公开(公告)号：US06375920B2

公开(公告)日：2002-04-23

申请号：US09284247

申请日：1999-04-15

申请人： Martin Fischer ,  Gerd Kaibel ,  Achim Stammer ,  Klemens Flick ,  Stefan Quaiser ,  Wolfgang Harder ,  Klemens Massonne

发明人： Martin Fischer ,  Gerd Kaibel ,  Achim Stammer ,  Klemens Flick ,  Stefan Quaiser ,  Wolfgang Harder ,  Klemens Massonne

IPC分类号： C01B1501

CPC分类号： B01J8/0492 ,  B01J8/0453 ,  B01J19/2465 ,  B01J19/2485 ,  B01J19/26 ,  B01J2208/00283 ,  B01J2208/00398 ,  B01J2208/00407 ,  C01B15/029

摘要： A process for preparing a hydrogen peroxide solution having a hydrogen peroxide content of not less than 2.5% by weight, which comprises continuously reacting hydrogen and oxygen in an aqueous, alcoholic or aqueous/alcoholic reaction medium in the presence of a catalyst containing palladium.

摘要翻译： 一种制备过氧化氢含量不小于2.5重量％的过氧化氢溶液的方法，其包括在含有钯的催化剂存在下，在含水，醇或水/醇反应介质中连续地使氢和氧反应。

公开(公告)号：US06518441B2

公开(公告)日：2003-02-11

申请号：US09424847

申请日：1999-12-06

申请人： Georg Heinrich Grosch ,  Ulrich Müller ,  Andreas Walch ,  Norbert Rieber ,  Martin Fischer ,  Stefan Quaiser ,  Wolfgang Harder ,  Karsten Eller ,  Peter Bassler ,  Anne Wenzel ,  Gerd Kaibel ,  Achim Stammer ,  Jochem Henkelmann ,  Arnd Böttcher ,  Joaquim Henrique Teles ,  Michael Schulz ,  Gert Treiber

发明人： Georg Heinrich Grosch ,  Ulrich Müller ,  Andreas Walch ,  Norbert Rieber ,  Martin Fischer ,  Stefan Quaiser ,  Wolfgang Harder ,  Karsten Eller ,  Peter Bassler ,  Anne Wenzel ,  Gerd Kaibel ,  Achim Stammer ,  Jochem Henkelmann ,  Arnd Böttcher ,  Joaquim Henrique Teles ,  Michael Schulz ,  Gert Treiber

IPC分类号： C07D30112

CPC分类号： C07D301/19 ,  B01J29/90 ,  B01J38/14 ,  C07B41/00 ,  C07D301/12 ,  Y02P20/584

摘要： A process for oxidizing an organic compound having at least one C—C double bond or a mixture of two or more thereof comprises the following steps: (I) preparing a hydroperoxide, (II) reacting an organic compound having at least one C—C double bond or a mixture of two or more thereof with the hydroperoxide prepared in step (I) in the presence of a zeolite catalyst, (III) regenerating the at least partially deactivated zeolite catalyst used in step (II), and (IV) conducting the reaction of step (II) using a zeolite catalyst containing the catalyst regenerated in step (III).

摘要翻译： 氧化具有至少一个CC双键的有机化合物或其两种或多种的混合物的方法包括以下步骤：（I）制备氢过氧化物，（II）使具有至少一个CC双键的有机化合物或 在沸石催化剂存在下，在步骤（I）中制备的氢过氧化物的两种或更多种的混合物与再生步骤（II）中使用的至少部分失活的沸石催化剂的（III）反应，和（Ⅳ）进行步骤 （II）使用含有在步骤（III）中再生的催化剂的沸石催化剂。

公开(公告)号：US06676919B1

公开(公告)日：2004-01-13

申请号：US09926274

申请日：2001-10-04

申请人： Martin Fischer ,  Markus Hölzle ,  Stefan Quaiser ,  Achim Stammer

发明人： Martin Fischer ,  Markus Hölzle ,  Stefan Quaiser ,  Achim Stammer

IPC分类号： C01B1501

CPC分类号： C01B15/029 ,  B01J23/40 ,  B01J35/0013 ,  B01J35/006 ,  B01J37/0225 ,  C07C29/145 ,  C07C33/22

摘要： The invention relates to a method for producing catalysts by immersion coating a metallic support with at least one platinum metal. An aqueous medium which comprises at least one platinum metal complex, at least one reduction agent and at least one complexer and which has a pH value of more than 4 is brought into contact with the metallic support in order to deposit the platinum metal, the platinum metal being deposited in the form of discreet, immobilised particles. The invention also relates to the catalysts obtained using this method and to their use for producing hydrogen peroxide and for hydrogenating organic compounds.

