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    Method for producing chlorine
    1.
    发明授权
    Method for producing chlorine 有权
    生产氯的方法

    公开(公告)号：US08097232B2

    公开(公告)日：2012-01-17

    申请号：US11816045

    申请日：2006-02-20

    申请人： Martin Sesing ,  Armin Diefenbacher ,  Hartwig Voss ,  Olga Schubert ,  Lothar Seidemann ,  Martin Karches ,  Thomas Grassler ,  Eckhard Stroefer

    发明人： Martin Sesing ,  Armin Diefenbacher ,  Hartwig Voss ,  Olga Schubert ,  Lothar Seidemann ,  Martin Karches ,  Thomas Grassler ,  Eckhard Stroefer

    IPC分类号： C01B7/04

    CPC分类号： C01B7/075 ,  C01B7/04 ,  C01B7/0743

    摘要： A catalytic process for preparing chlorine from hydrogen chloride, which includes recycle of process streams with reduced accumulation of inert gases in the system is provided. The process includes a step wherein a compressed liquid stream comprising chlorine, carbon dioxide and oxygen is recycled into a column countercurrent to the ascending gas phase and feeding part of the chlorine-rich liquid phase leaving the bottom of the column back into the top of the column. Carbon dioxide present in the ascending gas stream is dissolved out of the gas stream and can later be separated from chlorine without problems by distillation.

    摘要翻译： 提供了一种从氯化氢制备氯的催化方法，其包括在系统中减少惰性气体积聚的工艺流的再循环。 该方法包括一个步骤，其中将包含氯气，二氧化碳和氧气的压缩液体流循环到与上升气相逆流的塔中，并使离开塔底的富氯液相的一部分进入到顶部 柱。 存在于上升气流中的二氧化碳从气流中溶解出来，随后可以通过蒸馏从氯中分离而无问题。

    Method For Producing Chlorine
    2.
    发明申请
    Method For Producing Chlorine 有权
    氯生产方法

    公开(公告)号：US20080159948A1

    公开(公告)日：2008-07-03

    申请号：US11816045

    申请日：2006-02-20

    申请人： Martin Sesing ,  Armin Diefenbacher ,  Hartwig Voss ,  Olga Schubert ,  Lothar Seidemann ,  Martin Karches ,  Thomas Grassler ,  Eckhard Stroefer

    发明人： Martin Sesing ,  Armin Diefenbacher ,  Hartwig Voss ,  Olga Schubert ,  Lothar Seidemann ,  Martin Karches ,  Thomas Grassler ,  Eckhard Stroefer

    IPC分类号： C01B7/04

    CPC分类号： C01B7/075 ,  C01B7/04 ,  C01B7/0743

    摘要： Process for preparing chlorine from hydrogen chloride, which comprises the steps: a) feeding of a stream a1 comprising hydrogen chloride and of a stream a2 comprising oxygen into an oxidation zone and catalytic oxidation of hydrogen chloride to chlorine, giving a product gas stream a3 comprising chlorine, water, oxygen, carbon dioxide and inert gases; b) cooling of the product gas stream a3 and removal of water and hydrogen chloride as aqueous hydrochloric acid, leaving a gas stream b comprising chlorine, water, oxygen, carbon dioxide and inert gases; c) optional drying of the gas stream b) to leave a gas stream c which is substantially free of water and comprises chlorine, oxygen, carbon dioxide and inert gases; d) at least partial liquefaction of the gas stream c and of a chlorine-rich recycle stream f1 comprising chlorine, oxygen and carbon dioxide by compression and cooling, giving an at least partially liquefied stream d; e) gas/liquid separation of the stream d into a gas stream e1 comprising chlorine, oxygen, carbon dioxide and inert gases and into a liquid stream e2 comprising chlorine, oxygen and carbon dioxide; f) feeding of at least part of the gas stream e1 into a membrane separation unit and fractionation by membrane separation to give the chlorine-rich recycle stream f1 and a gas stream f2 which is low in chlorine and comprises chlorine, oxygen and carbon dioxide and recirculation of the chlorine-rich recycle stream f1 to step d); g) separation of the liquid stream e2 by distillation into a chlorine stream g1 and a stream g2 comprising essentially oxygen and carbon dioxide.

