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    Method for preparing light-absorbing polymeric compositions
    1.
    发明授权
    Method for preparing light-absorbing polymeric compositions 失效
    光吸收聚合物组合物的制备方法

    公开(公告)号：US06197223B1

    公开(公告)日：2001-03-06

    申请号：US09320002

    申请日：1999-05-26

    申请人： Max Allen Weaver ,  James John Krutak, Sr. ,  Brian Edison Maxwell ,  Gerry Foust Rhodes ,  Samuel David Hilbert ,  Jean Carroll Fleischer ,  William Whitfield Parham

    发明人： Max Allen Weaver ,  James John Krutak, Sr. ,  Brian Edison Maxwell ,  Gerry Foust Rhodes ,  Samuel David Hilbert ,  Jean Carroll Fleischer ,  William Whitfield Parham

    IPC分类号： F21V900

    CPC分类号： C09B31/02 ,  C09B1/32 ,  C09B1/585 ,  C09B1/62 ,  C09B5/14 ,  C09B29/0007 ,  C09B29/0025 ,  C09B29/08 ,  C09B29/36 ,  C09B69/101 ,  C09B69/106 ,  C09B69/109

    摘要： The present invention recites a method comprising reacting in a solvent in the presence of a base a) at least one diacidic monomer comprising about 1 to 100 mole % of at least one light-absorbing monomer having a light absorption maximum between about 300 nm and about 1200 nm and 99-0 mole % of a non-light absorbing monomer which does not absorb significant light at wavelengths above 300 nm or has a light absorption maximum below 300 nm, with b) an organic compound of Formula II X—B—X1 wherein B is a divalent organic radical to form a light absorbing composition comprising a mixture of a polymer having the formula and a cyclic compound having the general formula wherein B is as defined above; n is at least 2, m is 1, 2, 3 or 4 and A comprises the residue of a diacidic monomer comprising about 1 to 100 mole % of at least one light-absorbing monomer having a light absorption maximum between about 300 nm and about 1000 nm and wherein the remaining portion of A comprises the residue of a non-light absorbing monomer which does not absorb significant light at wavelengths above 300 nm or has a light absorption maximum below 300 nm.

    摘要翻译： 本发明描述了一种方法，包括在碱的存在下在溶剂中反应至少一种二酸单体，其包含约1至100摩尔％的至少一种光吸收单体，其光吸收最大值在约300nm至约1200 nm和99-0摩尔％的非光吸收单体，其不吸收波长高于300nm的显着光或具有300nm以下的光吸收最大值，b）式II的有机化合物，其中B是二价有机基团， 形成包含具有下式的聚合物和具有通式化合物B的环状化合物的混合物的光吸收组合物如上所定义; n至少为2，m为1,2,3或4，A包含二酸单体的残基，该二酸单体包含约1至100摩尔％的至少一种光吸收单体的光吸收最大值在约300nm至约 1000nm，并且其中A的剩余部分包含不吸收波长高于300nm或在300nm以下的光吸收最大值的不吸收光的非光吸收单体的残基。

    Method for preparing light-absorbing polymeric compositions
    2.
    发明授权
    Method for preparing light-absorbing polymeric compositions 失效
    光吸收聚合物组合物的制备方法

    公开(公告)号：US06776930B2

    公开(公告)日：2004-08-17

    申请号：US09751766

    申请日：2000-12-29

    申请人： Max Allen Weaver ,  James John Krutak, Sr. ,  Brian Edison Maxwell ,  Gerry Foust Rhodes ,  Samuel David Hilbert ,  Jean Carroll Fleischer ,  William Whitfield Parham

    发明人： Max Allen Weaver ,  James John Krutak, Sr. ,  Brian Edison Maxwell ,  Gerry Foust Rhodes ,  Samuel David Hilbert ,  Jean Carroll Fleischer ,  William Whitfield Parham

