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    Process for the preparation of a metal-organic compound comprising at least one imine ligand
    3.
    发明授权
    Process for the preparation of a metal-organic compound comprising at least one imine ligand 有权
    制备包含至少一种亚胺配体的金属 - 有机化合物的方法

    公开(公告)号：US07655592B2

    公开(公告)日：2010-02-02

    申请号：US10567098

    申请日：2004-08-03

    Applicant: Edwin Ijpeij ,  Henricus Arts ,  Gerardus van Doremaele ,  Felix Beijer ,  Francis Van Der Burgt ,  Martin Alexander Zuideveld

    Inventor： Edwin Ijpeij ,  Henricus Arts ,  Gerardus van Doremaele ,  Felix Beijer ,  Francis Van Der Burgt ,  Martin Alexander Zuideveld

    IPC: C08F4/6592 ,  B01J31/12 ,  C07F17/00

    CPC classification number: C08F10/00 ,  C07F7/00 ,  C07F7/28 ,  C07F7/30 ,  C07F9/00 ,  C07F9/5355 ,  C07F17/00 ,  C07F19/00 ,  C08F4/65908 ,  C08F4/6592 ,  C08F210/06 ,  C08F210/16 ,  C08F2420/04 ,  C08F2500/17

    Abstract: The invention relates to a process for the preparation of a metal-organic compound, comprising at least one phosphinimine ligand, characterized in that the HA adduct of a phosphinimine ligand according to formula (1) is contacted with a metal-organic reagent of formula (2) in the presence of at least 2 equivalents of a base, wherein HA represents an acid, of which H represents its proton and A its conjugate base, with Y═N—H as formula (1), and Mv(L1)k(L2)1(L3)m(L4)nX as formula (2), and wherein Y is a substituted phosphorous atom, and M represents a group 4 or group 5 metal ion, V represents the valency of the metal ion, being 3, 4 or 5 L1, L2, L3, and L4 represent a ligand or a group 17 halogen atom on M and may be equal or different, k, l, m, n=0, 1, 2, 3, 4 with k+l+m+n+l=V, and X represents a group 17 halogen atom. The invention further relates to a process for the preparation of a polyolefin by making a metal-organic compound according to the process of the invention, wherein the base is an olefin polymerisation compatible base, which metal-organic compound is activated anywhere in, or before a polymerisation reactor.

    Abstract translation: 本发明涉及一种制备金属有机化合物的方法，其包括至少一种膦亚胺配体，其特征在于将根据式（1）的膦亚胺配体的HA加合物与式（1）的金属有机试剂 2）在至少2当量的碱的存在下，其中HA表示酸，其中H表示其质子，A表示其共轭碱，YNH为式（1），Mv（L1）k（L2）1 （L3）m（L4）nX，其中Y是取代的磷原子，M表示第4族或第5族金属离子，V表示金属离子的化合价，为3,4或5 L1，L2，L3和L4表示M上的配体或17族卤素原子，并且可以相同或不同，k，l，m，n = 0,1,2,3,4，其中k + 1 + m + n + 1 = V，X表示17族卤素原子。 本发明还涉及通过制备根据本发明方法的金属 - 有机化合物来制备聚烯烃的方法，其中所述碱是烯烃聚合相容性碱，所述金属 - 有机化合物在任何地方或之前被活化 聚合反应器。

    Process for the Preparation of a Metal-Organic Compound Comprising at Least One Imine Ligand
    4.
    发明申请
    Process for the Preparation of a Metal-Organic Compound Comprising at Least One Imine Ligand 有权
    用于制备包含至少一种亚胺配体的金属有机化合物的方法

    公开(公告)号：US20080045719A1

    公开(公告)日：2008-02-21

    申请号：US10567098

    申请日：2004-08-03

    Applicant: Edwin Ijpeij ,  Henricus Arts ,  Gerardus van Doremaele ,  Felix Beijer ,  Francis Van Der Burgt ,  Martin Alexander Zuideveld

    Inventor： Edwin Ijpeij ,  Henricus Arts ,  Gerardus van Doremaele ,  Felix Beijer ,  Francis Van Der Burgt ,  Martin Alexander Zuideveld