    摘要翻译： 从氯化氢制备氯的方法，其包括以下步骤：a）将包含氯化氢的物流1和包含氧的物流2加入氧化区并将氯化氢催化氧化成氯，得到产物气流 a 3，包括氯，水，氧，二氧化碳和惰性气体; b）冷却产物气流a 3，除去水和氯化氢作为盐酸水溶液，留下包含氯，水，氧气，二氧化碳和惰性气体的气流b; c）气流的任选干燥b）留下基本上不含水的气流c，包括氯，氧，二氧化碳和惰性气体; d）通过压缩和冷却至少部分液化气流c和包含氯，氧和二氧化碳的富含氯的循环流f 1，产生至少部分液化的流d; e）将气流d气体/液体分离成包含氯气，氧气，二氧化碳和惰性气体的气流e 1并进入包含氯​​气，氧气和二氧化碳的液体流e 2中; f）将至少部分气流e 1进料到膜分离单元中并通过膜分离进行分馏，得到富氯循环流f 1和氯含量低的气流f 2，包括氯，氧和 二氧化碳和富氯循环流f 1再循环到步骤d）; g）通过蒸馏将液体流e 2分离成氯流g 1和基本上包含氧和二氧化碳的流g 2。

    Mechanically stable catalyst based on alpha-alumina
    4.
    发明授权
    Mechanically stable catalyst based on alpha-alumina 有权
    基于α-氧化铝的机械稳定催化剂

    公开(公告)号：US07910517B2

    公开(公告)日：2011-03-22

    申请号：US12064725

    申请日：2006-08-22

    申请人： Olga Schubert ,  Martin Sesing ,  Lothar Seidemann ,  Martin Karches ,  Thomas Grassler ,  Martin Sohn

    发明人： Olga Schubert ,  Martin Sesing ,  Lothar Seidemann ,  Martin Karches ,  Thomas Grassler ,  Martin Sohn

    IPC分类号： B01J23/00 ,  B01J21/00 ,  B01J20/00 ,  B01J29/00 ,  B01J37/00

    CPC分类号： C01B7/04 ,  B01J21/04 ,  B01J23/462 ,  B01J23/52 ,  B01J23/72 ,  B01J23/8926

    摘要： A catalyst for gas-phase reactions which has high mechanical stability and comprises one or more active metals on a support comprising aluminum oxide as support material, wherein the aluminum oxide in the support consists essentially of alpha-aluminum oxide.Ruthenium, copper and/or gold are preferred as active metal.Particularly preferred catalysts according to invention comprise a) from 0.001 to 10% by weight of ruthenium, copper and/or gold, b) from 0 to 5% by weight of one or more alkaline earth metals, c) from 0 to 5% by weight of one or more alkali metals, d) from 0 to 10% by weight of one or more rare earth metals, e) from 0 to 10% by weight of one or more further metals selected from the group consisting of palladium, platinum, osmium, iridium, silver and rhenium, in each case based on the total weight of the catalyst, on the support comprising alpha-Al2O3. The catalysts are preferably used in the oxidation of hydrogen chloride (Deacon reaction).

    摘要翻译： 一种用于气相反应的催化剂，其具有高机械稳定性并且在包含氧化铝作为载体材料的载体上包含一种或多种活性金属，其中载体中的氧化铝基本上由α-氧化铝组成。 作为活性金属，优选钌，铜和/或金。 根据本发明的特别优选的催化剂包含a）0.001至10重量％的钌，铜和/或金，b）0至5重量％的一种或多种碱土金属，c）0至5％ 一种或多种碱金属的重量，d）0至10重量％的一种或多种稀土金属，e）0至10重量％的一种或多种另外的金属，其选自钯，铂， 锇，铱，银和铼，在每种情况下，基于催化剂的总重量，在包含α-Al 2 O 3的载体上。 催化剂优选用于氯化氢的氧化（Deacon反应）。

    MECHANICALLY STABLE CATALYST BASED ON ALPHA-ALUMINA
    5.
    发明申请
    MECHANICALLY STABLE CATALYST BASED ON ALPHA-ALUMINA 有权
    基于ALPHA-ALUMINA的机械稳定催化剂

    公开(公告)号：US20110014114A1

    公开(公告)日：2011-01-20

    申请号：US12888082

    申请日：2010-09-22

    申请人： Olga SCHUBERT ,  Martin Sesing ,  Lothar Seidemann ,  Martin Karches ,  Thomas Grassler ,  Martin Sohn

    发明人： Olga SCHUBERT ,  Martin Sesing ,  Lothar Seidemann ,  Martin Karches ,  Thomas Grassler ,  Martin Sohn

