公开(公告)号：US20090229870A1

公开(公告)日：2009-09-17

申请号：US12470399

申请日：2009-05-21

申请人： Maw Soe Win ,  Toshiyuki Goshima ,  Eika Kyo ,  Shintaro Nakajima ,  Noriki Hayashi ,  Tohru Kashiwagi ,  Kenji Miyazaki ,  Katsuya Yamada ,  Naoyuki Yamabayashi ,  Shoji Nakagama ,  Hiroshi Okuyama ,  Fumio Kasabo ,  Ippei Tanaka

发明人： Maw Soe Win ,  Toshiyuki Goshima ,  Eika Kyo ,  Shintaro Nakajima ,  Noriki Hayashi ,  Tohru Kashiwagi ,  Kenji Miyazaki ,  Katsuya Yamada ,  Naoyuki Yamabayashi ,  Shoji Nakagama ,  Hiroshi Okuyama ,  Fumio Kasabo ,  Ippei Tanaka

IPC分类号： H05K1/00 ,  C09D131/06 ,  B05D5/00

CPC分类号： C09D11/102 ,  H05K3/28 ,  H05K2201/0154 ,  H05K2203/0783

摘要： The object is to provide a polyimide ink composition having good printing properties and good continuous printing properties, which composition can be dried at a low temperature of not higher than 220° C., and which composition gives a coating film, after being dried, having excellent dimensional stability, heat resistance, low modulus of elasticity, flexibility, resistance to warping, chemical resistance, adhesiveness with substrates, and plating resistance. This object is accomplished by a polyimide ink composition for printing, comprising a mixed solvent containing an benzoic acid ester solvent and a glyme solvent, and a polyimide soluble in the mixed solvent; wherein the polyimide is obtained by polycondensing a polyimide oligomer with a tetracarboxylic dianhydride component(s) and/or a diamine component(s) having no siloxane bond in molecular skeleton thereof, the polyimide oligomer being prepared by polycondensing a tetracarboxylic dianhydride component(s) and a diamine component(s) having siloxane bonds in molecular skeleton thereof in the presence of a base catalyst(s), or a mixed catalyst including a lactone(s) and/or an acidic compound(s) and a base(s); the content of the diamine component(s) having siloxane bonds based on the total diamine components being 15 to 85% by weight.

摘要翻译： 本发明的目的是提供具有良好的印刷性能和良好的连续印刷性能的聚酰亚胺油墨组合物，该组合物可以在不高于220℃的低温下干燥，并且该组合物在干燥后得到涂膜， 优异的尺寸稳定性，耐热性，低弹性模量，柔软性，抗翘曲性，耐化学性，与基材的粘合性和耐电镀性。 该目的通过用于印刷的聚酰亚胺油墨组合物实现，其包含含有苯甲酸酯溶剂和甘醇二甲醚溶剂的混合溶剂和可溶于混合溶剂的聚酰亚胺; 其中所述聚酰亚胺是通过将聚酰亚胺低聚物与其分子骨架中不含硅氧烷键的四羧酸二酐组分和/或二胺组分缩聚得到的，所述聚酰亚胺低聚物是通过使四羧酸二酐组分缩聚而制备的， 和在其基础催化剂存在下的分子骨架中具有硅氧烷键的二胺组分或包含内酯和/或酸性化合物和碱的混合催化剂， ; 基于总二胺成分的具有硅氧烷键的二胺成分的含量为15〜85重量％。

公开(公告)号：US20110127077A1

公开(公告)日：2011-06-02

申请号：US13025581

申请日：2011-02-11

申请人： Maw Soe WIN ,  Toshiyuki Goshima ,  Eika Kyo ,  Shintaro Nakajima ,  Noriki Hayashi ,  Tohru Kashiwagi ,  Kenji Miyazaki ,  Katsuya Yamada ,  Naoyuki Yamabayashi ,  Shoji Nakagama ,  Hiroshi Okuyama ,  Fumio Kasabo ,  Ippei Tanaka

发明人： Maw Soe WIN ,  Toshiyuki Goshima ,  Eika Kyo ,  Shintaro Nakajima ,  Noriki Hayashi ,  Tohru Kashiwagi ,  Kenji Miyazaki ,  Katsuya Yamada ,  Naoyuki Yamabayashi ,  Shoji Nakagama ,  Hiroshi Okuyama ,  Fumio Kasabo ,  Ippei Tanaka

