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    PROCESS FOR PREPARING CHLORINE FROM HCI
    1.
    发明申请
    PROCESS FOR PREPARING CHLORINE FROM HCI 审中-公开
    从HCI制备氯仿的方法

    公开(公告)号：US20120093711A1

    公开(公告)日：2012-04-19

    申请号：US13378082

    申请日：2010-06-17

    申请人： Martin Karches ,  Kati Bachmann ,  Martin Sesing ,  Lothar Seidemann ,  Knud Jacobsen

    发明人： Martin Karches ,  Kati Bachmann ,  Martin Sesing ,  Lothar Seidemann ,  Knud Jacobsen

    IPC分类号： C01B7/04

    摘要： Process for preparing chlorine by oxidation of hydrogen chloride by means of oxygen in the presence of a particulate catalyst in a fluidized-bed reactor, where the heat of reaction of the exothermic oxidation of hydrogen chloride is removed by means of water which circulates in the tubes of a shell-and-tube heat exchanger, where (i) the fluidized-bed reactor is heated up to an operating temperature in the range from 350 to 420° C. in a heating-up phase and (ii) hydrogen chloride is reacted with oxygen in an operating phase at the operating temperature, wherein (i-1) the fluidized-bed reactor is heated up to a temperature below the operating temperature in a first heating-up phase and (i-2) hydrogen chloride and oxygen are fed into the fluidized-bed reactor and reacted in a second heating-up phase in which the fluidized-bed reactor is heated up to the operating temperature by the heat of reaction of the exothermic oxidation of hydrogen chloride.

    摘要翻译： 通过在流化床反应器中的颗粒催化剂存在下通过氧气氧化氯化氢来制备氯的方法，其中通过在管中循环的水除去氯化氢的放热氧化的反应热 的管壳式热交换器，其中（i）流化床反应器在加热阶段被加热至350-420℃的操作温度，和（ii）使氯化氢反应 其中（i-1）在第一加热阶段将流化床反应器加热到低于工作温度的温度，（i-2）氯化氢和氧气是 进料到流化床反应器中并在第二加热阶段中反应，其中流化床反应器通过氯化氢的放热氧化的反应热被加热到操作温度。

    Process for preparing chlorine from HCI
    2.
    发明授权
    Process for preparing chlorine from HCI 有权

    公开(公告)号：US10703630B2

    公开(公告)日：2020-07-07

    申请号：US13378082

    申请日：2010-06-17

    申请人： Martin Karches ,  Kati Bachmann ,  Martin Sesing ,  Lothar Seidemann ,  Knud Jacobsen

    发明人： Martin Karches ,  Kati Bachmann ,  Martin Sesing ,  Lothar Seidemann ,  Knud Jacobsen

    IPC分类号： C01B7/04

    摘要： Process for preparing chlorine by oxidation of hydrogen chloride by means of oxygen in the presence of a particulate catalyst in a fluidized-bed reactor, where the heat of reaction of the exothermic oxidation of hydrogen chloride is removed by means of water which circulates in the tubes of a shell-and-tube heat exchanger, where (i) the fluidized-bed reactor is heated up to an operating temperature in the range from 350 to 420° C. in a heating-up phase and (ii) hydrogen chloride is reacted with oxygen in an operating phase at the operating temperature, wherein (i-1) the fluidized-bed reactor is heated up to a temperature below the operating temperature in a first heating-up phase and (i-2) hydrogen chloride and oxygen are fed into the fluidized-bed reactor and reacted in a second heating-up phase in which the fluidized-bed reactor is heated up to the operating temperature by the heat of reaction of the exothermic oxidation of hydrogen chloride.

    PROCESS FOR PREPARING CHLORINE
    3.
    发明申请
    PROCESS FOR PREPARING CHLORINE 审中-公开
    制备氯仿的方法

    公开(公告)号：US20110318259A1

    公开(公告)日：2011-12-29

    申请号：US13255111

    申请日：2010-03-25

    申请人： Martin Karches ,  Kati Bachmann ,  Martin Sesing ,  Bernd Rumpf ,  Oliver Odenwald ,  Lothar Seidemann

    发明人： Martin Karches ,  Kati Bachmann ,  Martin Sesing ,  Bernd Rumpf ,  Oliver Odenwald ,  Lothar Seidemann

    IPC分类号： C01B7/04

    CPC分类号： C01B7/04

    摘要： A process for preparing chlorine by oxidation of hydrogen chloride in the presence of a heterogeneous particulate catalyst by the Deacon process in a fluidized-bed reactor (1), in which the heat of reaction is removed by evaporative cooling by means of water which circulates in the tubes (2) of a shell-and-tube heat exchanger, with the water being fed from a steam drum (4) via a feed line (5) to the tubes (2) of the shell-and-tube heat exchanger at one end of these, being heated in the tubes (2) by uptake of the heat of reaction and partly vaporizing to give a water/steam mixture which at the other end of the tubes (2) of the shell-and-tube heat exchanger is recirculated via a return line (6) to the steam drum (4), wherein the maximum pressure for which the fluidized-bed reactor (1) has to be designed to allow for the event of rupture of a tube (2) of the shell-and-tube heat exchanger is minimized by a valve (7) which in the event of a pressure increase as a result of rupture of a tube (2) closes the feed line (5) and the return line (6) is installed in the feed line (5) and the return line (6) and thereby prevents water flowing from the steam drum (4) into the fluidized-bed reactor (1), is proposed.

