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    Titanocenes and a radiation-polymerizable composition containing these titanocenes
    2.
    发明授权
    Titanocenes and a radiation-polymerizable composition containing these titanocenes 失效
    钛菁和含有这些二茂钛的可放射线聚合组合物

    公开(公告)号：US4855468A

    公开(公告)日：1989-08-08

    申请号：US099362

    申请日：1987-09-11

    申请人： Martin Riediker ,  Kurt Meier ,  Hans Zweifel

    发明人： Martin Riediker ,  Kurt Meier ,  Hans Zweifel

    IPC分类号： C08F2/00 ,  C07F7/28 ,  C07F17/00 ,  C08F2/50 ,  C08F4/76 ,  G03C1/00 ,  G03F7/004 ,  G03F7/029

    CPC分类号： G03F7/029 ,  C07F17/00 ,  C07F7/28 ,  C08F2/50 ,  Y10S430/126 ,  Y10S430/148

    摘要： Titanocenes with .pi.-cyclopentadienyl ligands, in which one or two carbocyclic or heterocyclic aromatic rings are bonded to the metal, the aromatic rings being substituted in at least one of the two ortho-positions relative to the metal-carbon bonds by CF.sub.2 Z (Z=F or substituted or unsubstituted alkyl), are suitable as photoinitiators for the photopolymerization of ethylenically unsaturated compounds. They are distinguished by a high radiation sensitivity, stability to air and thermal effects, and high effectiveness in the range from UV light to visible light.

    摘要翻译： 其中一个或两个碳环或杂环芳环与金属键合，所述芳环在相对于金属 - 碳键的两个邻位中的至少一个中被CF 2 Z取代（Z = F或取代或未取代的烷基）适用作用于烯属不饱和化合物的光聚合的光引发剂。 它们的特征在于高辐射敏感性，对空气的稳定性和热效应，以及在从紫外光到可见光的范围内的高效率。

    Photoinitiator mixtures containing a titanocene and a 3-ketocoumarin
    3.
    发明授权
    Photoinitiator mixtures containing a titanocene and a 3-ketocoumarin 失效
    含有二茂钛和3-酮香豆素的光引发剂混合物

    公开(公告)号：US5011755A

    公开(公告)日：1991-04-30

    申请号：US473135

    申请日：1990-01-30

    申请人： Ottmar Rohde ,  Armin Schaffner ,  Martin Riediker ,  Kurt Meier

    发明人： Ottmar Rohde ,  Armin Schaffner ,  Martin Riediker ,  Kurt Meier

    IPC分类号： C08F2/50 ,  C08F290/00 ,  C08F299/02 ,  C08G73/10 ,  G03F7/028 ,  G03F7/029

    CPC分类号： G03F7/029 ,  C08F2/50 ,  Y10S430/107 ,  Y10S430/12 ,  Y10S430/125 ,  Y10S430/148 ,  Y10S502/522

    摘要： The present invention relates to compositions comprising(a) a titanocene photoinitiator of the formula I ##STR1## (b) a 3-ketocoumarin of the formula II ##STR2## in which both R.sup.1, R.sup.2 and R.sup.3 are as defined in claim 1, R.sup.4 is a radical of the formula V ##STR3## R.sup.5 is C.sub.1 -C.sub.20 alkyl, cycloalkyl having 5-7 ring carbon atoms, phenyl or naphthyl which are unsubstituted or substituted by one to three C.sub.1 -C.sub.6 alkyl groups, C.sub.1 -C.sub.6 alkoxy groups or halogen atoms or by one diphenylamino or C.sub.1 -C.sub.6 dialkylamino group, or is C.sub.7 -C.sub.9 aralkyl, a radical --(CH.dbd.CH).sub.a --C.sub.6 H.sub.5 or a radical of the formula V, a is 1 or 2, preferably 1, and R.sup.10, R.sup.11, R.sup.12, R.sup.13 and R.sup.14 independently of one another are hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkoxy, phenyl, tolyl, xylyl or benzyl, and R.sup.11 can additionally also be a group --NR.sup.15 R.sup.16 or --OR.sup.15, wherein R.sup.15 and R.sup.16 independently of one another are hydrogen or C.sub.1 -C.sub.6 alkyl, it also being possible for two or three of the radicals R.sup.10, R.sup.11, R.sup.12 and R.sup.13 together with the ring carbon atoms, to which they are attached, to form a fused ring having 5 or 6 ring atoms or a fused ring system having 5-membered or 6-membered rings. The photoinitiator mixtures can be used in combination with ethylenically unsaturated monomers, preferably with photopolymerizable precursors of thermally stable polymers. These mixtures can be processed especially on substrates having surfaces which are strongly scattering or strongly reflecting, to give relief structures with high resolution.

