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公开(公告)号：US4309525A
公开(公告)日：1982-01-05
申请号：US149956
申请日：1980-05-15
CPC分类号： C08J3/16 , C08J2323/08
摘要： A spherical powder of a hydrolyzed ethylene-vinyl acetate copolymer or its carboxyl modified product, is prepared by a method which comprises mixing 100 parts by weight of (1) a hydrolyzed product of an ethylene-vinyl acetate copolymer having 5 to 50% by weight of vinyl acetate group content or (2) a carboxyl modified product of the aforementioned hydrolyzed product obtained by reacting said hydrolyzed product with an unsaturated carboxylic acid or cyclic acid anhydride, with 10 to 100 parts by weight of an organic solvent capable of dissolving said hydrolyzed product or its carboxyl modified product, the solvent being not freely miscible with water and having a boiling point of not lower than 80.degree. C., 300 to 1000 parts by weight of water and 0.1 to 10 parts by weight of an alkylphenol ethylene oxide adduct having an HLB value of 10 to 20, emulsifying said mixture while it is maintained at a temperature of not lower than the softening point of said hydrolyzed product or carboxyl modified product, and decreasing the temperature of the system under stirring down to not higher than said softening point. The resultant powder is virtually spherical in its particle form, the particles are of almost equal size, and their particle size distribution is such that not less than 70% fall between 70 and 300.mu.. Such spherical powder, when used in electrostatic coating, can provide beautiful coating films.
摘要翻译： 通过以下方法制备水解的乙烯 - 乙酸乙烯酯共聚物或其羧基改性产物的球形粉末：将100重量份的（1）含有5至50重量％的乙烯 - 乙酸乙烯酯共聚物的水解产物 的乙酸乙烯酯基含量或（2）通过使所述水解产物与不饱和羧酸或环状酸酐反应而获得的上述水解产物的羧基改性产物与10至100重量份能够溶解所述水解产物的有机溶剂 产物或其羧基改性产物，溶剂不与水自由混溶，沸点不低于80℃，300至1000重量份水和0.1至10重量份烷基苯酚环氧乙烷加合物 HLB值为10〜20，在保持在不低于所述水解产物或羧基的软化点的温度下乳化所述混合物 并将系统的温度在搅拌下降至不高于所述软化点。 所得粉末的颗粒形状实际上是球形的，颗粒的尺寸几乎相等，并且它们的粒径分布使得不少于70％在70和300μm之间。 这种球形粉末，当用于静电涂层时，可以提供美丽的涂膜。
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公开(公告)号：US4418177A
公开(公告)日：1983-11-29
申请号：US341700
申请日：1982-01-22
IPC分类号： C09J129/04 , C09J123/08 , C09J163/00 , C08L23/26
CPC分类号： C09J163/00 , C09J123/08
摘要： A thermosetting adhesive composition is disclosed which contains (a) a half-ester product of a saponified ethylene/vinyl ester copolymer with a dicarboxylic acid and (b) a solid or liquid epoxy resin, and this composition may further optionally contain a compound bearing two or more carboxyl groups, which is useful as a structural adhesive. The composition has a good storage stability and a good solubility to solvents, and can be cured at relatively low temperature in a shortened time. After curing, the composition shows good heat-resistance and has good adhesive properties.
摘要翻译： 公开了一种热固性粘合剂组合物，其包含（a）皂化的乙烯/乙烯基酯共聚物与二羧酸的半酯产物和（b）固体或液体环氧树脂，并且该组合物还可任选地含有带有两个 或更多的羧基，其可用作结构粘合剂。 该组合物具有良好的储存稳定性和对溶剂的良好溶解性，并且可以在较短的时间内在较低的温度下固化。 固化后，该组合物显示出良好的耐热性，并具有良好的粘合性。
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公开(公告)号：US4276390A
公开(公告)日：1981-06-30
申请号：US119779
申请日：1980-02-08
IPC分类号： C08F8/00 , C08F8/30 , C08G18/00 , C08G18/62 , C08G18/80 , C09D5/03 , C09D5/46 , C09D175/04 , B05D1/08
CPC分类号： C08G18/6212 , C08G18/807 , C08G2150/20 , Y10S528/902
摘要： A powdered composition comprising (1) an organic polyisocyanate blocked with ethyleneimine and (2) a partially hydrolyzed product of an ethylene-vinyl ester copolymer and/or a carboxyl-modified-product of said partially hydrolyzed product exhibits exceedingly good levelling and post-curing characteristics and is advantageously flame-sprayed to give a coating film having good weatherability, heat resistance and chemical resistance.
