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公开(公告)号：US06303826B1
公开(公告)日：2001-10-16
申请号：US09487656
申请日：2000-01-19
申请人： Manoj V. Bhinde , Scott R. Keenan
发明人： Manoj V. Bhinde , Scott R. Keenan
IPC分类号： C07C4590
摘要： A method for purification of acetone containing at least one oxidizable impurity. The method comprises the steps of: (a) contacting acetone containing at least one oxidizable impurity with a heterogeneous oxidation catalyst in the presence of oxygen for a time and at a temperature sufficient to oxidize at least a portion of at least one of the oxidizable impurities; and (b) substantially separating purified acetone from the resulting mixture obtained from step (a).
摘要翻译： 一种纯化含有至少一种可氧化杂质的丙酮的方法。 该方法包括以下步骤：（a）在氧气存在下使包含至少一种可氧化杂质的丙酮与异相氧化催化剂接触一段时间，并且在足以氧化至少一部分可氧化杂质的温度 ; 和（b）从得自步骤（a）得到的混合物中基本上分离纯化的丙酮。
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2.发明授权Alkane oxidation with porphyrins and metal complexes thereof having haloalkyl side chains 失效卟啉及其具有卤代烷基侧链的金属络合物的烷烃氧化
公开(公告)号：US5770728A
公开(公告)日：1998-06-23
申请号：US769814
申请日：1996-12-19
IPC分类号： B01J31/18 , C07C29/132 , C07C29/50 , C07C45/33 , C07C45/36 , C07C45/53 , C07D487/22 , C07D519/00 , C07F15/02 , C07C45/32
CPC分类号： C07F15/025 , B01J31/1815 , C07C29/132 , C07C29/50 , C07C45/33 , C07C45/36 , C07C45/53 , C07D487/22 , C07D519/00 , C12C11/02 , B01J2531/025 , B01J2531/842 , C07C2101/14 , C07C2101/16
摘要： Transition metal complexes of meso-haloalkylporphyrins, wherein the haloalkyl groups contain 2 to 8 carbon atoms have been found to be highly effective catalysts for oxidation of alkanes and for the decomposition of hydroperoxides.
摘要翻译： 已经发现，其中卤代烷基含有2至8个碳原子的内消旋烷基卟啉的过渡金属络合物是用于烷烃氧化和氢过氧化物分解的高效催化剂。
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公开(公告)号：US5723697A
公开(公告)日：1998-03-03
申请号：US580918
申请日：1995-12-29
申请人： Manoj V. Bhinde , Thomas W. Bierl
发明人： Manoj V. Bhinde , Thomas W. Bierl
IPC分类号： B01J31/22 , C07B61/00 , C07C29/50 , C07C31/04 , C07C31/08 , C07C31/10 , C07C31/12 , C07C31/125
CPC分类号： C07C29/50
摘要： The presence of a base in the reaction mixture in a metal-ligand catalyzed partial oxidation of alkanes results in sustained catalyst activity, and in greater percent conversion as compared with oxidation in the absence of base, while maintaining satisfactory selectivity for the desired oxidation, for example the oxidation of isobutane to isobutanol.
摘要翻译： 在金属 - 配体催化的烷烃部分氧化中，反应混合物中碱的存在导致持续的催化剂活性，并且在不存在碱的情况下与氧化相比转化率更高百分比，同时保持对所需氧化的令人满意的选择性， 例如异丁烷氧化成异丁醇。
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4.发明授权
公开(公告)号：US5672778A
公开(公告)日：1997-09-30
申请号：US703423
申请日：1996-08-26
IPC分类号： A62D3/00 , A62D3/37 , A62D101/28 , B01J31/22 , C07B61/00 , C07C27/00 , C07C29/132 , C07C31/12 , C07C35/08 , C07C45/53 , C07C407/00 , C07C29/48 , C07C27/10 , C07C31/02
CPC分类号： C07C45/53 , A62D3/37 , C07C29/132 , C07C31/12 , C07C35/08 , C07C407/003 , A62D2101/28 , C07C2101/14
摘要： The invention comprises a method for the catalytic conversion of alkanes and alkylhydroperoxides to oxygenates, particularly alcohols, comprising the oxidation of alkanes to yield alkylhydroperoxides, alcohols, other reaction products and unreacted alkane, and the decomposition of said alkylhydroperoxides to form alcohols and oxygen. Decomposition of the alkylhydroperoxide in the presence of unreacted alkane increases the yield of alcohol. The process further comprises drying of the reaction mixture comprising alkylhydroperoxide. Suitable catalysts for the process of the invention comprise metal containing catalysts, including metal organic ligand catalysts such as unsubstituted and substituted metal complexes of porphyrins, phthalocyanines and acetylacetonates.
