摘要:
A method of simultaneously obtaining separate enriched fractions of heavier and lighter isotopes from mixtures thereof with the use of an ion exchange resin column by passing a ligand body containing this isotope mixture through the column. The isotopes, as they are passed through the column, are present in the forms of ligand-containing coordination compounds having different valence states and are followed by an eluant and form a band which travels through the column, the front and rear portions of which are respectively enriched in one of the isotopes and depleted in the other.
摘要:
A method of simultaneously obtaining separate enriched fractions of .sup.235 U and .sup.238 U from isotopic mixtures thereof with the use of an ion exchange column by passing a liquid body containing the isotopic mixture through the column. The uranium as it is passed through the column is present as a U(IV) coordination compound with a ligand at different valent states and is followed by an eluant and forms a band which travels through the column, the front and rear portions of which are respectively enriched in one of the isotopes and depleted in the other.
摘要:
A multi-cell electrolyzer comprising a plurality of unit cells, each of which is composed of an anode chamber containing an anode and a cathode chamber containing a cathode and a cation exchange membrane for partitioning said unit cell into said anode chamber and said cathode chamber, and each of which is adapted to have an internal pressure maintained at a level higher than the atmospheric pressure in operation of the electrolyzer, said plurality of unit cells being arranged in series and adapted to be energized through a plurality of current lead plates, and rigid multi-contact electrically conductive means provided between the adjacent unit cells and/or between each current lead plate and the unit cell adjacent thereto, thereby establishing electrical connection between the adjacent unit cells and/or between each current lead plate and the unit cell adjacent thereto. With such a structure, not only is the electrical contact resistance between the adjacent unit cells and between each current lead plate and the unit cell adjacent thereto extremely reduced but also the current density in the unit cells is rendered uniform. Further, the present multi-cell electrolyzer can be easily constructed either in a bipolar form or in a monopolar form using unit cells common to both of the bipolar and monopolar forms.
摘要:
A perfluorocarbon type cation exchange membrane prepared by treatment with an oxidizing agent of a cation exchange membrane containing perfluorocarbon polymers having specific pendant N-sulfonamide groups has improved electrochemical characteristics when used as a membrane in electrolysis of aqueous alkali halide solution.
摘要:
A solid solution of a noble metal oxide, titanium oxide and zirconium oxide, containing 1 to 50 mol % of titanium oxide and zirconium oxide as the total content, is coated on an anti-corrosive substrate, e.g. titanium metal to give an electrode which is excellent in low oxygen content in chlorine gas, low electrode consumption and low chlorine overvoltage when it is used as anode for electrolysis of an aqueous sodium chloride solution.
摘要:
In a process for electrolysis of sodium chloride in an electrolytic cell divided into the anode chamber and the cathode chamber by a cation exchange membrane, well brine is used as the starting material for the electrolysis and the dilute aqueous sodium chloride solution formed as the result of the electrolysis is subjected to concentration for re-use as the starting material.
摘要:
A mixture containing formaldehyde and water is separated effectively by contacting with adsorbents of specific type A zeolites containing exchanged cations of the elements from Group IA (4) to (6) or Group IIA (6) or mixture thereof of the Periodic Table of Elements.
摘要:
Cation exchange membranes characterized by carboxylic or carboxylic and sulfonic acid groups pendant from a fluorocarbon polymer are utilized for the electrolysis of aqueous sodium chloride.
摘要:
An electrolytic cell having anode and cathode chambers separated by a cation exchange membrane comprising a fluorocarbon polymer containing pendant carboxylic acid or salt groups of the formula ##STR1## wherein R is a group containing perfluoroalkyl or perfluoroalkoxy having 1 to 5 carbon atoms and M is hydrogen, an alkali or alkaline earth metal or ammonium as a surface stratum on the cathode side of the membrane. The fluorocarbon polymer may also contain sulfonic acid groups of the formula ##STR2##
摘要:
A hydrocarbon mixture is fed to a system of adsorbents in a plug flow so as to form at least one displacement boundary in the system to accumulate the composition in the vicinity of the boundary. The process is simple to operate and suitable for separation of a hydrocarbon mixture containing components with similar physical and chemical properties such as a mixture of hydrocarbon isomers.