摘要翻译： 本发明涉及通过用至少一种铂金浸渍涂覆金属载体来制备催化剂的方法。 包含至少一种铂金属络合物，至少一种还原剂和至少一种络合器并且pH值大于4的水性介质与金属载体接触以沉积铂金属，铂 金属以谨慎的，固定的颗粒的形式沉积。 本发明还涉及使用该方法获得的催化剂及其用于生产过氧化氢和用于氢化有机化合物的用途。

公开(公告)号：US06592840B1

公开(公告)日：2003-07-15

申请号：US09673247

申请日：2000-10-23

申请人： Martin Fischer ,  Achim Stammer ,  Stefan Quaiser

发明人： Martin Fischer ,  Achim Stammer ,  Stefan Quaiser

IPC分类号： C01B1501

CPC分类号： H01L21/02052 ,  C01B15/01 ,  C01B15/013 ,  C01B15/0135 ,  C01B15/029

摘要： Disclosed are a highly pure aqueous hydrogen peroxide solution for use in the electronics industry and a process for the preparation of such solutions, which are essentially free from organics, which comprises catalytically converting hydrogen and oxygen, electrochemically reducing oxygen or electrolyzing an acidic ammonium sulfate solution, in each case in water and with the exclusion of organic compounds and materials which release such compounds.

摘要翻译： 公开了一种用于电子工业的高纯度过氧化氢水溶液，以及制备基本上不含有机物的溶液的方法，该方法包括催化转化氢和氧，电化学还原氧或电解酸性硫酸铵溶液 在每种情况下都是在水中，排除释放这些化合物的有机化合物和材料。

公开(公告)号：US06427985B1

公开(公告)日：2002-08-06

申请号：US09625486

申请日：2000-07-25

申请人： Gerd Kaibel ,  Manfred Stroezel ,  Achim Stammer

发明人： Gerd Kaibel ,  Manfred Stroezel ,  Achim Stammer

IPC分类号： B01F304

CPC分类号： F28C3/08 ,  B01J19/32 ,  B01J2219/3221 ,  B01J2219/32213 ,  B01J2219/32227 ,  B01J2219/32258 ,  B01J2219/32272 ,  B01J2219/32408 ,  B01J2219/32466 ,  Y10S261/72

摘要： A structured packing for heat exchange and mass transfer between a liquid and a gas in a column having at least one packing layer with a first, lower end and a second, upper end is described, the packing layer having an internal geometry which varies over its height so that by suitably setting the liquid and gas flow rates in a first, in particular lower, region of the packing layer a bubbling layer having a predominantly disperse gas phase forms in a targeted manner and simultaneously in a second, in particular upper, region of the packing layer a film flow of the liquid having a predominantly continuous gas phase forms in a targeted manner.

摘要翻译： 描述了一种用于在具有至少一个具有第一，下端和第二上端的填料层的塔中的液体和气体之间的热交换和质量传递的规整填料，所述填料层具有内部几何形状 高度，使得通过适当地将液体和气体流速设定在填料层的第一个，特别是较低的区域中，具有主要分散气相的起泡层以目标方式形成，同时在第二特别是上部区域 的填料层，以目标的方式形成具有主要连续气相的液体的膜流。

公开(公告)号：US07431804B2

公开(公告)日：2008-10-07

申请号：US10477466

申请日：2002-05-17

申请人： Eckhard Ströfer ,  Gerd Kaibel ,  Achim Stammer ,  Carsten Oost ,  Martin Sohn ,  Manfred Stroezel ,  Walter Dobler

