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116 条记录 (耗时 0.017 秒)

    Process for the preparation of dyestuff compositions
    1.
    发明授权
    Process for the preparation of dyestuff compositions 失效

    公开(公告)号：US4061464A

    公开(公告)日：1977-12-06

    申请号：US620385

    申请日：1975-10-07

    申请人： Manfred Hahnke ,  Kurt Hohmann ,  Theodor Papenfuhs

    发明人： Manfred Hahnke ,  Kurt Hohmann ,  Theodor Papenfuhs

    IPC分类号： C09B1/28 ,  C09B1/503 ,  C09B11/10 ,  C09B11/20 ,  C09B11/22 ,  C09B11/26 ,  C09B11/28 ,  C09B29/00 ,  C09B31/02 ,  C09B67/42 ,  C09B67/00

    CPC分类号： C09B1/28 ,  C09B1/503 ,  C09B11/10 ,  C09B11/20 ,  C09B11/22 ,  C09B11/26 ,  C09B11/28 ,  C09B29/00 ,  C09B31/02 ,  C09B67/0071 ,  Y10S8/907

    摘要： A process for the preparation of new dyestuff compositions which contain one or more basic dyestuffs in the form of dyestuff bases from the series of the triarylmethane, indoldiarylmethane, azine, oxazine, thiazine or xanthene dyestuffs or one or more basic dyestuffs of the series of the azo, anthraquinone, phthalocyanine, styryl, quinophthalone, benzoxanthene, naphthoylene-benzimidazole, naphthalimide or nitro series, carrying a primary, secondary or tertiary amino group or a guanidino or hydrazino group, as well as one or more non-ionic or slightly cationic surface-active agents and, optionally, water and/or an organic solvent miscible with water, which process comprises synthesizing the dyestuff in the surface-active agent optionally containing water and/or an organic solvent miscible with water, and then adding, if necessary, water and/or a solvent miscible with water and a further surface-active agent, this process of the invention having the advantage that an intermediate isolation, drying or grinding of the dyestuffs contained in the dyestuff compositions defined above is not necessary, so that the dyestuffs need not be introduced as substance into the surface-active agent and the solvent in a process wherein compositions of this type are prepared by a usual mixing, kneading or melting process; moreover, higher dyestuff yields are obtained in the dyestuff synthesis, and it allows to prepare dyestuff compositions from dyestuffs which are difficult to be isolated in substance after synthesis and often precipitate as oily or smeary products. The dyestuff compositions obtained according to the process of the invention, which are pastes or liquids, have a high stability upon storage. After being diluted with an aqueous solution of an amount at least equivalent to the dyestuff of an inorganic or organic acid, as well as, optionally, after the addition of dyeing and/or printing auxiliaries, the novel dyestuff compositions are suitable for dyeing or printing textile material containing acid groups.

    Process for the preparation of violet dyestuffs of the triphenylmethane series
    2.
    发明授权
    Process for the preparation of violet dyestuffs of the triphenylmethane series 失效
    制备三苯甲烷系列紫色染料的方法

    公开(公告)号：US4062877A

    公开(公告)日：1977-12-13

    申请号：US730207

    申请日：1976-10-06

    申请人： Manfred Hahnke ,  Theodor Papenfuhs

    发明人： Manfred Hahnke ,  Theodor Papenfuhs

    IPC分类号： C09B11/00 ,  C09B11/20 ,  C09B11/10

    CPC分类号： C09B11/20

    摘要： A novel process had been found for preparing novel violet dyestuffs of the triphenylmethane series which is characterized by that an aluminum chloride or borotrifluoride or iron-III-chloride-complex compound of a 4,4',4"-trihalogenotriphenylmethylhalide is reacted with phenyl- or naphthylamine which are substituted in the m- or p-position in a molar ratio of 1 to 1.5 at 110.degree. to 135.degree. C and in an inert organic solvent, and the mono-phenyl or -naphthylamino- substituted halide formed is reacted with 5 - 20 mols of an ortho-substituted phenyl- or naphthylamine at 150.degree. to 190.degree. C. The dyestuffs so prepared are well suitable for printing paper and plastics and dyeing polyacrylonitrile fibers.