    摘要翻译： 本发明涉及组合物，其包含（a）式I的二茂钛光引发剂（I）（b）式II的3-酮香豆素（II），其中R1，R2和R3均为 权利要求1中定义的R 4是式V的基团（V）R 5是C 1 -C 20烷基，具有5-7个环碳原子的环烷基，未被取代或被一至三个C 1 -C 6烷基取代的苯基或萘基 C 1 -C 6烷氧基或卤素原子或一个二苯基氨基或C 1 -C 6二烷基氨基，或者是C 7 -C 9芳烷基，基团 - （CH = CH）a -C 6 H 5或式V基团，a是1或2，优选 1和R 10，R 11，R 12，R 13和R 14彼此独立地是氢，C 1 -C 6烷基，C 1 -C 6烷氧基，苯基，甲苯基，二甲苯基或苄基，R 11还可以是基团-NR 15 R 16或-OR 15，其中 R 15和R 16彼此独立地是氢或C 1 -C 6烷基，基团R 10，R 11，R 12和R 13中的两个或三个与环碳原子一起也可以 它们相连，形成具有5或6个环原子的稠环或具有5元环或6元环的稠环体系。 光引发剂混合物可以与烯属不饱和单体组合使用，优选与热稳定聚合物的可光聚合前体一起使用。 这些混合物可以特别在具有强散射或强烈反射的表面的基底上进行加工，以提供高分辨率的浮雕结构。

    Hardenable composition and its use
    4.
    发明授权
    Hardenable composition and its use 失效
    硬化组合物及其用途

    公开(公告)号：US5494944A

    公开(公告)日：1996-02-27

    申请号：US292658

    申请日：1994-08-18

    申请人： Kurt Meier ,  Hans Zweifel

    发明人： Kurt Meier ,  Hans Zweifel

    IPC分类号： C08F2/46 ,  C08F2/54 ,  C08G59/68 ,  C08G85/00 ,  G03F7/029

    CPC分类号： C08G85/00 ,  C08G59/68 ,  G03F7/029

    摘要： A hardenable composition containing:a) a material polymerizable by free radical or cationic polymerization,b) at least one iron compound of the formula I ##EQU1## wherein a is 1 or 2 and q is 1, 2 or 3,L is a divalent to heptavalent metal or non-metal,Q is a halogen atom,m is an integer corresponding to the sum of the values of L and q,R.sup.1 is an unsubstituted or substituted .eta..sup.6 -benzene andR.sup.2 is an unsubstituted or substituted cyclopentadienyl anion, andc) at least one sensitizer for the compound of the formula I,and, in the case of materials polymerizable by free radical polymerization, also d) an electron acceptor as an oxidizing agent, which is also advantageously used concomitantly for the material polymerizable by cationic polymerization. The composition is suitable for the production of protective layers and photographic images.

    摘要翻译： 一种可硬化组合物，其包含：a）通过自由基或阳离子聚合可聚合的材料，b）至少一种式I（I）的铁化合物，其中a为1或2，q为1,2或3，L 是二价至七价金属或非金属，Q是卤素原子，m是对应于L和q的值之和的整数，R 1是未取代或取代的η6 - 苯，R 2是未取代或取代的 环戊二烯基阴离子，和c）至少一种式I化合物的敏化剂，并且在通过自由基聚合反应的物质的情况下，还可以d）作为氧化剂的电子受体，其也有利地同时用于 通过阳离子聚合可聚合的材料。 该组合物适用于生产保护层和摄影图像。