IPC分类号： H05K1/00 ,  C08K5/101 ,  C08K5/3492 ,  C08K5/5399 ,  C08K5/3475 ,  C08L79/08 ,  B05D5/00

CPC分类号： C09D11/102 ,  H05K3/28 ,  H05K2201/0154 ,  H05K2203/0783

摘要： The object is to provide a polyimide ink composition having good printing properties and good continuous priming properties, which composition can be dried at a low temperature of not higher than 220° C., and which composition gives a coating film, after being dried, having excellent dimensional stability, heat resistance, low modulus of elasticity, flexibility, resistance to warping, chemical resistance, adhesiveness with substrates, and plating resistance. This object is accomplished by a polyimide ink composition for printing, comprising a mixed solvent containing an benzoic acid ester solvent and a glyme solvent, and a polyimide soluble in the mixed solvent; wherein the polyimide is obtained by polycondensing a polyimide oligomer with a tetracarboxylic dianhydride component(s) and/or a diamine component(s) having no siloxane bond in molecular skeleton thereof, the polyimide oligomer being prepared by polycondensing a tetracarboxylic dianhydride component(s) and a diamine component(s) having siloxane bonds in molecular skeleton thereof in the presence of a base catalyst(s), or a mixed catalyst including a lactone(s) and/or an acidic compound(s) and a base(s); the content of the diamine component(s) having siloxane bonds based on the total diamine components being 15 to 85% by weight.

摘要翻译： 本发明的目的是提供具有良好的印刷性能和良好的连续起始性能的聚酰亚胺油墨组合物，该组合物可以在不高于220℃的低温下干燥，并且该组合物在干燥后得到涂膜，具有 优异的尺寸稳定性，耐热性，低弹性模量，柔软性，抗翘曲性，耐化学性，与基材的粘合性和耐电镀性。 该目的通过用于印刷的聚酰亚胺油墨组合物实现，其包含含有苯甲酸酯溶剂和甘醇二甲醚溶剂的混合溶剂和可溶于混合溶剂的聚酰亚胺; 其中所述聚酰亚胺是通过将聚酰亚胺低聚物与其分子骨架中不含硅氧烷键的四羧酸二酐组分和/或二胺组分缩聚得到的，所述聚酰亚胺低聚物是通过使四羧酸二酐组分缩聚而制备的， 和在其基础催化剂存在下的分子骨架中具有硅氧烷键的二胺组分或包含内酯和/或酸性化合物和碱的混合催化剂， ; 基于总二胺成分的具有硅氧烷键的二胺成分的含量为15〜85重量％。

公开(公告)号：US20080275181A1

公开(公告)日：2008-11-06

申请号：US11597694

申请日：2005-05-24

申请人： Maw Soe Win ,  Toshiyuki Goshima ,  Eika Kyo ,  Shintaro Nakajima ,  Noriki Hayashi ,  Tohru Kashiwagi ,  Kenji Miyazaki ,  Katsuya Yamada ,  Naoyuki Yamabayashi ,  Shoji Nakagama ,  Hiroshi Okuyama ,  Fumio Kasabo ,  Ippei Tanaka

发明人： Maw Soe Win ,  Toshiyuki Goshima ,  Eika Kyo ,  Shintaro Nakajima ,  Noriki Hayashi ,  Tohru Kashiwagi ,  Kenji Miyazaki ,  Katsuya Yamada ,  Naoyuki Yamabayashi ,  Shoji Nakagama ,  Hiroshi Okuyama ,  Fumio Kasabo ,  Ippei Tanaka

IPC分类号： C08G73/10

CPC分类号： C09D11/102 ,  H05K3/28 ,  H05K2201/0154 ,  H05K2203/0783

摘要： The object is to provide a polyimide ink composition having good printing properties and good continuous printing properties, which composition can be dried at a low temperature of not higher than 220° C., and which composition gives a coating film, after being dried, having excellent dimensional stability, heat resistance, low modulus of elasticity, flexibility, resistance to warping, chemical resistance, adhesiveness with substrates, and plating resistance. This object is accomplished by a polyimide ink composition for printing, comprising a mixed solvent containing an benzoic acid ester solvent and a glyme solvent, and a polyimide soluble in the mixed solvent; wherein the polyimide is obtained by polycondensing a polyimide oligomer with a tetracarboxylic dianhydride component(s) and/or a diamine component(s) having no siloxane bond in molecular skeleton thereof the polyimide oligomer being prepared by polycondensing a tetracarboxylic dianhydride component(s) and a diamine component(s) having siloxane bonds in molecular skeleton thereof in the presence of a base catalyst(s), or a mixed catalyst including a lactone(s) and/or an acidic compound(s) and a base(s); the content of the diamine component(s) having siloxane bonds based on the total diamine components being 15 to 85% by weight.

