公开(公告)号：US08283401B2

公开(公告)日：2012-10-09

申请号：US13133084

申请日：2009-12-04

申请人： Masato Murakami ,  Koji Shiba ,  Takeshi Shoda ,  Mitsuharu Anbe

发明人： Masato Murakami ,  Koji Shiba ,  Takeshi Shoda ,  Mitsuharu Anbe

IPC分类号： C08K3/34 ,  C08L9/00

CPC分类号： C08F4/545 ,  C08F36/04 ,  C08K3/36 ,  C08K5/548 ,  C08L7/00 ,  C08L9/00 ,  C08L2666/08

摘要： Provided by using a catalyst containing an yttrium compound is conjugated diene polymer with very low solution viscosity, improved workability, high degree of branching, and high content of cis-1,4 structures. Also provided is a rubber composition utilizing the polymer and allowing excellent dispersion of reinforcing agent. According to a method of manufacturing a conjugated diene polymer characterized by polymerizing a conjugated diene at 50 to 120° C. in the presence of a catalyst obtained from (A) an yttrium compound, (B) an ionic compound consisting of a non-coordinating anion and a cation, and (C) an organoaluminum compound, the conjugated diene polymer has the following characteristics that: (1) a ratio (Tcp/ML1+4) between a 5 wt % toluene solution viscosity (Tcp) measured at 25° C. and a Mooney viscosity (ML1+4) at 100° C. is 0.1 to 1.2; and (2) a content of cis-1,4 structures is 80% or higher, and a content of 1,2 structures is lower than 5%.

摘要翻译： 通过使用含有钇化合物的催化剂提供的是具有非常低的溶液粘度，改进的加工性，高支化度和高含量的顺式-1,4结构的共轭二烯聚合物。 还提供了一种利用该聚合物的橡胶组合物，并且能够提供增强剂的优异分散性。 根据制备共轭二烯聚合物的方法，其特征在于在（A）钇化合物得到的催化剂存在下，在50〜120℃下共聚共轭二烯，（B）由非配位的 阴离子和阳离子，和（C）有机铝化合物，共轭二烯聚合物具有以下特性：（1）在25℃下测量的5重量％甲苯溶液粘度（Tcp）之间的比率（Tcp / ML1 + 4） 在100℃下的门尼粘度（ML1 + 4）为0.1〜1.2; 和（2）顺式-1,4结构的含量为80％以上，1,2结构的含量低于5％。

公开(公告)号：US20110269899A1

公开(公告)日：2011-11-03

申请号：US13133084

申请日：2009-12-04

申请人： Masato Murakami ,  Koji Shiba ,  Takeshi Shoda ,  Mitsuharu Anbe

发明人： Masato Murakami ,  Koji Shiba ,  Takeshi Shoda ,  Mitsuharu Anbe

IPC分类号： C08K3/36 ,  C08L9/00 ,  C08F4/72 ,  C08F4/54 ,  C08F136/06

CPC分类号： C08F4/545 ,  C08F36/04 ,  C08K3/36 ,  C08K5/548 ,  C08L7/00 ,  C08L9/00 ,  C08L2666/08

摘要： Provided by using a catalyst containing an yttrium compound is conjugated diene polymer with very low solution viscosity, improved workability, high degree of branching, and high content of cis-1,4 structures. Also provided is a rubber composition utilizing the polymer and allowing excellent dispersion of reinforcing agent. According to a method of manufacturing a conjugated diene polymer characterized by polymerizing a conjugated diene at 50 to 120° C. in the presence of a catalyst obtained from (A) an yttrium compound, (B) an ionic compound consisting of a non-coordinating anion and a cation, and (C) an organoaluminum compound, the conjugated diene polymer has the following characteristics that: (1) a ratio (Tcp/ML1+4) between a 5 wt % toluene solution viscosity (Tcp) measured at 25° C. and a Mooney viscosity (ML1+4) at 100° C. is 0.1 to 1.2; and (2) a content of cis-1,4 structures is 80% or higher, and a content of 1,2 structures is lower than 5%.