    摘要翻译： 已经发现了一种制备三苯甲烷系列的新型紫色染料的新方法，其特征在于使4,4'，4“ - 三卤代三苯甲基卤化物的氯化铝或三氟化硼或三氯化铁络合物与苯基 - 或萘胺在110〜135℃的摩尔比为1〜1.5，在惰性有机溶剂中在m-或p-位上取代，形成的单苯基或 - 萘基氨基取代的卤化物反应 在150至190℃下加入5-20摩尔邻位取代的苯基或萘胺。如此制备的染料非常适合印刷纸张和塑料以及染色聚丙烯腈纤维。

    "> Process for the preparation of symmetric 4-halogen-4',4
    3.
    发明授权
    Process for the preparation of symmetric 4-halogen-4',4"-diarylamino-triphenylmethane compounds 失效
    对称4-卤素-4 {40,4 {41-二芳基氨基 - 三苯基甲烷化合物的制备方法

    公开(公告)号：US4041054A

    公开(公告)日：1977-08-09

    申请号：US587413

    申请日：1975-06-17

    申请人： Manfred Hahnke ,  Theodor Papenfuhs

    发明人： Manfred Hahnke ,  Theodor Papenfuhs

    IPC分类号： C09B11/00 ,  C09B11/20 ,  C09B11/10

    CPC分类号： C09B11/20

    摘要： An improved process for the preparation of symmetric 4-halogeno-4',4"-diarylamino-triphenyl-methane compounds by reacting a complex compound of a 4,4',4"-trihalogeno-triphenyl-methyl-halide and aliminiumchloride, iron(III)chloride or bortrifluoride with an aromatic amine, which is substituted in m- or p-position to the amino group, at an elevated temperature had been found wherein 1 mol of the complex compound is reacted with more than 4 mol of the aromatic amine and the so obtained complex compound from 4-halogen-4',4"-diarylamino-triphenyl-methyl-halide and aluminiumchloride, iron(III)chloride or bortrifluoride is subsequently converted into the anhydro- or carbinol base of the dyestuff with the aid of an aqueous alkali metal hydroxide solution whereupon the salt of the dyestuff is precipitated by addition of an acid in excess.This novel process obviates the formation of red mono- and blue tri-reaction products, the use of solvents and leads to very clean products which are very well suitable for spin-dyeing solutions.

    摘要翻译： 通过使4,4'，4“ - 三卤代 - 三苯甲基 - 卤化物和氯化铝的配合物反应制备对称4-卤代-4'，4” - 二芳基氨基 - 三苯基 - 甲烷化合物的改进方法 已经发现，在升高的温度下，已经发现在升高的温度下，与氨基取代m或对位的芳族胺的氯化铁（III）或三氟化硼，其中1摩尔的络合物与大于4摩尔 芳香胺和由此得到的4-卤素-4'，4“ - 二芳基氨基 - 三苯甲基卤化物和氯化铝，氯化铁（III）或三氟化硼的络合物随后转化为 借助于碱金属氢氧化物水溶液的染料，然后通过加入过量的酸沉淀染料的盐。

    Process for the spin-dyeing of polymers or copolymers of acrylonitrile
    4.
    发明授权
    Process for the spin-dyeing of polymers or copolymers of acrylonitrile 失效
    丙烯腈聚合物或共聚物的纺丝染色方法

    公开(公告)号：US4020037A

    公开(公告)日：1977-04-26

    申请号：US527414

    申请日：1974-11-26

    申请人： Manfred Hahnke ,  Theodor Papenfuhs ,  Wolfgang Teige

    发明人： Manfred Hahnke ,  Theodor Papenfuhs ,  Wolfgang Teige

    IPC分类号： C08L33/00 ,  C08J3/20 ,  C08K5/00 ,  C08L33/02 ,  C08L33/04 ,  C08L33/18 ,  D01F6/18 ,  D01F6/54 ,  D06P3/76 ,  C08L33/20 ,  D01F1/06

