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公开(公告)号：US20100166691A1
公开(公告)日：2010-07-01
申请号：US12721309
申请日：2010-03-10
Applicant: Mark S. Pavlin
Inventor： Mark S. Pavlin
CPC classification number: C08G69/40 , A61K8/0229 , A61K8/042 , A61K8/90 , A61Q1/14 , A61Q15/00 , A61Q17/02 , A61Q17/04 , A61Q19/00 , C08G2650/50 , C08L71/02 , C08L77/00 , C08L77/06 , C08L2205/05 , C08L2666/20
Abstract: Copolymers having linked internal polyether blocks and internal polyamide blocks have advantageous physical properties and solvent-gelling abilities. The copolymer may be prepared from a reaction mixture that contains 1,4-cyclohexane dicarboxylic acid (CHDA) and poly(alkyleneoxy)diamine (PAODA). Optionally, the reaction mixture contains no monofunctional compound reactive with either amine or carboxylic acid groups, however some of this monofunctional compound may be present. Dimer diamine and/or dimer acid may be present in the reaction mixture. A copolymer may also be prepared from a reaction mixture containing dimer acid and at least two diamine compound(s) including PAODA and short-chain aliphatic diamine having 2-6 carbons (SDA), wherein: a) the reaction mixture comprises x grams of PAODA and y grams of SDA, and x/(x+y) is 0.8-0.98; b) the reaction mixture weighs z grams, and x/z is at least 0.25; and c) the reaction mixture contains either no co-diacid, or comprises a small amount of co-diacid, wherein, if the reaction mixture comprises a small amount of co-diacid, then acid equivalents from co-diacid contribute less than 25% of the total acid equivalents present in the reaction mixture.
Abstract translation: 具有连接的内部聚醚嵌段和内部聚酰胺嵌段的共聚物具有有利的物理性能和溶剂胶凝性能。 共聚物可以由含有1,4-环己烷二羧酸（CHDA）和聚（亚烷基氧基）二胺（PAODA）的反应混合物制备。 任选地，反应混合物不含有与胺或羧酸基团反应的单官能化合物，然而这些单官能化合物可能存在一些。 二聚体二胺和/或二聚酸可存在于反应混合物中。 共聚物也可以由包含二聚酸和至少两种二胺化合物（包括PAODA）和具有2-6个碳原子的短链脂族二胺（SDA）的反应混合物制备，其中：a）反应混合物包含x克 PAODA和y克的SDA，x /（x + y）为0.8-0.98; b）反应混合物重Zg，x / z至少为0.25; 和c）反应混合物不含共二酸或包含少量的共二酸，其中如果反应混合物包含少量的共二酸，则来自共二酸的酸当量贡献小于25重量％ 的反应混合物中存在的总酸当量。
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公开(公告)号：US20090076175A1
公开(公告)日：2009-03-19
申请号：US12326846
申请日：2008-12-02
Applicant: Mark S. Pavlin
Inventor： Mark S. Pavlin
CPC classification number: C08G69/40 , A61K8/0229 , A61K8/042 , A61K8/90 , A61Q1/14 , A61Q15/00 , A61Q17/02 , A61Q17/04 , A61Q19/00 , C08G2650/50 , C08L71/02 , C08L77/00 , C08L77/06 , C08L2205/05 , C08L2666/20
Abstract: Copolymers having linked internal polyether blocks and internal polyamide blocks have advantageous physical properties and solvent-gelling abilities. The copolymer may be prepared from a reaction mixture that contains 1,4-cyclohexane dicarboxylic acid (CHDA) and poly(alkyleneoxy) diamine (PAODA). Optionally, the reaction mixture contains no monofunctional compound reactive with either amine or carboxylic acid groups, however some of this monofunctional compound may be present. Dimer diamine and/or dimer acid may be present in the reaction mixture. A copolymer may also be prepared from a reaction mixture containing dimer acid and at least two diamine compound(s) including PAODA and short-chain aliphatic diamine having 2-6 carbons (SDA), wherein: a) the reaction mixture comprises x grams of PAODA and y grams of SDA, and x/(x+y) is 0.8-0.98; b) the reaction mixture weighs z grams, and x/z is at least 0.25; and c) the reaction mixture contains either no co-diacid, or comprises a small amount of co-diacid, wherein, if the reaction mixture comprises a small amount of co-diacid, then acid equivalents from co-diacid contribute less than 25% of the total acid equivalents present in the reaction mixture.
