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1.发明授权Metal mold for manufacturing amorphous alloy and molded product of amorphous alloy 失效用于制造非晶合金的金属模具和非晶态合金的模制产品公开(公告)号：US06453977B2
公开(公告)日：2002-09-24
申请号：US09878332
申请日：2001-06-12
申请人： Masahide Onuki , Akihisa Inoue , Hisashi Kakiuchi
发明人： Masahide Onuki , Akihisa Inoue , Hisashi Kakiuchi
IPC分类号： B22D1800
CPC分类号： B22D23/06 , B22D11/0405 , B22D18/02
摘要： A metal mold for manufacturing amorphous alloy. A metal mold is composed of a lower mold having a portion for fusing metal material and a cavity portion, and an upper mold working with the lower mold which presses molten metal in the portion for fusing metal material and pours the molten metal into the cavity portion to mold. And, surface roughness of a part of or all of an inner surface of the metal mold is arranged to be more than 12S in JIS indication.
摘要翻译： 一种用于制造非晶合金的金属模具。 金属模具由具有用于熔融金属材料的部分和空腔部分的下模具以及与下模具一起工作的上模具，该下模具将用于熔融金属材料的部分中的熔融金属挤压并将熔融金属倒入空腔部分 模具。 并且，在JIS指示中，金属模具的内表面的一部分或全部的表面粗糙度被设置为大于12S。
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2.发明授权Metal mold for manufacturing amorphous alloy and molded product of amorphous alloy 失效用于制造非晶合金的金属模具和非晶态合金的模制产品公开(公告)号：US06267171B1
公开(公告)日：2001-07-31
申请号：US09207273
申请日：1998-12-08
申请人： Masahide Onuki , Akihisa Inoue , Hisashi Kakiuchi
发明人： Masahide Onuki , Akihisa Inoue , Hisashi Kakiuchi
IPC分类号： B22D1800
CPC分类号： B22D23/06 , B22D11/0405 , B22D18/02
摘要： A metal mold for manufacturing amorphous alloy. A metal mold is composed of a lower mold having a portion for fusing metal material and a cavity portion, and an upper mold working with the lower mold which presses molten metal in the portion for fusing metal material and pours the molten metal into the cavity portion to mold. And, surface roughness of a part of or all of an inner surface of the metal mold is arranged to be more than 12 S in JIS indication.
摘要翻译： 一种用于制造非晶合金的金属模具。 金属模具由具有用于熔融金属材料的部分和空腔部分的下模具以及与下模具一起工作的上模具，该下模具将用于熔融金属材料的部分中的熔融金属挤压并将熔融金属倒入空腔部分 模具。 并且，在JIS指示中，金属模具的内表面的一部分或全部的表面粗糙度被设置为大于12S。
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公开(公告)号：US06267170B1
公开(公告)日：2001-07-31
申请号：US09476209
申请日：1999-12-30
申请人： Masahide Onuki , Hisashi Kakiuchi , Akihisa Inoue
发明人： Masahide Onuki , Hisashi Kakiuchi , Akihisa Inoue
IPC分类号： B22D1800
摘要： A metal mold is composed of a lower mold having a portion for fusing metal material and a cavity portion, and an upper mold working with the lower mold which presses molten metal in the portion for fusing metal material and pours the molten metal into the cavity portion to mold. And, the portion for fusing metal material is composed of a material having a heat conductivity equal to or less than 250 kcal/(m·h·° C.).
摘要翻译： 金属模具由具有用于熔融金属材料的部分和空腔部分的下模具以及与下模具一起工作的上模具，该下模具将用于熔融金属材料的部分中的熔融金属挤压并将熔融金属倒入空腔部分 模具。 并且，用于熔融金属材料的部分由导热率等于或小于250kcal /（m.h.℃）的材料组成。
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公开(公告)号：US06371195B1
公开(公告)日：2002-04-16
申请号：US09515897
申请日：2000-02-29
IPC分类号： B22D2709
CPC分类号： A63B53/04 , A63B53/0466 , A63B53/047 , A63B2053/0416 , B22D18/02 , B22D23/06 , B22D27/04
摘要： A metal material is placed on a lower mold of a press metal mold which has an upper mold and the lower mold not having engagement portions. The metal material is fused by a high energy heat source, and obtained molten metal over a melting point is pressed with the press metal mold and transformed into a predetermined configuration. The molten metal is cooled at a rate over a critical cooling rate simultaneously with or after the transformation, and the molded product of amorphous metal in predetermined configuration is obtained.
