摘要:
Thermoplastic molding compositions, comprisingE) from 10 to 99.9% by weight of a thermoplastic polymer,F) from 0.01 to 10% by weight of a copolymer obtainable via free-radical-initiated aqueous emulsion polymerization of ethylenically unsaturated monomers in the presence of at least one dispersing agent and of at least one free-radical initiator by the feed process, where the emulsion polymerization uses from 70 to 99.5% by weight of α,β-monoethylenically unsaturated compounds [monomers A], and from 0.5 to 30% by weight of compounds having at least two ethylenically unsaturated groups capable of free-radical copolymerization [monomers B], and also, if appropriate, up to 5% by weight of α,β-monoethylenically unsaturated mono- or dicarboxylic acids having from 3 to 6 carbon atoms and/or their amides [monomers C], where the monomers A to C give a total of 100% by weight (entire amount of monomers) and the monomer feeds take place in such a way that ≧60% by weight of the entire amount of monomers B are fed to the polymerization mixture under polymerization conditions at a juncture after ≧60% by weight of the entire amount of monomer have been fed to the polymerization mixture under polymerization conditions, from 0 to 70% by weight of further additives,where the total of the percentages by weight of components A) to C) gives 100%.
摘要翻译:热塑性模塑组合物,其包含E)10至99.9重量%的热塑性聚合物,F)0.01至10重量%的共聚物,其通过烯键式不饱和单体的自由基引发的水乳液聚合在有 至少一种分散剂和至少一种自由基引发剂,其中乳液聚合使用70-99.5重量%的α,β-单烯属不饱和化合物[单体A]和0.5-30重量% 具有至少两个能够自由基共聚的烯属不饱和基团(单体B)的化合物的重量,以及如果合适的话,至多5重量%的具有3至6个碳原子的α,β-单烯属不饱和单或二羧酸 碳原子和/或它们的酰胺[单体C],其中单体A至C的总量为100重量%(单体的总量),并且单体进料的发生方式使得≥60重量% e 在聚合条件下,在聚合条件下,在聚合条件下,聚合条件下,在聚合条件下,在聚合条件下,将0〜70重量%的全部量的单体进料量= 60重量% 添加剂,其中组分A)至C)的重量百分比的总和给出100%。
摘要:
Thermoplastic molding compositions comprising A) from 10 to 69% by weight of a thermoplastic polyester B) from 30 to 79% by weight of an aluminum oxide C) from 0.01 to 10% by weight of an organic or inorganic acid or mixture of these D) from 0 to 10% by weight of D1) at least one highly branched or hyperbranched polycarbonate with an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, part 2), or D2) at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.1, or a mixture of these E) from 0 to 50% by weight of other additives, where the entirety of the percentages by weight of components A) to E) gives 100%.
摘要:
A process is proposed for production of low-emission moldings for continuous operating temperatures >50° C. composed of a thermoplastic molding composition comprising A) from 10 to 99.9% by weight of polybutylene terephthalate or a mixture thereof with polyethylene terephthalate and/or polypropylene terephthalate, B) from 0.1 to 50% by weight of at least one terpolymer obtainable from b1) at least one vinylaromatic monomer, b2) at least one C1-C4-alkyl (meth)acrylate or (meth)acrylonitrile, and b3) from 0.1 to 10% by weight, based on the total weight of components b1) to b3), of at least one monomer which comprises an α,β-unsaturated anhydride, and C) from 0 to 60% by weight of other additives, where the total of the percentages by weight of the components (A) to (C) is 100%, via injection molding, which comprises carrying out the injection molding by means of a vented plastifying unit with a cylinder with inlet aperture for the thermoplastic molding composition, with a screw which conveys and plastifies the thermoplastic molding composition within a screw channel, and with one or more vents for discharge of volatile content from the plastified thermoplastic molding composition from the screw channel outward from the vented plastifying unit.
摘要:
Thermoplastic molding compositions comprising A) from 10 to 69% by weight of a thermoplastic polyester B) from 30 to 79% by weight of an aluminum oxide C) from 0.01 to 10% by weight of an organic or inorganic acid or mixture of these D) from 0 to 10% by weight of D1) at least one highly branched or hyperbranched polycarbonate with an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, part 2), or D2) at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.1, or a mixture of these E) from 0 to 50% by weight of other additives, where the entirety of the percentages by weight of components A) to E) gives 100%.
摘要:
Lighting elements composed of thermoplastic molding compositions comprising A) from 10 to 99.9% by weight of at least one thermoplastic polyester, B) from 0.1 to 50% by weight of at least one terpolymer, obtainable from b1) at least one vinylaromatic monomer, b2) at least one C1-C4-alkyl (meth)acrylate or (meth)acrylonitrile, and b3) from 0.1 to 10% by weight, based on the total weight of the components b1) to b3), of at least one monomer which comprises an α,β-unsaturated anhydride, and C) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to C) is 100%.