    IPC分类号： F21V900

    CPC分类号： C09B31/02 ,  C09B1/32 ,  C09B1/585 ,  C09B1/62 ,  C09B5/14 ,  C09B29/0007 ,  C09B29/0025 ,  C09B29/08 ,  C09B29/36 ,  C09B69/101 ,  C09B69/106 ,  C09B69/109

    摘要： The present invention recites a method comprising reacting in a solvent in the presence of a base a) at least one diacidic monomer comprising about 1 to 100 mole % of at least one light-absorbing monomer having a light absorption maximum between about 300 nm and about 1200 nm and 99-0 mole % of a non-light absorbing monomer which does not absorb significant light at wavelengths above 300 nm or has a light absorption maximum below 300 nm, with b) an organic compound of Formula II X—B—X1  wherein B is a divalent organic radical to form a light absorbing composition comprising a mixture of a polymer having the formula  and a cyclic compound having the general formula  wherein B is as defined above; n is at least 2, m is 1, 2, 3 or 4 and A comprises the residue of a diacidic monomer comprising about 1 to 100 mole % of at least one light-absorbing monomer having a light absorption maximum between about 300 nm and about 1000 nm and wherein the remaining portion of A comprises the residue of a non-light absorbing monomer which does not absorb significant light at wavelengths above 300 nm or has a light absorption maximum below 300 nm.

    摘要翻译： 本发明描述了一种方法，包括在碱的存在下在溶剂中反应至少一种二酸单体，其包含约1至100摩尔％的至少一种光吸收单体，其光吸收最大值在约300nm至约1200 nm和99-0摩尔％的非光吸收单体，其不吸收波长高于300nm的显着光或具有300nm以下的光吸收最大值，b）式II的有机化合物，其中B是二价有机基团， 形成包含具有下式的聚合物和具有通式化合物B的环状化合物的混合物的光吸收组合物如上所定义; n至少为2，m为1,2,3或4，A包含二酸单体的残基，该二酸单体包含约1至100摩尔％的至少一种光吸收单体的光吸收最大值在约300nm至约 1000nm，并且其中A的剩余部分包含不吸收波长高于300nm或在300nm以下的光吸收最大值的不吸收光的非光吸收单体的残基。

    Anthraquinone colorants containing copolymerizable vinyl groups
    4.
    发明授权
    Anthraquinone colorants containing copolymerizable vinyl groups 失效
    含有可共聚乙烯基的蒽醌着色剂

    公开(公告)号：US06630521B2

    公开(公告)日：2003-10-07

    申请号：US10054285

    申请日：2001-11-13

    申请人： Michael John Cyr ,  Max Allen Weaver ,  Gerry Foust Rhodes ,  Jason Clay Pearson ,  Jean Carroll Fleischer

    发明人： Michael John Cyr ,  Max Allen Weaver ,  Gerry Foust Rhodes ,  Jason Clay Pearson ,  Jean Carroll Fleischer

    IPC分类号： C07C22534

    CPC分类号： C09B69/101 ,  C08F246/00

    摘要： Disclosed are thermally-stable, red, anthraquinone colorants which contain one or more ethylenically-unsaturated, photopolymerizable radicals and which may be copolymerized with ethylenically-unsaturated monomers to produce colored compositions such as colored acrylic polymers, colored polystyrenes, and similar colored polymeric materials derived from other ethylenically-unsaturated monomers. The compounds possess good stability to ultraviolet light, good solubility in vinyl monomers, good color strength and thermal stability. Also disclosed are acrylic polymeric materials, i.e., polymers derived from acrylic acid esters, methacrylic acid esters and/or other copolymerizable vinyl compounds, having copolymerized therein one or more of the colorant compounds of the present invention.

