BLOCK COPOLYMERIZED POLYIMIDE INK COMPOSITION FOR PRINTING
    1.
    发明申请
    BLOCK COPOLYMERIZED POLYIMIDE INK COMPOSITION FOR PRINTING 审中-公开
    用于印刷的嵌段共聚物聚酰胺油墨组合物

    公开(公告)号:US20090229870A1

    公开(公告)日:2009-09-17

    申请号:US12470399

    申请日:2009-05-21

    IPC分类号: H05K1/00 C09D131/06 B05D5/00

    摘要: The object is to provide a polyimide ink composition having good printing properties and good continuous printing properties, which composition can be dried at a low temperature of not higher than 220° C., and which composition gives a coating film, after being dried, having excellent dimensional stability, heat resistance, low modulus of elasticity, flexibility, resistance to warping, chemical resistance, adhesiveness with substrates, and plating resistance. This object is accomplished by a polyimide ink composition for printing, comprising a mixed solvent containing an benzoic acid ester solvent and a glyme solvent, and a polyimide soluble in the mixed solvent; wherein the polyimide is obtained by polycondensing a polyimide oligomer with a tetracarboxylic dianhydride component(s) and/or a diamine component(s) having no siloxane bond in molecular skeleton thereof, the polyimide oligomer being prepared by polycondensing a tetracarboxylic dianhydride component(s) and a diamine component(s) having siloxane bonds in molecular skeleton thereof in the presence of a base catalyst(s), or a mixed catalyst including a lactone(s) and/or an acidic compound(s) and a base(s); the content of the diamine component(s) having siloxane bonds based on the total diamine components being 15 to 85% by weight.

    摘要翻译: 本发明的目的是提供具有良好的印刷性能和良好的连续印刷性能的聚酰亚胺油墨组合物,该组合物可以在不高于220℃的低温下干燥,并且该组合物在干燥后得到涂膜, 优异的尺寸稳定性,耐热性,低弹性模量,柔软性,抗翘曲性,耐化学性,与基材的粘合性和耐电镀性。 该目的通过用于印刷的聚酰亚胺油墨组合物实现,其包含含有苯甲酸酯溶剂和甘醇二甲醚溶剂的混合溶剂和可溶于混合溶剂的聚酰亚胺; 其中所述聚酰亚胺是通过将聚酰亚胺低聚物与其分子骨架中不含硅氧烷键的四羧酸二酐组分和/或二胺组分缩聚得到的,所述聚酰亚胺低聚物是通过使四羧酸二酐组分缩聚而制备的, 和在其基础催化剂存在下的分子骨架中具有硅氧烷键的二胺组分或包含内酯和/或酸性化合物和碱的混合催化剂, ; 基于总二胺成分的具有硅氧烷键的二胺成分的含量为15〜85重量%。

    BLOCK COPOLYMERIZED POLYIMIDE INK COMPOSITION FOR PRINTING
    2.
    发明申请
    BLOCK COPOLYMERIZED POLYIMIDE INK COMPOSITION FOR PRINTING 审中-公开
    用于印刷的嵌段共聚物聚酰胺油墨组合物

    公开(公告)号:US20110127077A1

    公开(公告)日:2011-06-02

    申请号:US13025581

    申请日:2011-02-11

    摘要: The object is to provide a polyimide ink composition having good printing properties and good continuous priming properties, which composition can be dried at a low temperature of not higher than 220° C., and which composition gives a coating film, after being dried, having excellent dimensional stability, heat resistance, low modulus of elasticity, flexibility, resistance to warping, chemical resistance, adhesiveness with substrates, and plating resistance. This object is accomplished by a polyimide ink composition for printing, comprising a mixed solvent containing an benzoic acid ester solvent and a glyme solvent, and a polyimide soluble in the mixed solvent; wherein the polyimide is obtained by polycondensing a polyimide oligomer with a tetracarboxylic dianhydride component(s) and/or a diamine component(s) having no siloxane bond in molecular skeleton thereof, the polyimide oligomer being prepared by polycondensing a tetracarboxylic dianhydride component(s) and a diamine component(s) having siloxane bonds in molecular skeleton thereof in the presence of a base catalyst(s), or a mixed catalyst including a lactone(s) and/or an acidic compound(s) and a base(s); the content of the diamine component(s) having siloxane bonds based on the total diamine components being 15 to 85% by weight.