    CPC分类号： D01F6/18 ,  C08K5/0041 ,  D01F1/06 ,  D01F6/38

    摘要： The novel improved process of the invention for spin-dyeing of acid-modified polymers or copolymers of acrylonitrile with basic dyestuffs wherein the spinning solutions of the polymers contain the basic dyestuffs in form of their free dyestuff bases as anhydro or carbinol bases is conducted with completely transparent spinning solutions avoiding clogging and mechanical abrasion of the spinning nozzles and yields filaments and fibers which do not show matting effects but have a high tinctorial strength and good and improved fastnesses to rubbing, to light and to wet-processing.

    摘要翻译： 酸改性聚合物或丙烯腈共聚物与碱性染料的纺丝染色的本发明改进方法，其中聚合物的纺丝溶液含有作为脱水或甲醇碱的游离染料碱形式的碱性染料，完全用 透明的纺丝溶液，避免纺丝喷嘴的堵塞和机械磨损，并产生细丝和纤维，其不显示消光效果，但具有高着色强度，并且具有良好和改善的耐摩擦牢度，耐光照和湿润加工性。

    Process for the preparation of hydroxycarboxanilides
    7.
    发明授权
    Process for the preparation of hydroxycarboxanilides 失效
    羟基羧酰苯胺的制备方法

    公开(公告)号：US5631403A

    公开(公告)日：1997-05-20

    申请号：US493272

    申请日：1995-06-21

    申请人： Andreas Dierdorf ,  Siegfried Planker ,  Theodor Papenfuhs

    发明人： Andreas Dierdorf ,  Siegfried Planker ,  Theodor Papenfuhs

    IPC分类号： C07C231/12 ,  C07C235/16 ,  C07C253/30 ,  C07C233/05 ,  C07C233/88

    CPC分类号： C07C235/16 ,  C07C231/12 ,  C07C253/30

    摘要： The present invention relates to a process for the preparation of hydroxycarboxanilides of the formula (1) ##STR1## in which R.sup.1 and R.sup.2 are identical or different and are hydrogen, halogen, a nitro group, a cyano group, a straight-chain or branched alkyl, alkenyl, alkynyl or alkoxy group having 1 to 12 carbon atoms, an aralkyl group having 7 to 12 carbon atoms, a cycloalkyl group having 6 to 12 carbon atoms or an aryl group having 6 to 12 carbon atoms, R.sup.3 is hydrogen or a straight-chain or branched alkyl group having 1 to 12 carbon atoms and n is an integer from 1 to 12, by reacting a halocarboxanilide of the formula (2) ##STR2## in which R.sup.1, R.sup.2, R.sup.3 and n have the same meaning as in formula (1) and Hal is chlorine, bromine or iodine, with a basic compound in a solvent mixture comprising water and one or more polar aprotic solvents at a temperature of 40.degree. to 180.degree. C.

    摘要翻译： 本发明涉及制备式（1）的羟基羧酰苯胺的方法，其中R 1和R 2相同或不同，为氢，卤素，硝基，氰基， 具有1至12个碳原子的直链或支链烷基，烯基，炔基或烷氧基，具有7至12个碳原子的芳烷基，具有6至12个碳原子的环烷基或具有6至12个碳原子的芳基，R3是 氢或具有1至12个碳原子的直链或支链烷基，n为1至12的整数，通过使式（2）的卤代甲酰苯胺（2）反应，其中R 1，R 2，R 3和 n具有与式（1）中相同的含义，Hal是氯，溴或碘，在含有水和一种或多种极性非质子溶剂的溶剂混合物中，在40至180℃的温度下使用碱性化合物。