摘要:
A process for the manufacture of polyester polyalcohols with amino and amide groups by the reaction of polyester polyalcohols with polyamines is characterized in that unsaturated polyester polyalcohols if necessary in admixture with saturated polyester polyalcohols are used as polyester polyalcohols, and low molecular weight, aliphatic polyamines with two primary amino groups are used as polyamines.
摘要:
The present invention relates to a heat curable adhesive system comprising a prepolymer (P) based on isocyanate groups and polyether segments, and at least one polyhydroxyl compound (C), and a catalyst (D) characterized in that(a) the prepolymer (P) is formed on the basis of one or more polyols (A) containing polyether segments and having an average hydroxyl number of from 50 to 160 and an average functionality of from 2.05 to 2.6 and o at least one diphenylmethane diisocyanate (B) and(b) the polyhydroxyl compound (c) contains at least three hydroxyl groups per molecule and is dispersed in prepolymer (P) in a quantity of from 1 to 10 hydroxyl groups for each isocyanate group still available in the prepolymer (P) and melts at a temperature above 110.degree. C. and(c) the catalyst (D) consists of at least one carboxylic acid salt of bismuth, cadminum, lead or zinc containing more than 12, in particular 14 carbon atoms, used in a solid form melting at a temperature above 100.degree. C.
摘要:
Aqueous solutions and dispersions of polyisocyanate polyaddition products containing 2 to 200 milliequivalents chemically incorporated carboxylate and/or sulfonate groups per 100 g solids and 0 to 25% by weight, based on solids, of incorporated ethylene oxide units arranged within terminal and/or lateral polyether chains, in the production of which primary and/or secondary monoamino compounds are usd, a process for their production and their use as adhesives.
摘要:
An adhesive consisting substantially of an aqueous solution or dispersion of a polyurethane containing chemically incorporated carboxylate and/or sulphonate groups is prepared from a mixture of at least two (cyclo)-aliphatic diisocyanate and selected polyester diols based on (i) adipic acid and (ii) tetramethylenediol, hexamethylenediol or mixtures of these diols. The use of such aqueous solutions for the formation of bonds on any substrates, in particular on leather, plastics, rubber materials and/or polyvinyl chloride containing plasticizer, with the same material or with other materials is disclosed.
摘要:
The present invention relates to aqueous solutions or dispersions of polyisocyanate polyaddition products containing from about 2 to 200 milliequivalents per 100 g of solids of chemically incorporated, ternary or quaternary ammonium groups and up to about 25%, based on solids, of incorporated ethylene oxide units present within terminally and/or laterally arranged polyether chains, characterized in that the polyisocyanate polyaddition products contain from about 20 to 95% by weight of polyester segments Q incorporated through urethane groups, whereinQ represents a radical of the type obtained by removing the hydroxyl groups from(i) dicarboxylic acid polyester polyols having a molecular weight in the range from about 700 to 1400and/or(ii) hydroxyl-terminated lactone homopolymers or copolymers having a molecular weight in the range from about 700 to 2500.The present invention also relates to the preparation of these polyisocyanate polyaddition products and their use for bonding substrates, in particular rubber.
摘要:
The invention relates to moisture-curable adhesive or sealant compositions comprising a) prepolymers based on aliphatic polyisocyanates and having isocyanate contents of 2 to 20 wt. %, and b) bis(dimethylaminoethyl)ether as catalyst. The compositions exhibit good storability, processability can be adjusted within wide limits and also provide rapid through-hardening.
摘要:
The present invention relates to a process for bonding two or more wood substrates by using as the adhesive isocyanate-terminated prepolymers having an isocyanate content of 8 to 20 wt. % and containing the reaction product of a) at least one organic polyisocyanate with b) at least one organic polyhydroxyl compound containing the reaction products of i) organic polyisocyanates with ii) polyamines, hydrazines and/or hydrazides having primary and/or secondary amino groups dispersed in a iii) polyethers having at least two hydroxyl groups and a number average molecular weight of 500 to 12,000; and, the present invention also relates to the bonded substrates obtained by this process.
摘要:
A process for the decomposition of polyurethane plastic waste materials in which a compound containing at least two isocyanate-reactive hydrogen atoms (e.g., glycol) and polyurethane plastic, together with 2 to 20 times the amount of previously regenerated material, are treated in a mixing and comminution device.
摘要:
The present invention is directed to a polyurethane system containing isocyanate groups prepared by reactingA) 70 to 98 parts by weight of at least one polyester diol having a melting point of 30.degree. C. to 60.degree. C. and a molecular weight of 800 to 8,000,B) 2 to 30 parts by weight of at least one polyester diol having a melting point of 65.degree. C. to 150.degree. C. and a molecular weight of 600 to 8,000, andC) no more than 1 mole of a diol having a molecular weight of less than 600 per moles of A) plus B), with,D) at least one organic polyisocyanate, the ratio of isocyanate groups to hydroxyl groups is between 3:1 and 1.2:1.
摘要:
The present invention relates to a magnetic storage medium consisting of a non-magnetic layer support and, applied thereto, a binder-containing magnetic layer, the binder consisting of from 25 to 100% of a thermoplastic polyurethane substantially free from reactive terminal groups obtained by reacting a linear polyester of at least one dicarboxylic acid containing from 2 to 8 carbon atoms and/or hydroxy carboxylic acid containing from 4 to 6 carbon atoms and at least one glycol containing from 2 to 6 carbon atoms, the polyester having a molecular weight of from 1200 to 6000, at least one diisocyanate and a mixture of at least two glycols containing from 2 to 20 carbon atoms, the molar fraction of the individual components not exceeding 0.8. The polyurethane has a hardness of from 80 to 100 Shore A, a tensile strength of from 30 to 75 MPa and a breaking elongation of from 320 to 520%.