摘要翻译： 本发明的目的是提供具有良好的印刷性能和良好的连续印刷性能的聚酰亚胺油墨组合物，该组合物可以在不高于220℃的低温下干燥，并且该组合物在干燥后得到涂膜， 优异的尺寸稳定性，耐热性，低弹性模量，柔软性，抗翘曲性，耐化学性，与基材的粘合性和耐电镀性。 该目的通过用于印刷的聚酰亚胺油墨组合物实现，其包含含有苯甲酸酯溶剂和甘醇二甲醚溶剂的混合溶剂和可溶于混合溶剂的聚酰亚胺; 其中所述聚酰亚胺通过聚酰亚胺低聚物与其分子骨架中不具有硅氧烷键的四羧酸二酐组分和/或二胺组分缩聚得到，所述聚酰亚胺低聚物是通过将四羧酸二酐组分和 在基础催化剂或含有内酯和/或酸性化合物和碱的混合催化剂存在下，在其分子骨架上具有硅氧烷键的二胺组分; 基于总二胺成分的具有硅氧烷键的二胺成分的含量为15〜85重量％。

公开(公告)号：US08349537B2

公开(公告)日：2013-01-08

申请号：US13007373

申请日：2011-01-14

申请人： Maw Soe Win ,  Toshiyuki Goshima ,  Sigemasa Segawa ,  Shintaro Nakajima ,  Eika Kyo ,  Yoshikazu Nishikawa ,  Shuzo Waki

发明人： Maw Soe Win ,  Toshiyuki Goshima ,  Sigemasa Segawa ,  Shintaro Nakajima ,  Eika Kyo ,  Yoshikazu Nishikawa ,  Shuzo Waki

IPC分类号： G03F7/00 ,  G03F7/004 ,  C08G77/04

CPC分类号： H05K3/287 ,  C08G73/106 ,  C08G77/455 ,  C08L79/08 ,  C08L83/10 ,  C09D11/101

摘要： Disclosed is a photosensitive ink which can form a coated film that is excellent in insulation properties, heat resistance, low warping, low elasticity and adhesion with the substrate, when used as an ink for screen printing, and with which clogging of the screen, bleeding, blur, chipping and the like are unlikely to occur even when the screen printing is repeatedly carried out, so that which has an excellent ease of handling in printing. The ink composition comprises 100 parts by weight of an organic solvent-soluble polyimide block copolymer(s), and 1 to 100 parts by weight of a photoacid generator(s). The polyimide block copolymer(s) and the photoacid generator(s) are dissolved in an organic solvent. The polyimide block copolymer(s) contain(s) in its molecular skeleton a diamine having a siloxane bond, and an aromatic diamine having a hydroxyl group(s) and/or carboxyl group(s) at ortho-position with respect to an amino group.

摘要翻译： 公开了一种感光油墨，当用作丝网印刷的油墨时，可以形成绝缘性能，耐热性，低翘曲性，低弹性和与基材的粘合性优异的涂膜，并且使丝网堵塞，渗色 ，即使重复执行丝网印刷也不可能发生模糊，碎片等，从而在印刷中具有极好的处理容易性。 油墨组合物包含100重量份的有机溶剂可溶性聚酰亚胺嵌段共聚物和1至100重量份的光酸产生剂。 将聚酰亚胺嵌段共聚物和光酸产生剂溶解在有机溶剂中。 聚酰亚胺嵌段共聚物在其分子骨架中含有具有硅氧烷键的二胺和相对于氨基的邻位羟基和/或羧基的芳族二胺 组。

公开(公告)号：US20090186295A1

公开(公告)日：2009-07-23

申请号：US12224593

申请日：2007-03-02

申请人： Maw Soe Win ,  Toshiyuki Goshima ,  Sigemasa Segawa ,  Shintaro Nakajima ,  Eika Kyo ,  Yoshikazu Nishikawa ,  Shuzo Waki

