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公开(公告)号：US4565898A
公开(公告)日：1986-01-21
申请号：US708832
申请日：1985-03-06
IPC分类号： C07C11/02 , B01J23/00 , B01J23/62 , C07B61/00 , C07C1/00 , C07C5/333 , C07C5/48 , C07C15/46 , C07C67/00
CPC分类号： C07C15/46 , C07C5/333 , C07C5/48 , B01J23/626
摘要： Dehydrogenatable hydrocarbons may be subjected to a dehydrogenation reaction in which the hydrocarbons are treated with a dehydrogenation catalyst comprising a modified iron compound in the presence of steam in a multicatalyst bed system. The reaction mixture containing unconverted hydrocarbons, dehydrogenated hydrocarbons, hydrogen and steam is then contacted with an oxidation catalyst whereby hydrogen is selectively oxidized in preference to carbon dioxide and carbon monoxide or hydrocarbons. The selective oxidation of hydrogen will improve the combustion thereof and supply the necessary heat which is required for a subsequent dehydrogenation treatment. The selective oxidation catalyst which is used will comprise a noble metal of Group VIII of the Periodic Table and, if so desired, a metal of Group IA or IIA of the Periodic Table composited on a porous inorganic support. The inorganic support will have been calcined prior to impregnation thereof at a temperature in the range of from about 900.degree. to about 1500.degree. C. in the absense or presence of steam to provide a catalyst which possesses increased stability and activity when compared to prior catalysts.
摘要翻译： 可脱氢烃可以进行脱氢反应，其中烃在多催化床系统中在蒸汽存在下用含有改性铁化合物的脱氢催化剂处理。 然后将含有未转化的烃，脱氢烃，氢气和蒸汽的反应混合物与氧化催化剂接触，由此优选选择性地氧化二氧化碳和一氧化碳或烃。 氢的选择性氧化将改善其燃烧并提供随后的脱氢处理所需的必要的热量。 使用的选择性氧化催化剂将包括元素周期表第VIII族的贵金属，如果需要，在多孔无机载体上合成元素周期表的IA或IIA族金属。 无机载体在浸渍之前必须在大约900℃至大约1500℃的温度下在蒸汽的存在或存在下进行煅烧，以提供与现有催化剂相比具有增加的稳定性和活性的催化剂 。
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公开(公告)号：US4717779A
公开(公告)日：1988-01-05
申请号：US893754
申请日：1986-08-06
CPC分类号： C07C15/46 , C07C5/3332 , C07C5/48
摘要： Dehydrogenatable hydrocarbons may be subjected to a dehydrogenation reaction in which the hydrocarbons are treated with a dehydrogenation catalyst comprising a modified iron catalyst in the presence of steam in a multicatalyst bed system. The reaction mixture containing unconverted hydrocarbons, dehydrogenated hydrocarbons, hydrogen and steam is then contacted with an oxidation catalyst whereby hydrogen is selectively oxidized. The selective oxidation catalyst which is used will comprise a noble metal of Group VIII of the Periodic Table, a metal of Group IVA and, if so desired, a metal of Group IA or IIA composited on a porous inorganic support. The inorganic support will comprise an alumina precursor which possesses and ABD less than about 0.6 g/cc, a pore volume greater than about 0.5 cc/g, and a pore distribution such that between 10% and 70% of the pore volume is present as pores whose diameters are greater than about 300 Angstroms. After peptizing and calcination at a temperature of about 900.degree. to about 1500.degree. C., the resulting alumina will possess an ABD in the range of from about 0.3 to about 1.1 g/cm, a pore volume greater than about 0.2 cc/g, a pore distribution such that more than 40% of the pore volume is present in pores greater than 1500 Angstroms, a piece density in the range of from about 0.3 to about 2.0 g/cc, and a particle size which possesses a diameter of at least 2 mm.
