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    Process for the preparation of synthesis gas
    3.
    发明授权
    Process for the preparation of synthesis gas 有权
    合成气的制备方法

    公开(公告)号：US07087192B2

    公开(公告)日：2006-08-08

    申请号：US10667392

    申请日：2003-09-23

    申请人： Thomas Rostrup-Nielsen ,  Niels Erikstrup ,  Peter Seier Christensen ,  Kim Aasberg-Petersen ,  Jens-Henrik Bak Hansen ,  Ib Dybkjaer

    发明人： Thomas Rostrup-Nielsen ,  Niels Erikstrup ,  Peter Seier Christensen ,  Kim Aasberg-Petersen ,  Jens-Henrik Bak Hansen ,  Ib Dybkjaer

    IPC分类号： C01B3/38

    CPC分类号： C01B3/384 ,  C01B3/382 ,  C01B2203/0233 ,  C01B2203/0816 ,  C01B2203/1011 ,  C01B2203/1023 ,  C01B2203/1035 ,  C01B2203/142 ,  Y02P20/129

    摘要： Process and apparatus for the preparation of synthesis gas by catalytic steam and/or CO2 reforming of a hydrocarbon feedstock comprising the following steps: (a) heating the reaction mixture of hydrocarbon feedstock and steam and/or CO2 in the flue gas containing waste heat section from the fired tubular reformer (b) adiabatic reforming of the reaction mixture outside the waste heat section by contact with a solid reforming catalyst (c) repeating steps (a) and (b) until the desired reaction mixture composition and temperature is reached (d) feeding the reaction mixture to the fired tubular reformer and further reforming the mixture to the desired composition and temperature, wherein the adiabatic reforming of the reaction mixture is conducted in the process gas piping system in the flue gas-containing waste heat section, the piping system having adiabatic zones outside the heating section and containing solid reforming catalysts comprising one or more catalyzed structured elements.

    摘要翻译： 通过烃原料的催化蒸汽和/或CO 2重整制备合成气的方法和装置，包括以下步骤：（a）加热烃原料和蒸汽和/或CO的反应混合物 （b）通过与固体重整催化剂（c）接触使反应混合物在废热段外部进行绝热重整，重复步骤（a）， 和（b）直到达到所需的反应混合物组成和温度（d）将反应混合物进料到烧制的管状重整器中，并进一步将混合物重整成所需的组成和温度，其中反应混合物的绝热重整在 含烟道气废热段的处理气体管道系统，该管道系统在加热段外部具有绝热区，并含有固体重整催化剂，其包含一个或多个催化的st 被推翻的元素。

    Process for the preparation of a synthesis gas
    5.
    发明授权
    Process for the preparation of a synthesis gas 有权
    合成气的制备方法

    公开(公告)号：US07094363B2

    公开(公告)日：2006-08-22

    申请号：US10668295

    申请日：2003-09-24

    申请人： Peter Seier Christensen ,  Thomas Rostrup Nielsen ,  Niels Erikstrup ,  Kim Aasberg-Petersen ,  Jens-Henrik Bak Hansen ,  Ib Dybkjaer

    发明人： Peter Seier Christensen ,  Thomas Rostrup Nielsen ,  Niels Erikstrup ,  Kim Aasberg-Petersen ,  Jens-Henrik Bak Hansen ,  Ib Dybkjaer

    IPC分类号： C01B3/38

    CPC分类号： C01B3/382 ,  C01B3/384 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/0816 ,  C01B2203/0844 ,  C01B2203/1011 ,  C01B2203/1035 ,  C01B2203/143 ,  Y02P20/129 ,  Y02P20/142

    摘要： Process and apparatus for the preparation of synthesis gas by catalytic steam and/or CO2 reforming of a hydrocarbon feedstock comprising the following steps: (a) heating the reaction mixture of hydrocarbon and steam and/or CO2 in a heated steam reforming unit integrated with the flue gas containing waste heat section from the fired tubular reformer in which reforming of the reaction mixture takes place by contact with a solid reforming catalyst (b) feeding the partially steam reformed mixture to the fired tubular reformer and further reforming the mixture to the desired composition and temperature, wherein the heated steam reforming unit comprises a piping system containing reaction sections with solid reforming catalyst comprising catalyst pellets and/or catalysed structured elements, the piping system being part of the process gas piping system integrated with the flue gas-containing waste heat section.