发明人： Maw Soe Win ,  Toshiyuki Goshima ,  Sigemasa Segawa ,  Shintaro Nakajima ,  Eika Kyo ,  Yoshikazu Nishikawa ,  Shuzo Waki

IPC分类号： G03F7/004 ,  G03F7/20

CPC分类号： H05K3/287 ,  C08G73/106 ,  C08G77/455 ,  C08L79/08 ,  C08L83/10 ,  C09D11/101

摘要： Disclosed is a photosensitive ink which can form a coated film that is excellent in insulation properties, heat resistance, low warping, low elasticity and adhesion with the substrate, when used as an ink for screen printing, and with which clogging of the screen, bleeding, blur, chipping and the like are unlikely to occur even when the screen printing is repeatedly carried out, so that which has an excellent ease of handling in printing. The ink composition comprises 100 parts by weight of an organic solvent-soluble polyimide block copolymer(s), and 1 to 100 parts by weight of a photoacid generator(s). The polyimide block copolymer(s) and the photoacid generator(s) are dissolved in an organic solvent. The polyimide block copolymer(s) contain(s) in its molecular skeleton a diamine having a siloxane bond, and an aromatic diamine having a hydroxyl group(s) and/or carboxyl group(s) at ortho-position with respect to an amino group.

摘要翻译： 公开了一种感光油墨，当用作丝网印刷的油墨时，可以形成绝缘性能，耐热性，低翘曲性，低弹性和与基材的粘合性优异的涂膜，并且使丝网堵塞，渗色 ，即使重复执行丝网印刷也不可能发生模糊，碎片等，从而在印刷中具有极好的处理容易性。 油墨组合物包含100重量份的有机溶剂可溶性聚酰亚胺嵌段共聚物和1至100重量份的光酸产生剂。 将聚酰亚胺嵌段共聚物和光酸产生剂溶解在有机溶剂中。 聚酰亚胺嵌段共聚物在其分子骨架中含有具有硅氧烷键的二胺和相对于氨基的邻位羟基和/或羧基的芳族二胺 组。

公开(公告)号：US20110111351A1

公开(公告)日：2011-05-12

申请号：US13007373

申请日：2011-01-14

申请人： Maw Soe Win ,  Toshiyuki Goshima ,  Sigemasa Segawa ,  Shintaro Nakajima ,  Eika Kyo ,  Yoshikazu Nishikawa ,  Shuzo Waki

发明人： Maw Soe Win ,  Toshiyuki Goshima ,  Sigemasa Segawa ,  Shintaro Nakajima ,  Eika Kyo ,  Yoshikazu Nishikawa ,  Shuzo Waki

IPC分类号： G03F7/20 ,  G03C1/00

CPC分类号： H05K3/287 ,  C08G73/106 ,  C08G77/455 ,  C08L79/08 ,  C08L83/10 ,  C09D11/101

摘要： Disclosed is a photosensitive ink which can form a coated film that is excellent in insulation properties, heat resistance, low warping, low elasticity and adhesion with the substrate, when used as an ink for screen printing, and with which clogging of the screen, bleeding, blur, chipping and the like are unlikely to occur even when the screen printing is repeatedly carried out, so that which has an excellent ease of handling in printing. The ink composition comprises 100 parts by weight of an organic solvent-soluble polyimide block copolymer(s), and 1 to 100 parts by weight of a photoacid generator(s). The polyimide block copolymer(s) and the photoacid generator(s) are dissolved in an organic solvent. The polyimide block copolymer(s) contain(s) in its molecular skeleton a diamine having a siloxane bond, and an aromatic diamine having a hydroxyl group(s) and/or carboxyl group(s) at ortho-position with respect to an amino group.