    Cationically polymerizable compositions containing iron metallolene salt
    6.
    发明授权
    Cationically polymerizable compositions containing iron metallolene salt 失效
    含有金属茂金属盐的阳离子聚合性组合物

    公开(公告)号：US5371115A

    公开(公告)日：1994-12-06

    申请号：US870156

    申请日：1992-04-15

    申请人： Kurt Meier ,  Hans Zweifel

    发明人： Kurt Meier ,  Hans Zweifel

    IPC分类号： C08F2/46 ,  C08F2/54 ,  C08G59/68 ,  C08G85/00 ,  G03F7/029 ,  C08G59/72 ,  G03F7/004 ,  G03F7/038

    CPC分类号： C08G85/00 ,  C08G59/68 ,  G03F7/029

    摘要： A hardenable composition containing:a) a material polymerizable by free radical or cationic polymerization,b) at least one iron compound of the formula I ##EQU1## wherein a is 1 or 2 and q is 1, 2 or 3,L is a divalent to heptavalent metal or non-metal,Q is a halogen atom,m is an integer corresponding to the sum of the values of L and q,R.sup.1 is an unsubstituted or substituted .eta..sup.6 -benzene andR.sup.2 is an unsubstituted or substituted cyclopentadienyl anion, andc) at least one sensitizer for the compound of the formula I,and, in the case of materials polymerizable by free radical polymerization, also d) an electron acceptor as an oxidizing agent, which is also advantageously used concomitantly for the material polymerizable by cationic polymerization. The composition is suitable for the production of protective layers and photographic images.

    摘要翻译： 一种可硬化组合物，其包含：a）通过自由基或阳离子聚合可聚合的材料，b）至少一种式I（I）的铁化合物，其中a为1或2，q为1,2或3，L 是二价至七价金属或非金属，Q是卤素原子，m是对应于L和q的值之和的整数，R 1是未取代或取代的η6 - 苯，R 2是未取代或取代的 环戊二烯基阴离子，和c）至少一种式I化合物的敏化剂，并且在通过自由基聚合反应的物质的情况下，还可以d）作为氧化剂的电子受体，其也有利地同时用于 通过阳离子聚合可聚合的材料。 该组合物适用于生产保护层和摄影图像。

    Epoxy acrylates
    8.
    发明授权
    Epoxy acrylates 失效
    环氧丙烯酸酯

    公开(公告)号：US06479596B1

    公开(公告)日：2002-11-12

    申请号：US08652394

    申请日：1996-05-23

    申请人： Martin Roth ,  Roger Salvin ,  Kurt Meier ,  Bernhard Sailer ,  Rolf Wiesendanger

    发明人： Martin Roth ,  Roger Salvin ,  Kurt Meier ,  Bernhard Sailer ,  Rolf Wiesendanger

    IPC分类号： C08F28300

    CPC分类号： C08G59/1466 ,  C08G59/066 ,  Y10S525/922

    摘要： Novel epoxy acrylates and carboxyl group-containing epoxy acrylates of formulae II and III of the claims that are relatively highmolecular and are chemically crosslinkable can be used in photoresist formulations with the additional use of highly polymerised polymer binders. Such resist formulations are used in particular in the field of printed circuit boards and printing plates, are applicable from aqueous medium, are almost tack-free and have very good edge coverage, especially on conductors.

    摘要翻译： 具有相对高分子量且化学可交联的权利要求的式II和III的新型环氧丙烯酸酯和含羧基的环氧丙烯酸酯可以用于另外使用高度聚合的聚合物粘合剂的光致抗蚀剂制剂中。 这种抗蚀剂制剂特别用于印刷电路板和印刷版领域，适用于水性介质，几乎无粘性，并且具有非常好的边缘覆盖率，特别是在导体上。

    Process for ensuring a neutral vehicle handling during cornering and a simultaneous load change
    9.
    发明授权
    Process for ensuring a neutral vehicle handling during cornering and a simultaneous load change 失效
    在转弯期间确保中性车辆处理和同时进行负载更换的过程