摘要翻译： 通过使用含有钇化合物的催化剂提供的是具有非常低的溶液粘度，改进的加工性，高支化度和高含量的顺式-1,4结构的共轭二烯聚合物。 还提供了一种利用该聚合物的橡胶组合物，并且能够提供增强剂的优异分散性。 根据制备共轭二烯聚合物的方法，其特征在于在（A）钇化合物得到的催化剂存在下，在50〜120℃下共聚共轭二烯，（B）由非配位的 阴离子和阳离子，和（C）有机铝化合物，共轭二烯聚合物具有以下特性：（1）在25℃下测量的5重量％甲苯溶液粘度（Tcp）之间的比率（Tcp / ML1 + 4） 在100℃下的门尼粘度（ML1 + 4）为0.1〜1.2; 和（2）顺式-1,4结构的含量为80％以上，1,2结构的含量低于5％。

公开(公告)号：US6114451A

公开(公告)日：2000-09-05

申请号：US136457

申请日：1998-08-19

申请人： Takeshi Shoda ,  Naomi Okamoto ,  Koji Ohkawa

发明人： Takeshi Shoda ,  Naomi Okamoto ,  Koji Ohkawa

IPC分类号： B60C1/00 ,  C08L9/00 ,  C08F8/00 ,  C08L47/00

CPC分类号： B60C1/0016 ,  C08L9/00 ,  C08L2205/03

摘要： In a rubber blend consisting of:a polybutadiene blend (A)+(B) composed of:(A) not less than 30% by weight but less than 70% by weight of a high molecular weight polybutadiene comprising as the main component a polybutadiene having an intrinsic viscosity [.eta.] of 3.0 to 7.0 as measured in toluene at 30.degree. C. and a cis-1,4-configuration content of at least 80% and(B) more than 30% by weight but not more than 70% by weight of a low molecular weight polybutadiene comprising, as the main component, a polybutadiene having an intrinsic viscosity [.eta.] of 0.1 to 0.5 as measured in toluene at 30.degree. C., and(C) a diene type rubber other than the above components (A) and (B),the rubber blend (A)+(B) is contained in a proportion of 35 to 95 percent by total weight of rubber blend (A)+(B)+(C), thereby providing a rubber blend suitable for a tire; said blend being greatly improved in wet skid performance and ice skid performance with retention of the abrasion resistance of a conventional polybutadiene.

摘要翻译： 在由以下组成的橡胶共混物中组成的聚丁二烯共混物（A）+（B）：（A）不低于30重量％但小于70重量％的包含作为主要组分的聚丁二烯的高分子量聚丁二烯 其在30℃下在甲苯中测得的特性粘度η为3.0至7.0，并且顺式-1,4-构型含量为至少80％，（B）大于30重量％但不大于70 重量％的低分子量聚丁二烯，其包含作为主要组分的在30℃下在甲苯中测定的特性粘度η为0.1至0.5的聚丁二烯和（C）除 上述组分（A）和（B），橡胶共混物（A）+（B）的含量按橡胶共混物（A）+（B）+（C）的总重量计为35-95％ 适用于轮胎的橡胶混合物; 所述共混物通过保持常规聚丁二烯的耐磨性而大大改善了防滑性能和防滑性能。

公开(公告)号：US07702979B2

公开(公告)日：2010-04-20

申请号：US11397899

申请日：2006-04-05

申请人： Masayuki Arai ,  Kazuhiko Iwasaki ,  Satoshi Fukumoto ,  Takeshi Shoda ,  Junichi Nishimoto

发明人： Masayuki Arai ,  Kazuhiko Iwasaki ,  Satoshi Fukumoto ,  Takeshi Shoda ,  Junichi Nishimoto

IPC分类号： G01R31/28

CPC分类号： G01R31/318544 ,  G01R31/318536

摘要： An object of the invention is to drastically reduce the area overhead in a semiconductor integrated circuit incorporating a test configuration that uses a partially rotational scan circuit. To achieve this, in the semiconductor integrated circuit incorporating the test configuration that comprises a combinational circuit (3) and a scan chain (2) constructed by connecting a plurality of scan flip-flops (5) in a chain, the scan chain (2) is divided into a plurality of sub scan-chains (20a to 20n) each of which has a partially rotational scan (PRS) function and a test response compaction (MISR) function. By performing a scan test in a plurality of steps while changing the combination of the sub scan-chains to be set as PRS and the sub scan-chains to be set as MISR, the test can be performed without having to provide a test response compactor separately from the scan chain, and thus the area overhead can be reduced.

摘要翻译： 本发明的一个目的是大大减少包含使用部分旋转扫描电路的测试配置的半导体集成电路中的面积开销。 为了实现这一点，在包括组合电路（3）和通过连接多个扫描触发器（5）构成的扫描链（2）的测试配置的半导体集成电路中，扫描链（2） ）被分成多个子扫描链（20a至20n），每个子扫描链具有部分旋转扫描（PRS）功能和测试响应压缩（MISR）功能。 通过在将要设置为PRS的子扫描链和将被设置为MISR的副扫描链的组合改变的同时执行多个步骤中的扫描测试，可以执行测试而不必提供测试响应压缩器 与扫描链分开，因此可以减少面积开销。

公开(公告)号：US5895798A

公开(公告)日：1999-04-20

申请号：US944420

申请日：1997-10-06

申请人： Naomi Okamoto ,  Takeshi Shoda

发明人： Naomi Okamoto ,  Takeshi Shoda

IPC分类号： C08G18/69 ,  C08L19/00 ,  C08L21/00 ,  C08L9/00

CPC分类号： C08L19/006 ,  C08G18/69 ,  C08L21/00 ,  C08L9/00

摘要： A liquid rubber composition including a 1,2-polybutadiene resin component dispersed in the form of fine particles in a liquid rubber component in a weight ratio of 1:100 to 50:100 has a high dispersion stability and a low specific gravity and is useful for forming a cured rubber article having a high elastic modulus and a satisfactory mechanical strength and ultimate elongation.

