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    ELECTRODE FOR ACTIVE OXYGEN SPECIES AND SENSOR USING THE ELECTRODE
    1.
    发明申请
    ELECTRODE FOR ACTIVE OXYGEN SPECIES AND SENSOR USING THE ELECTRODE 审中-公开
    用于活性氧物质的电极和使用电极的传感器

    公开(公告)号：US20140061063A1

    公开(公告)日：2014-03-06

    申请号：US14071265

    申请日：2013-11-04

    申请人： Makoto Yuasa ,  Hitoshi Takebayashi ,  Masahiko Abe

    发明人： Makoto Yuasa ,  Masahiko Abe ,  Aritomo Yamaguchi ,  Asako Shiozawa ,  Masuhide Ishikawa ,  Katsuya Eguchi ,  Shigeru Kido

    IPC分类号： G01N27/333 ,  G01N27/327

    CPC分类号： G01N27/3335 ,  A61B5/1473 ,  C11D3/0015 ,  C11D3/2093 ,  C11D3/50 ,  G01N27/3271 ,  G01N33/4925

    摘要： An electrode for active oxygen species comprising a conductive component with a polymer membrane of a metal porphyrin complex formed on the surface is disclosed. The electrode for active oxygen species can detect active oxygen species such as superoxide anion radicals, hydrogen peroxide, and .OH and other active radical species (NO, ONOO—, etc.) in any environment including in vivo environment as well as in vitro environment. The electrode thus can be used for specifying various diseases and examining active oxygen species in food or in water such as tap water and sewage water.

    摘要翻译： 公开了一种用于活性氧物质的电极，其包含在表面上形成的具有金属卟啉络合物的聚合物膜的导电组分。 用于活性氧的电极可以在包括体内环境以及体外环境的任何环境中检测活性氧，如超氧阴离子自由基，过氧化氢和.OH等活性自由基（NO，ONOO-等） 。 因此，电极可以用于指定各种疾病并检查食物或水中的活性氧，例如自来水和污水。

    ELECTRODE FOR SUPEROXIDE ANION AND SENSOR INCLUDING THE SAME
    4.
    发明申请
    ELECTRODE FOR SUPEROXIDE ANION AND SENSOR INCLUDING THE SAME 审中-公开
    用于超氧化物阴离子和包括其的传感器的电极

    公开(公告)号：US20150160152A1

    公开(公告)日：2015-06-11

    申请号：US14531666

    申请日：2014-11-03

    申请人： Makoto Yuasa ,  Kenichi Oyaizu ,  Aritomo Yamaguchi ,  Masuhide Ishikawa ,  Katsuya Eguchi ,  Tomohiro Kobayashi ,  Satoshi Tsutsui ,  Yuujirou Toyoda

    发明人： Makoto Yuasa ,  Kenichi Oyaizu ,  Aritomo Yamaguchi ,  Masuhide Ishikawa ,  Katsuya Eguchi ,  Tomohiro Kobayashi ,  Satoshi Tsutsui ,  Yuujirou Toyoda

    IPC分类号： G01N27/333 ,  C25D5/00

    CPC分类号： G01N27/3335 ,  C25D5/00

    摘要： An electrode for superoxide anions characterized by comprising a conductive component and, superimposed on a surface thereof, a film resulting from electrolytic polymerization of a metal thiofurylporphyrin/axial ligand complex; and a sensor for measuring a superoxide anion concentration including the same. The electrode for superoxide anions, by virtue of not only the excellent performance of electrode provided with the metal porphyrin complex polymer film, but also the presence of the axial ligand, can prevent poisoning by a catalyst poison such as hydrogen peroxide. Accordingly, in any of in vitro or in vivo environments, this electrode for superoxide anions enables detection of superoxide anion radicals without suffering any influence from a catalyst poison such as hydrogen peroxide. Moreover, quantitative assay of superoxide anions can be performed by the use of this electrode for superoxide anion in combination with a counter electrode or a reference electrode. Thus, this electrode for superoxide anions can find wide applicability in various fields.

    摘要翻译： 一种超氧化物阴离子的电极，其特征在于包括导电成分，并且在其表面上叠加由金属硫代卟啉/轴配体络合物的电解聚合得到的膜; 以及用于测量包含该超氧化物阴离子浓度的超氧化物阴离子浓度的传感器。 超氧化物阴离子电极不仅具有金属卟啉复合聚合物膜的电极的优异性能，而且还具有轴配体的存在，可以防止催化剂毒物如过氧化氢的中毒。 因此，在任何体外或体内环境中，这种超氧化物阴离子电极能够检测超氧阴离子自由基，而不会受到诸如过氧化氢等催化剂毒物的任何影响。 此外，超氧阴离子的定量测定可以通过将该电极与对电极或参比电极结合使用来实现超氧阴离子。 因此，这种超氧阴离子电极可以在各个领域得到广泛的应用。

    ELECTRODE FOR SUPEROXIDE ANION AND SENSOR INCLUDING THE SAME
    5.
    发明申请
    ELECTRODE FOR SUPEROXIDE ANION AND SENSOR INCLUDING THE SAME 审中-公开
    用于超氧化物阴离子和包括其的传感器的电极