Abstract translation: 具有连接的内部聚醚嵌段和内部聚酰胺嵌段的共聚物具有有利的物理性能和溶剂胶凝性能。 共聚物可以由含有1,4-环己烷二羧酸（CHDA）和聚（亚烷基氧基）二胺（PAODA）的反应混合物制备。 任选地，反应混合物不含有与胺或羧酸基团反应的单官能化合物，然而这些单官能化合物可能存在一些。 二聚体二胺和/或二聚酸可存在于反应混合物中。 共聚物也可以由包含二聚酸和至少两种二胺化合物（包括PAODA）和具有2-6个碳原子的短链脂族二胺（SDA）的反应混合物制备，其中：a）反应混合物包含x克 PAODA和y克的SDA，x /（x + y）为0.8-0.98; b）反应混合物重Zg，x / z至少为0.25; 和c）反应混合物不含共二酸或包含少量的共二酸，其中如果反应混合物包含少量的共二酸，则来自共二酸的酸当量贡献小于25重量％ 的反应混合物中存在的总酸当量。
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公开(公告)号：US07253249B2
公开(公告)日：2007-08-07
申请号：US11005320
申请日：2004-12-06
Applicant: Mark S. Pavlin
Inventor： Mark S. Pavlin
IPC: C08G63/02
CPC classification number: A61Q15/00 , A61K8/02 , A61K8/068 , A61K8/8158 , A61K8/88 , A61K2800/262 , A61K2800/872 , A61Q1/02 , A61Q1/06 , A61Q1/10 , A61Q1/12 , A61Q13/00 , A61Q17/04 , A61Q19/00 , A61Q19/001
Abstract: A resin composition is prepared by reacting components comprising dibasic acid, diamine, polyol and monoalcohol, wherein (a) at least 50 equivalent percent of the dibasic acid comprises polymerized fatty acid; (b) at least 50 equivalent percent of the diamine comprises ethylene diamine; (c) 10-60 equivalent percent of the total of the hydroxyl and amine equivalents provided by diamine, polyol and monoalcohol are provided by monoalcohol; and (d) no more than 50 equivalent percent of the total of the hydroxyl and amine equivalents provided by diamine, polyol and monoalcohol are provided by polyol. This resin composition may be formulated into, for example, personal care products, fragrance releasing products and candles.
Abstract translation: 通过使包含二元酸，二胺，多元醇和一元醇的组分反应制备树脂组合物，其中（a）至少50当量的二元酸包括聚合的脂肪酸; （b）至少50当量的二胺包括乙二胺; （c）由二胺，多元醇和一元醇提供的羟基和胺等价物的总量的10-60当量由一元醇提供; 和（d）由二胺，多元醇和一元醇提供的羟基和胺当量的总和不超过50当量由多元醇提供。 该树脂组合物可以配制成例如个人护理产品，香料释放产品和蜡烛。
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4.发明授权Hydrocarbon-terminated polyether-polyamide block copolymers and uses thereof 有权烃封端的聚醚 - 聚酰胺嵌段共聚物及其用途公开(公告)号：US06399713B1
公开(公告)日：2002-06-04
申请号：US09769081
申请日：2001-01-24
Applicant: Richard C. MacQueen , Mark S. Pavlin
Inventor： Richard C. MacQueen , Mark S. Pavlin
IPC: C08L7700
CPC classification number: A61Q15/00 , A61K8/042 , A61K8/86 , A61K8/88 , A61K8/90 , A61K9/06 , A61K2800/48 , A61L9/01 , A61L9/012 , A61L9/12 , A61Q1/00 , A61Q19/00 , C08G69/34 , C08G69/40 , C08L23/00 , C08L77/00 , C09D9/00 , C09G1/16 , C09J123/04 , C09J123/0869 , C11C5/002 , C11D3/3719 , C11D3/3769 , C11D3/3788 , C11D17/0021 , C11D17/003 , C23F11/173
Abstract: A block copolymer of the formula hydrocarbon-polyether-polyamide-polyether-hydrocarbon is described. The copolymer may be prepared by reacting together reactants that include dimer acid, diamine, and a polyether having both hydrocarbon termination and termination selected from one of amine, hydroxyl and carboxyl. The copolymer may be combined with a solvent to form a gel, where the gel may be transparent and may be incorporated into household and consumer products including antiperspirants.