    IPC: C07D233/00 ,  C07F9/02

    CPC classification number: C08F10/00 ,  C07F7/00 ,  C07F7/28 ,  C07F7/30 ,  C07F9/00 ,  C07F9/5355 ,  C07F17/00 ,  C07F19/00 ,  C08F4/65908 ,  C08F4/6592 ,  C08F210/06 ,  C08F210/16 ,  C08F2420/04 ,  C08F2500/17

    Abstract: The invention relates to a process for the preparation of a metal-organic compound, comprising at least one phosphinimine ligand, characterized in that the HA adduct of a phosphinimine ligand according to formula (1) is contacted with a metal-organic reagent of formula (2) in the presence of at least 2 equivalents of a base, wherein HA represents an acid, of which H represents its proton and A its conjugate base, with Y═N—H as formula (1), and Mv(L1)k(L2)1(L3)m(L4)nX as formula (2), and wherein Y is a substituted phosphorous atom, and M represents a group 4 or group 5 metal ion, V represents the valency of the metal ion, being 3, 4 or 5 L1, L2, L3, and L4 represent a ligand or a group 17 halogen atom on M and may be equal or different, k, l, m, n=0, 1, 2, 3, 4 with k+l+m+n+l=V, and X represents a group 17 halogen atom. The invention further relates to a process for the preparation of a polyolefin by making a metal-organic compound according to the process of the invention, wherein the base is an olefin polymerisation compatible base, which metal-organic compound is activated anywhere in, or before a polymerisation reactor.

    Abstract translation: 本发明涉及一种制备金属有机化合物的方法，其包括至少一种膦亚胺配体，其特征在于将根据式（1）的膦亚胺配体的HA加合物与式（1）的金属有机试剂 2）在至少2当量碱的存在下，其中HA代表酸，其中H代表其质子，A代表其共轭碱，YNH如式（1）所示，M代表氢， （L 1/2）2（L 3）（L 1） （2），其中Y是取代的磷原子，M表示4或4位的基团（L 4） 5金属离子，V表示金属离子的化合价，为3,4或5个L 1，L 2，L 3 3和 L 4代表M上的配位体或17族卤素原子，可以相同或不同，k，l，m，n = 0,1,2,3,4，其中k + 1 + m + n + 1 = V，X表示17族卤素原子。 本发明还涉及通过制备根据本发明方法的金属 - 有机化合物来制备聚烯烃的方法，其中所述碱是烯烃聚合相容性碱，所述金属 - 有机化合物在任何地方或之前被活化 聚合反应器。

    BORANE ACTIVATED TITANIUM CATALYST SYSTEM COMPRISING GUANIDINE AND DIENE LIGANDS
    7.
    发明申请
    BORANE ACTIVATED TITANIUM CATALYST SYSTEM COMPRISING GUANIDINE AND DIENE LIGANDS 审中-公开
    BORANE活性钛催化剂体系，包括胍类和二胺配位体

    公开(公告)号：US20140249283A1

    公开(公告)日：2014-09-04

    申请号：US14008863

    申请日：2012-03-29

    Applicant: Van Gerardus Henricus Josephus Doremaele ,  Martin Alexander Zuideveld ,  Victor Fidel Quiroga Norambuena ,  Philip Mountford ,  Richard Scott

    Inventor： Van Gerardus Henricus Josephus Doremaele ,  Martin Alexander Zuideveld ,  Victor Fidel Quiroga Norambuena ,  Philip Mountford ,  Richard Scott

    IPC: C08F4/642

    CPC classification number: C08F10/02 ,  C08F4/65908 ,  C08F4/65912 ,  C08F110/02 ,  C08F2420/04 ,  C08F4/6592 ,  C08F210/16 ,  C08F210/06

    Abstract: The invention relates to a catalyst system for the polymerization of olefms comprising a metal complex of formula and an activating cocatalyst, wherein M is titanium, Cy is a cyclopentadienyl-type ligand, D is a diene, L is a guanidinate-containing ligand of the formula wherein each A is independently selected from nitrogen or phosphorous and R, R 1,R2 and R3 are independently selected from the group consisting of hydrogen, hydrocarbyl, silyl and germyl residues, substituted or not with one or more halogen, amido, phosphido, alkoxy, or aryloxy radicals, and the activating cocatalyst is a boron compound represented by the general formula BR4R5R6, wherein B is a boron atom in the trivalent valence state and R4, R5 and R6 are individually selected from the group consisting of halogen atom, hydrocarbyl, halogenated hydrocarbyl, substituted silyl, alkoxy or di-substituted amino residue. The invention further relates to a process for the preparation of a polymer comprising at least one aliphatic or aromatic hydrocarbyl C2-20 olefin wherein the at least one aliphatic or aromatic olefm is contacted with the catalyst system of the present invention.

