14 ,  C09B11/10 ,  C07D209/04 ,  C07D209/18 ,  C07D265/30

CPC分类号： C09B11/14

摘要： A process for the preparation of triarylmethane compounds which comprises reacting a benzene or naphthalene compound with a formylating agent for such compounds in the presence of an acid catalyst to form an aromatic aldehyde compound; adding water to the reaction mixture and thereby hydrolyzing the acid catalyst without isolating the aromatic aldehyde compound from the reaction mixture; and uninterruptedly condensing the aromatic aldehyde compound with an aromatic compound in the resulting mixture.

摘要翻译： PCT No.PCT / JP83 / 00133 Sec。 371日期：1983年12月2日 102（e）1983年12月2日日期PCT提交1983年4月28日PCT公布。 出版物WO83 / 03840 日本1983年11月10日。一种制备三芳基甲烷化合物的方法，其包括在酸催化剂存在下使苯或萘化合物与甲酰化剂反应形成芳族醛化合物; 向反应混合物中加入水，从而水解酸催化剂，而不从反应混合物中分离出芳族醛化合物; 并在所得混合物中不间断地将芳族醛化合物与芳族化合物缩合。