摘要:
This invention relates to flame retardants for polyester and polyamide compositions, and specifically relates to compositions containing (1) about 30 to about 70 weight percent of a polyester or a synthetic, aliphatic polyamide; (2) about 15 to about 40 weight percent of glass or mineral reinforcing agent; and (3) a flame retardant of (a) about 20 to about 30 weight percent of melamine phosphate and up to about 10 weight percent of a charring catalyst; (b) about 15 to about 30 weight percent of melamine phosphate, up to about 10 weight percent of a charring catalyst and up to about 10 weight percent of a char former; (c) about 25 to about 30 weight percent of melamine pyrophosphate; (d) about 15 to about 30 weight percent of melamine pyrophosphate and up to about 10 weight percent of a charring catalyst; or (e) about 15 to about 30 weight percent of melamine pyrophosphate, up to about 10 weight percent of a charring catalyst and up to about 10 weight percent of a char former, wherein all percents by weight are based on the total weight of (1)+(2)+(3) only.
摘要:
Disclosed is a thermoplastic composition including (A) a polyamide resin independently selected from the group consisting of Group (I) Polyamides having a melting point of at least 260° C., and comprising (a) greater than 95 mole percent semiaromatic repeat units and (b) less than 5 mole percent aliphatic repeat units; (B) 0 to 60 weight percent of one or more reinforcement agents; and(C) 0 to 50 weight percent of one or more a polymeric tougheners; wherein the weight percentages are based on the total weight of said thermoplastic composition; and wherein said polyamide resin has at least 50 meq/Kg of acid ends.
摘要:
Polyamides made from 1,6-hexanediamine, and the dicarboxylic acids 1,10-decandioic acid and/or 1,12-dodecanedioic acid, and terephthalic acid in specified proportions are particularly resistant to salt stressed (induced) corrosion cracking. This makes them particularly useful as vehicular parts which may be exposed to salts. Particularly when these polyamides contain tougheners and/or plasticizers they are especially useful for hoses and tubes.
摘要:
The present invention relates to a flame resistant polyamide resin compositions for moulded articles and articles formed therefrom, comprising aromatic polyamide with phosphinate and/or diphosphinate flame retardant and, optionally, glass fibers. Further provided are articles for use in a variety of applications including electrical and electronic parts requiring electrical insulation.
摘要:
Disclosed is a copolyamide including at least two repeat units selected from the group consisting of structures (I) to (IV), —C(O)(CH2)10C(O)NH(CH2)nNH— (I); —C(O)(CH2)12C(O)NH(CH2)nNH— (II); —C(O)(CH2)14C(O)NH(CH2)nNH— (II); and —C(O)(CH2)16C(O)NH(CH2)nNH— (IV); and n is an integer selected from 4, 6, 10 or 12; wherein at least one repeat unit is selected from structures (I) and (II); and any one the repeat units may be present up to about 92 mole percent. Also disclosed is a process for providing the copolyamide; and thermoplastic compositions and tubing including the copolyamides.
摘要:
Disclosed is a polyamide composition including at least one semi-aromatic copolyamide, said semi-aromatic copolyamide consisting essentially of about 25 to about 55 mole percent repeat units of the formula —C(O)(CH2)mC(O)NHCH2ArCH2NH— (I) and about 45 to about 75 mole percent repeat units of the formula —C(O)(CH2)mC(O)NH(CH2)nNH— (II) wherein m is 8, 10, and/or 12, n is 6, 10 and/or 12 and Ar is a meta-substituted benzene ring; and said polyamide has a melting point equal to or less than 225° C.; and 0.25 to 20 weight percent of one or more polyhydroxy polymer(s) having a number average molecular weight of at least 2000 and selected from the group consisting of ethylene/vinyl alcohol copolymer and poly(vinyl alcohol). Also disclosed are molded or extruded articles including the polyamide composition.
摘要:
Disclosed is a thermoplastic composition including (A) a polyamide resin independently selected from the group consisting of Group (IV) Polyamides comprising (aa) about 50 to about 95 mole percent semiaromatic repeat and (bb) about 5 to about 50 mole percent aliphatic repeat units; and Group (VI) Polyamides having no melting point, (B) about 0.25 to about 15 weight percent of one or more polyhydric alcohols having more than two hydroxyl groups and a having a number average molecular weight (Mn) of less than 2000; (C) 0 to 60 weight percent of one or more reinforcement agents; and (D) 0 to 50 weight percent of a polymeric toughener wherein said polyamide resin has at least about 70 meq/Kg of amine ends.
摘要:
Disclosed is a polyamide composition including at least one semi-aromatic copolyamide, said semi-aromatic copolyamide consisting essentially of about 25 to about 55 mole percent repeat units of the formula —C(O)(CH2)mC(O)NHCH2ArCH2NH— (I) and about 45 to about 75 mole percent repeat units of the formula —C(O)(CH2)mC(O)NH(CH2)nNH— (II) wherein m is 8, 10, and/or 12, n is 6, 10 and/or 12 and Ar is a meta-substituted benzene ring; and said polyamide has a melting point equal to or less than 225° C.; and 0.25 to 20 weight percent of one or more polyhydroxy polymer(s) having a number average molecular weight of at least 2000 and selected from the group consisting of ethylene/vinyl alcohol copolymer and poly(vinyl alcohol). Also disclosed are molded or extruded articles including the polyamide composition.
摘要:
Polyamides made from a combination of adipic acid, terephthalic acid and 1,6-hexanediamine in specified proportions have excellent salt stress corrosion cracking resistance. These polyamides are especially useful for vehicular parts that are exposed to contact with salts such as sodium chloride or calcium chloride that are used, for instance, for melting ice and/or snow on roadways.
摘要:
This invention relates to flame retardants for polyester and polyamide compositions, and specifically relates to compositions containing (1) about 30 to about 70 weight percent of a polyester or a synthetic, aliphatic polyamide and synthetic aliphatic, aromatic polyamide copolymers or a mixture thereof; (2) about 15 to about 40 weight percent of glass or mineral reinforcing agent; and (3) a flame retardant of (a) about 5 to about 45 weight percent of melamine polyphosphate; (b) about 15 to about 30 weight percent of melamine polyphosphate and up to about 10 weight percent of a charring catalyst; (c) about 15 to about 30 weight percent of melamine polyphosphate, up to about 10 weight percent of a charring catalyst and up to about 10 weight percent of a char former, wherein all percents by weight are based on the total weight of (1)+(2)+(3) only.