摘要翻译： 公开了一种感光油墨，当用作丝网印刷的油墨时，可以形成绝缘性能，耐热性，低翘曲性，低弹性和与基材的粘合性优异的涂膜，并且使丝网堵塞，渗色 ，即使重复执行丝网印刷也不可能发生模糊，碎片等，从而在印刷中具有极好的处理容易性。 油墨组合物包含100重量份的有机溶剂可溶性聚酰亚胺嵌段共聚物和1至100重量份的光酸产生剂。 将聚酰亚胺嵌段共聚物和光酸产生剂溶解在有机溶剂中。 聚酰亚胺嵌段共聚物在其分子骨架中含有具有硅氧烷键的二胺和相对于氨基的邻位羟基和/或羧基的芳族二胺 组。

公开(公告)号：US20100108533A1

公开(公告)日：2010-05-06

申请号：US12451336

申请日：2008-05-07

申请人： Masanori Fujii ,  Toshihiro Zushi ,  Hiromasa Honjo ,  Toyokazu Nagato ,  Maw Soe Win ,  Shintaro Nakajima ,  Toshiyuki Goshima ,  Kiyoshi Ishii

发明人： Masanori Fujii ,  Toshihiro Zushi ,  Hiromasa Honjo ,  Toyokazu Nagato ,  Maw Soe Win ,  Shintaro Nakajima ,  Toshiyuki Goshima ,  Kiyoshi Ishii

IPC分类号： C25D9/02

CPC分类号： C09D5/4484 ,  C09D179/08 ,  C09D183/10 ,  C25D13/06

摘要： A suspension type electrodeposition coating composition containing, as a resin component, block copolyimide having a siloxane bond in a molecular structure and an anionic group in a molecule. Preferably, the above-mentioned block copolyimide contains, as one of the diamine components, diamine having a siloxane, bond in a molecular structure. In addition, preferably, the above-mentioned anionic group is a carboxylic acid group or a salt thereof and/or a sulfonic acid group or a salt thereof. The electrodeposition coating composition has superior heat resistance, which does not easily develop peeling and cracks in the electrodeposited body, and is capable of efficiently forming a high-insulation electrodeposited film superior in the uniformity of film property.

摘要翻译： 一种悬浮液型电沉积涂料组合物，其含有分子结构中具有硅氧烷键和阴离子基团的嵌段共聚酰亚胺作为树脂成分。 优选地，上述嵌段共聚酰亚胺作为二胺成分之一，含有分子结构键合的具有硅氧烷的二胺。 另外，上述阴离子性基团优选为羧酸基或其盐和/或磺酸基或其盐。 电沉积涂料组合物具有优异的耐热性，其不易在电沉积体中产生剥离和裂纹，并且能够有效地形成膜性能均匀性优异的高绝缘电沉积膜。

公开(公告)号：US08372257B2

公开(公告)日：2013-02-12

申请号：US12451336

申请日：2008-05-07

申请人： Masanori Fujii ,  Toshihiro Zushi ,  Hiromasa Honjo ,  Toyokazu Nagato ,  Maw Soe Win ,  Shintaro Nakajima ,  Toshiyuki Goshima ,  Kiyoshi Ishii

发明人： Masanori Fujii ,  Toshihiro Zushi ,  Hiromasa Honjo ,  Toyokazu Nagato ,  Maw Soe Win ,  Shintaro Nakajima ,  Toshiyuki Goshima ,  Kiyoshi Ishii

IPC分类号： C25D13/06 ,  C08G77/26

CPC分类号： C09D5/4484 ,  C09D179/08 ,  C09D183/10 ,  C25D13/06

摘要： A suspension type electrodeposition coating composition containing, as a resin component, block copolyimide having a siloxane bond in a molecular structure and an anionic group in a molecule. Preferably, the above-mentioned block copolyimide contains, as one of the diamine components, diamine having a siloxane, bond in a molecular structure. In addition, preferably, the above-mentioned anionic group is a carboxylic acid group or a salt thereof and/or a sulfonic acid group or a salt thereof. The electrodeposition coating composition has superior heat resistance, which does not easily develop peeling and cracks in the electrodeposited body, and is capable of efficiently forming a high-insulation electrodeposited film superior in the uniformity of film property.

摘要翻译： 一种悬浮液型电沉积涂料组合物，其含有分子结构中具有硅氧烷键和阴离子基团的嵌段共聚酰亚胺作为树脂成分。 优选地，上述嵌段共聚酰亚胺作为二胺成分之一，含有分子结构键合的具有硅氧烷的二胺。 另外，上述阴离子性基团优选为羧酸基或其盐和/或磺酸基或其盐。 电沉积涂料组合物具有优异的耐热性，其不易在电沉积体中产生剥离和裂纹，并且能够有效地形成膜性能均匀性优异的高绝缘电沉积膜。