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    Method for the preparation of olefin polysulfides, the products obtained and their utilization as lubricant additives
    1.
    发明授权
    Method for the preparation of olefin polysulfides, the products obtained and their utilization as lubricant additives 失效
    制备烯烃多硫化物的方法，获得的产品及其作为润滑剂添加剂的利用

    公开(公告)号：US4645610A

    公开(公告)日：1987-02-24

    申请号：US725278

    申请日：1985-04-19

    申请人： Maurice Born ,  Guy Parc ,  Lucienne Briquet ,  Daniel Paquer

    发明人： Maurice Born ,  Guy Parc ,  Lucienne Briquet ,  Daniel Paquer

    IPC分类号： C07G99/00 ,  C10M135/00 ,  C10M135/02 ,  C10M135/04 ,  C07C149/00

    CPC分类号： C10M135/04 ,  C07G17/004 ,  C10M135/02 ,  C10M2203/06 ,  C10M2205/028 ,  C10M2207/281 ,  C10M2207/282 ,  C10M2207/283 ,  C10M2207/286 ,  C10M2207/34 ,  C10M2219/02 ,  C10M2219/022 ,  C10M2223/04 ,  C10M2223/042 ,  C10M2223/045

    摘要： A method for the preparation of olefin polysulfides that can be used in particular as extreme pressure additives for lubricants is described. This method comprises: (1) reacting sulfur monochloride or dichloride with at least one mono-olefin containing 2 to 5 carbon atoms (in general isobutene) resulting in the formation of an adduct; (2) bringing into contact said adduct, conjointly with a hydrocarbyl halide, with a sulfur compound (for example, alkaline sulfides, hydrosulfides or polysulfides) and, in most cases, elemental sulfur, in an aqueous or aqueous-alcoholic medium; (3) heating the mixture and, after it has settled into two phases, separating the organic phase containing the olefin polysulfide; and if necessary (4) treating the product obtained with a base.The olefin polysulfides obtained contain a high proportion of sulfur, have a satisfactory viscosity and are sufficiently soluble in mineral oils as well as synthetic oils to be used as extreme pressure additives in the formulation of gear oils. Some of these products are also advantageous in the formulation of oils intended to be used in metal work.

    摘要翻译： 描述了可用于特别用作润滑剂的极压添加剂的烯烃多硫化物的制备方法。 该方法包括：（1）使一氯化硫或二氯化物与至少一种含2至5个碳原子的单烯烃（通常为异丁烯）反应，形成加合物; （2）在含水或含水醇介质中与硫化合物（例如碱性硫化物，氢硫化物或多硫化物）和多数情况下元素硫接触所述加合物，与烃基卤化物接触; （3）加热混合物，在两相分离后，分离含有烯烃多硫化物的有机相; 如果需要（4）处理用碱获得的产物。 获得的烯烃聚硫化物含有高比例的硫，具有令人满意的粘度，并且足够溶于矿物油以及用作齿轮油制剂中的极压添加剂的合成油。 这些产品中的一些在用于金属加工的油的配方中也是有利的。

    Polysulfided olefin compositions, their preparation and use as additives for lubricants
    2.
    发明授权
    Polysulfided olefin compositions, their preparation and use as additives for lubricants 失效
    多硫烯烃组合物，它们的制备和用作润滑剂的添加剂

    公开(公告)号：US4795576A

    公开(公告)日：1989-01-03

    申请号：US920340

    申请日：1986-10-17

    申请人： Maurice Born ,  Lucienne Briquet ,  Guy Parc ,  Daniel Paquer

    发明人： Maurice Born ,  Lucienne Briquet ,  Guy Parc ,  Daniel Paquer

    IPC分类号： C07C67/00 ,  C07C313/00 ,  C07C319/16 ,  C07C319/24 ,  C07C321/14 ,  C07C323/03 ,  C07G99/00 ,  C10M135/04 ,  C10M159/12 ,  C10N30/06 ,  C10N40/04 ,  C10N40/20 ,  C10M135/00 ,  C07C149/00

    CPC分类号： C10M135/04 ,  C07G17/004 ,  C10M2219/022 ,  C10N2240/04 ,  C10N2240/042 ,  C10N2240/044 ,  C10N2240/046 ,  C10N2240/08 ,  C10N2240/40