摘要翻译： 将金属材料放置在具有上模具和下模具不具有接合部分的冲压金属模具的下模具上。 金属材料通过高能量热源熔化，并且在压力金属模上挤压熔融金属并转化为预定的构型。 熔融金属以与临界冷却速率同时或转化后的速度冷却，得到预定构造的非晶态金属的成型体。
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公开(公告)号：US06481088B1
公开(公告)日：2002-11-19
申请号：US09112360
申请日：1998-07-09
申请人： Akihisa Inoue , Eiichi Makabe , Masahide Onuki
发明人： Akihisa Inoue , Eiichi Makabe , Masahide Onuki
IPC分类号： B21B146
CPC分类号： B21J1/006 , A63B53/04 , A63B53/0466 , A63B53/047 , A63B60/00 , A63B2053/0408 , A63B2053/042 , A63B2209/00 , B22D25/02 , B22D27/04 , Y10T29/49988
摘要： A golf club which has a clubface of desired shape comprising an alloy metal is provided. The golf club has excellent strength properties as well as excellent ball hitting properties. The clubface is free from casting defects such as cold shuts, and preferably, free from the crystalline phase formed from crystal nuclei through nonuniform nucleation since the club face is produced in a simple, highly reproducible, one-step process by selectively cooling the molten metal at a temperature above the melting point at a rate higher than the critical cooling rate, and the product comprises a single amorphous phase. The metallic glass face used in the golf club is produced by filling a metal material in a hearth; melting said metal material by using a high-energy heat source which is capable of melting said the metal material; pressing said the molten metal at a temperature above the melting point of said the metal material to deform the molten metal into the desired shape by at least one of compressive stress and shear stress at a temperature above the melting point, while avoiding the surfaces of the molten metal cooled to a temperature below the melting point of said the metal material from meeting with each other during the pressing; and cooling said the molten metal at a cooling rate higher than the critical cooling rate of the metal material simultaneously with or after said the deformation to produce the metallic glass face of desired form.
摘要翻译： 提供具有包括合金金属的所需形状的球杆面的高尔夫球杆。 高尔夫球杆具有优异的强度性能以及出色的击球性能。 球杆表面没有铸造诸如冷切之类的缺陷，并且优选地，通过非均匀成核而不存在由晶核形成的结晶相，因为球杆表面通过选择性地冷却熔融金属以简单，高度可重复的一步法生产 在高于临界冷却速率的熔点的温度下，产物包含单一非晶相。 在高尔夫球杆中使用的金属玻璃面通过将金属材料填充在炉床中而制成; 通过使用能够熔化所述金属材料的高能热源来熔化所述金属材料; 在高于所述金属材料的熔点的温度下压制所述熔融金属，以通过在高于熔点的温度下的压应力和剪切应力中的至少一种将熔融金属变形为期望的形状，同时避免 熔融金属在压制期间被冷却到低于所述金属材料的熔点的温度彼此相遇的温度; 并且在所述变形之后或之后以比金属材料的临界冷却速度高的冷却速率冷却熔融金属，以产生所需形式的金属玻璃面。
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公开(公告)号：US06258183B1
公开(公告)日：2001-07-10
申请号：US09131341
申请日：1998-08-07
IPC分类号： C22C4500
CPC分类号： A63B53/04 , A63B53/0466 , A63B53/047 , A63B2053/0416 , B22D18/02 , B22D23/06 , B22D27/04
摘要： A metal material is placed on a lower mold of a press metal mold which has an upper mold and the lower mold not having engagement portions. The metal material is fused by a high energy heat source, and obtained molten metal over a melting point is pressed with the press metal mold and transformed into a predetermined configuration. The molten metal is cooled at a rate over a critical cooling rate simultaneously with or after the transformation, and the molded product of amorphous metal in predetermined configuration is obtained.
摘要翻译： 将金属材料放置在具有上模具和下模具不具有接合部分的冲压金属模具的下模具上。 金属材料通过高能量热源熔化，并且在压力金属模上挤压熔融金属并转化为预定的构型。 熔融金属以与临界冷却速率同时或转化后的速度冷却，得到预定构造的非晶态金属的成型体。
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公开(公告)号：US6089992A
公开(公告)日：2000-07-18
申请号：US130444
申请日：1998-08-06
CPC分类号： B22D27/04 , A63B53/04 , A63B53/0466 , A63B53/047 , B22D25/02 , A63B2053/0416 , A63B2209/00
摘要： In a golf club head having a face body, the face body is composed of a hybrid of an amorphous phase layer and a crystal phase layer. The crystal phase layer is disposed on a reverse face side of a face. And, thickness of the face body is 0.5 mm to 5.0 mm, thickness of the amorphous phase layer is, on average in whole area of the face body, more than 50% of the thickness of the face body, and thickness of the crystal phase layer is arranged to be 0.01 mm to 3.0 mm.