Abstract translation: 描述了式 - 烃 - 聚醚 - 聚酰胺 - 聚醚 - 烃的嵌段共聚物。 共聚物可以通过使包括二聚酸，二胺和具有选自胺，羟基和羧基之一的终止和终止的两端的聚醚反应在一起来制备。 共聚物可以与溶剂组合以形成凝胶，其中凝胶可以是透明的，并且可以并入家用和消费品中，包括止汗剂。
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5.发明授权Resinous binders comprising a metal rosin resinate and a pendant tertiary amine polymer 失效树脂粘合剂包含金属松香树脂酸盐和叔胺聚合物
公开(公告)号：US5026754A
公开(公告)日：1991-06-25
申请号：US340108
申请日：1989-04-18
Applicant: Mark S. Pavlin
Inventor： Mark S. Pavlin
IPC: C08L93/00 , C08L93/04 , C08L101/00 , C08L101/02 , C09D11/02 , C09D11/08 , C09D11/10
Abstract: A resinous binder is disclosed which is composed of a metal rosin resinate and a dilution increasing effective amount of a pendant tertiary amine polymer type resin having greater than 50,000 weight average molecular weight.Also disclosed is a gravure printing ink which comprises a solvent, a colorant and a binder wherein all or a portion of the binder consists of the resinous binder of this invention. The use of the resinous binder of this invention in ink compositions results in significant dilution improvement without adversely affecting other desirable properties.
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Patent Agency Ranking6.发明授权Resinous binders comprising a metal rosin resinate and a carboxylated polystyrene resin 失效包含金属松香树脂酸盐和羧化聚苯乙烯树脂的树脂粘合剂
公开(公告)号：US5026753A
公开(公告)日：1991-06-25
申请号：US313926
申请日：1989-02-22
Applicant: James C. West , Mark S. Pavlin
Inventor： James C. West , Mark S. Pavlin
IPC: C08L25/04 , C08L25/00 , C08L25/08 , C08L89/00 , C08L93/04 , C09D11/08 , C09D125/00 , C09D125/04
Abstract: A resinous binder is disclosed which is composed of a metal rosin resinate and a dilution increasing effective amount of polystyrene type resin having greater than 50,000 weight average molecular weight and an acid number less than 200.Also disclosed is a gravure printing ink which comprises a solvent, a colorant and a binder component wherein all or a portion of the binder component consists of the resinous binder of this invention. The use of the resinous binder of this invention in ink compositions results in significant dilution improvement without adversely affecting other desirable properties.
Abstract translation: 公开了一种树脂粘合剂，其由金属松香树脂酸盐和具有大于50,000重均分子量和酸值小于200的聚苯乙烯类树脂的稀释增加有效量组成。还公开了一种凹版印刷油墨，其包含溶剂 ，着色剂和粘合剂组分，其中所述或部分粘合剂组分由本发明的树脂粘合剂组成。 在油墨组合物中使用本发明的树脂粘合剂可显着地提高稀释度，而不会不利地影响其它所需的性能。
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公开(公告)号：US08119741B2
公开(公告)日：2012-02-21
申请号：US12326849
申请日：2008-12-02
Applicant: Mark S. Pavlin
Inventor： Mark S. Pavlin
IPC: C08L77/02
CPC classification number: C08G69/40 , A61K8/0229 , A61K8/042 , A61K8/90 , A61Q1/14 , A61Q15/00 , A61Q17/02 , A61Q17/04 , A61Q19/00 , C08G2650/50 , C08L71/02 , C08L77/00 , C08L77/06 , C08L2205/05 , C08L2666/20
Abstract: Copolymers having linked internal polyether blocks and internal polyamide blocks have advantageous physical properties and solvent-gelling abilities. The copolymer may be prepared from a reaction mixture that contains 1,4-cyclohexane dicarboxylic acid (CHDA) and poly(alkyleneoxy)diamine (PAODA). Optionally, the reaction mixture contains no monofunctional compound reactive with either amine or carboxylic acid groups, however some of this monofunctional compound may be present. Dimer diamine and/or dimer acid may be present in the reaction mixture. A copolymer may also be prepared from a reaction mixture containing dimer acid and at least two diamine compound(s) including PAODA and short-chain aliphatic diamine having 2-6 carbons (SDA), wherein: a) the reaction mixture comprises x grams of PAODA and y grams of SDA, and x/(x+y) is 0.8-0.98; b) the reaction mixture weighs z grams, and x/z is at least 0.25; and c) the reaction mixture contains either no co-diacid, or comprises a small amount of co-diacid, wherein, if the reaction mixture comprises a small amount of co-diacid, then acid equivalents from co-diacid contribute less than 25% of the total acid equivalents present in the reaction mixture.