    公开(公告)号：US20120145562A1

    公开(公告)日：2012-06-14

    申请号：US13270608

    申请日：2011-10-11

    申请人： Makoto Yuasa ,  Kenichi Oyaizu ,  Aritomo Yamaguchi ,  Masuhide Ishikawa ,  Katsuya Eguchi ,  Tomohiro Kobayashi ,  Satoshi Tsutsui ,  Yuujirou Toyoda

    发明人： Makoto Yuasa ,  Kenichi Oyaizu ,  Aritomo Yamaguchi ,  Masuhide Ishikawa ,  Katsuya Eguchi ,  Tomohiro Kobayashi ,  Satoshi Tsutsui ,  Yuujirou Toyoda

    IPC分类号： G01N27/333 ,  G01N27/26

    CPC分类号： G01N27/3335 ,  C25D5/00

    摘要： An electrode for superoxide anions which contains a conductive component and, superimposed on a surface thereof, a film resulting from electrolytic polymerization of a metal thiofurylporphyrin/axial ligand complex; and a sensor for measuring a superoxide anion concentration including the same. The electrode for superoxide anions can prevent poisoning by a catalyst poison such as hydrogen peroxide. Accordingly, in any of in vitro or in vivo environments, this electrode for superoxide anions enables detection of superoxide anion radicals without suffering any influence from a catalyst poison such as hydrogen peroxide. Moreover, quantitative assay of superoxide anions can be performed with this electrode for superoxide anion in combination with a counter electrode or a reference electrode. Thus, this electrode for superoxide anions can find wide applicability in various fields.

    摘要翻译： 一种超氧阴离子的电极，其包含导电成分，并且在其表面上叠加由金属硫卟啉/轴配位体络合物的电解聚合得到的膜; 以及用于测量包含该超氧阴离子浓度的超氧化物阴离子浓度的传感 超氧化物阴离子电极可以防止催化剂毒物如过氧化氢中毒。 因此，在任何体外或体内环境中，这种超氧化物阴离子电极能够检测超氧阴离子自由基，而不会受到诸如过氧化氢等催化剂毒物的任何影响。 此外，超氧化物阴离子的定量测定可以用该电极进行，其中超氧阴离子与对电极或参比电极组合。 因此，这种超氧阴离子电极可以在各个领域得到广泛的应用。

    Electrode for Superoxide Anion and Sensor Including the Same
    6.
    发明申请
    Electrode for Superoxide Anion and Sensor Including the Same 审中-公开
    超氧阴离子电极及其传感器

    公开(公告)号：US20080289960A1

    公开(公告)日：2008-11-27

    申请号：US10592469

    申请日：2004-03-12

    申请人： Makoto Yuasa ,  Kenichi Oyaizu ,  Aritomo Yamaguchi ,  Masuhide Ishikawa ,  Katsuya Eguchi ,  Tomohiro Kobayashi ,  Satoshi Tsutsui ,  Yuujirou Toyoda

    发明人： Makoto Yuasa ,  Kenichi Oyaizu ,  Aritomo Yamaguchi ,  Masuhide Ishikawa ,  Katsuya Eguchi ,  Tomohiro Kobayashi ,  Satoshi Tsutsui ,  Yuujirou Toyoda

    IPC分类号： G01N27/26

    CPC分类号： G01N27/3335 ,  C25D5/00

    摘要： An electrode for superoxide anions characterized by comprising a conductive component and, superimposed on a surface thereof, a film resulting from electrolytic polymerization of a metal thiofurylporphyrin/axial ligand complex; and a sensor for measuring a superoxide anion concentration including the same. The electrode for superoxide anions, by virtue of not only the excellent performance of electrode provided with the metal porphyrin complex polymer film, but also the presence of the axial ligand, can prevent poisoning by a catalyst poison such as hydrogen peroxide. Accordingly, in any of in vitro or in vivo environments, this electrode for superoxide anions enables detection of superoxide anion radicals without suffering any influence from a catalyst poison such as hydrogen peroxide. Moreover, quantitative assay of superoxide anions can be performed by the use of this electrode for superoxide anion in combination with a counter electrode or a reference electrode. Thus, this electrode for superoxide anions can find wide applicability in various fields.

    摘要翻译： 一种超氧化物阴离子的电极，其特征在于包括导电成分，并且在其表面上叠加由金属硫代卟啉/轴配体络合物的电解聚合得到的膜; 以及用于测量包含该超氧化物阴离子浓度的超氧化物阴离子浓度的传感器。 超氧化物阴离子电极不仅具有金属卟啉复合聚合物膜的电极的优异性能，而且还具有轴配体的存在，可以防止催化剂毒物如过氧化氢的中毒。 因此，在任何体外或体内环境中，这种超氧化物阴离子电极能够检测超氧阴离子自由基，而不会受到诸如过氧化氢等催化剂毒物的任何影响。 此外，超氧阴离子的定量测定可以通过将该电极与对电极或参比电极结合使用来实现超氧阴离子。 因此，这种超氧阴离子电极可以在各个领域得到广泛的应用。