摘要翻译： 包含以液体橡胶组分以液体橡胶组分分散的1,2-聚丁二烯树脂组分的液体橡胶组合物，其重量比为1:100至50:100，具有高分散稳定性和低比重，并且是有用的 用于形成具有高弹性模量和令人满意的机械强度和极限伸长率的固化橡胶制品。

公开(公告)号：US07299394B2

公开(公告)日：2007-11-20

申请号：US10400911

申请日：2003-03-28

申请人： Ken-ichi Ichino ,  Masayuki Arai ,  Satoshi Fukumoto ,  Kazuhiko Iwasaki ,  Takeshi Shoda ,  Masayuki Sato

发明人： Ken-ichi Ichino ,  Masayuki Arai ,  Satoshi Fukumoto ,  Kazuhiko Iwasaki ,  Takeshi Shoda ,  Masayuki Sato

IPC分类号： G01R31/28

CPC分类号： G06F11/261 ,  G01R31/3172 ,  G01R31/318342 ,  G01R31/318371

摘要： The purpose of the invention is to determine an optimum initial value to be input to a test pattern generator in order to achieve efficient testing of an integrated circuit. To achieve this purpose, a minimum test length is obtained by performing a fault simulation and a reverse-order fault simulation using an arbitrarily given initial value; the next initial value that is likely to yield a test length shorter than the minimum test length is computed and a fault simulation is performed using the thus computed initial value; and the next initial value that is likely to yield a test length shorter than that test length is computed and a fault simulation is performed using the thus computed initial value. By repeating this process, an initial value that yields the shortest test length is obtained.

摘要翻译： 本发明的目的是确定要输入到测试图案发生器的最佳初始值，以便实现集成电路的有效测试。 为了达到这个目的，通过使用任意给定的初始值执行故障模拟和反向故障模拟来获得最小测试长度; 计算可能产生比最小测试长度短的测试长度的下一个初始值，并且使用由此计算的初始值来执行故障模拟; 并且计算可能产生比该测试长度短的测试长度的下一个初始值，并且使用由此计算的初始值来执行故障模拟。 通过重复该过程，获得产生最短测试长度的初始值。

公开(公告)号：US20060282730A1

公开(公告)日：2006-12-14

申请号：US11397899

申请日：2006-04-05

申请人： Masayuki Arai ,  Kazuhiko Iwasaki ,  Satoshi Fukumoto ,  Takeshi Shoda ,  Junichi Nishimoto

发明人： Masayuki Arai ,  Kazuhiko Iwasaki ,  Satoshi Fukumoto ,  Takeshi Shoda ,  Junichi Nishimoto

IPC分类号： G01R31/28

CPC分类号： G01R31/318544 ,  G01R31/318536

摘要： An object of the invention is to drastically reduce the area overhead in a semiconductor integrated circuit incorporating a test configuration that uses a partially rotational scan circuit. To achieve this, in the semiconductor integrated circuit incorporating the test configuration that comprises a combinational circuit (3) and a scan chain (2) constructed by connecting a plurality of scan flip-flops (5) in a chain, the scan chain (2) is divided into a plurality of sub scan-chains (20a to 20n) each of which has a partially rotational scan (PRS) function and a test response compaction (MISR) function. By performing a scan test in a plurality of steps while changing the combination of the sub scan-chains to be set as PRS and the sub scan-chains to be set as MISR, the test can be performed without having to provide a test response compactor separately from the scan chain, and thus the area overhead can be reduced.

摘要翻译： 本发明的一个目的是大大减少包含使用部分旋转扫描电路的测试配置的半导体集成电路中的面积开销。 为了实现这一点，在包括组合电路（3）和通过连接多个扫描触发器（5）构成的扫描链（2）的测试配置的半导体集成电路中，扫描链（2） ）被分成多个子扫描链（20a至20n），每个子扫描链具有部分旋转扫描（PRS）功能和测试响应压缩（MISR）功能。 通过在将要设置为PRS的子扫描链和将被设置为MISR的副扫描链的组合改变的同时执行多个步骤中的扫描测试，可以执行测试而不必提供测试响应压缩器 与扫描链分开，因此可以减少面积开销。