    Abstract translation: 本发明涉及一种用于烯烃聚合的催化剂体系，其包括式的金属配合物和活化助催化剂，其中M是钛，Cy是环戊二烯基型配体，D是二烯，L是含胍基的配体 其中每个A独立地选自氮或磷，R 1，R 2，R 2和R 3独立地选自氢，烃基，甲硅烷基和己基残基，被一个或多个卤素，酰胺基，磷酰基， 烷氧基或芳氧基，活化助催化剂是由通式BR4R5R6表示的硼化合物，其中B是三价价态的硼原子，R4，R5和R6分别选自卤素原子，烃基 卤代烃基，取代的甲硅烷基，烷氧基或二取代的氨基残基。 本发明还涉及制备包含至少一种脂族或芳族烃基C 2-20烯烃的聚合物的方法，其中所述至少一种脂族或芳族烯烃与本发明的催化剂体系接触。

    Process for the preparation of a metal-organic compound comprising a spectator ligand
    8.
    发明申请
    Process for the preparation of a metal-organic compound comprising a spectator ligand 失效
    制备包含观察配体的金属 - 有机化合物的方法

    公开(公告)号：US20090137830A1

    公开(公告)日：2009-05-28

    申请号：US12066468

    申请日：2006-09-13

    Applicant: Edwin Gerard Ijpeij ,  Martin Alexander Zuideveld ,  Henricus Johannes Arts ,  Francis Van Der Burgt ,  Gerardus Henricus Josephus Van Doremaele

    Inventor： Edwin Gerard Ijpeij ,  Martin Alexander Zuideveld ,  Henricus Johannes Arts ,  Francis Van Der Burgt ,  Gerardus Henricus Josephus Van Doremaele

    IPC: C07F7/28

    CPC classification number: C07F7/28 ,  C08F4/65912 ,  C08F10/00 ,  C08F210/18 ,  C08F4/6592 ,  C08F210/06 ,  C08F232/00 ,  C08F2500/03

    Abstract: The invention relates to a process for the production of an organometallic compound according to formula (1): MALjYrX(p·(n+v+r)Rn (formula 1) where: M is a metal of groups 3-13 or the lanthanide series, and p is the valency of the metal M, A represents an anionic spectator ligand whose valency v is 1 or 2, Y is a spectator ligand represented by formula (2): wherein the spectator ligand is covalently bonded to the metal M via the imine nitrogen atom, Sub1 is a substituent, which comprises a group 14 atom through which SUb1 is bonded to the imine carbon atom, Sub2 is a substituent, which comprises an atom of groups 15-16, through which Sub2 is bonded to the imine carbon atom, sub1 and sub2 might be connected to each other forming a ring system, r is an integer>0, L is an optional neutral Lewis basic ligand, j is an integer denoting the number of neutral ligands L, X is an halide, and R is an anionic ligand, wherein an organometallic reagent according to formula (3), MALjXp−v (formula 3), is contacted with an alkylating agent, thus forming a precursor in which at least one of the halide atoms is replaced by an anionic ligand R that may be independently selected from the group consisting of alkyl, arylalkyl, aryl, or a combination thereof, which precursor is subsequently contacted with an imine according to formula (2).