    IPC分类号： C01B7/04

    CPC分类号： C01B7/04 ,  B01J21/04 ,  B01J23/462 ,  B01J23/52 ,  B01J23/72 ,  B01J23/8926

    摘要： A catalyst for gas-phase reactions which has high mechanical stability and comprises one or more active metals on a support comprising aluminum oxide as support material, wherein the aluminum oxide in the support consists essentially of alpha-aluminum oxide.Ruthenium, copper and/or gold are preferred as active metal.Particularly preferred catalysts according to invention comprise a) from 0.001 to 10% by weight of ruthenium, copper and/or gold, b) from 0 to 5% by weight of one or more alkaline earth metals, c) from 0 to 5% by weight of one or more alkali metals, d) from 0 to 10% by weight of one or more rare earth metals, e) from 0 to 10% by weight of one or more further metals selected from the group consisting of palladium, platinum, osmium, iridium, silver and rhenium, in each case based on the total weight of the catalyst, on the support comprising alpha-Al2O3. The catalysts are preferably used in the oxidation of hydrogen chloride (Deacon reaction).

    摘要翻译： 一种用于气相反应的催化剂，其具有高机械稳定性并且在包含氧化铝作为载体材料的载体上包含一种或多种活性金属，其中载体中的氧化铝基本上由α-氧化铝组成。 作为活性金属，优选钌，铜和/或金。 根据本发明的特别优选的催化剂包含a）0.001至10重量％的钌，铜和/或金，b）0至5重量％的一种或多种碱土金属，c）0至5％ 一种或多种碱金属的重量，d）0至10重量％的一种或多种稀土金属，e）0至10重量％的一种或多种另外的金属，其选自钯，铂， 锇，铱，银和铼，在每种情况下，基于催化剂的总重量，在包含α-Al 2 O 3的载体上。 催化剂优选用于氯化氢的氧化（Deacon反应）。

    Mechanically Stable Catalyst Based on Alpha-Alumina
    6.
    发明申请
    Mechanically Stable Catalyst Based on Alpha-Alumina 有权
    基于α-氧化铝的机械稳定催化剂

    公开(公告)号：US20080247941A1

    公开(公告)日：2008-10-09

    申请号：US12064725

    申请日：2006-08-22

    申请人： Olga Schubert ,  Martin Sesing ,  Lothar Seidemann ,  Martin Karches ,  Thomas Grassler ,  Martin Sohn

    发明人： Olga Schubert ,  Martin Sesing ,  Lothar Seidemann ,  Martin Karches ,  Thomas Grassler ,  Martin Sohn

    IPC分类号： C01B7/04 ,  B01J23/02 ,  B01J23/04 ,  B01J23/10 ,  B01J23/42 ,  B01J23/72 ,  B01J23/44 ,  B01J23/46 ,  B01J23/50 ,  B01J23/52

    CPC分类号： C01B7/04 ,  B01J21/04 ,  B01J23/462 ,  B01J23/52 ,  B01J23/72 ,  B01J23/8926

    摘要： A catalyst for gas-phase reactions which has high mechanical stability and comprises one or more active metals on a support comprising aluminum oxide as support material, wherein the aluminum oxide in the support consists essentially of alpha-aluminum oxide.Ruthenium, copper and/or gold are preferred as active metal.Particularly preferred catalysts according to invention comprise a) from 0.001 to 10% by weight of ruthenium, copper and/or gold, b) from 0 to 5% by weight of one or more alkaline earth metals, c) from 0 to 5% by weight of one or more alkali metals, d) from 0 to 10% by weight of one or more rare earth metals, e) from 0 to 10% by weight of one or more further metals selected from the group consisting of palladium, platinum, osmium, iridium, silver and rhenium, in each case based on the total weight of the catalyst, on the support comprising alpha-Al2O3. The catalysts are preferably used in the oxidation of hydrogen chloride (Deacon reaction).

    摘要翻译： 一种用于气相反应的催化剂，其具有高机械稳定性并且在包含氧化铝作为载体材料的载体上包含一种或多种活性金属，其中载体中的氧化铝基本上由α-氧化铝组成。 作为活性金属，优选钌，铜和/或金。 根据本发明的特别优选的催化剂包含a）0.001至10重量％的钌，铜和/或金，b）0至5重量％的一种或多种碱土金属，c）0至5％ 一种或多种碱金属的重量，d）0至10重量％的一种或多种稀土金属，e）0至10重量％的一种或多种另外的金属，其选自钯，铂， 锇，铱，银和铼，在每种情况下，基于催化剂的总重量，在包含α-Al 2 O 3 3的载体上。 催化剂优选用于氯化氢的氧化（Deacon反应）。

    PROCESS FOR PREPARING CHLORINE
    8.
    发明申请
    PROCESS FOR PREPARING CHLORINE 审中-公开
    制备氯仿的方法