    摘要翻译： 公开了含有一个或多个烯键式不饱和的光聚合基团的热稳定的红色蒽醌着色剂，其可以与烯键式不饱和单体共聚以产生着色的组合物，例如着色的丙烯酸聚合物，着色的聚苯乙烯和类似的着色的聚合物材料 来自其它烯属不饱和单体。 该化合物对紫外线具有良好的稳定性，在乙烯基单体中的良好溶解性，良好的着色强度和热稳定性。 还公开了丙烯酸聚合物材料，即衍生自丙烯酸酯，甲基丙烯酸酯和/或其它可共聚的乙烯基化合物的聚合物，其中共聚有一种或多种本发明的着色剂化合物。

    Thermoplastic polymer composition containing dye compositions
    5.
    发明授权
    Thermoplastic polymer composition containing dye compositions 失效
    含有染料组合物的热塑性聚合物组合物

    公开(公告)号：US06248816B1

    公开(公告)日：2001-06-19

    申请号：US09309987

    申请日：1999-05-11

    申请人： Max Allen Weaver ,  Clarence Alvin Coates, Jr. ,  Jean Carroll Fleischer ,  Brian Edison Maxwell

    发明人： Max Allen Weaver ,  Clarence Alvin Coates, Jr. ,  Jean Carroll Fleischer ,  Brian Edison Maxwell

    IPC分类号： C08K534

    CPC分类号： C09B5/52 ,  C08K5/0041

    摘要： The present invention relates to a polymeric composition suitable for use in films, molded articles and fibers, including microdenier fibers. The polymeric composition comprises a thermoplastic resin in an amount from about 50 weight percent to about 99.9 weight percent of the polymeric composition, and a dye composition in an amount from about 0.1 weight percent to about 50 weight percent of the polymeric composition. The dye composition contains an indanthrone compound as a major component. As used herein, indanthrone compounds are defined as compounds having the general structure represented by Formula I: wherein R is hydrogen or at least one group independently selected from C1-C8 alkyl, C1-C8 alkoxy, halogen, hydroxy, trifluoromethyl, aryloxy, arylthio, arylamino, C1-C8 carbalkoxy, —CO2H, C1-C8 alkanoyloxy, arylazo, —CN, —NO2, —SO2-C1-C8 alkyl, —SO2N(R1)R2, and —CON(R1)R2, wherein R1 and R2 are independently selected from C1-C8 alkyl, C3-C8 cycloalkyl, aryl and hydrogen. A process for preparing the polymeric composition, processes for preparing the dye composition and articles formed from the polymeric composition are also disclosed.

    摘要翻译： 本发明涉及适用于薄膜，模制品和纤维的聚合物组合物，包括微旦尼尔纤维。 聚合物组合物包含聚合物组合物的约50重量％至约99.9重量％的量的热塑性树脂，和聚合物组合物的约0.1重量％至约50重量％的量的染料组合物。 染料组合物含有阴丹酮化合物作为主要成分。 如本文所用，阴丹酮化合物定义为具有由式I表示的通式结构的化合物：其中R是氢或至少一个独立地选自C 1 -C 8烷基，C 1 -C 8烷氧基，卤素，羟基，三氟甲基，芳氧基，芳硫基 ，芳基氨基，C1-C8烷氧基，-CO2H，C1-C8烷酰氧基，芳基偶氮，-CN，-NO2，-SO2-C1-C8烷基，-SO2N（R1）R2和-CON（R1）R2，其中R1和 R 2独立地选自C 1 -C 8烷基，C 3 -C 8环烷基，芳基和氢。 还公开了制备聚合物组合物的方法，制备染料组合物的方法和由聚合物组合物形成的制品。

    Thermoplastic polymer compositions containing black dye compositions
    6.
    发明授权
    Thermoplastic polymer compositions containing black dye compositions 失效
    含有黑色染料组合物的热塑性聚合物组合物

    公开(公告)号：US5973038A

    公开(公告)日：1999-10-26

    申请号：US78227

    申请日：1998-05-13

    申请人： Max Allen Weaver ,  Clarence Alvin Coates, Jr. ,  Jean Carroll Fleischer ,  Brian Edison Maxwell