摘要翻译： 可脱氢烃可以进行脱氢反应，其中烃在多催化床系统中在蒸汽存在下用含有改性铁催化剂的脱氢催化剂处理。 然后将含有未转化的烃，脱氢烃，氢和蒸汽的反应混合物与氧化催化剂接触，由此氢被选择性氧化。 使用的选择性氧化催化剂将包括元素周期表第VIII族的贵金属，IVA族的金属，如果需要的话，将复合在多孔无机载体上的IA或IIA族金属。 无机载体将包含具有小于约0.6g / cc的ABD的氧化铝前体，大于约0.5cc / g的孔体积和孔分布，使孔体积的10％至70％存在于 直径大于约300埃的孔。 在约900℃至约1500℃的温度下进行胶溶和煅烧之后，所得氧化铝的ABD将为约0.3至约1.1g / cm 3，孔体积大于约0.2cc / g， 孔分布使得孔大于40％的孔体积存在于大于1500埃的孔中，片密度在约0.3至约2.0g / cc范围内，并且具有至少具有直径的粒径 2毫米。
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公开(公告)号：US4812597A
公开(公告)日：1989-03-14
申请号：US92355
申请日：1987-09-02
申请人： Tamotsu Imai , Jeffery C. Bricker
发明人： Tamotsu Imai , Jeffery C. Bricker
CPC分类号： C07C5/3337
摘要： Dehydrogenatable hydrocarbons may be subjected to a dehydrogenation reaction in which the hydrocarbons such as ethylbenzene are treated with a dehydrogenation catalyst comprising a modified iron catalyst in the presence of steam. The reaction mixture containing unconverted ethylbenzene, styrene, hydrogen and steam is then contacted with an oxidation catalyst in a second zone whereby hydrogen is selectively oxidized to the substantial exclusion of oxidation of the hydrocarbon. The selective oxidation catalyst which is employed will comprise a noble metal of Group VIII of the Periodic Table, a metal of Group IVA and, if so desired, a metal of Group IA or IIA composited on a porous inorganic support such as alumina. The noble metal of Group VIII of the Periodic Table will be present in the exterior surface of the support which possesses a depth in the range of from about 10 to about 300 microns in an average concentration at least 10% than the Group VIII noble metal average concentration in the core of the support.
摘要翻译： 可脱氢烃可以进行脱氢反应，其中在蒸汽存在下，用含有改性铁催化剂的脱氢催化剂处理烃如乙苯。 然后将含有未转化的乙苯，苯乙烯，氢气和蒸汽的反应混合物与第二区中的氧化催化剂接触，由此氢被选择性地氧化以实质上排除烃的氧化。 所用的选择性氧化催化剂将包括元素周期表第VIII族的贵金属，ⅣA族的金属，如果需要，将其复合在多孔无机载体如氧化铝上的IA或IIA族金属。 元素周期表第VIII族的贵金属将存在于载体的外表面，其深度范围为约10至约300微米，平均浓度至少比第VIII族贵金属平均值高10％ 集中在支持的核心。
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4.发明授权Non-oxidative removal of hydrogen sulfide from gaseous, petrochemical, and other streams 失效从气态，石油化学和其他物流中非氧化除去硫化氢
公开(公告)号：US5034118A
公开(公告)日：1991-07-23
申请号：US414802
申请日：1989-09-29
申请人： Jeffery C. Bricker , Tamotsu Imai
发明人： Jeffery C. Bricker , Tamotsu Imai
IPC分类号： C10G29/20
CPC分类号： C10G29/205
摘要： Hydrogen sulfide can be conveniently removed from streams containing up to about 1,000 ppm of H.sub.2 S by reacting the latter with an olefin using a bed of an acidic solid catalyst in a non-oxidative process for the removal of hydrogen sulfide. The reaction can be effected under relatively mild conditions and is very selective for the removal of hydrogen sulfide without being attended by other unwanted reactions such as oligomerization, disproportionation, and skeletal rearrangement. Levels of hydrogen sulfide in the treated product of no more than about 5 ppm can be readily attained using a broad variety of acidic solid catalysts and unsaturated hydrocarbons, especially olefins.
摘要翻译： 通过使用酸性固体催化剂床在非氧化方法中使后者与烯烃反应除去硫化氢，可以方便地从含有高达约1,000ppm的H 2 S的流中除去硫化氢。 反应可以在相对温和的条件下进行，并且对于除去硫化氢是非常有选择性的，而不受其它不希望的反应如低聚，歧化和骨架重排的影响。 使用各种酸性固体催化剂和不饱和烃，特别是烯烃，可以容易地获得处理产物中不超过约5ppm的硫化氢含量。
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公开(公告)号：US4786625A
公开(公告)日：1988-11-22
申请号：US131882
申请日：1987-12-11
CPC分类号： C10G45/00 , B01J23/622 , B01J23/6567 , B01J35/0006 , Y10S502/514 , Y10S502/523
摘要： A novel catalytic composite comprising a platinum group metal component; a modifier metal component selected from the group consisting of a tin component, germanium component, rhenium component and mixtures thereof; an optional alkali or alkaline earth metal component or mixtures thereof, an optional halogen component, and an optional catalytic modifier component on a refractory oxide support having a nominal diameter of at least about 850 microns. The distribution of the platinum group metal component is such that the platinum group component is surface-impregnated where substantially all of the platinum group metal component is located at most within a 400 micron exterior layer of the support. The effective amount of the modifier metal component is uniformly dispersed throughout the refractory oxide support. The distribution of the surface-impregnated platinum metal component is such that the novel catalyst has particular utility as a hydrocarbon dehydrogenation catalyst in a hydrocarbon dehydrogenation process.
