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1.发明授权Surface-modified mixed oxides containing precious metal and titanium, for the selective oxidation of hydrocarbons 失效含有贵金属和钛的表面改性混合氧化物，用于烃的选择性氧化公开(公告)号：US06734133B1
公开(公告)日：2004-05-11
申请号：US09980603
申请日：2002-02-21
IPC分类号： C04B3503
CPC分类号： B01J31/0274 , B01J23/48 , B01J29/89 , B01J31/122 , B01J2231/72 , C07D301/10 , C07D303/04
摘要： This invention relates to a process for the production of a composition containing gold and/or silver particles, mixed oxides containing titanium and silicon which have been surface-modified, to the compositions producible in this process and to the use thereof in processes for the selective oxidation of hydrocarbons in the presence of oxygen and a reducing agent. The catalytically active compositions exhibit constantly high selectivities and productivities.
摘要翻译： 本发明涉及一种生产包含金和/或银颗粒，含有钛和硅的混合氧化物的组合物的方法，所述混合氧化物已被表面改性，可用于该方法中可生产的组合物及其在选择性方法中的用途 在氧气和还原剂存在下氧化烃。 催化活性组合物表现出不断高的选择性和生产率。
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2.发明授权Sol-gel hybrid materials containing precious metals as catalysts for partial oxidation of hydrocarbons 失效含有贵金属的溶胶 - 凝胶杂化材料作为烃部分氧化的催化剂公开(公告)号：US06753287B1
公开(公告)日：2004-06-22
申请号：US10019997
申请日：2001-10-19
IPC分类号： C07D30103
CPC分类号： C07D303/04 , B01J23/52 , B01J37/036 , C07C45/34 , C07D301/10 , C07C49/08
摘要： The present invention relates to a process for preparing a composition containing gold and/or silver particles and an amorphous, organic/inorganic titanium/silicon mixed oxide, the compositions which can be prepared by this process and their use as catalysts for the selective oxidation of hydrocarbons.
摘要翻译： 本发明涉及一种制备含有金和/或银颗粒和无定形有机/无机钛/硅混合氧化物的组合物的方法，该组合物可以通过该方法制备及其作为催化剂用于选择性氧化 碳氢化合物。
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3.发明授权公开(公告)号：US06995113B1
公开(公告)日：2006-02-07
申请号：US10149056
申请日：2000-11-27
CPC分类号： C07D301/10 , B01J23/50 , B01J23/52 , B01J31/0274 , B01J2231/72
摘要： The present invention relates to noble metal-containing catalysts which are composed of at least one organic/inorganic hybrid material which is composed of at least one titanium component and at least one Si—H group. The catalysts of the present invention have increased activity compared to known catalysts.
摘要翻译： 本发明涉及由至少一种由至少一种钛组分和至少一种Si-H基组成的有机/无机混合材料组成的含贵金属的催化剂。 与已知的催化剂相比，本发明的催化剂具有增加的活性。
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公开(公告)号：US06603028B1
公开(公告)日：2003-08-05
申请号：US09762179
申请日：2001-03-23
IPC分类号： C07D30110
CPC分类号： C07D301/10 , C07B41/00 , C07C29/50 , C07D301/04 , Y10S977/773 , Y10S977/775 , Y10S977/811 , Y10S977/89 , Y10S977/896 , C07C31/12
摘要： The invention relates to a method for oxidizing hydrocarbons with a hydrogen/oxygen mixture in the presence of a catalyst. The catalyst contains a) a support material which contains titanium and b) silver particles having an average particle size ranging from 0.3 to 100 nm.
摘要翻译： 本发明涉及一种在催化剂存在下用氢/氧混合物氧化烃的方法。 该催化剂含有a）含有钛的载体材料和b）平均粒度范围为0.3-100nm的银颗粒。
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5.发明授权公开(公告)号：US06548682B1
公开(公告)日：2003-04-15
申请号：US09601260
申请日：2000-09-18
申请人： Markus Weisbeck , Ernst-Ulrich Dorf , Gerhard Wegener , Christoph Schild , Bernhard Lücke , Herbert Dilcher , Ulrich Schülke
发明人： Markus Weisbeck , Ernst-Ulrich Dorf , Gerhard Wegener , Christoph Schild , Bernhard Lücke , Herbert Dilcher , Ulrich Schülke
IPC分类号： C07D30110
CPC分类号： B01J23/52 , B01J35/0013 , C07D301/10 , Y10S977/775 , Y10S977/89 , Y10S977/896 , Y10S977/931
摘要： A supported catalyst coated with gold particles is produced. This supported catalyst is used to oxidize unsaturated hydrocarbons in the gas phase with a hydrogen/oxygen mixture.
摘要翻译： 制备涂有金颗粒的载体催化剂。 该载体催化剂用于用氢/氧混合物氧化气相中的不饱和烃。
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公开(公告)号：US06504039B2
公开(公告)日：2003-01-07
申请号：US10146248
申请日：2002-05-15
申请人： Markus Weisbeck , Ernst-Ulrich Dorf , Gerhard Wegener , Christoph Schild , Bernhard Lücke , Herbert Dilcher , Ulrich Schülke
发明人： Markus Weisbeck , Ernst-Ulrich Dorf , Gerhard Wegener , Christoph Schild , Bernhard Lücke , Herbert Dilcher , Ulrich Schülke
IPC分类号： C07D30110
CPC分类号： B01J23/52 , B01J35/0013 , C07D301/10 , Y10S977/775 , Y10S977/89 , Y10S977/896 , Y10S977/931
摘要： The present invention relates to supported catalysts which are composed of titanium oxide hydrates coated with nanoscale gold particles. The catalysts of the present invention have increased activity over known catalysts.