    摘要翻译: 本发明的目的是提供具有良好的印刷性能和良好的连续起始性能的聚酰亚胺油墨组合物,该组合物可以在不高于220℃的低温下干燥,并且该组合物在干燥后得到涂膜,具有 优异的尺寸稳定性,耐热性,低弹性模量,柔软性,抗翘曲性,耐化学性,与基材的粘合性和耐电镀性。 该目的通过用于印刷的聚酰亚胺油墨组合物实现,其包含含有苯甲酸酯溶剂和甘醇二甲醚溶剂的混合溶剂和可溶于混合溶剂的聚酰亚胺; 其中所述聚酰亚胺是通过将聚酰亚胺低聚物与其分子骨架中不含硅氧烷键的四羧酸二酐组分和/或二胺组分缩聚得到的,所述聚酰亚胺低聚物是通过使四羧酸二酐组分缩聚而制备的, 和在其基础催化剂存在下的分子骨架中具有硅氧烷键的二胺组分或包含内酯和/或酸性化合物和碱的混合催化剂, ; 基于总二胺成分的具有硅氧烷键的二胺成分的含量为15〜85重量%。

    Block Copolymerized Polyimide Ink Composition for Printing
    3.
    发明申请
    Block Copolymerized Polyimide Ink Composition for Printing 审中-公开
    用于印刷的嵌段共聚聚酰亚胺油墨组合物

    公开(公告)号:US20080275181A1

    公开(公告)日:2008-11-06

    申请号:US11597694

    申请日:2005-05-24

    IPC分类号: C08G73/10

    摘要: The object is to provide a polyimide ink composition having good printing properties and good continuous printing properties, which composition can be dried at a low temperature of not higher than 220° C., and which composition gives a coating film, after being dried, having excellent dimensional stability, heat resistance, low modulus of elasticity, flexibility, resistance to warping, chemical resistance, adhesiveness with substrates, and plating resistance. This object is accomplished by a polyimide ink composition for printing, comprising a mixed solvent containing an benzoic acid ester solvent and a glyme solvent, and a polyimide soluble in the mixed solvent; wherein the polyimide is obtained by polycondensing a polyimide oligomer with a tetracarboxylic dianhydride component(s) and/or a diamine component(s) having no siloxane bond in molecular skeleton thereof the polyimide oligomer being prepared by polycondensing a tetracarboxylic dianhydride component(s) and a diamine component(s) having siloxane bonds in molecular skeleton thereof in the presence of a base catalyst(s), or a mixed catalyst including a lactone(s) and/or an acidic compound(s) and a base(s); the content of the diamine component(s) having siloxane bonds based on the total diamine components being 15 to 85% by weight.

    摘要翻译: 本发明的目的是提供具有良好的印刷性能和良好的连续印刷性能的聚酰亚胺油墨组合物,该组合物可以在不高于220℃的低温下干燥,并且该组合物在干燥后得到涂膜, 优异的尺寸稳定性,耐热性,低弹性模量,柔软性,抗翘曲性,耐化学性,与基材的粘合性和耐电镀性。 该目的通过用于印刷的聚酰亚胺油墨组合物实现,其包含含有苯甲酸酯溶剂和甘醇二甲醚溶剂的混合溶剂和可溶于混合溶剂的聚酰亚胺; 其中所述聚酰亚胺通过聚酰亚胺低聚物与其分子骨架中不具有硅氧烷键的四羧酸二酐组分和/或二胺组分缩聚得到,所述聚酰亚胺低聚物是通过将四羧酸二酐组分和 在基础催化剂或含有内酯和/或酸性化合物和碱的混合催化剂存在下,在其分子骨架上具有硅氧烷键的二胺组分; 基于总二胺成分的具有硅氧烷键的二胺成分的含量为15〜85重量%。

    Photosensitive ink composition for screen printing and method of forming positive relief pattern with use thereof
    4.
    发明授权
    Photosensitive ink composition for screen printing and method of forming positive relief pattern with use thereof 有权
    用于丝网印刷的感光性油墨组合物及其使用形成正浮雕图案的方法

    公开(公告)号:US08349537B2

    公开(公告)日:2013-01-08

    申请号:US13007373

    申请日:2011-01-14

    IPC分类号: G03F7/00 G03F7/004 C08G77/04

    摘要: Disclosed is a photosensitive ink which can form a coated film that is excellent in insulation properties, heat resistance, low warping, low elasticity and adhesion with the substrate, when used as an ink for screen printing, and with which clogging of the screen, bleeding, blur, chipping and the like are unlikely to occur even when the screen printing is repeatedly carried out, so that which has an excellent ease of handling in printing. The ink composition comprises 100 parts by weight of an organic solvent-soluble polyimide block copolymer(s), and 1 to 100 parts by weight of a photoacid generator(s). The polyimide block copolymer(s) and the photoacid generator(s) are dissolved in an organic solvent. The polyimide block copolymer(s) contain(s) in its molecular skeleton a diamine having a siloxane bond, and an aromatic diamine having a hydroxyl group(s) and/or carboxyl group(s) at ortho-position with respect to an amino group.