    发明人： Max Allen Weaver ,  Clarence Alvin Coates, Jr. ,  Jean Carroll Fleischer ,  Brian Edison Maxwell

    IPC分类号： C08K5/00 ,  C09B5/52 ,  C08K5/34 ,  C09F9/00

    CPC分类号： C08K5/0041 ,  C09B5/52

    摘要： The present invention relates to a black polymeric composition suitable for use in films, fibers and molded articles, where a soluble, easily dispersed colorant is desirable. The black polymeric composition provides a high black color quality and is small enough to function as a black colorant in microdenier fibers. The black polymeric composition comprises a thermoplastic resin in an amount between about 50 weight percent and about 99.9 weight percent of the black polymeric composition, and a black dye composition in an amount between about 0.1 weight percent and about 50 weight percent of the black polymeric composition. The black dye composition contains a black indanthrone compound as a major component. As used herein, black indanthrone compounds are defined as compounds having the general structure represented by Formula I: ##STR1## wherein R is hydrogen or at least one group independently selected from C.sub.1 -C.sub.8 alkyl, C.sub.1 -C.sub.8 alkoxy, halogen, hydroxy, trifluoromethyl, aryloxy, arylthio, arylamino, C.sub.1 -C.sub.8 carbalkoxy, --CO.sub.2 H, C.sub.1 -C.sub.8 alkanoyloxy, arylazo, --CN, --NO.sub.2, --SO.sub.2 --C.sub.1 -C.sub.8 alkyl, --SO.sub.2 N(R1)R2, and --CON(R1)R2, wherein R1 and R2 are independently selected from C.sub.1 -C.sub.8 alkyl, C.sub.3 -C.sub.8 cycloalkyl, aryl and hydrogen. The present invention further relates to a process for preparing the black polymeric composition, processes for preparing the black dye composition and articles formed from the black polymeric composition.

    摘要翻译： 本发明涉及适用于薄膜，纤维和模塑制品的黑色聚合物组合物，其中可溶性易分散的着色剂是期望的。 黑色聚合物组合物提供高的黑色品质，并且足够小以用作微旦尼尔纤维中的黑色着色剂。 黑色聚合物组合物包含的量为黑色聚合物组合物的约50重量％至约99.9重量％的热塑性树脂，黑色聚合物组合物的约0.1重量％至约50重量％的黑色染料组合物 。 黑色染料组合物含有黑色阴丹酮化合物作为主要成分。 如本文所用，黑色阴丹酮化合物定义为具有由式I表示的一般结构的化合物：其中R是氢或至少一个独立地选自C 1 -C 8烷基，C 1 -C 8烷氧基，卤素，羟基，三氟甲基，芳氧基， 芳基硫基，芳基氨基，C1-C8烷氧基，-CO2H，C1-C8烷酰氧基，芳基偶氮，-CN，-NO2，-SO2-C1-C8烷基，-SO2N（R1）R2和-CON（R1）R2，其中R1 并且R 2独立地选自C 1 -C 8烷基，C 3 -C 8环烷基，芳基和氢。 本发明还涉及制备黑色聚合物组合物的方法，制备黑色染料组合物的方法和由黑色聚合物组合物形成的制品。

    Polyester/naphthalenedicarboxylic acid-containing polymer blends displaying reduced fluorescence
    8.
    发明授权
    Polyester/naphthalenedicarboxylic acid-containing polymer blends displaying reduced fluorescence 失效
    聚酯/萘二甲酸的聚合物共混物显示出降低的荧光