    摘要： The disclosed polysulfided olefin compositions can be used in particular as extreme-pressure additives for lubricants. They are prepared by a process comprising the steps of:(1) reacting sulfur monochloride and/or dichloride with at least one monoolefin having 2 to 5 carbon atoms (generally isobutene) to form an "adduct"; (2) contacting said "adduct" jointly with an unsaturated monohalogenated hydrocarbon compound, in a proportion corresponding to a number of halogen gram-atoms from about 1 to 70% of the number of halogen gram-atoms of the assembly "monohalogenated hydrocarbon compound+adduct", with a sulfur compound (e.g. alkaline sulfide, hydrogenosulfide or polysulfide) and, mostly, element sulfur, in a proportion of 0 to 7 gram-atoms per mole of sulfur compound, within an aqueous or hydroalcoholic medium; (3) heating the mixture and, after settling in 2 phases, separating the organic phase containing the polysulfided olefin, and (4) optionally treating the obtained product with a base.The obtained polysulfided olefins, depending on their sulfur content, may be used as extreme-pressure additives in oil compositions for gears or for metal working.

    摘要翻译： 所公开的聚硫化烯烃组合物可特别用作润滑剂的极压添加剂。 它们通过包括以下步骤的方法制备：（1）使一氯化物和/或二氯化物与至少一种具有2至5个碳原子的单烯烃（通常为异丁烯）反应以形成“加合物”; （2）使所述“加合物”与不饱和一卤代烃化合物联合，其比例对应于卤素原子数的数量为组合物“一卤代烃化合物+”的组合物的卤素原子数的约1-70％ 加合物“，含水或水醇介质中的硫化合物（例如碱金属硫化物，硫化氢或多硫化物）和大部分为0至7克数原子/摩尔硫化合物的元素硫; （3）加热混合物，在两相沉淀后，分离含有聚硫烯烃的有机相，和（4）任选地用碱处理得到的产物。 取决于其硫含量的所得聚硫化烯烃可用作齿轮油或金属加工用油组合物中的极压添加剂。

    Polysulphurized olefin compositions, their preparation and their use as additives for lubricants
    3.
    发明授权
    Polysulphurized olefin compositions, their preparation and their use as additives for lubricants 失效
    多硫化烯烃组合物，它们的制备及其作为润滑剂添加剂的用途

    公开(公告)号：US5045221A

    公开(公告)日：1991-09-03

    申请号：US403968

    申请日：1989-09-07

    申请人： Maurice Born ,  Lucienne Briquet ,  Jacques Lallement ,  Guy Parc

    发明人： Maurice Born ,  Lucienne Briquet ,  Jacques Lallement ,  Guy Parc

    IPC分类号： C07C319/14 ,  C07C321/00 ,  C10M135/04 ,  C10N30/06 ,  C10N40/04 ,  C10N40/22

    CPC分类号： C10M135/04

    摘要： Polysulphurized olefin compositions used as additives for gear oils, cutting oils, and as sulphurizing agents in organic media are obtained by a process comprising:a stage (1) in which at least one compound chosen from among sulphur dichloride and monochloride is reacted with at least one aliphatic monpolefin with 2 to 12 carbon atoms, thus forming an adduct;a stage (2) in which sulphurized hydrogen and at least one mercaptan is reacted with ammonium or alkali metal hydroxide dissolved in at least one aliphatic monoalcohol with 1 to 4 carbon atoms, which is substantially anhydrous, so as to give an alcoholic solution;a stage (3) in which contacting takes place between the adduct obtained in stage (1) and the alcoholic solution obtained in stage (2);a stage (4), in which the resulting mixture is heated and then the aliphatic monoalcohol is eliminated by distillation, while adding water in a quantity adequate for maintaining in solution the reagents and the mineral products formed during the reaction; anda stage (5) in which elimination takes place of the aqueous phase and recovery takes place of the organic phase mainly constituted by the polysulphurized olefin composition.

    摘要翻译： 用于齿轮油，切削油和作为有机介质中的硫化剂的添加剂的多硫化烯烃组合物通过以下方法获得，该方法包括：其中至少一种选自二氯化硫和一氯化物的化合物至少与 一种具有2至12个碳原子的脂族单烯烃，从而形成加合物; 使硫化氢和至少一种硫醇与溶解在至少一种具有1-4个碳原子的脂族一元醇中的铵或碱金属氢氧化物反应的阶段（2），其基本上是无水的，以得到醇溶液; 在阶段（1）中获得的加合物和阶段（2）中获得的醇溶液之间发生接触的阶段（3）; 加热得到的混合物，然后通过蒸馏除去脂肪族一元醇的阶段（4），同时加入足以维持溶液中的水，反应物中形成的试剂和矿物产物; 以及主要由多硫化烯烃组合物构成的有机相进行水相脱除发生阶段（5）。

    Olefin polysulfide compositions of high sulfur content and very low chlorine content, their manufacture and use as additives for lubricants
    4.
    发明授权
    Olefin polysulfide compositions of high sulfur content and very low chlorine content, their manufacture and use as additives for lubricants 失效
    含硫量高，氯含量非常低的烯烃多硫化物组合物，其制造和用作润滑剂的添加剂