Abstract translation: 具有连接的内部聚醚嵌段和内部聚酰胺嵌段的共聚物具有有利的物理性能和溶剂胶凝性能。 共聚物可以由含有1,4-环己烷二羧酸（CHDA）和聚（亚烷基氧基）二胺（PAODA）的反应混合物制备。 任选地，反应混合物不含有与胺或羧酸基团反应的单官能化合物，然而这些单官能化合物可能存在一些。 二聚体二胺和/或二聚酸可存在于反应混合物中。 共聚物也可以由包含二聚酸和至少两种二胺化合物（包括PAODA）和具有2-6个碳原子的短链脂族二胺（SDA）的反应混合物制备，其中：a）反应混合物包含x克 PAODA和y克的SDA，x /（x + y）为0.8-0.98; b）反应混合物重Zg，x / z至少为0.25; 和c）反应混合物不含共二酸或包含少量的共二酸，其中如果反应混合物包含少量的共二酸，则来自共二酸的酸当量贡献小于25重量％ 的反应混合物中存在的总酸当量。
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公开(公告)号：US08114387B2
公开(公告)日：2012-02-14
申请号：US11753447
申请日：2007-05-24
Applicant: Mark S. Pavlin
Inventor： Mark S. Pavlin
CPC classification number: C08G69/40 , A61K8/0229 , A61K8/042 , A61K8/90 , A61Q1/14 , A61Q15/00 , A61Q17/02 , A61Q17/04 , A61Q19/00 , C08G2650/50 , C08L71/02 , C08L77/00 , C08L77/06 , C08L2205/05 , C08L2666/20
Abstract: Copolymers having linked internal polyether blocks and internal polyamide blocks have advantageous physical properties and solvent-gelling abilities. The copolymer may be prepared from a reaction mixture that contains 1,4-cyclohexane dicarboxylic acid (CHDA) and poly(alkyleneoxy) diamine (PAODA). Optionally, the reaction mixture contains no monofunctional compound reactive with either amine or carboxylic acid groups, however some of this monofunctional compound may be present. Dimer diamine and/or dimer acid may be present in the reaction mixture. A copolymer may also be prepared from a reaction mixture containing dimer acid and at least two diamine compound(s) including PAODA and short-chain aliphatic diamine having 2-6 carbons (SDA), wherein: a) the reaction mixture comprises x grams of PAODA and y grams of SDA, and x/(x+y) is 0.8-0.98; b) the reaction mixture weighs z grams, and x/z is at least 0.25; and c) the reaction mixture contains either no co-diacid, or comprises a small amount of co-diacid, wherein, if the reaction mixture comprises a small amount of co-diacid, then acid equivalents from co-diacid contribute less than 25% of the total acid equivalents present in the reaction mixture.