    摘要翻译: 公开了一种感光油墨,当用作丝网印刷的油墨时,可以形成绝缘性能,耐热性,低翘曲性,低弹性和与基材的粘合性优异的涂膜,并且使丝网堵塞,渗色 ,即使重复执行丝网印刷也不可能发生模糊,碎片等,从而在印刷中具有极好的处理容易性。 油墨组合物包含100重量份的有机溶剂可溶性聚酰亚胺嵌段共聚物和1至100重量份的光酸产生剂。 将聚酰亚胺嵌段共聚物和光酸产生剂溶解在有机溶剂中。 聚酰亚胺嵌段共聚物在其分子骨架中含有具有硅氧烷键的二胺和相对于氨基的邻位羟基和/或羧基的芳族二胺 组。

    Photosensitive Ink Composition for Screen Printing and Method of Forming Positive Relief Pattern with Use Thereof
    5.
    发明申请
    Photosensitive Ink Composition for Screen Printing and Method of Forming Positive Relief Pattern with Use Thereof 有权
    用于丝网印刷的感光油墨组合物及其使用形成正浮雕图案的方法

    公开(公告)号:US20110111351A1

    公开(公告)日:2011-05-12

    申请号:US13007373

    申请日:2011-01-14

    IPC分类号: G03F7/20 G03C1/00

    摘要: Disclosed is a photosensitive ink which can form a coated film that is excellent in insulation properties, heat resistance, low warping, low elasticity and adhesion with the substrate, when used as an ink for screen printing, and with which clogging of the screen, bleeding, blur, chipping and the like are unlikely to occur even when the screen printing is repeatedly carried out, so that which has an excellent ease of handling in printing. The ink composition comprises 100 parts by weight of an organic solvent-soluble polyimide block copolymer(s), and 1 to 100 parts by weight of a photoacid generator(s). The polyimide block copolymer(s) and the photoacid generator(s) are dissolved in an organic solvent. The polyimide block copolymer(s) contain(s) in its molecular skeleton a diamine having a siloxane bond, and an aromatic diamine having a hydroxyl group(s) and/or carboxyl group(s) at ortho-position with respect to an amino group.

    摘要翻译: 公开了一种感光油墨,当用作丝网印刷的油墨时,可以形成绝缘性能,耐热性,低翘曲性,低弹性和与基材的粘合性优异的涂膜,并且使丝网堵塞,渗色 ,即使重复执行丝网印刷也不可能发生模糊,碎片等,从而在印刷中具有极好的处理容易性。 油墨组合物包含100重量份的有机溶剂可溶性聚酰亚胺嵌段共聚物和1至100重量份的光酸产生剂。 将聚酰亚胺嵌段共聚物和光酸产生剂溶解在有机溶剂中。 聚酰亚胺嵌段共聚物在其分子骨架中含有具有硅氧烷键的二胺和相对于氨基的邻位羟基和/或羧基的芳族二胺 组。

    Photosensitive Ink Composition for Screen Printing and Method of Forming Positive Relief Pattern with Use Thereof
    6.
    发明申请
    Photosensitive Ink Composition for Screen Printing and Method of Forming Positive Relief Pattern with Use Thereof 审中-公开
    用于丝网印刷的感光油墨组合物及其使用形成正浮雕图案的方法

    公开(公告)号:US20090186295A1

    公开(公告)日:2009-07-23

    申请号:US12224593

    申请日:2007-03-02

    IPC分类号: G03F7/004 G03F7/20

    摘要: Disclosed is a photosensitive ink which can form a coated film that is excellent in insulation properties, heat resistance, low warping, low elasticity and adhesion with the substrate, when used as an ink for screen printing, and with which clogging of the screen, bleeding, blur, chipping and the like are unlikely to occur even when the screen printing is repeatedly carried out, so that which has an excellent ease of handling in printing. The ink composition comprises 100 parts by weight of an organic solvent-soluble polyimide block copolymer(s), and 1 to 100 parts by weight of a photoacid generator(s). The polyimide block copolymer(s) and the photoacid generator(s) are dissolved in an organic solvent. The polyimide block copolymer(s) contain(s) in its molecular skeleton a diamine having a siloxane bond, and an aromatic diamine having a hydroxyl group(s) and/or carboxyl group(s) at ortho-position with respect to an amino group.

