摘要:
The invention relates to a method of making a polymer-modified polyol having a solid content from 13 to 55 wt. % wherein an olamine is reacted with an organic polyisocyanate in the presence of a base polyol and at least one catalyst, wherein said at least one catalyst is a zinc carboxylate, and wherein the base polyol has hydroxyl functions wherein more than 20% of said hydroxyl functions are primary hydroxyl functions. The invention further relates to a polymer-modified polyol obtainable with the method of the invention, the use of the polymer-modified polyol for the preparation of optionally foamed plastics, and to a method for the preparation of optionally foamed plastics using the polymer-modified polyol of the invention.
摘要:
The invention relates to peelable and chemically resistant coatings for metal and plastic substrates, and to the coating agent compositions required to produce same. The invention also relates to a process for producing such coatings and to the use of the coating agent compositions to protectively coat metal and plastic substrates in the field of aircraft construction.
摘要:
A process for forming a conventional flexible polyurethane foam includes providing a polyol component including a PIPA polyol that is a dispersion having a solids content from 10% to 75 wt %, based on a total weight of the PIPA polyol, providing an isocyanate component that includes at least one polyisocyanate, providing an additive component that includes a catalyst, and forming a reaction mixture including the polyol component, the isocyanate component, and the additive component to form a flexible polyurethane foam with a resiliency value below 45%. The reaction mixture has an isocyanate index from 90 to 150. The PIPA polyol is a reaction product of a mixture including at least a low equivalent weight polyol having a number average hydroxyl equivalent weight of less than 80, a polyisocyanate compound having a number average isocyanate equivalent weight that is less than 225, and a liquid base poly ether polyol having a number average hydroxyl equivalent weight from 200 to 1500 and at least 80% of secondary hydroxyl groups based on a total amount of hydroxyl groups in the liquid base polyether polyol.
摘要:
Embodiments include polymer polyol dispersions which include a polyol liquid phase and solid particle phase. Embodiments include methods of making the polymer polyol dispersions. The polymer polyol dispersions are essentially free of tin, have a solid content of between about 20 and 50 wt % based on the total weight of the polymer polyol dispersion, and have a viscosity at 20 C. of less than 9000 mPas. The solid particle phase has more than 90% by weight of particles in the solid particle phase having a particle diameter of less than 5 μm.
摘要:
Aqueous cold-cure flexible foam stabilizer including the following components: a) from ≧0.1 to ≦80% by weight of at least one water-insoluble polysiloxane compound having a molecular weight of from ≧300 g/mol to ≦10 000 g/mol, b) ≧2% by weight of water, c) ≧0.1% by weight of surfactant, d) from ≧0 to 10% by weight of additives selected from the group consisting of thickeners, antifreezes, organic solvents and biocides, e) ≧0% by weight of water-soluble siloxane(s), with the proportion by weight of the abovementioned components being selected so that the sum of the proportions by weight of the components is not more than 100% by weight, based on the aqueous cold-cure flexible foam stabilizer formulation.
摘要:
Polymer-modified polyol, for use as a starting material for polyurethane foam, is made by reacting an olamine, such as triethanolamine, with an isocyanate in the presence of a metal organic catalyst. The catalyst is a metal salt of an organic acid and the viscosity of the polymer-modified polyol is at least 2250 mPa·s. In one embodiment the catalyst is of the formulat M(O.CO.R.CH3)2 where M is a metal and R is a carbon chain of 6 to 20 carbons. A metal salt of a monohydroxy fatty acid, particularly ricinoleic acid may be used.
摘要:
The present invention relates to PIPA polyols, to a process for the preparation of these PIPA polyols, and to a process for the production of highly elastic flexible polyurethane foams from these PIPA polyols.
摘要:
A catalyst for polyurethane production is provided which is non-corrosive and exhibits effective delay of catalyst action. The catalyst comprises a mixture of a tertiary amine, and a saturated dicarboxylic acid represented by General Formula: HOOC—(CH2)n—COOHwhere n is an integer of from 2 to 14.
摘要:
Process for preparing a polyol comprising particulate material in dispersed form by reacting an MDI-based polyisocyanate and a polyol having an equivalent weight of up to 400, the reaction being carried out in a polyol having an equivalent weight of 500 or more wherein the polyol having an equivalent weight of 500 or more is a polyoxyethylene polyoxypropylene polyol having an oxyethylene content of 15-49% by weight calculated on the total oxyalkylene groups present wherein 20-80% of the oxyethylenegroups resides at the end of the polymer chains.