    公开(公告)号：US20110318259A1

    公开(公告)日：2011-12-29

    申请号：US13255111

    申请日：2010-03-25

    申请人： Martin Karches ,  Kati Bachmann ,  Martin Sesing ,  Bernd Rumpf ,  Oliver Odenwald ,  Lothar Seidemann

    发明人： Martin Karches ,  Kati Bachmann ,  Martin Sesing ,  Bernd Rumpf ,  Oliver Odenwald ,  Lothar Seidemann

    IPC分类号： C01B7/04

    CPC分类号： C01B7/04

    摘要： A process for preparing chlorine by oxidation of hydrogen chloride in the presence of a heterogeneous particulate catalyst by the Deacon process in a fluidized-bed reactor (1), in which the heat of reaction is removed by evaporative cooling by means of water which circulates in the tubes (2) of a shell-and-tube heat exchanger, with the water being fed from a steam drum (4) via a feed line (5) to the tubes (2) of the shell-and-tube heat exchanger at one end of these, being heated in the tubes (2) by uptake of the heat of reaction and partly vaporizing to give a water/steam mixture which at the other end of the tubes (2) of the shell-and-tube heat exchanger is recirculated via a return line (6) to the steam drum (4), wherein the maximum pressure for which the fluidized-bed reactor (1) has to be designed to allow for the event of rupture of a tube (2) of the shell-and-tube heat exchanger is minimized by a valve (7) which in the event of a pressure increase as a result of rupture of a tube (2) closes the feed line (5) and the return line (6) is installed in the feed line (5) and the return line (6) and thereby prevents water flowing from the steam drum (4) into the fluidized-bed reactor (1), is proposed.

    摘要翻译： 在流化床反应器（1）中通过Deacon方法在异相颗粒催化剂存在下通过氯化氢氧化制备氯的方法，其中反应热通过在水中循环的水蒸发冷却除去 管式热交换器的管（2），其中水从蒸汽鼓（4）通过供给管线（5）供给到管壳式热交换器的管（2） 其一端通过吸收反应热并部分蒸发而在管（2）中加热，得到水/蒸汽混合物，其在管壳式热交换器的管（2）的另一端 通过返回管线（6）再循环到蒸汽鼓（4），其中流化床反应器（1）必须被设计成允许管（2）的破裂的事件的最大压力 管壳式换热器通过阀（7）最小化，阀（7）在由于管的破裂而发生压力增加的情况下 （2）关闭进料管线（5），并且返回管线（6）安装在进料管线（5）和返回管线（6）中，从而防止水从蒸汽鼓（4）流入流化床 反应堆（1）。

    PROCESS FOR PREPARING CHLORINE FROM HCI
    9.
    发明申请
    PROCESS FOR PREPARING CHLORINE FROM HCI 审中-公开
    从HCI制备氯仿的方法

    公开(公告)号：US20120093711A1

    公开(公告)日：2012-04-19

    申请号：US13378082

    申请日：2010-06-17

    申请人： Martin Karches ,  Kati Bachmann ,  Martin Sesing ,  Lothar Seidemann ,  Knud Jacobsen

    发明人： Martin Karches ,  Kati Bachmann ,  Martin Sesing ,  Lothar Seidemann ,  Knud Jacobsen

    IPC分类号： C01B7/04

    摘要： Process for preparing chlorine by oxidation of hydrogen chloride by means of oxygen in the presence of a particulate catalyst in a fluidized-bed reactor, where the heat of reaction of the exothermic oxidation of hydrogen chloride is removed by means of water which circulates in the tubes of a shell-and-tube heat exchanger, where (i) the fluidized-bed reactor is heated up to an operating temperature in the range from 350 to 420° C. in a heating-up phase and (ii) hydrogen chloride is reacted with oxygen in an operating phase at the operating temperature, wherein (i-1) the fluidized-bed reactor is heated up to a temperature below the operating temperature in a first heating-up phase and (i-2) hydrogen chloride and oxygen are fed into the fluidized-bed reactor and reacted in a second heating-up phase in which the fluidized-bed reactor is heated up to the operating temperature by the heat of reaction of the exothermic oxidation of hydrogen chloride.

    摘要翻译： 通过在流化床反应器中的颗粒催化剂存在下通过氧气氧化氯化氢来制备氯的方法，其中通过在管中循环的水除去氯化氢的放热氧化的反应热 的管壳式热交换器，其中（i）流化床反应器在加热阶段被加热至350-420℃的操作温度，和（ii）使氯化氢反应 其中（i-1）在第一加热阶段将流化床反应器加热到低于工作温度的温度，（i-2）氯化氢和氧气是 进料到流化床反应器中并在第二加热阶段中反应，其中流化床反应器通过氯化氢的放热氧化的反应热被加热到操作温度。