Abstract translation: 具有连接的内部聚醚嵌段和内部聚酰胺嵌段的共聚物具有有利的物理性能和溶剂胶凝性能。 共聚物可以由含有1,4-环己烷二羧酸（CHDA）和聚（亚烷基氧基）二胺（PAODA）的反应混合物制备。 任选地，反应混合物不含有与胺或羧酸基团反应的单官能化合物，然而这些单官能化合物可能存在一些。 二聚体二胺和/或二聚酸可存在于反应混合物中。 共聚物也可以由包含二聚酸和至少两种二胺化合物（包括PAODA）和具有2-6个碳原子的短链脂族二胺（SDA）的反应混合物制备，其中：a）反应混合物包含x克 PAODA和y克的SDA，x /（x + y）为0.8-0.98; b）反应混合物重Zg，x / z至少为0.25; 和c）反应混合物不含共二酸或包含少量的共二酸，其中如果反应混合物包含少量的共二酸，则来自共二酸的酸当量贡献小于25重量％ 的反应混合物中存在的总酸当量。
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9.发明申请POLYALKYLENE GLYCOL-BASED POLY(ESTER-AMIDE) POLYMERS, METHODS OF MAKING AND METHODS OF USING SAME, COMPOSITIONS AND PRODUCTS COMPRISING SAME 失效聚对苯二甲酸乙二醇酯聚（聚酰胺）聚合物，其制备方法及其使用方法，组合物和包含其的产品公开(公告)号：US20100069286A1
公开(公告)日：2010-03-18
申请号：US12211248
申请日：2008-09-16
Applicant: Mark S. Pavlin
Inventor： Mark S. Pavlin
Abstract: Polyether poly(ester-amide) block copolymer having a softening point between 60° C. and 180° C., formed from reaction mixtures comprising a diacid, a poly(alkyleneoxy)diamine, and a poly(alkyleneoxy)polyol, wherein said diacid is a cyclohexane dicarboxylic acid; or formed from reaction mixtures comprising a diacid, a short chain aliphatic diamine having 2-6 carbons, and a poly(alkyleneoxy)polyol. Methods for making and using said block copolymers, compositions and articles comprising said block copolymers.
Abstract translation: 由包含二酸，聚（亚烷氧基）二胺和聚（亚烷氧基）多元醇的反应混合物形成的软化点在60℃和180℃之间的聚醚聚（酯 - 酰胺）嵌段共聚物，其中所述二酸 是环己烷二羧酸; 或由包含二酸，具有2-6个碳的短链脂族二胺和聚（亚烷氧基）多元醇的反应混合物形成。 制备和使用所述嵌段共聚物，包含所述嵌段共聚物的组合物和制品的方法。
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公开(公告)号：US06268466B1
公开(公告)日：2001-07-31
申请号：US09225889
申请日：1999-01-04
Applicant: Richard C. MacQueen , Mark S. Pavlin
Inventor： Richard C. MacQueen , Mark S. Pavlin
IPC: C08G6902
CPC classification number: A61Q19/00 , A61K8/0229 , A61K8/042 , A61K8/31 , A61K8/375 , A61K8/88 , A61K2800/52 , A61Q1/06 , A61Q15/00 , C08G69/34 , C08G69/48
Abstract: A low molecular weight, tertiary amide terminated polyamide may be blended with a liquid hydrocarbon to form a transparent composition having gel consistency. The tertiary amide terminated polyamide may be prepared by reacting “x” equivalents of dicarboxylic acid wherein at least 50% of those equivalents are from polymerized fatty acid, “y” equivalents of diamine such as ethylene diamine, and “z” equivalents of a monofunctional reactant having a secondary amine group as the only reactive functionality. The stoichiometry of the reaction mixture is preferably such that 0.9≦{x/(y+z)}≦1.1 and 0.1≦{z/(y+z)}≦0.7. The gel contains about 5-50% tertiary amide terminated polyamide, with the remainder preferably being pure hydrocarbon. The gels are useful in formulating personal care products and other articles wherein some degree of gel-like or self-supporting consistency is desired.
Abstract translation: 可以将低分子量叔胺封端的聚酰胺与液体烃混合以形成具有凝胶稠度的透明组合物。 叔酰胺封端的聚酰胺可以通过使“x”当量的二羧酸反应，其中至少50％的那些当量来自聚合的脂肪酸，“y”当量的二胺例如乙二胺，“z”当量的单官能 具有仲胺基团的反应物作为唯一的反应性官能团。 反应混合物的化学计量优选为0.9 <= {x /（y + z）} <= 1.1和0.1 <= {z /（y + z）} <= 0.7。 凝胶含有约5-50％叔酰胺封端的聚酰胺，其余的优选为纯烃。 凝胶可用于配制个人护理产品和其它需要一定程度的凝胶状或自支撑稠度的制品。
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