    公开(公告)号：US5286395A

    公开(公告)日：1994-02-15

    申请号：US883793

    申请日：1992-05-14

    申请人： Maurice Born ,  Lucienne Briquet ,  Guy Parc

    发明人： Maurice Born ,  Lucienne Briquet ,  Guy Parc

    IPC分类号： C07G99/00 ,  C10M135/04

    CPC分类号： C10M135/04 ,  C07G17/004 ,  C10M2219/022 ,  C10N2240/02 ,  C10N2240/401

    摘要： Olefin polysulfide compositions of high sulfur content and of very low chlorine content are obtained by a process comprising the steps of: (1) reacting sulfur mono- and/or dichloride with at least one aliphatic monoolefin of 2-12 carbon atoms, to form an addition product or "adduct", (2) reacting hydrogen sulfide with an alkali hydroxide or ammonium hydroxide dissolved in at least one substantially anhydrous C.sub.1 -C.sub.4 aliphatic monoalcohol, with optional addition of elemental sulfur, (3) contacting said "adduct" together with at least one monohalogenated hydrocarbon compound, with the alcoholic solution obtained at the end of step (2), (4) heating the resultant mixture from step (3), removing the monoalcohol, while adding water, and (5) after settling and removal of the aqueous phase, recovering the organic phase formed at least in major part of the desired olefin polysulfide composition. These compositions, of sulfur content up to 65% by weight and of chlorine content generally lower than about 0.1% by weight, are used in particular as additives for improving the extreme-pressure properties of lubricants.

    摘要翻译： 通过包括以下步骤的方法获得高硫含量和非常低氯含量的烯烃多硫化物组合物：（1）使单 - 和/或二氯化物与至少一种2-12个碳原子的脂族单烯烃反应，形成 加成产物或“加合物”，（2）使硫化氢与溶于至少一种基本上无水的C 1 -C 4脂族一元醇中的碱金属氢氧化物或氢氧化铵反应，任选加入元素硫，（3）使所述“加合物”与 至少一种一卤化烃化合物与步骤（2）结束时得到的醇溶液，（4）加热步骤（3）的所得混合物，同时加入水，除去一元醇，和（5）沉淀和除去后 的水相，回收至少大部分所需的烯烃多硫化物组合物形成的有机相。 这些硫含量高达65重量％，氯含量通常低于约0.1重量％的组合物特别用作改善润滑剂的极压性能的添加剂。

    (Poly) sulfurized carboxylic compounds, their preparation and their use as petroleum additives for lubricating oils
    9.
    发明授权
    (Poly) sulfurized carboxylic compounds, their preparation and their use as petroleum additives for lubricating oils 失效
    （聚）硫化羧酸化合物，它们的制备及其作为润滑油的石油添加剂的用途

    公开(公告)号：US5284592A

    公开(公告)日：1994-02-08

    申请号：US872196

    申请日：1992-04-22

    申请人： Ourida Aberkane ,  Maurice Born ,  Jean-Luc Mieloszynski ,  Daniel Paquer ,  Guy Parc

    发明人： Ourida Aberkane ,  Maurice Born ,  Jean-Luc Mieloszynski ,  Daniel Paquer ,  Guy Parc

    IPC分类号： C10M135/26 ,  C07C319/20 ,  C07C323/12 ,  C10M135/24 ,  C10N30/06

    CPC分类号： C10M135/24 ,  C07C323/12 ,  C10M2219/084

    摘要： Novel (poly)sulfurized carboxylic compounds, their preparation, and their use as additives to lubricating oils are disclosed. Such novel carboxylic compounds are more particularly esters of the general formula:[R.sup.3 --OC(O)--].sub.q R.sup.2 {--C(O)O--(CH.sub.2).sub.m --CH.sub.3-z [--(CH.sub.2).sub.n --S.sub.x --R.sup.1 ].sub.z }.sub.p (1)wherein R.sup.1 is a saturated or unsaturated monovalent aliphatic radical with 1 to 30 carbon atoms; the number x is equal to or greater than 1; z equals 1 or 2; when z equals 1, n is an integer from 0 to 5 and m an integer from 0 to 0.5, with m+n an integer from 1 to 10; when z equals 2, n is an integer from 1 to 5 and m an integer from 0 to 5, with m+n an integer from 1 to 10; R.sup.2 is a hydrocarbon radical with 1 to 31 carbon atoms and a valency of p+q; R.sup.3 is a hydrogen atom or an aliphatic radical with 1 to 30 carbon atoms; p is an integer from 1 to 4; and q is an integer from 0 to 3, with p+q being an integer from 1 to 4. They are obtained by esterifying carboxylic acid R.sup.2 (--COOH).sub.p+q with a (poly)sulfurized monoalcohol:[R.sup.1 --S.sub.x --(CH.sub.2).sub.n --].sub.z CH.sub.3-z --(CH.sub.2).sub.m --OHand possibly an alcohol R.sup.3 OH. They are used as anti-wear and extreme pressure additives in lubricating oils.