摘要:
Lighting elements composed of thermoplastic molding compositions comprising A) from 10 to 99.9% by weight of at least one thermoplastic polyester, B) from 0.1 to 50% by weight of at least one terpolymer, obtainable from b1) at least one vinylaromatic monomer, b2) at least one C1-C4-alkyl (meth)acrylate or (meth)acrylonitrile, and b3) from 0.1 to 10% by weight, based on the total weight of the components b1) to b3), of at least one monomer which comprises an α,β-unsaturated anhydride, and C) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to C) is 100%.
摘要:
Thermoplastic molding compositions, comprising A) from 10 to 98% by weight of at least one thermoplastic polymer, B) from 0.01 to 50% by weight of B1) at least one highly branched or hyperbranched polycarbonate having an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, Part 2), or B2) at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.1, or a mixture of these, C) from 1 to 40% by weight of a halogen-free flame retardant, selected from the group of the phosphorus-containing or nitrogen-containing compounds, or of the P—N condensates, or a mixture of these, D) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to D) is 100%.
摘要翻译:热塑性模塑组合物,其包含A)10至98重量%的至少一种热塑性聚合物,B)0.01至50重量%的B1)至少一种高度支化或超支化聚碳酸酯,其OH值为1至600 mg KOH / g聚碳酸酯(根据DIN 53240第2部分)或B2)至少一种高度支化或超支化的A x B B y Y y型聚酯,其中x为 至少1.1和y为至少2.1,或这些的混合物,C)1至40重量%的无卤阻燃剂,选自含磷或含氮化合物,或 PN缩合物,或它们的混合物,D)0至60重量%的其它添加剂,其中组分A)至D)的重量百分比的总和为100%。
摘要:
Thermoplastic molding compositions comprising A) from 10 to 98.9% by weight of at least one thermoplastic polyester, B) from 0.01 to 50% by weight of B1) at least one highly branched or hyperbranched polycarbonate with an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, Part 2), or B2) at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.1, or a mixture of these, C) from 0.1 to 40% by weight of a thermoplastic polyester elastomer, D) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to D) is 100%.
摘要翻译:热塑性成型组合物,其包含A)10至98.9重量%的至少一种热塑性聚酯,B)0.01至50重量%的B1)至少一种高度支化或超支化聚碳酸酯,其OH数为1至600mg KOH / g聚碳酸酯(根据DIN 53240,第2部分)或B2)至少一种高度支化或超支化的A x B B y y y型聚酯,其中x在 至少1.1和y为至少2.1,或这些的混合物,C)0.1至40重量%的热塑性聚酯弹性体,D)0至60重量%的其它添加剂,其中通过 组分A)至D)的重量为100%。
摘要:
Thermoplastic molding compositions comprising a mixture of a component (A), a component (B), a component (C) and a component (D), methods for their preparation and use, and mold-release agents for thermoplastic molding compositions: wherein the component (A) comprises a methyl methacrylate polymer; wherein the component (B) comprises a copolymer prepared by polymerizing from 75 to 88% by weight of a vinylaromatic monomer and from 12 to 25% by weight of a vinyl cyamide; wherein the component (C) comprises a graft copolymer prepared by copolymerizing: from 60 to 90% by weight, based on component (C), of a core, from 5 to 20% by weight, based on component (C), of a first graft shell, and from 5 to 20% by weight, based on component (C), of a second graft shell; and wherein the component (D) comprises at least one highly branched or hyperbranched polymer selected from the group consisting of (D1) highly branched or hyperbranched polycarbonates, (D2) highly branched or hyperbranched polyesters of Ax+By type, where x is at least 1.1 and y is at least 2.1, and mixtures thereof.
摘要翻译:包含组分(A),组分(B),组分(C)和组分(D)的混合物的热塑性模塑组合物,其制备和使用方法以及用于热塑性模塑组合物的脱模剂:其中 组分(A)包括甲基丙烯酸甲酯聚合物; 其中组分(B)包括通过使75至88重量%的乙烯基芳族单体和12至25重量%的乙烯基芳族聚酰胺聚合而制备的共聚物; 其中组分(C)包括通过以下组分制备的接枝共聚物:基于组分(C),基于组分(C)的60至90重量%的核心,基于组分(C)5至20重量% 第一接枝壳,和基于组分(C)5至20重量%的第二接枝壳; 并且其中组分(D)包含至少一种选自(D1)高度支化或超支化聚碳酸酯的高度支化或超支化聚合物,(D2)高支化或超支化的A x + 其中x至少为1.1,y为至少2.1,以及它们的混合物。