发明人： Eckhard Ströfer ,  Gerd Kaibel ,  Achim Stammer ,  Carsten Oost ,  Martin Sohn ,  Manfred Stroezel ,  Walter Dobler

IPC分类号： B01D3/28 ,  B01D3/42 ,  B01V19/32

CPC分类号： B01D3/009 ,  B01J19/32 ,  B01J2219/3221 ,  B01J2219/32213 ,  B01J2219/32227 ,  B01J2219/32258 ,  B01J2219/32272 ,  B01J2219/32408 ,  B01J2219/32466 ,  B01J2219/3306 ,  B01J2219/3325 ,  C07C17/38 ,  C07C17/383 ,  C07C263/20 ,  Y02P20/127 ,  Y10S203/06 ,  Y10S203/11 ,  Y10S261/72 ,  C07C25/06 ,  C07C265/14

摘要： A process is proposed for the distillation or reactive distillation of a mixture that includes at least one toxic component, the process being carried out in a column containing a structured packing, having at least one packing layer (1) having a lower end (2) and an upper end (3), the packing layer having an internal geometry varying over its height, in such a manner that in the distillation or reactive distillation, in a first, lower region (6) of the packing layer (1) a bubbling layer having a predominantly disperse gas phase can be established and simultaneously in a second, upper region (7) of the packing layer (1) a film flow having a predominantly continuous gas phase can be established.

摘要翻译： 提出了一种包括至少一种有毒成分的混合物的蒸馏或反应蒸馏的方法，该方法在含有规整填料的塔中进行，该塔具有至少一个具有下端（2）的填料层（1） 和上端（3），所述填充层具有在其高度上变化的内部几何形状，使得在所述蒸馏或反应蒸馏中，在所述填充层（1）的第一下部区域（6）中具有鼓泡 可以建立具有主要分散气相的层，同时在填料层（1）的第二上部区域（7）中建立具有主要连续气相的膜流。

公开(公告)号：US06511053B2

公开(公告)日：2003-01-28

申请号：US09888610

申请日：2001-06-26

申请人： Gerd Kaibel ,  Achim Stammer ,  Manfred Stroezel

发明人： Gerd Kaibel ,  Achim Stammer ,  Manfred Stroezel

IPC分类号： B01F304

CPC分类号： B01J19/32 ,  B01J2219/3221 ,  B01J2219/32213 ,  B01J2219/32237 ,  B01J2219/32262 ,  B01J2219/32408 ,  Y10S261/72

摘要： The invention relates to a packing sheet having straight-line kinks which divide the packing sheet into kink areas which have a width a, measured from kink edge to kink edge, and passage apertures, where a proportion X of at least 60% of the passage apertures has a separation b of at most 0.4 a from a kink edge.

公开(公告)号：US20120065339A1

公开(公告)日：2012-03-15

申请号：US13226568

申请日：2011-09-07

申请人： Rolf-Egbert Grützner ,  Shankara Narayanan Keelapandal Ramamoorthy ,  Faissal-Ali El-Toufaili ,  Achim Gerstlauer ,  Achim Stammer

发明人： Rolf-Egbert Grützner ,  Shankara Narayanan Keelapandal Ramamoorthy ,  Faissal-Ali El-Toufaili ,  Achim Gerstlauer ,  Achim Stammer

IPC分类号： C08G69/48

CPC分类号： C08G69/48 ,  C08G69/46

摘要： Process for producing polyamides that are stable during processing, by treating the polyamide during the solid-phase postcondensation process with a gas which comprises carrier gas (inert gas), water, and acid, or an anhydride or lactone or a mixture of these or, respectively, comprises ammonia, or amine, or a mixture of these, at a temperature from 130 to 200° C. and at a pressure of from 0.01 to 10 bar.