摘要翻译： 一种包含铂族金属组分的新型催化复合材料; 选自锡组分，锗组分，铼组分及其混合物的改性金属组分; 任选的碱金属或碱土金属组分或其混合物，任选的卤素组分和在耐火氧化物载体上的任选的催化改性剂组分，其标称直径为至少约850微米。 铂族金属组分的分布使得铂基组分被表面浸渍，其中基本上所有的铂族金属组分位于载体的400微米外层内。 改性金属组分的有效量均匀分散在整个难熔氧化物载体上。 表面浸渍的铂金属组分的分布使得新型催化剂在烃脱氢方法中作为烃脱氢催化剂具有特别的用途。
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公开(公告)号：US4717781A
公开(公告)日：1988-01-05
申请号：US28844
申请日：1987-03-23
CPC分类号： C07C15/46 , B01J23/622 , B01J23/8966 , B01J35/026 , C07C5/3332 , C07C5/48 , Y10S585/906
摘要： Unsaturated hydrocarbons may be prepared by subjecting a dehydrogenatable hydrocarbon to dehydrogenation in the presence of a dehydrogenation catalyst. The effluent stream from this step, comprising unconverted hydrocarbons, dehydrogenated hydrocarbons, hydrogen and steam, may then be passed to a selective oxidation step in which the hydrogen is selectively oxidized in the presence of an oxygen-containing gas to the substantial exclusion of the oxidation of the hydrocarbons. The oxidation catalyst which is employed will comprise a Group VIII noble metal, a Group IVA metal and a Group IA or IIA metal composited on a metal oxide support. The metal oxide support such as alumina will possess a particular configuration having one or more open channels such as a tubular or cartwheel particle having an outside to inside diameter ratio of the channels ranging from 1.1 to 8 and having a ratio of shape surface to catalyst volume greater than [4D+2L] in which D is the largest representative diameter of the particle and L is the length of the particle.
摘要翻译： 不饱和烃可以通过在脱氢催化剂存在下使可脱氢烃脱氢来制备。 然后将包含未转化的烃，脱氢烃，氢气和蒸汽的来自该步骤的流出物流传递到选择性氧化步骤，其中在含氧气体存在下氢被选择性氧化，从而基本排除了氧化 的烃。 所用的氧化催化剂将包含在金属氧化物载体上复合的VIII族贵金属，IVA族金属和IA或IIA族金属。 金属氧化物载体如氧化铝将具有一个具有一个或多个开放通道的特定构型，例如管状或滚轮颗粒，其通道的内外径比范围为1.1至8，并且具有形状表面与催化剂体积之比 大于[4D + 2L]，其中D是颗粒的最大代表直径，L是颗粒的长度。
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7.发明授权
公开(公告)号：US4827072A
公开(公告)日：1989-05-02
申请号：US221977
申请日：1988-07-20
IPC分类号： B01J23/62 , B01J23/656 , B01J35/00 , C10G45/00 , C07C5/32
CPC分类号： B01J23/6567 , B01J23/622 , B01J35/0006 , C10G45/00
摘要： A novel catalytic composite comprising a platinum group metal component; a modifier metal component selected from the group consisting of a tin component, germanium component, rhenium component and mixtures thereof; an optional alkali or alkaline earth metal component or mixtures thereof, an optional halogen component, and an optional catalytic modifier component on a refractory oxide support having a nominal diameter of at least about 850 microns. The distribution of the platinum group metal component is such that the platinum group component is surface-impregnated where substantially all of the platinum group metal component is located at most within a 400 micron exterior layer of the support. The effective amount of the modifier metal component is uniformly dispersed throughout the refractory oxide support. The distribution of the surface-impregnated platinum metal component is such that the novel catalyst has particular utility as a hydrocarbon dehydrogenation catalyst in a hydrocarbon dehydrogenation process.
