公开(公告)号：US06762242B1

公开(公告)日：2004-07-13

申请号：US09958209

申请日：2002-02-05

申请人： Marco Del Torto ,  Fabienne Howe ,  Alain Pouchelon ,  Christian Pusineri

发明人： Marco Del Torto ,  Fabienne Howe ,  Alain Pouchelon ,  Christian Pusineri

IPC分类号： C08L8305

CPC分类号： A61K6/10 ,  C08K9/04 ,  C08K9/06 ,  C08L83/04

摘要： Silicone material crosslinkable into silicone elastomer by polyaddition reactions is described. A material is provided offering a compromise between the following characteristics: fluidity (in non-crosslinked state), hydrophilicity (in non-crosslinked or crossliked state) and high mechanical properties (in crosslinked state). The following materials are added to crosslinkable silicone material: (i) a reinforcing siliceous filler in the form of a suspension obtained by subjecting the filler to a treatment in two stages by an agent providing compatibility and by operating in the presence of a polyorganosiloxane with Si-alkenyl functions; and (ii) one or more non-ionic, ionic or amphoteric surfactants. Said silicone material is particularly useful for impressions, for example dental impressions and for making pads used in pad printing techniques.

摘要翻译： 描述通过加聚反应可交联成硅氧烷弹性体的硅氧烷材料。 提供的材料提供以下特征之间的折衷：流动性（非交联状态），亲水性（非交联或交联状态）和高机械性能（交联状态）。 将以下材料加入到可交联硅氧烷材料中：（i）悬浮液形式的增强硅质填料，其通过使提供相容性的试剂和通过在聚有机硅氧烷与Si的存在下操作在两个阶段中进行处理而获得 烯基官能团 和（ii）一种或多种非离子，离子或两性表面活性剂。 所述硅氧烷材料对于印模特别有用，例如牙印模和用于垫片印刷技术中使用的垫片。

公开(公告)号：US07151149B1

公开(公告)日：2006-12-19

申请号：US09958181

申请日：2000-04-07

申请人： Georges Barrandon ,  Fabienne Howe ,  Olivier Loubet ,  Bernard Moulin ,  Alain Pouchelon

发明人： Georges Barrandon ,  Fabienne Howe ,  Olivier Loubet ,  Bernard Moulin ,  Alain Pouchelon

IPC分类号： C08G77/08 ,  C08L83/05 ,  C08L83/07

CPC分类号： F02F7/006 ,  C08G77/12 ,  C08G77/20 ,  C08G77/24 ,  C08G77/26 ,  C08G77/70 ,  C08L83/04 ,  C09K3/1018 ,  C08L2666/04

摘要： A non-drip, preferably self-adhesive, silicone elastomer composition crosslinkable by polyaddition, such as those polyorganosilanes (POS) bearing C2═C6≡Si-alkenyl units and ≡Si—H units but excluding fluorinated POS. The composition includes at least a thixotropic additive containing at least a fluorinated resin, preferably based on polyfluoroethylene (PTFE). The composition may be prepared from a Si—Vi polydimethylsiloxane (PDMS) and a Si—H PDMS crosslinked by platinum catalysis. Polytetrafluorethylene, a filler, particularly one containing silicone, optionally a ternary adherence promoter such as vinyltrimethosilane/glycidoxypropyltrimethoxysilane/butyl orthotitanate, and other typical additives may be added to the composition. The composition (not excluding the fluorinated POS as a possible constituent in the composition) may be used to produce joints in situ and/or as an adhesive, particularly in upholstery.

摘要翻译： 通过加聚可交联的非滴落的，优选自粘性的有机硅弹性体组合物，例如那些带有C 2 -C 6 -C 6烯基单元的聚有机硅烷（POS）和 ≡Si-H单元，但不包括氟化POS。 该组合物至少包含至少含有氟化树脂的触变添加剂，优选基于聚氟乙烯（PTFE）。 组合物可以由Si-Vi聚二甲基硅氧烷（PDMS）和通过铂催化交联的Si-H PDMS制备。 聚四氟乙烯，特别是含有硅氧烷的填料，任选的三元粘附促进剂如乙烯基三甲硅烷/缩水甘油氧基丙基三甲氧基硅烷/原钛酸丁酯，以及其它典型的添加剂可以加入到组合物中。 组合物（不排除作为组合物中的可能成分的氟化POS）可以用于原位和/或粘合剂，特别是在室内装饰中的接合。