    摘要翻译： 通过烃原料的催化蒸汽和/或CO 2重整制备合成气的方法和装置，包括以下步骤：（a）加热烃和蒸汽和/或CO的反应混合物， 在与来自燃烧的管状重整器的含有废热部分的废气的一体化的加热蒸汽重整单元中，其中反应混合物的重整通过与固体重整催化剂（b）接触而进行的，所述固体重整催化剂（b） 重整混合物到烧制的管式重整器中，并进一步将混合物重整成所需的组成和温度，其中加热的蒸汽重整单元包括含有反应段的管道系统，固体重整催化剂包含催化剂颗粒和/或催化的结构化元素，管道系统 与含烟气的废热段集成的工艺气体管道系统的一部分。

    Process for the production of electrical energy in an internal reforming high temperature fuel cell
    7.
    发明授权
    Process for the production of electrical energy in an internal reforming high temperature fuel cell 失效
    在内部重整型高温燃料电池中生产电能的方法

    公开(公告)号：US5688609A

    公开(公告)日：1997-11-18

    申请号：US535750

    申请日：1995-09-28

    申请人： Jens Rostrup-Nielsen ,  Lars J. Christiansen ,  Kim Aasberg-Petersen

    发明人： Jens Rostrup-Nielsen ,  Lars J. Christiansen ,  Kim Aasberg-Petersen

    IPC分类号： H01M8/0612 ,  H01M8/1231 ,  H01M8/124 ,  H01M8/10

    CPC分类号： H01M8/0625 ,  H01M8/1231 ,  H01M2008/1293 ,  H01M2300/0074

    摘要： A process for producing electrical energy in an internal reforming, high-temperature fuel cell. Steam reforming of a carbonaceous feed gas takes place in the presence of a steam-reforming catalyst in heat-conducting relationship with electrochemical reactions in the fuel cell. The steam reformed feed gas is electrochemically reacted in an anode compartment of the fuel cell. The process is improved by controlled addition of a gaseous, sulfur-containing compound to the carbonaceous feed gas in an amount sufficient to obtain a sulfur coverage on the steam reforming catalyst of between 0.1 to 0.9.

    摘要翻译： 一种在内部重整高温燃料电池中产生电能的方法。 含碳进料气体的蒸汽重整在与燃料电池中的电化学反应导热的蒸汽重整催化剂存在下进行。 蒸汽重整的进料气体在燃料电池的阳极室中电化学反应。 该方法通过将适量的气态含硫化合物以足以获得0.1至0.9的蒸汽重整催化剂上的硫覆盖的量向含碳进料气体中加入来提高。

    Process for generating electrical energy in a high temperature fuel cell
    8.
    发明授权
    Process for generating electrical energy in a high temperature fuel cell 失效
    在高温燃料电池中产生电能的方法

    公开(公告)号：US5705288A

    公开(公告)日：1998-01-06

    申请号：US619833

    申请日：1996-03-19

    申请人： Christian Olsen ,  Jens Rostrup Nielsen ,  Kim Aasberg-Petersen

    发明人： Christian Olsen ,  Jens Rostrup Nielsen ,  Kim Aasberg-Petersen

    IPC分类号： C01B3/40 ,  B01J23/89 ,  C10L3/00 ,  H01M8/0612 ,  H01M8/14 ,  H01M8/06

    CPC分类号： H01M8/0625 ,  H01M2008/147 ,  H01M2300/0051 ,  Y02E60/526

    摘要： Process for the generation of electrical energy in an internal reforming high temperature fuel cell, comprising steam and/or carbon dioxide reforming of a hydrocarbon feed gas in contact with a catalyst having activity in the steam reforming of the carbonaceous gas to fuel cell fuel gas and being arranged within the fuel cell in heat conducting relationship with electrochemical reactions proceeding in the cell; and electrochemically reacting the fuel gas in an anode compartment of the cell for the generation of electric energy, wherein the steam reforming activity of the catalyst has been reduced by including one or more salts of metals selected from Group IA, IB, IIA, IVA and VA of the Periodic Table in the catalyst.

    摘要翻译： 在内部重整高温燃料电池中产生电能的方法，包括与在碳质气体与燃料电池燃料气体的蒸汽转化中具有活性的催化剂接触的烃进料气体的蒸汽和/或二氧化碳重整，以及 在与电池中进行的电化学反应的热传导关系中布置在燃料电池内; 并且使电池的阳极室中的燃料气体电化学反应以产生电能，其中催化剂的蒸汽重整活性已经通过包括一种或多种选自IA，IB，IIA，IVA族和 VA在催化剂中的周期表。