    摘要翻译： 在流化床反应器（1）中通过Deacon方法在异相颗粒催化剂存在下通过氯化氢氧化制备氯的方法，其中反应热通过在水中循环的水蒸发冷却除去 管式热交换器的管（2），其中水从蒸汽鼓（4）通过供给管线（5）供给到管壳式热交换器的管（2） 其一端通过吸收反应热并部分蒸发而在管（2）中加热，得到水/蒸汽混合物，其在管壳式热交换器的管（2）的另一端 通过返回管线（6）再循环到蒸汽鼓（4），其中流化床反应器（1）必须被设计成允许管（2）的破裂的事件的最大压力 管壳式换热器通过阀（7）最小化，阀（7）在由于管的破裂而发生压力增加的情况下 （2）关闭进料管线（5），并且返回管线（6）安装在进料管线（5）和返回管线（6）中，从而防止水从蒸汽鼓（4）流入流化床 反应堆（1）。

    METHOD FOR PRODUCING CHLORINE BY GAS PHASE OXIDATION OF HYDROGEN CHLORIDE IN A FLUIDIZED-BED REACTOR
    4.
    发明申请
    METHOD FOR PRODUCING CHLORINE BY GAS PHASE OXIDATION OF HYDROGEN CHLORIDE IN A FLUIDIZED-BED REACTOR 审中-公开
    通过在流化床反应器中氯化氢气相氧化生产氯的方法

    公开(公告)号：US20120134913A1

    公开(公告)日：2012-05-31

    申请号：US13389081

    申请日：2010-07-28

    申请人： Martin Karches ,  Kati Bachmann ,  Martin Sesing ,  Lothar Seidemann ,  Michael Pilz

    发明人： Martin Karches ,  Kati Bachmann ,  Martin Sesing ,  Lothar Seidemann ,  Michael Pilz

    IPC分类号： C01B7/04

    CPC分类号： C01B7/04 ,  B01J8/0055 ,  B01J8/18

    摘要： A process for preparing chlorine by gas-phase oxidation of hydrogen chloride over a heterogeneous, particulate catalyst in a fluidized-bed reactor to give a product gas mixture which is freed of entrained catalyst particles in cyclones (1) which are arranged in the upper region of the fluidized-bed reactor, which comprises a cylindrical upper part (2) which has a tangential or spiral-shaped inlet (3) for the product gas mixture and tapers at its lower end via a conical section (4) into a cyclone downcomer tube (5) and also a central downward-extending tube (6) in the upper region of the cyclone (1) for discharging the product gas mixture which has been freed of entrained catalyst particles, whereinfrom one to seven cascades of in each case from two to five cyclones (1) connected in series are used, with the cyclones (1) of each cascade, with the exception of the first cyclone (1) through which flow occurs in each case, which is designed so that about 90 to 99% by weight of the entrained catalyst particles are precipitated, each having a trickle valve (7) comprising an angled tube end piece (8) and also a loose flap (9) suspended at an angle α to the vertical at the lower end of the cyclone downcomer tube (5), where the angle α and the weight of the flap (9) are designed so that the torque of the flap (9) divided by the diameter of the outlet opening from the angled tube end piece (8) is in the range from 2 to 300 N/m2, is proposed.

    摘要翻译： 一种通过在流化床反应器中的非均相颗粒催化剂上对氯化氢进行气相氧化制备氯的方法，得到产物气体混合物，其在旋风分离器（1）中排除夹带的催化剂颗粒，该气旋混合物排列在上部区域 的流化床反应器，其包括具有用于产物气体混合物的切向或螺旋形入口（3）的圆柱形上部（2），并且在其下端通过锥形部分（4）逐渐变细成旋风下降管 管（5），并且在旋风分离器（1）的上部区域还有中心向下延伸的管（6），用于排出已经没有夹带的催化剂颗粒的产物气体混合物，其中在每种情况下从一到七级联 使用串联连接的2到5个旋风分离器（1），每个级联的旋风分离器（1）除了在每种情况下都发生流体的第一旋流器（1）之外，其被设计为使得大约90至 99％重量的夹带物 催化剂颗粒沉淀，每个具有滴流阀（7），其包括成角度的管端部件（8），以及松散的挡板（9），其与旋风降低管（5）的下端处的垂直方向成α ），其中角度α和翼片（9）的重量被设计成使得翼片（9）的扭矩除以与成角度的管端部件（8）的出口开口直径的距离在2 至300 N / m2。