公开(公告)号：US06462104B1

公开(公告)日：2002-10-08

申请号：US09868383

申请日：2001-08-27

申请人： Dominique Canpont ,  Fabienne Howe ,  Alain Pouchelon

发明人： Dominique Canpont ,  Fabienne Howe ,  Alain Pouchelon

IPC分类号： C08K906

CPC分类号： C08K3/36 ,  C08K9/06 ,  C08L83/04

摘要： The invention concerns a method for preparing a silica suspension in a silicone matrix, said suspension capable of being used for producing organopolysiloxanes crosslinkable by polycondensation. The invention aims at seeking a technical compromise between the rheology of said compositions and the mechanical properties of the resulting crosslinked elastomers. As a solution, the invention discloses a method for preparing a silica suspension treated with organosilazane in a silicone material comprising a linear reactive polyorganosiloxane bearing for example at each chain end a hydroxy group. The invention is characterized in that it consists essentially in introducing the organosilozane in the preparation medium: before and/or substantially simultaneously before bringing together at least part of the silicone material and the particulate filler used, said organosilozane introduction being carried out with a fraction of organosilazane corresponding to a proportion ranging between 8% and 30% by dry weight relatively to the silica filler, and after bringing together the filler and all or part of the silicone material.

摘要翻译： 本发明涉及一种在硅氧烷基质中制备二氧化硅悬浮液的方法，所述悬浮液可用于生产通过缩聚可交联的有机聚硅氧烷。 本发明旨在寻求所述组合物的流变学和所得交联弹性体的机械性能之间的技术妥协。 作为解决方案，本发明公开了一种制备在硅氧烷材料中用有机硅氮烷处理的二氧化硅悬浮液的方法，该硅氧烷悬浮液包含例如在每个链末端具有羟基的线性反应性聚有机硅氧烷。 本发明的特征在于其主要在于将有机硅烷烷烃引入制备介质中：在将至少一部分硅氧烷材料和所用的颗粒填料结合在一起之前和/或基本上同时地将所述有机硅烷烷烃引入与一部分 有机硅氮烷相对于二氧化硅填料相对于干重为8％至30％的比例，并将填料与全部或部分硅氧烷材料接合在一起。

公开(公告)号：US07572514B2

公开(公告)日：2009-08-11

申请号：US10518404

申请日：2003-06-17

申请人： Fabienne Howe ,  Alain Pouchelon

发明人： Fabienne Howe ,  Alain Pouchelon

IPC分类号： B32B9/00

CPC分类号： C08J5/12 ,  B05D1/38 ,  C08J2383/04 ,  Y10T428/31663

摘要： A process for production of an assembly including several silicone elements crosslinked by polyaddition of ≡Si—H units onto ≡Si-alkenyl (preferably ≡Si-vinyl) units, the elements adhering to one another without detracting from their mechanical properties. The process includes: (I) forming (1st coating) a silicone element (i) with a liquid silicone preparation (i) containing polyorganosiloxanes (POS) A with ≡Si-vinyl units, (POS) B with ≡Si—H units, a platinum catalyst C; (II) crosslinking so that (i) has a surface density SD of unreacted, residual vinyl, per nm2, of 0.0100≧SD≧0.0040; (III) optionally repeating steps (I) and (II) n times to give n elements (i) that adhere to one another; (IV) forming (2nd coating) a silicone element (ii) with a liquid silicone preparation (ii) of the same type as described above; (v) crosslinking to give crosslinked (ii) that adheres to (i).

摘要翻译： 一种用于生产组件的方法，其包括通过将≡Si-H单元加成≡Si-烯基（优选≡Si-乙烯基）单元而交联的几个硅氧烷元素，所述元件彼此粘附而不降低其机械性能。 该方法包括：（I）用含有≡Si-乙烯基单元的聚有机硅氧烷（POS）A与（≡Si-H）单元的（POS）B）的液体硅氧烷制备物（i）形成（第一次涂覆） 铂催化剂C; （II）交联，使得（i）具有未反应的残留乙烯基，每nm 2的表面密度SD为0.0100> = SD> = 0.0040; （III）任选地重复步骤（I）和（II）n次以产生彼此粘附的n个元素（i）; （Ⅳ）用与上述相同类型的液体硅氧烷制剂（ⅱ）形成（第二次涂覆）硅树脂元件（ⅱ）; （v）交联以得到粘附于（i）的交联（ii）。