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公开(公告)号：US20080015371A1
公开(公告)日：2008-01-17
申请号：US11891800
申请日：2007-08-13
IPC分类号： B01J29/06 , B01J37/00 , C07D301/03
CPC分类号： B01J29/89 , C07D301/12
摘要： The present invention provides a catalyst containing titanium in bonded form, non-crystalline silicon dioxide and at least one crystalline silicate phase which has a zeolite structure, wherein the non-crystalline silicon dioxide is applied to at least one of the crystalline silicate phases which have a zeolite structure and wherein at least one of the crystalline silicate phases which have a zeolite structure contains silicon-carbon bonds with which non-hydrolytically separable organic groups R are bonded to silicon. Furthermore, the present invention provides a process for preparing this catalyst and a process for producing an epoxide from a compound which contains a carbon-carbon double bond (preferably from propene) comprising reacting the compound which contains a carbon-carbon double bond with hydrogen peroxide in the presence of the catalyst according to the invention.
摘要翻译： 本发明提供一种催化剂，其含有键合形式的钛，非结晶二氧化硅和至少一种具有沸石结构的结晶硅酸盐相，其中将非结晶二氧化硅施加到至少一个结晶硅酸盐相，其具有 沸石结构，并且其中具有沸石结构的结晶硅酸盐相中的至少一个含有硅 - 碳键，非水解可分离的有机基团R与硅键合。 此外，本发明提供了一种制备该催化剂的方法和由含有碳 - 碳双键（优选丙烯）的化合物制备环氧化物的方法，包括使含有碳 - 碳双键的化合物与过氧化氢 在根据本发明的催化剂的存在下。
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公开(公告)号：US07271116B2
公开(公告)日：2007-09-18
申请号：US10842994
申请日：2004-05-11
CPC分类号： B01J29/89 , C07D301/12
摘要： The present invention provides a catalyst containing titanium in bonded form, non-crystalline silicon dioxide and at least one crystalline silicate phase which has a zeolite structure, wherein the non-crystalline silicon dioxide is applied to at least one of the crystalline silicate phases which have a zeolite structure and wherein at least one of the crystalline silicate phases which have a zeolite structure contains silicon-carbon bonds with which non-hydrolytically separable organic groups R are bonded to silicon. Furthermore, the present invention provides a process for preparing this catalyst and a process for producing an epoxide from a compound which contains a carbon-carbon double bond (preferably from propene) comprising reacting the compound which contains a carbon-carbon double bond with hydrogen peroxide in the presence of the catalyst according to the invention.
摘要翻译： 本发明提供一种催化剂，其含有键合形式的钛，非结晶二氧化硅和至少一种具有沸石结构的结晶硅酸盐相，其中将非结晶二氧化硅施加到至少一个结晶硅酸盐相，其具有 沸石结构，并且其中具有沸石结构的结晶硅酸盐相中的至少一个含有硅 - 碳键，非水解可分离的有机基团R与硅键合。 此外，本发明提供了一种制备该催化剂的方法和由含有碳 - 碳双键（优选丙烯）的化合物制备环氧化物的方法，包括使含有碳 - 碳双键的化合物与过氧化氢 在根据本发明的催化剂的存在下。
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公开(公告)号：US06770765B2
公开(公告)日：2004-08-03
申请号：US10340289
申请日：2003-01-10
IPC分类号： C07D30104
CPC分类号： C07D301/10 , B01J23/48 , B01J23/52 , B01J37/0209 , B01J37/0211 , B01J37/0215 , B01J37/033 , C07C45/33 , C07C45/34 , C07C47/22
摘要： The present invention provides hydro-oxidation catalysts for the oxidation of hydrocarbons, containing an organic-inorganic hybrid material as well as gold particles and/or silver particles, a process for the production thereof, and the use thereof as a catalyst.
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公开(公告)号：US07456303B2
公开(公告)日：2008-11-25
申请号：US11891800
申请日：2007-08-13
IPC分类号： C07D301/12
CPC分类号： B01J29/89 , C07D301/12
摘要： The present invention provides a catalyst containing titanium in bonded form, non-crystalline silicon dioxide and at least one crystalline silicate phase which has a zeolite structure, wherein the non-crystalline silicon dioxide is applied to at least one of the crystalline silicate phases which have a zeolite structure and wherein at least one of the crystalline silicate phases which have a zeolite structure contains silicon-carbon bonds with which non-hydrolytically separable organic groups R are bonded to silicon. Furthermore, the present invention provides a process for preparing this catalyst and a process for producing an epoxide from a compound which contains a carbon-carbon double bond (preferably from propene) comprising reacting the compound which contains a carbon-carbon double bond with hydrogen peroxide in the presence of the catalyst according to the invention.
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