摘要翻译： 一种粉末状组合物，其包含（1）用乙烯亚胺封端的有机多异氰酸酯和（2）所述部分水解产物的乙烯 - 乙烯基酯共聚物和/或羧基改性产物的部分水解产物显示出非常好的流平和后固化 特性，有利地进行火焰喷涂，得到具有良好的耐候性，耐热性和耐化学性的涂膜。
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公开(公告)号：US4352749A
公开(公告)日：1982-10-05
申请号：US235028
申请日：1981-02-17
IPC分类号： C08L23/00 , C08L23/26 , C08L29/04 , C08L51/00 , C08L51/02 , C08L101/00 , C09J123/26 , C09J129/04 , C09J151/00 , C08L91/08 , C08L93/00
CPC分类号： C09J129/04 , C09J151/00
摘要： A hot-melt adhesive composition containing (i) a first component consisting of (a) 20 to 100 weight percent of a hydrolyzed ethylene-vinyl acetate copolymer whose vinyl acetate unit content is in the range of 5 to 50 weight percent and its hydrolysis degree is at least 50 percent and/or a carboxyl-containing product obtained by grafting said copolymer with a carboxyl-containing unsaturated compound or anhydride thereof and (b) 0 to 80 weight percent of a resin compatible with said copolymer and/or said carboxyl-containing product and (ii) a second component which is a tackifying resin, the proportion of said first component being not less than 20 weight percent and that of said second component being not less than 20 weight percent, both based on said two components, and said composition optionally may further contain (iii) a wax as a third component is highly improved in adhesivity as compared with the hitherto known hot-melt adhesive compositions.
摘要翻译： 一种热熔粘合剂组合物，其包含（i）由（a）20至100重量％的乙酸乙烯酯单元含量为5至50重量％的水解乙烯 - 乙酸乙烯酯共聚物组成的第一组分和其水解度 至少为50％，和/或通过用含羧基的不饱和化合物或其酸酐接枝所述共聚物得到的含羧基的产物和（b）0-80％（重量）与所述共聚物和/ （ii）作为增粘树脂的第二成分，所述第一成分的比例不小于20重量％，所述第二成分的比例不小于20重量％，基于所述两种成分，以及 所述组合物任选地可以进一步含有（iii）作为第三组分的蜡与迄今已知的热熔粘合剂组合物相比，粘合性高度改善。
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公开(公告)号：US4314042A
公开(公告)日：1982-02-02
申请号：US173908
申请日：1980-07-30
申请人： Jugo Goto , Fumihiro Doura
发明人： Jugo Goto , Fumihiro Doura
IPC分类号： C08L57/00 , C08L23/00 , C08L101/00 , C09D5/46 , C09D129/04 , C08F8/30
CPC分类号： C09D129/04 , Y10T428/31645 , Y10T428/31692
摘要： A composition for powder coating which comprises a carboxyl-containing polymer of not lower than 40.degree. C. in softening point prepared by reacting a dicarboxylic acid anhydride with a hydroxyl-containing polymer obtained by saponifying a copolymer from a vinyl ester of a saturated monocarboxylic acid and a copolymerizable vinyl monomer, and a compound having two or more oxazaline rings in the molecule, from which are obtained coating layers with toughness and flexibility useful for coating glass bottles, etc.
摘要翻译： 一种用于粉末涂料的组合物，其包含不低于40℃的含羧基聚合物，其软化点是通过使二羧酸酐与通过饱和一元羧酸的乙烯基酯皂化共聚物而获得的含羟基聚合物反应制备的 和可共聚的乙烯基单体，以及在分子中具有两个或更多个恶唑环的化合物，得到具有用于涂覆玻璃瓶等的韧性和柔性的涂层。
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公开(公告)号：US4613652A
公开(公告)日：1986-09-23
申请号：US742529
申请日：1985-06-07
IPC分类号： C08F20/00 , C08F20/10 , C08F20/34 , C08F220/34 , C08F220/40 , C08F265/04 , C08F290/00 , C08F299/00 , C08F299/02 , C09D4/00 , C09D4/06 , C09J4/06 , C08F259/04 , C08F259/08
CPC分类号： C09D4/06 , C08F265/04 , C09J4/06
摘要： A curable resin composition which comprises (1) a copolymer composed of an aminoalkyl acrylate and/or aminoalkyl methacrylate and an ethylenically unsaturated monomer being formulated with (2) a compound having at least two acryloyl groups in the molecule.The composition can be cured at low temperatures in the range of ordinary temperature to 120.degree. C., and therefore advantageously used for the formation of coating films in the application fields, such as plastics, wood and concrete, where heat treatment cannot be performed. Also, the composition which exhibits excellent adherence toward various kinds of substrates can be used as adhesives and different kinds of primers, as well. Furthermore, the composition can provide coating films that excel in terms of water resistance, weathering resistance and solvent resistance, and therefore be utilized for overpaints, etc.