摘要翻译： 在具有面体的高尔夫球杆头中，面体由非晶相层和结晶相层的混合构成。 晶相层设置在面的背面侧。 并且，面体的厚度为0.5mm〜5.0mm，平面体的平均面积平均为非晶相层的面积的50％以上，并且结晶相的厚度 层设置为0.01mm至3.0mm。
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公开(公告)号：US06652673B1
公开(公告)日：2003-11-25
申请号：US09153309
申请日：1998-09-15
申请人： Akihisa Inoue , Tao Zhang , Masahide Onuki , Tetsuo Yamaguchi
发明人： Akihisa Inoue , Tao Zhang , Masahide Onuki , Tetsuo Yamaguchi
IPC分类号： C22C4500
CPC分类号： C22C45/10
摘要： A zirconium system amorphous alloy having a composition expressed by a general formula Zr100-X-Y-a-b Tix Aly Cua Nib wherein a, b, X, and Y in the formula represent atomic percentage, and fulfill X 5, Y
摘要翻译： 具有由通式Zr100-XYab Tix Aly Cua Nib表示的组成的锆系非晶合金，其中式中的a，b，X和Y表示原子百分比，并且满足X <10，Y> 5，Y < - （ 1/2）X + 35 / 2,15 <= a <= 25和5 <= b <= 15，锆系非晶合金具有大于合金体积的50体积％的非晶相。
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公开(公告)号：US06533681B2
公开(公告)日：2003-03-18
申请号：US09852678
申请日：2001-05-11
IPC分类号： A63B5304
CPC分类号： A63B53/04 , A63B53/0466 , A63B53/047 , A63B53/0487 , A63B2053/0408 , A63B2053/0416 , A63B2209/00
摘要： A golf club head comprises a face part defining a face for striking a golf ball, and at least a part of the face part made of an alloy satisfying the following three conditions: (1) the alloy is composed of at least three different metallic elements whose group numbers in the periodic system are at least two consecutive numbers; (2) a difference in the atomic radius between at least two of said at least three different metallic elements is not less than 10%; and (3) the heat of mixing of the element that is the major component of the alloy and at least one of the remaining components or the remaining component is not less than −10 kcal/mol.
摘要翻译： 高尔夫球杆头包括限定用于击打高尔夫球的面的面部，以及由满足以下三个条件的合金制成的面部的至少一部分：（1）该合金由至少三种不同的金属元素 其周期系统中的组号至少是两个连续的数字; （2）所述至少三种不同金属元素中的至少两种之间的原子半径的差不小于10％; 和（3）作为合金的主要成分的元素与剩余成分或剩余成分中的至少一种的混合热不小于-10kcal / mol。
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公开(公告)号：US09279186B2
公开(公告)日：2016-03-08
申请号：US13574854
申请日：2010-10-22
申请人： Hidemi Kato , Takeshi Wada , Kunio Yubuta , Akihisa Inoue
发明人： Hidemi Kato , Takeshi Wada , Kunio Yubuta , Akihisa Inoue
CPC分类号： C23C26/02 , B22F2998/00 , C22B9/02 , C22B26/22 , C23F1/00 , C23F4/04 , Y02P10/234 , Y10T428/12479 , C22C1/0425 , C22C1/0433 , C22C33/02
摘要： A metallic material containing both a second constituent and a third constituent having positive and negative heats of mixing relative to a first constituent, respectively, and including a compound, an alloy or a nonequilibrium alloy having a melting point that is higher than the solidifying point of a metal bath made of the first constituent is placed in the metal bath. The metal bath is controlled to a temperature lower than a minimum value of a liquidus temperature within a range of compositional variations in which the amount of the third constituent in the metallic material decreases down to a point where the metallic material becomes substantially the second constituent so that the third constituent is selectively dissolved into the metal bath.
摘要翻译： 一种含有第二成分和第三成分的金属材料，分别具有相对于第一成分的正和负的混合热，并且包括熔点高于凝固点的化合物，合金或非平衡合金 将由第一成分制成的金属浴放置在金属浴中。 将金属浴控制在低于液相线温度的最小值的温度范围内，其中金属材料中的第三成分的量减少到金属材料基本上变成第二成分的程度 第三组分选择性地溶解到金属浴中。
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