    摘要翻译: 公开了一种感光油墨,当用作丝网印刷的油墨时,可以形成绝缘性能,耐热性,低翘曲性,低弹性和与基材的粘合性优异的涂膜,并且使丝网堵塞,渗色 ,即使重复执行丝网印刷也不可能发生模糊,碎片等,从而在印刷中具有极好的处理容易性。 油墨组合物包含100重量份的有机溶剂可溶性聚酰亚胺嵌段共聚物和1至100重量份的光酸产生剂。 将聚酰亚胺嵌段共聚物和光酸产生剂溶解在有机溶剂中。 聚酰亚胺嵌段共聚物在其分子骨架中含有具有硅氧烷键的二胺和相对于氨基的邻位羟基和/或羧基的芳族二胺 组。

    MODIFIED POLYIMIDE AND METHOD FOR PRODUCING MODIFIED POLYIMIDE
    9.
    发明申请
    MODIFIED POLYIMIDE AND METHOD FOR PRODUCING MODIFIED POLYIMIDE 失效
    改性聚酰亚胺和生产改性聚酰亚胺的方法

    公开(公告)号:US20120097439A1

    公开(公告)日:2012-04-26

    申请号:US13266925

    申请日:2010-04-30

    IPC分类号: H05K1/02 C08G73/10

    摘要: The present invention discloses a method of producing a modified polyimide comprising a polycarbonate, which modified polyimide has excellent electric properties and adhesion as well as excellent heat resistance, flexibility, bending property, low warping, chemical resistance and storage stability; and the modified polyimide. Also disclosed are a composition comprising the modified polyimide and used thereof. According to the method in which an isocyanate-terminated oligomer comprising a polycarbonate component having excellent flexibility is allowed to react with a tetracarboxylic dianhydride to synthesize a tetracarboxylic dianhydride oligomer comprising the polycarbonate component and the thus obtained oligomer is then further allowed to react with an aromatic diamine and aromatic tetracarboxylic dianhydride to produce a polyimide block copolymer, by selecting the aromatic diamine from a wide range of selectable aromatic diamines, an excellent modified polyimide satisfying all of the above-described various characteristics can be produced.

    摘要翻译: 本发明公开了一种改性聚酰亚胺的制造方法,该改性聚酰亚胺具有优异的电性能和粘合性,耐热性,柔软性,弯曲性,低翘曲性,耐化学性和储存稳定性优异。 和改性聚酰亚胺。 还公开了包含改性聚酰亚胺并使用的组合物。 根据其中含有具有优异柔性的聚碳酸酯组分的异氰酸酯封端的低聚物与四羧酸二酐反应以合成包含聚碳酸酯组分的四羧酸二酐低聚物和由此得到的低聚物进一步与芳族化合物反应的方法 二胺和芳香族四羧酸二酐以制备聚酰亚胺嵌段共聚物,通过从宽范围的可选择的芳族二胺中选择芳族二胺,可以制备出满足所有上述各种特性的优异的改性聚酰亚胺。

    Modified polyimide and method for producing modified polyimide
    10.
    发明授权
    Modified polyimide and method for producing modified polyimide 失效
    改性聚酰亚胺及改性聚酰亚胺的制造方法

    公开(公告)号:US08779085B2

    公开(公告)日:2014-07-15

    申请号:US13266925

    申请日:2010-04-30

    IPC分类号: C08G69/36

    摘要: The present invention discloses a method of producing a modified polyimide comprising a polycarbonate, which modified polyimide has excellent electric properties and adhesion as well as excellent heat resistance, flexibility, bending property, low warping, chemical resistance and storage stability; and the modified polyimide. Also disclosed are a composition comprising the modified polyimide and used thereof. According to the method in which an isocyanate-terminated oligomer comprising a polycarbonate component having excellent flexibility is allowed to react with a tetracarboxylic dianhydride to synthesize a tetracarboxylic dianhydride oligomer comprising the polycarbonate component and the thus obtained oligomer is then further allowed to react with an aromatic diamine and aromatic tetracarboxylic dianhydride to produce a polyimide block copolymer, by selecting the aromatic diamine from a wide range of selectable aromatic diamines, an excellent modified polyimide satisfying all of the above-described various characteristics can be produced.

    摘要翻译: 本发明公开了一种改性聚酰亚胺的制造方法,该改性聚酰亚胺具有优异的电性能和粘合性,耐热性,柔软性,弯曲性,低翘曲性,耐化学性和储存稳定性优异。 和改性聚酰亚胺。 还公开了包含改性聚酰亚胺并使用的组合物。 根据其中含有具有优异柔性的聚碳酸酯组分的异氰酸酯封端的低聚物与四羧酸二酐反应以合成包含聚碳酸酯组分的四羧酸二酐低聚物和由此得到的低聚物进一步与芳族化合物反应的方法 二胺和芳香族四羧酸二酐以制备聚酰亚胺嵌段共聚物,通过从宽范围的可选择的芳族二胺中选择芳族二胺,可以制备出满足所有上述各种特性的优异的改性聚酰亚胺。