摘要翻译： 一种包含铂族金属组分的新型催化复合材料; 选自锡组分，锗组分，铼组分及其混合物的改性金属组分; 任选的碱金属或碱土金属组分或其混合物，任选的卤素组分和在耐火氧化物载体上的任选的催化改性剂组分，其标称直径为至少约850微米。 铂族金属组分的分布使得铂基组分被表面浸渍，其中基本上所有的铂族金属组分位于载体的400微米外层内。 改性金属组分的有效量均匀分散在整个难熔氧化物载体上。 表面浸渍的铂金属组分的分布使得新型催化剂在烃脱氢方法中作为烃脱氢催化剂具有特别的用途。
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公开(公告)号：US4775462A
公开(公告)日：1988-10-04
申请号：US65243
申请日：1987-06-22
申请人： Tamotsu Imai , Jeffery C. Bricker
发明人： Tamotsu Imai , Jeffery C. Bricker
CPC分类号： C10G29/205 , C10G29/06
摘要： This invention relates to a non-oxidative method of sweetening a sour hydrocarbon fraction. The method comprises treating a sour hydrocarbon fraction containing mercaptans with an acid-type catalyst in the presence of an unsaturated hydrocarbon at reaction conditions thereby converting said mercaptans to thioethers. Acid type catalysts which may be used include polymeric sulfonic acid resins, intercalate compounds, sollid acid catalysts and acidic inorganic oxide catalysts.
摘要翻译： 本发明涉及一种甜化酸性烃馏分的非氧化方法。 该方法包括在反应条件下，在不饱和烃存在下用酸型催化剂处理含有硫醇的酸性烃馏分，从而将所述硫醇转化为硫醚。 可以使用的酸型催化剂包括聚合磺酸树脂，插层化合物，sollid酸催化剂和酸性无机氧化物催化剂。
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公开(公告)号：US4652687A
公开(公告)日：1987-03-24
申请号：US882856
申请日：1986-07-07
申请人： Tamotsu Imai , Jeffery C. Bricker
发明人： Tamotsu Imai , Jeffery C. Bricker
CPC分类号： C07C5/321 , B01J35/026 , C07C5/3332 , B01J23/626
摘要： Unsaturated hydrocarbons may be prepared by subjecting dehydrogenatable hydrocarbon to dehydrogenation in the presence of a dehydrogenation catalyst. The effluent stream from this step, comprising unconverted hydrocarbons, dehydrogenated hydrocarbons, hydrogen and steam, may then be passed to a selective oxidation step in which the hydrogen is selectively oxidized in the presence of an oxygen-containing gas to the substantial exclusion of the oxidation of the hydrocarbons. The oxidation catalyst which is employed will comprise a Group VIII noble metal, a Group IVA metal and a Group IA or IIA metal composited on a metal oxide support. The metal oxide support such as alumina will possess a particular configuration such as a polylobular particle containing from 3 to about 8 lobes and having a ratio of exterior surface to catalyst volume greater than [4D+2L] in which D is the largest representative diameter and L is the length of the particle.
摘要翻译： 不饱和烃可以通过在脱氢催化剂存在下使可脱氢烃脱氢来制备。 然后将包含未转化的烃，脱氢烃，氢气和蒸汽的来自该步骤的流出物流送入选择性氧化步骤，其中在含氧气体存在下氢被选择性地氧化，从而基本排除了氧化 的烃。 所用的氧化催化剂将包含在金属氧化物载体上复合的VIII族贵金属，IVA族金属和IA或IIA族金属。 金属氧化物载体如氧化铝将具有特定的构型，例如含有3至约8个裂片的多球形颗粒，并且具有大于[4D + 2L]的外表面与催化剂体积的比例，其中D是最大的代表性直径， L是粒子的长度。
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公开(公告)号：US4329521A
公开(公告)日：1982-05-11
申请号：US239960
申请日：1981-03-03
CPC分类号： B01J31/0237 , B01J31/20 , B01J31/2234 , B01J31/4046 , C07C29/16 , C07C29/88 , B01J2231/321 , B01J2231/643 , B01J2531/0205 , B01J2531/822 , B01J31/1805 , Y02P20/584
摘要： Alcohols may be synthesized by treating an olefinic hydrocarbon with carbon monoxide and hydrogen in a hydroformylation zone using a rhodium complex catalyst and an amine modifier to effect the reaction. Following the formation of the alcohol, a catalyst may be extracted from said alcohol by treatment with an aqueous ammonium hydroxide solution. Following this, the aqueous ammonium solution containing the rhodium catalyst is subjected to an extraction process utilizing the amine modifier as the extractant and thereafter recycling the rhodium complex catalyst and amine modifier to the hydroformylation zone.
摘要翻译： 醇可以通过使用铑配合物催化剂和胺改性剂在加氢甲酰化区中用一氧化碳和氢处理烯烃来合成，以进行反应。 醇形成后，可以通过用氢氧化铵水溶液处理从所述醇中提取催化剂。 然后，使用胺改性剂作为萃取剂，对含有铑催化剂的铵水溶液进行萃取，然后将铑配合物催化剂和胺改性剂再循环到加氢甲酰化区。
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