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公开(公告)号:US20160340293A1
公开(公告)日:2016-11-24
申请号:US15104822
申请日:2014-12-19
申请人: Mansour TAFTAF , Jaiprakash Brijlal SAINANI , Vladimir Aleksandrovich ZAKHAROV , Gennadii Dimitrievich BUKATOV , Vimalkumar Mahendrabhai PATEL , Sergei Andreevich SERGEEV , Martin Alexander ZUIDEVELD , Aurora Alexandra BATINAS-GEURTS , Nourdin GHALIT , SAUDI BASIC INDUSTRIES CORPORATION , SABIC GLOBAL TECHNOLOGIES B.V.
发明人: Mansour I. TAFTAF , Jaiprakash Brijlal SAINANI , Vladimir Aleksandrovich ZAKHAROV , Gennadii Dimitrievich BUKATOV , Vimalkumar Mahendrabhai PATEL , Sergei Andreevich SERGEEV , Martin Alexander ZUIDEVELD , Aurora Alexandra BATINAS-GEURTS , Nourdin GHALIT
IPC分类号: C07C233/69 , C07C235/48 , C08F110/06 , C07C233/18
CPC分类号: C07C233/69 , B01J31/0202 , B01J2231/64 , B01J2531/007 , C07C233/18 , C07C235/48 , C08F110/06 , C08F2410/01 , C08F4/651 , C08F2500/04 , C08F2500/12 , C08F2500/15 , C08F4/6565
摘要: A catalyst composition including the compound of Formula I as an internal electron donor, wherein: R1, R2, R3, R4, R5 and R6 are independently selected from a group consisting of hydrogen, straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; R7 is selected from a group consisting of straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; and R8 is selected from a group consisting of aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms. Also disclosed is a process for preparing said polymerization catalyst composition; a polymerization catalyst system comprising said catalyst composition, a co-catalyst and optionally an external electron donor; a polyolefin obtainable by the process; and use of the compound of Formula I as in internal electron donor in catalysts for polymerization of olefins.
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公开(公告)号:US20170129974A1
公开(公告)日:2017-05-11
申请号:US15406124
申请日:2017-01-13
申请人: Mansour TAFTAF , Jaiprakash Brijlal SAINANI , Vladimir Aleksandrovich ZAKHAROV , Gennadii Dimitrievich BUKATOV , Vimalkumar Mahendrabhai PATEL , Sergei Andreevich SERGEEV , Martin Alexander Zuideveld , Aurora Alexandra BATINAS-GEURTS
发明人: Mansour TAFTAF , Jaiprakash Brijlal SAINANI , Vladimir Aleksandrovich ZAKHAROV , Gennadii Dimitrievich BUKATOV , Vimalkumar Mahendrabhai PATEL , Sergei Andreevich SERGEEV , Martin Alexander Zuideveld , Aurora Alexandra BATINAS-GEURTS
IPC分类号: C08F110/06
CPC分类号: C08F110/06 , C07C233/18 , C07C233/23 , C07C233/69 , C07C2601/14 , C08F4/649 , C08F4/6546 , C08F4/655 , C08F10/06 , C08F10/00 , C08F4/6565 , C08F4/651 , C08F2500/04 , C08F2500/12 , C08F2500/24
摘要: The present invention relates to a process for preparing a catalyst component for polymerization of an olefin comprising the steps of: i) contacting a compound R9zMgXz2-z wherein R9 is aromatic, aliphatic or cyclo-aliphatic group containing up to 20 carbon atoms, X is a halide, and z is in a range of larger than 0 and smaller than 2, with an alkoxy- or aryloky-containing silane compound pound to given first intermediate reaction product; ii) contacting the first intermediate reaction product with at least one activating compound selected from the group formed by electron donors and compounds of formula M(OR10)v-w(OR11)w, wherein M can be Ti, Zr, HI, Al or Si, and M(OR10)v-w(R11)w, wherein M is Si, each R10 and R11, independently, represent an alkyl, alkenyl or aryl group, v is the valency of M, v being either 3 or 4, and w is smaller than v, to give a second intermediate reaction product; and iii) contacting the second intermediate reaction product with a halogen-containing Ti-compound, a monoester as activating agent, a 1,3-diether as an internal electron donor, and optionally a diester as an additional internal electron donor.
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公开(公告)号:US20150353656A1
公开(公告)日:2015-12-10
申请号:US14762279
申请日:2014-01-28
申请人: Mansour TAFTAF , Jaiprakash Brijlal SAINANI , Vladimir Aleksandrovich ZAKHAROV , Gennadii Dimitrievich BUKATOV , Mahendrabhai Patel VIMALKUMAR , Sergei Andreevich GEEV , Martin Alexander ZUIDEVELD , Aurora Alexandra BATINAS-GEURTS , SAUDI BASIC INDUSTRIES CORPORATION
发明人: Mansour TAFTAF , Jaiprakash Brijlal SAINANI , Vladimir Aleksandrovich ZAKHAROV , Gennadii Dimitrievich BUKATOV , Vimalkumar Mahendrabhai PATEL , Sergei Andreevich SERGEEV , Martin Alexander ZUIDEVELD , Aurora Alexandra BATINAS-GEURTS
IPC分类号: C08F110/06 , C07C233/23 , C07C233/18 , C07C233/69
CPC分类号: C08F110/06 , C07C233/18 , C07C233/23 , C07C233/69 , C07C2601/14 , C08F4/649 , C08F4/6546 , C08F4/655 , C08F10/06 , C08F10/00 , C08F4/6565 , C08F4/651 , C08F2500/04 , C08F2500/12 , C08F2500/24
摘要: A catalyst composition comprising a monoester, the compound represented by formula (I) as an internal electron donor, and optionally an additional internal electron donor selected from a group consisting of diesters and diethers, wherein: R1, R2, R3, R4, R5 and R6 are hydrogen, straight, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms, R7 is a straight, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms, and R8 is an aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms. Also described is a process for preparing the polymerization catalyst composition, a polymerization catalyst system comprising the catalyst composition, a co-catalyst and optionally an external electron donor; and use of the catalyst system for polymerization of olefins.
摘要翻译: 一种催化剂组合物,其包含单酯,由式(I)表示的作为内电子给体的化合物,以及任选的另外的选自二酯和二醚的内给电子体,其中:R1,R2,R3,R4,R5和 R6是氢,具有至多20个碳原子的直链,支链和环状烷基,以及具有6至20个碳原子的芳族取代和未取代的烃基,R7是具有至多20个碳原子的直链,支链和环状烷基,芳基取代和未取代的烃基 具有6至20个碳原子,并且R 8是具有6至20个碳原子的芳族取代和未取代的烃基。 还描述了制备聚合催化剂组合物的方法,包含催化剂组合物,助催化剂和任选的外电子给体的聚合催化剂体系; 以及催化剂体系用于烯烃聚合的用途。
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