摘要翻译： 用于制备在加工过程中稳定的聚酰胺的方法，通过在固相缩聚过程中用包含载气（惰性气体），水和酸的酸性物质或其酸酐或内酯或其混合物的气体处理聚酰胺， 分别包含氨或胺，或它们的混合物，温度为130-200℃，压力为0.01至10巴。

公开(公告)号：US08013087B2

公开(公告)日：2011-09-06

申请号：US12443554

申请日：2007-10-02

申请人： Dennis Lösch ,  Marco Krüger ,  Achim Stammer

发明人： Dennis Lösch ,  Marco Krüger ,  Achim Stammer

IPC分类号： C08F20/06 ,  C08F2/00 ,  B01J20/22 ,  B01J20/26

CPC分类号： C08F2/00 ,  C08F2/01 ,  C08F2/10 ,  C08F2/16 ,  C08F2/18 ,  C08F220/06 ,  C08F222/1006 ,  Y10S526/93

摘要： A process for preparing water-absorbing polymer beads by polymerizing droplets of a monomer solution in a gas phase surrounding the droplets, the initiator being added to the monomer solution from 0.5 to 60 seconds before the droplets are generated.

摘要翻译： 通过在包围液滴的气相中聚合单体溶液的液滴来制备吸水聚合物珠粒的方法，该引发剂在液滴产生之前从0.5至60秒添加到单体溶液中。

公开(公告)号：US20070155972A1

公开(公告)日：2007-07-05

申请号：US10583696

申请日：2004-12-21

申请人： Neven Lang ,  Eckhard Stroefer ,  Achim Stammer ,  Thorsten Friese ,  Markus Siegert ,  Michael Ott ,  Hans Hasse ,  Thomas Grutzner ,  Sergej Blagov

发明人： Neven Lang ,  Eckhard Stroefer ,  Achim Stammer ,  Thorsten Friese ,  Markus Siegert ,  Michael Ott ,  Hans Hasse ,  Thomas Grutzner ,  Sergej Blagov

IPC分类号： C07D305/12 ,  C07C41/03

CPC分类号： C07D323/06 ,  B01D3/146 ,  B01D3/36 ,  Y02P20/127

摘要： A process for removing trioxane from a mixture I of formaldehyde, trioxane and water, by a) distilling the mixture I in a first distillation stage at a pressure of from 0.1 to 2 bar to obtain a stream II which comprises formaldehyde and a stream III which comprises predominantly trioxane and additionally water and formaldehyde, b) mixing the stream III with a recycle stream VII which comprises predominantly trioxane and additionally water and formaldehyde to obtain a stream IIIa which comprises predominantly trioxane and additionally water and formaldehyde, c) distilling the stream IIIa, if appropriate after removing low boilers from the stream III or IIIa in a further distillation stage, in a second distillation stage at a pressure of from 0.2 to 10 bar, the pressure in the second distillation stage being at least 0.1 bar higher than the pressure in the first distillation stage, to obtain a stream IV of trioxane and a stream V which comprises predominantly trioxane and additionally water and formaldehyde, d) distilling the stream V in a third distillation stage at a pressure of from 0.1 to 4 bar to obtain a stream VI which comprises predominantly water and additionally formaldehyde, and the recycle stream VII which comprises predominantly trioxane and additionally water and formaldehyde, e) if appropriate, distilling the stream VI in a fourth distillation stage to obtain a stream VIII which comprises predominantly water, and a stream IX which comprises predominantly formaldehyde.

摘要翻译： 一种从甲醛，三恶烷和水的混合物I中除去三恶烷的方法，通过以下步骤a）在0.1至2巴的压力下在第一蒸馏阶段中蒸馏混合物I以获得包含甲醛和流III的流II 主要包含三恶烷，另外还含有水和甲醛，b）将流III与主要包含三恶烷，另外含有水和甲醛的再循环流VII混合，得到主要含有三恶烷，另外含有水和甲醛的流IIIa，c）蒸馏流IIIa 如果适当，则在进一步蒸馏阶段从流III或IIIa除去低锅炉后，在0.2至10巴的压力的第二蒸馏阶段中，第二蒸馏阶段中的压力比压力高至少0.1巴 在第一蒸馏阶段，获得三恶烷的流IV和主要包含三恶烷并另外包含的流V 和d）在0.1至4巴的压力下在第三蒸馏阶段中蒸馏物流V以获得主要包含水和另外甲醛的物流VI，以及主要包含三恶烷和另外的水的再循环流VII，以及 甲醛，e）如果合适，在第四蒸馏阶段中蒸馏物流VI以获得主要包含水的物流VIII和主要包含甲醛的物流IX。