摘要翻译： 一种可固化树脂组合物，其包含（1）由丙烯酸氨基烷基酯和/或甲基丙烯酸氨基烷基酯和烯属不饱和单体组成的共聚物，其由（2）在分子中具有至少两个丙烯酰基的化合物配制。 该组合物可以在常温至120℃的低温下固化，因此有利地用于在不能进行热处理的应用领域例如塑料，木材和混凝土中形成涂膜。 此外，对各种基材表现出优异粘附性的组合物也可以用作粘合剂和不同种类的底漆。 此外，组合物可以提供在耐水性，耐候性和耐溶剂性方面优异的涂膜，因此可用于过度涂覆等。
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公开(公告)号：US4666981A
公开(公告)日：1987-05-19
申请号：US742527
申请日：1985-06-07
申请人： Fumihiro Doura , Kazuo Asada , Kouichi Inoue
发明人： Fumihiro Doura , Kazuo Asada , Kouichi Inoue
IPC分类号： C08L33/00 , C08K5/54 , C08K5/56 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L25/14 , C08L27/00 , C08L33/02 , C08L33/04 , C08L83/00 , C08L101/00 , C08L33/14
摘要： A resin composition which comprises a coupling agent in an amount of about 0.5 part by weight to about 50 parts by weight against 100 parts by weight of a copolymer composed of an aminoalkyl acrylate and/or aminoalkyl methacrylate and an ethylenically unsaturated monomer.The resin composition excels, as compared with the conventional ones, in terms of any properties to be developed toward a wide range of various substrates inclusive of inorganic materials and plastic materials, such as adherence, water resistance, weathering resistance and yellowing resistance, and consequently are advantageously used in such fields as coatings, adhesives and printing ink.
摘要翻译： 一种树脂组合物，其包含相对于100重量份由丙烯酸氨基烷基酯和/或甲基丙烯酸氨基烷基酯和烯属不饱和单体组成的共聚物，其量为约0.5重量份至约50重量份的偶联剂。 与常规的树脂组合物相比，对于包括无机材料和塑料材料在内的各种基材的宽范围，例如粘附性，耐水性，耐候性和耐黄变性等性能而言，该成分优异，因此 有利地用于涂料，粘合剂和印刷油墨等领域。
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公开(公告)号：US4656211A
公开(公告)日：1987-04-07
申请号：US885393
申请日：1986-07-10
申请人： Kohji Nasu , Fumihiro Doura
发明人： Kohji Nasu , Fumihiro Doura
CPC分类号： C08G18/6283 , C08G18/8061
摘要： A curable resin composition which comprises (1) a copolymer composed of an aminoalkyl acrylate and/or aminoalkyl methacrylate and an ethylenically unsaturated monomer and (2) a blocked polyisocyanate compound formulated therein.The curable resin composition undergoes curing at by far lowered temperatures as compared with the conventionally employed baking paints consisting of hydroxyl-containing resins and blocked polyisocyanate compounds, and are therefore useful, for example, as a low-temperature baking type paint or adhesive. Heating brings about the crosslinking through the reaction between isocyanate and amino groups, thus providing coating films with excellent flexibility, chemical resistance, water resistance, impact resistance, corrosion resistance, etc. The composition can be used to such substrates as metal, heat-resistant plastics and inorganic materials, and can be applied onto electrical appliances for household uses, automobiles, building materials and the like.
摘要翻译： 一种可固化树脂组合物，其包含（1）由丙烯酸氨基烷基酯和/或甲基丙烯酸氨基烷基酯和烯键式不饱和单体组成的共聚物和（2）配制在其中的封端多异氰酸酯化合物。 与常规使用的由含羟基的树脂和封端的多异氰酸酯化合物组成的烤漆相比，可固化树脂组合物在远低于温度下固化，因此可用作例如低温烘烤型涂料或粘合剂。 加热通过异氰酸酯和氨基之间的反应引起交联，从而提供具有优异的柔韧性，耐化学性，耐水性，耐冲击性，耐腐蚀性等的涂膜。该组合物可用于诸如金属，耐热性 塑料和无机材料，并且可以应用于家用电器，汽车，建筑材料等。
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