公开(公告)号：US20060046077A1

公开(公告)日：2006-03-02

申请号：US10518404

申请日：2003-06-17

申请人： Fabienne Howe ,  Alain Pouchelon

发明人： Fabienne Howe ,  Alain Pouchelon

IPC分类号： B32B25/20 ,  C08G77/06

CPC分类号： C08J5/12 ,  B05D1/38 ,  C08J2383/04 ,  Y10T428/31663

摘要： A process for production of an assembly including several silicone elements crosslinked by polyaddition of ≡Si—H units onto ≡Si-alkenyl (preferably ≡Si-vinyl) units, the elements adhering to one another without detracting from their mechanical properties. The process includes: (I) forming (1st coating) a silicone element (i) with a liquid silicone preparation (i) containing polyorganosiloxanes (POS) A with ≡Si-vinyl units, (POS) B with ≡Si—H units, a platinum catalyst C; (II) crosslinking so that (i) has a surface density SD of unreacted, residual vinyl, per nm2, of 0.0100≧SD≧0.0040; (III) optionally repeating steps (I) and (II) n times to give n elements (i) that adhere to one another; (IV) forming (2nd coating) a silicone element (ii) with a liquid silicone preparation (ii) of the same type as described above; (v) crosslinking to give crosslinked (ii) that adheres to (i).

摘要翻译： 一种用于生产组件的方法，其包括通过将≡Si-H单元加成≡Si-烯基（优选≡Si-乙烯基）单元而交联的若干硅氧烷元素，所述元件彼此粘附而不降低其机械性能。 该方法包括：（I）用含有≡Si-乙烯基单元（POS）的聚有机硅氧烷（POS）A的液体硅氧烷制剂（i）形成（1）硅氧烷元素（i） B与≡Si-H单元，铂催化剂C; （II）交联，使得（i）具有0.0100> = SD> = 0.0040的未反应的残留乙烯基的表面密度SD， （III）任选地重复步骤（I）和（II）n次以产生彼此粘附的n个元素（i）; （Ⅳ）用与上述相同类型的液体硅氧烷制剂（ⅱ）形成硅氧烷元素（ⅱ）; （v）交联以得到粘附于（i）的交联（ii）。

公开(公告)号：US06455617B1

公开(公告)日：2002-09-24

申请号：US09582400

申请日：2000-06-23

申请人： Michel Gay ,  Fabienne Howe ,  Christian Pusineri ,  Joëlle Viennet

发明人： Michel Gay ,  Fabienne Howe ,  Christian Pusineri ,  Joëlle Viennet

IPC分类号： C08K53432

CPC分类号： C08K5/38 ,  C08K5/3435 ,  C08K5/526 ,  C08L83/04

摘要： The invention concerns the use, for increasing the durability of moulds made of silicone elastomer crosslinkable by a poly addition or polycondensation reaction, of additive capable of stabilizing the silicone elastomer constituting the mold with respect to materials to be molded, of an additive selected among: (a) antioxidant additives comprising, in their structure additives containing at least one R—Sq—R′ group in which R and R′ are monovalent hydrocarbon groups with at least 3 carbon atoms or a monovalent hydrocarbon group with an ester bond or R and R′ together form a cycle, q being a whole number between 1 and 3 inclusively, (b) additives inhibitors of free radicals capable, in moulding conditions of generating radicals ═N—O; the invention concerns the synergistic combination of (a)+(b), the synergistic combination of (a) and/or (b) with phosphites (c), except for the use of bis(1-octyloxy-2,2,6,6-tetramethyl-4-piperidyl) sebacate as only additive in a silicone elastomer mould cross-linked by polycondensation.

摘要翻译： 本发明涉及用于增加能够通过聚合或缩聚反应可交联的硅氧烷弹性体的模具的耐久性，所述添加剂能够使构成模具的硅氧烷弹性体相对于待模制材料稳定，所述添加剂选自： （a）抗氧化添加剂，在其结构中含有至少一种R-Sq-R'基团的添加剂，其中R和R'是具有至少3个碳原子的一价烃基或具有酯键的一价烃基或R和 R'一起形成循环，q为1〜3的整数，（b）自由基添加剂抑制剂，能够在产生自由基的成型条件= NO; 本发明涉及（a）+（b），（a）和/或（b）与亚磷酸酯（c）的协同组合的协同组合，除了使用双（1-辛氧基-2,2,6 ，6-四甲基-4-哌啶基）癸二酸酯作为仅通过缩聚交联的硅氧烷弹性体模具中的添加剂。