    公开(公告)号：US5705600A

    公开(公告)日：1998-01-06

    申请号：US577796

    申请日：1995-12-22

    申请人： Allan Scott Jones ,  Jean Carroll Fleischer ,  Max Allen Weaver

    发明人： Allan Scott Jones ,  Jean Carroll Fleischer ,  Max Allen Weaver

    IPC分类号： C08L67/02 ,  C08L77/12 ,  C08G63/189

    CPC分类号： C08L67/02 ,  C08L77/12

    摘要： The present invention relates to blends of a polyester, polyamide or polyester/amide containing a copolymerizable fluorescence quenching compound and a second polymer. The blends of the present invention display reduced fluorescence. Specifically the blends comprise (a) a polyester/amide comprising: (1) a dicarboxylic acid component which comprises at least 0.1 mol % of a dicarboxylic acid selected from the group consisting of terephthalic acid and/or terephthalate ester; (2) a diol and/or diamine component; (3) 0.1 to 99.9 mol %, based on 100 mol % dicarboxylic acid and 100 mol % diol, of a copolymerizable fluorescence quenching compound; (b) a second polymer selected from the group poly(alkylene terephthalate) homo and copolyesters, poly(alkylene naphthalate) homo and copolyesters, poly(cycloalkylene terephthalate) homo and copolyesters, poly(alkylene 1,4-cyclohexanedicarboxylate) homo and copolyesters, and polycarbonate homo and copolymers.

    摘要翻译： 本发明涉及含可共聚荧光淬灭化合物和第二聚合物的聚酯，聚酰胺或聚酯/酰胺的共混物。 本发明的共混物显示出降低的荧光。 具体地，共混物包含（a）聚酯/酰胺，其包含：（1）二羧酸组分，其包含至少0.1mol％的选自对苯二甲酸和/或对苯二甲酸酯的二羧酸; （2）二醇和/或二胺组分; （3）相对于100摩尔％二羧酸和100摩尔％二醇的可共聚荧光淬灭化合物为0.1〜99.9摩尔％ （b）选自聚（对苯二甲酸亚烷基酯）均聚和共聚酯，聚（萘二甲酸亚烷基酯）均聚和共聚酯，聚（对苯二甲酸亚烷基酯）共聚酯和共聚酯，聚（1,4-环己烷二羧酸亚烷基酯）均聚和共聚酯的第二聚合物， 和聚碳酸酯均聚物和共聚物。

    Ethylenically-unsaturated blue anthraquinone dyes
    10.
    发明授权
    Ethylenically-unsaturated blue anthraquinone dyes 失效
    乙烯不饱和蓝色蒽醌染料

    公开(公告)号：US07172634B2

    公开(公告)日：2007-02-06

    申请号：US10647827

    申请日：2003-08-25

    申请人： Jason Clay Pearson ,  Max Allen Weaver ,  Jean Carroll Fleischer ,  Greg Alan King

    发明人： Jason Clay Pearson ,  Max Allen Weaver ,  Jean Carroll Fleischer ,  Greg Alan King

    IPC分类号： C09B67/00

    CPC分类号： C09D4/00 ,  C09B69/101

    摘要： This invention pertains to certain novel colorant compounds containing one or more ethylenically-unsaturated, photopolymerizable radicals that may be copolymerized (or cured) with ethylenically-unsaturated monomers to produce colored compositions such as colored acrylic polymers. Suitable compositions having the present colorants copolymerized therein include, e.g., polymers produced from acrylate and methacrylate esters, colored polystyrenes, and similar colored polymeric materials derived from other ethylenically-unsaturated monomers. The present invention also pertains to processes for preparing the photopolymerizable colorant compounds. The ethylenically unsaturated colorant compounds may be suitable for use in coatings that are applied to wood, glass, metal, thermoplastics and the like.

    摘要翻译： 本发明涉及含有一种或多种烯属不饱和光可聚合基团的某些新型着色剂化合物，其可以与烯属不饱和单体共聚（或固化）以产生着色组合物如着色丙烯酸聚合物。 其中共聚有本发明着色剂的合适的组合物包括例如由丙烯酸酯和甲基丙烯酸酯衍生的聚合物，着色聚苯乙烯以及衍生自其它烯属不饱和单体的类似有色聚合物。 本发明还涉及制备可光聚合着色剂化合物的方法。 烯属不饱和着色剂化合物可适用于施用于木材，玻璃，金属，热塑性塑料等的涂料中。