    公开(公告)号：US5908225A

    公开(公告)日：1999-06-01

    申请号：US807747

    申请日：1997-02-27

    申请人： Kurt Meier

    发明人： Kurt Meier

    IPC分类号： B60T8/1766 ,  B60T8/32

    CPC分类号： B60T8/1766 ,  Y10S303/06

    摘要： A process for ensuring a neutral vehicle handling during cornering and a simultaneous load change is provided by the operation of a vehicle system having at least one driven axle, an axle differential gear, wheel brakes for the selective deceleration of an individual wheel, a device for recognizing a cornering and a device for recognizing a coasting operation and for generating a signal corresponding to the intensity of the coasting operation. The problem of rear-wheel driven and front-wheel driven vehicles is the vehicle handling during cornering in the coasting operation. As a result, depending on the method of operation, an oversteering or understeering of the vehicle is caused. The process avoids these problems in that, during a cornering, a wheel of the driven axle is decelerated at least as a function of the coasting operation signal such that the moment generated thereby, such as a counter-yawing moment, compensates the yawing moment caused by the cornering during the coasting operation.

    摘要翻译： 通过具有至少一个从动轴，车轴差速齿轮，用于单个车轮的选择性减速的车轮制动器的车辆系统的操作来提供用于确保转弯期间的中立车辆处理和同时负载变化的过程，用于单个车轮的选择性减速的装置 识别转弯和用于识别惯性操作并产生对应于惯性操作强度的信号的装置。 后轮驱动和前轮驱动车辆的问题是在滑行操作中转弯期间的车辆处理。 结果，根据操作方法，引起车辆过度转向或转向不足。 该过程避免了这些问题，即在转弯期间，至少根据惯性操作信号使从动轴的车轮减速，使得由此产生的力矩（例如反偏转力矩）补偿所引起的偏航力矩 在滑行期间转弯。

    Cationically polymerizable mixtures containing selected metallocene complex salts as curing agents
    10.
    发明授权
    Cationically polymerizable mixtures containing selected metallocene complex salts as curing agents 失效
    含有选择的茂金属络合盐作为固化剂的阳离子可聚合混合物

    公开(公告)号：US5565500A

    公开(公告)日：1996-10-15

    申请号：US310452

    申请日：1994-09-22

    申请人： Kurt Meier ,  Roger P. Salvin

    发明人： Kurt Meier ,  Roger P. Salvin

    IPC分类号： C08K5/56 ,  C07F17/02 ,  C08F2/50 ,  C08G59/40 ,  C08L101/00 ,  C09D5/00 ,  G03F7/029 ,  C08G59/18 ,  C08F16/18 ,  C08F18/04

    CPC分类号： G03F7/029 ,  Y10S430/115

    摘要： The invention relates to mixtures containing:a) a cationically polymerizable compound andb) a compound of the formula I[R.sup.1 (Fe.sup.II R.sup.2).sub.a ].sub.q.sup..sym.an anX.sup..crclbar.q (I)in which a is 1 or 2, n is 1 or 2, R.sup.1 is a substituted or unsubstituted .pi.-arene, R.sup.2 is a substituted or unsubstituted .pi.-arene or cyclopentadienyl anion or indenyl anion, q is an integer from 1 to 3 and X is FSO.sub.3.sup.- or a q-valent anion of an organic sulfonic acid or of a carboxylic acid; R.sup.1 can also be a polymeric, aromatic ligand. The invention also relates to the novel compounds of the formula I. The curable mixtures can be processed in particular for the production of coatings having a good resistance to heat.

    摘要翻译： 本发明涉及含有：a）阳离子可聚合化合物和b）式I [R1（FeIIR2）a] q（+）ananX（ - ）q（I）的化合物，其中a为1或2，n 是1或2，R1是取代或未取代的对 - 芳基，R2是取代或未取代的对 - 芳基或环戊二烯基阴离子或茚基阴离子，q是1至3的整数，X是FSO 3 - 或q-价阴离子 的有机磺酸或羧酸; R1也可以是聚合的芳族配体。 本发明还涉及式I的新型化合物。可固化混合物可特别用于制备具有良好耐热性的涂料。