公开(公告)号：US06972313B2

公开(公告)日：2005-12-06

申请号：US10265007

申请日：2002-10-04

申请人： Fabienne Howe ,  Christian Pusineri

发明人： Fabienne Howe ,  Christian Pusineri

IPC分类号： C08K7/22 ,  C08L83/04 ,  C08L83/07 ,  C09J183/07 ,  C08G77/20 ,  C08L83/00

CPC分类号： C08K7/22 ,  C08G77/12 ,  C08G77/20 ,  C08G77/70 ,  C08L83/04 ,  C08L2666/04

摘要： The invention concerns a silicone composition cross-linkable by hydrosilylation into adhesive gel and absorber, characterized in that it comprises: (I) at least a polyorganosiloxane POS (I); (II) at least a polyorganosiloxane POS (II); (III) at least an adhesive promoter (III); (IV) hollow organic microspheres; (V) optionally at least a polyorganosiloxane POS (V) particularly useful as diluent of POS (I); (VI) an effective amount of hydrosilylation catalyst, preferably of the platinous type.

摘要翻译： 本发明涉及通过氢化硅烷化成可粘合凝胶和吸收剂可交联的硅氧烷组合物，其特征在于其包含：（I）至少一种聚有机硅氧烷POS（I）; （II）至少一种聚有机硅氧烷POS（II）; （III）至少一种粘合促进剂（III）; （IV）中空有机微球; （V）任选地至少一种特别用作POS（I）的稀释剂的聚有机硅氧烷POS（V）; （VI）有效量的氢化硅烷化催化剂，优选铂型。

公开(公告)号：US06486237B1

公开(公告)日：2002-11-26

申请号：US09530401

申请日：2000-06-21

申请人： Fabienne Howe ,  Christian Pusineri

发明人： Fabienne Howe ,  Christian Pusineri

IPC分类号： C08L8507

CPC分类号： C08K7/22 ,  C08G77/12 ,  C08G77/20 ,  C08G77/70 ,  C08L83/04 ,  C08L2666/04

摘要： The invention concerns a silicone composition cross-linkable by hydrosilylation into adhesive gel and absorber, characterized in that it comprises:(I) at least a polyorganosiloxane POS (I); (II) at least a polyorganosiloxane POS (II); (III) at least an adhesive promoter (III); (IV) hollow organic microspheres ; (V) optionally at least a polyorganosiloxane POS (V) particularly useful as diluent of POS (I); (VI) an effective amount of hydrosilylation catalyst, preferably of the platinous type.

摘要翻译： 本发明涉及通过氢化硅烷化成可粘合凝胶和吸收剂可交联的硅氧烷组合物，其特征在于其包含：（I）至少一种聚有机硅氧烷POS（I）; （II）至少一种聚有机硅氧烷POS（II）; （III）至少一种粘合促进剂（III）; （IV）中空有机微球; （V）任选地至少一种特别用作POS（I）的稀释剂的聚有机硅氧烷POS（V）; （VI）有效量的氢化硅烷化催化剂，优选铂型。

公开(公告)号：US20050171278A1

公开(公告)日：2005-08-04

申请号：US10506207

申请日：2003-02-28

申请人： Fabienne Howe ,  Jens Heilman

发明人： Fabienne Howe ,  Jens Heilman

IPC分类号： B29C33/40 ,  B29K21/00 ,  C08K5/54 ,  C08K9/06 ,  C08L83/04 ,  C09C1/28 ,  C09C3/12

CPC分类号： C08K9/06 ,  B29C33/405 ,  B29K2883/00 ,  C08L83/04

摘要： The present invention relates to the use, for improving the longevity of moulds made of polycondensation-crosslinking silicone elastomer, of an additive capable of stabilizing the silicone elastomer of which the mould is made with respect to materials to be moulded and especially polyester resins. This stabilizer is based on silica pretreated with a silane. It is preferably a ground quartz treated with an alkyl silane.

摘要翻译： 本发明涉及用于改善由缩聚交联的硅氧烷弹性体制成的模具的使用寿命的添加剂，该添加剂能使相对于待模塑材料特别是聚酯树脂制成模具的硅氧烷弹性体稳定。 该稳定剂基于用硅烷预处理的二氧化硅。 优选地是用烷基硅烷处理的研磨石英。