    摘要翻译： 公开了新型（多）硫化羧酸化合物，它们的制备及其作为润滑油添加剂的用途。 这样的新型羧酸化合物更特别是以下通式的酯：（R3-OC（O） - ）qR2（-C（O）O-（CH2）m-CH3-z（ - （CH2）n-Sx-R1） z）p（1）其中R1是具有1至30个碳原子的饱和或不饱和的一价脂族基; 数x等于或大于1; z等于1或2; 当z为1时，n为0〜5的整数，m为0〜0.5的整数，m + n为1〜10的整数。 当z为2时，n为1〜5的整数，m为0〜5的整数，m + n为1〜10的整数。 R2是具有1至31个碳原子并且p + q的化合价的烃基; R3是氢原子或具有1至30个碳原子的脂族基团; p是1至4的整数; 并且q为0〜3的整数，p + q为1〜4的整数。它们是通过用（多）硫化一元醇将羧酸R2（-COOH）p + q酯化得到的：（R1-Sx- （CH 2）n - ）z CH 3 -Z-（CH 2）m -OH以及可能的醇R 3 OH。 它们用作润滑油中的抗磨和极压添加剂。

    New phosphosulfides compounds and use thereof as oil lubricants
    10.
    发明授权
    New phosphosulfides compounds and use thereof as oil lubricants 失效
    新的磷硫化物化合物及其作为油润滑剂的用途

    公开(公告)号：US5306436A

    公开(公告)日：1994-04-26

    申请号：US749783

    申请日：1991-08-26

    申请人： Maurice Born ,  Ourida Aberkane ,  Jean-Luc Mieloszynski ,  Daniel Paquer ,  Guy Parc

    发明人： Maurice Born ,  Ourida Aberkane ,  Jean-Luc Mieloszynski ,  Daniel Paquer ,  Guy Parc

    IPC分类号： C07F9/09 ,  C07F9/141 ,  C07F9/165 ,  C07F9/173 ,  C10M137/02 ,  C10M137/10 ,  C10M137/14 ,  C10N10/04 ,  C10N30/06 ,  C10N30/10 ,  C10N40/04 ,  C10M137/06

    CPC分类号： C10M137/14 ,  C07F9/091 ,  C07F9/1411 ,  C07F9/1651 ,  C10M137/02 ,  C10M137/105

    摘要： Useful as additive for lubricating oils are novel phosphosulphur compounds in accordance with the general formula (I):(((R.sup.1 --S.sub.x --O.sub.y --A--).sub.r B.sub.v).sub.p P(X)--Y.sub.t --).sub.q Z.sub.min which e.g. R.sup.1 represents an alkyl or alkenyl group, A represents the group --(CH.sub.2).sub.n --O--, B represents the group --P(S)--S--CH.sub.2 --(CH.sub.3)--O--, X represents an oxygen atom or a sulphur atom, Y represents an oxygen atom, a sulphur atom or an oxygen or sulphur-containing hydrocarbon chain, Z represents a hydrogen, chlorine or sulphur atom, a polysulphide chain, a metal or an alkyl or alkenyl group, x=1,2 or 3, y=0, 1 or 2, v is 0 or 1, r is 1 (if v=0) or r=2 (if v=1), p=2 or 3, t=0 or 1, m=0,1 or 2, q=the valency of Z if Z is a metal or q=1 or 2 and n is an integer from 1 to 30.

    摘要翻译： 可用作润滑油的添加剂是根据通式（I）：（（（R1-Sx-Oy-A-）rBv）pP（X）-Yt-）qZm的新型磷硫化合物，其中例如 R1表示烷基或烯基，A表示 - （CH2）nO-基团，B表示基团-P（S）-S-CH2-（CH3）-O-，X表示氧原子或硫原子， Y表示氧原子，硫原子或含氧或含硫烃链，Z表示氢，氯或硫原子，多硫化物链，金属或烷基或烯基，x = 1,2或3， y = 0,1或2，v为0或1，r为1（如果v = 0）或r = 2（如果v = 1），p = 2或3，t = 0或1，m = 1或2，如果Z是金属或q = 1或2，且n是1至30的整数，q = Z的化合价。