摘要翻译： 本发明包括将烷烃和烷基氢过氧化物催化转化为含氧化合物，特别是醇的方法，其包括烷烃的氧化以产生烷基氢过氧化物，醇，其它反应产物和未反应的烷烃，以及所述烷基氢过氧化物分解形成醇和氧。 在未反应的烷烃存在下分解烷基氢过氧化物可提高醇的产率。 该方法还包括干燥包含烷基过氧化氢的反应混合物。 用于本发明方法的合适的催化剂包括含金属的催化剂，包括金属有机配体催化剂，例如卟啉，酞菁和乙酰丙酮化合物的未取代和取代的金属络合物。
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公开(公告)号：US5608054A
公开(公告)日：1997-03-04
申请号：US405684
申请日：1995-03-17
IPC分类号： B01J31/18 , C07C29/132 , C07C29/50 , C07C45/33 , C07C45/36 , C07C45/53 , C07D487/22 , C07D519/00 , C07F15/02
CPC分类号： C07F15/025 , B01J31/1815 , C07C29/132 , C07C29/50 , C07C45/33 , C07C45/36 , C07C45/53 , C07D487/22 , C07D519/00 , C12C11/02 , B01J2531/025 , B01J2531/842 , C07C2101/14 , C07C2101/16
摘要： Transition metal complexes of meso-haloalkylporphyrins, wherein the haloalkyl groups contain 2 to 8 carbon atoms have been found to be highly effective catalysts for oxidation of alkanes and for the decomposition of hydroperoxides.
摘要翻译： 已经发现，其中卤代烷基含有2至8个碳原子的内消旋烷基卟啉的过渡金属络合物是用于烷烃氧化和氢过氧化物分解的高效催化剂。
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公开(公告)号：US5550301A
公开(公告)日：1996-08-27
申请号：US398024
申请日：1995-03-03
IPC分类号： A62D3/00 , A62D3/37 , A62D101/28 , B01J31/22 , C07B61/00 , C07C27/00 , C07C29/132 , C07C31/12 , C07C35/08 , C07C45/53 , C07C407/00 , C07C29/00 , C07C33/22 , C07C35/14
CPC分类号： C07C45/53 , A62D3/37 , C07C29/132 , C07C31/12 , C07C35/08 , C07C407/003 , A62D2101/28 , C07C2101/14
摘要： Organic hydroperoxides are decomposed by drying a reaction mixture containing the organic hydroperoxide and an organic solvent such that said dried reaction mixture comprises approximately 1 weight percent or less of water and contacting the dried reaction mixture with a metal organic ligand catalyst under hydroperoxide decomposition conditions. An organic co-solvent for the hydroperoxide may also be used. Particularly effective catalysts are cobalt acetylacetonates and ruthenium acetylacetonates and combinations thereof.
摘要翻译： 通过干燥含有机氢过氧化物和有机溶剂的反应混合物来分解有机氢过氧化物，使得所述干燥的反应混合物包含约1重量％或更少的水，并在氢过氧化物分解条件下使干燥的反应混合物与金属有机配体催化剂接触。 也可以使用氢过氧化物的有机助溶剂。 特别有效的催化剂是乙酰丙酮钴和乙酰丙酮钌及其组合。
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7.发明授权
公开(公告)号：US5494569A
公开(公告)日：1996-02-27
申请号：US184159
申请日：1994-01-21
IPC分类号： B01J27/053 , C10G47/14
CPC分类号： B01J27/053
摘要： A hydrocracking process is provided which process utilizes a sulfated solid catalyst comprising (1) oxide or hydroxide of Group III or Group IV element, e.g. zirconium, and (2) a first metal comprising a metal or combination of metals selected from the group consisting of platinum, palladium, nickel, platinum and rhenium, and platinum and tin. The catalyst may further comprise (3) a second metal selected from the group consisting of Group VIII elements, e.g. iron. One embodiment of the invention further comprises (4) a third metal selected from the group consisting of Group V, VI and VII elements, e.g. manganese.