    Abstract translation: 本发明涉及一种制备根据式（1）的有机金属化合物的方法：MALjYrX（p。（n + v + r）Rn（式1）其中：M是3-13族金属或镧系元素 并且p是金属M的化合价，A表示其价态v为1或2的阴离子观察配体，Y为由式（2）表示的旁观者配体：其中旁观者配体与金属M共价键合，通过 亚胺氮原子，Sub1是一个取代基，它包括一个14族原子，SUb1通过该原子与亚胺碳原子键合，Sub2是一个取代基，它包含一个第15-16族的原子，Sub2通过它与亚胺键合 碳原子，亚1和亚2可以彼此连接形成环系，r是> 0的整数，L是任选的中性路易斯碱性配体，j是表示中性配体L的数的整数，X是卤素， 并且R是阴离子配体，其中根据式（3）的有机金属试剂，MALjXp-v（式3）， 与烷基化剂接触，从而形成其中至少一个卤素原子被可独立地选自烷基，芳烷基，芳基或其组合的阴离子配体R代替的前体，该前体 随后与式（2）的亚胺接触。

    Polymerization Catalyst Comprising Amidine Ligand
    9.
    发明申请
    Polymerization Catalyst Comprising Amidine Ligand 有权
    包含脒配体的聚合催化剂

    公开(公告)号：US20090012246A1

    公开(公告)日：2009-01-08

    申请号：US10592861

    申请日：2005-03-14

    Applicant: Edwin Ijpeij ,  Henricus Arts ,  Gerardus van Doremaele ,  Peter Windmuller ,  Francis Van der Burgt ,  Martin Alexander Zuideveld

    Inventor： Edwin Ijpeij ,  Henricus Arts ,  Gerardus van Doremaele ,  Peter Windmuller ,  Francis Van der Burgt ,  Martin Alexander Zuideveld

    IPC: B01J31/12 ,  C08F4/76 ,  C07F7/28 ,  C07D209/14 ,  C08F110/02

    CPC classification number: C08F10/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F210/18 ,  C08F236/20 ,  C08F2420/04 ,  C08F4/6592 ,  C08F210/06 ,  C08F2500/25 ,  C08F2500/03 ,  C08F2500/17

    Abstract: The invention relates to a process for the preparation of a polymer comprising at least one aliphatic or aromatic hydrocarbyl C2-20 olefin in the presence of an ionic catalyst comprising an organometallic compound and an activator, and optionally a scavenger, characterized in that the organometallic compound is a compound according to formula (1): where: M is a metal of group 3, 4, 5, 6 or 7, or the lanthanide series, and p is the valency of the metal M, A represents a neutral or anionic spectator ligand whose valency v is 0, 1 or 2, and q is an integer denoting the number of spectator ligands A, Z is an optional bridging moiety, n is the integer number of parallel bridging moieties Z, Y is an amidine-containing spectator ligand represented by formula (2): wherein the amidine-containing ligand is covalently bonded to the metal M via the imine nitrogen atom, Sub1 is a substituent, which comprises a group 14 atom through which Sub1 is bonded to the imine carbon atom. Sub2 is a substituent, which comprises a heteroatom of group 15-16, through which Sub2 is bonded to the imine carbon atom, r is an integer >0, L is an optional neutral Lewis basic ligand, j is an integer denoting the number of neutral ligands L, and X is an anionic ligand. The invention further relates to a organometallic compound according to formula (1) and a process for the preparation of this compound as well as to a UHMWPE having a weight average molecular weight of at least 4.000 kg/mol and a molecular weight distribution Mw/Mn of less than 2.6.

    Abstract translation: 本发明涉及在包含有机金属化合物和活化剂的离子催化剂和任选的清除剂的存在下，制备包含至少一种脂族或芳族烃基C 2-20烯烃的聚合物的方法，其特征在于有机金属化合物 是根据式（1）的化合物：其中：M是第3,4,5,6或7族的金属或镧系，p是金属M的化合价，A代表中性或阴离子观察者 配位体的化合价v为0,1或2，q为表示配体A的数的整数，Z为任选的桥连部分，n为平行桥连部分Z的整数，Y为含脒的观察配体 由式（2）表示：其中含脒配体通过亚胺氮原子与金属M共价结合，Sub1为取代基，其包含与亚氨基碳原子键合的14族原子。 Sub2是一个取代基，它包含15-16的杂原子，Sub2与亚氨基碳原子键合，r是大于0的整数，L是任选的中性路易斯碱性配体，j是一个整数， 中性配体L和X是阴离子配体。 本发明还涉及式（1）的有机金属化合物和该化合物的制备方法以及重均分子量至少为4.000kg / mol，分子量分布Mw / Mn的UHMWPE 小于2.6。

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