摘要翻译： 提供加氢裂化方法，该方法利用硫酸化固体催化剂，其包含（1）III族或IV族元素的氧化物或氢氧化物，例如 锆，和（2）包含选自铂，钯，镍，铂和铼的金属或金属组合的第一金属以及铂和锡。 催化剂还可以包含（3）选自VIII族元素的第二种金属，例如。 铁。 本发明的一个实施方案还包括（4）选自第V，VI和VII族元素的第三种金属，例如。 锰。
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公开(公告)号：US07037480B2
公开(公告)日：2006-05-02
申请号：US10820395
申请日：2004-04-08
申请人： Manoj V. Bhinde
发明人： Manoj V. Bhinde
CPC分类号： C01F11/32 , Y10S210/915
摘要： Significant amounts of soluble fluoride, known to create problems in processes requiring high quality grade calcium chloride, are removed from calcium chloride solution using hydroxyapatite as a removal mechanism. Under acidic conditions, calcium chloride solution is purified to about less than 10 ppm fluoride, significantly, to less than 1 ppm fluoride. At least 0.1 weight percent hydroxyapatite and concentrated hydrochloric acid are added to calcium chloride solution and slurried to remove fluoride and create a highly purified calcium chloride solution, substantially free of fluoride.
摘要翻译： 使用羟基磷灰石作为去除机理，从氯化钙溶液中除去大量可溶性氟化物，已知在需要高品质级氯化钙的方法中产生问题。 在酸性条件下，将氯化钙溶液纯化至大约低于10ppm的氟化物，显着地提纯至小于1ppm的氟化物。 将至少0.1重量％的羟基磷灰石和浓盐酸加入到氯化钙溶液中并浆化以除去氟化物，并产生基本上不含氟化物的高度纯化的氯化钙溶液。
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公开(公告)号：US07002048B2
公开(公告)日：2006-02-21
申请号：US10944315
申请日：2004-09-16
IPC分类号： C07L37/68
摘要： A method is provided for the efficient, low cost removal of acetol from a phenol stream. The method results in removal of substantially all of the acetol from the phenol stream without the formation of substantial amounts of additional methylbenzofuran. The method also avoids the use of expensive reagents and capital intensive distillation equipment.
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公开(公告)号：US5767272A
公开(公告)日：1998-06-16
申请号：US769974
申请日：1996-12-19
IPC分类号： B01J31/18 , C07C29/132 , C07C29/50 , C07C45/33 , C07C45/36 , C07C45/53 , C07D487/22 , C07D519/00 , C07F15/02
CPC分类号： C07F15/025 , B01J31/1815 , C07C29/132 , C07C29/50 , C07C45/33 , C07C45/36 , C07C45/53 , C07D487/22 , C07D519/00 , C12C11/02 , B01J2531/025 , B01J2531/842 , C07C2101/14 , C07C2101/16
摘要： Transition metal complexes of meso-haloalkylporphyrins, wherein the haloalkyl groups contain 2 to 8 carbon atoms have been found to be highly effective catalysts for oxidation of alkanes and for the decomposition of hydroperoxides. Also disclosed is a process for the preparation of meso-halocarbyl-porphyrins which comprises contacting a halocarbyl dipyrromethane with a halocarbyl-substituted aldehyde in the presence of an acid granular solid catalyst. Also disclosed is a process for the preparation of meso-halocarbyl-porphyrins which comprises contacting a halocarbyl dipyrromethane with a halocarbyl-substituted aldehyde in the presence of an acid granular solic catalyst.
摘要翻译： 已经发现，其中卤代烷基含有2至8个碳原子的内消旋烷基卟啉的过渡金属络合物是用于烷烃氧化和氢过氧化物分解的高效催化剂。 还公开了一种制备内消旋咔咔卟啉的方法，其包括在酸性颗粒状固体催化剂存在下使卤代烃基二吡咯烷与卤代烃基取代的醛接触。 还公开了制备内消旋咔咔卟啉的方法，其包括在酸性颗粒状催化剂存在下使卤代烃基二吡咯烷与卤代烃基取代的醛接触。
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