公开(公告)号：US07141685B2

公开(公告)日：2006-11-28

申请号：US10734630

申请日：2003-12-12

申请人： Michael John Cyr ,  Max Allen Weaver ,  Gerry Foust Rhodes ,  Jason Clay Pearson ,  Phillip Michael Cook ,  Jos Simon De Wit ,  Larry Keith Johnson

发明人： Michael John Cyr ,  Max Allen Weaver ,  Gerry Foust Rhodes ,  Jason Clay Pearson ,  Phillip Michael Cook ,  Jos Simon De Wit ,  Larry Keith Johnson

IPC分类号： C09B1/00 ,  C09B1/16

CPC分类号： C08F290/14 ,  C08F246/00 ,  C08F283/00 ,  C08F283/008 ,  C08F290/06 ,  C08F290/061 ,  C08F290/141 ,  C09B69/101 ,  C09D4/00 ,  C09D4/06

摘要： Disclosed are thermally-stable, anthraquinone colorant compounds (dyes) which contain one or more vinyl groups which render the compounds copolymerizable with reactive vinyl monomers to produce colored, polymeric compositions such as acrylate and methacrylate polymeric materials. The compounds possess good fastness (stability) to ultraviolet (UV) light, good solubility in vinyl monomers, good color strength and excellent thermal stability. Also disclosed are (1) coating composition comprising (i) one or more polymerizable vinyl compounds, (ii) one or more of the dye compounds described above, and (iii) a photoinitiator and (2) polymeric materials, i.e., polymers derived from one or more acrylic acid esters, one or more methacrylic acid esters, one or more other polymerizable vinyl compounds or mixtures of any two or more thereof, having copolymerized therein one or more of the anthraquinone colorant compounds.

公开(公告)号：US06870062B2

公开(公告)日：2005-03-22

申请号：US10719883

申请日：2003-11-21

申请人： Michael John Cyr ,  Max Allen Weaver ,  Gerry Foust Rhodes ,  Jason Clay Pearson ,  Phillip Michael Cook ,  Jos Simon De Wit ,  Larry Keith Johnson

发明人： Michael John Cyr ,  Max Allen Weaver ,  Gerry Foust Rhodes ,  Jason Clay Pearson ,  Phillip Michael Cook ,  Jos Simon De Wit ,  Larry Keith Johnson

IPC分类号： C09B1/28 ,  C07D249/08 ,  C07D249/12 ,  C08F246/00 ,  C08F283/00 ,  C08F290/06 ,  C08F290/14 ,  C09B1/32 ,  C09B1/58 ,  C09B1/62 ,  C09B69/10 ,  C09D4/00 ,  C09D4/06 ,  C09D7/12 ,  C09D201/00 ,  C09B1/00 ,  C09B1/34

CPC分类号： C08F290/14 ,  C08F246/00 ,  C08F283/00 ,  C08F283/008 ,  C08F290/06 ,  C08F290/061 ,  C08F290/141 ,  C09B69/101 ,  C09D4/00 ,  C09D4/06

摘要： Disclosed are thermally-stable, anthraquinone colorant compounds (dyes) which contain one or more vinyl groups which render the compounds copolymerizable with reactive vinyl monomers to produce colored, polymeric compositions such as acrylate and methacrylate polymeric materials. The compounds possess good fastness (stability) to ultraviolet (UV) light, good solubility in vinyl monomers, good color strength and excellent thermal stability. Also disclosed are (1) coating composition comprising (i) one or more polymerizable vinyl compounds, (ii) one or more of the dye compounds described above, and (iii) a photoinitiator and (2) polymeric materials, i.e., polymers derived from one or more acrylic acid esters, one or more methacrylic acid esters, one or more other polymerizable vinyl compounds or mixtures of any two or more thereof, having copolymerized therein one or more of the anthraquinone colorant compounds.

公开(公告)号：US06197851B1

公开(公告)日：2001-03-06

申请号：US08918086

申请日：1997-08-25

申请人： Brian Edison Maxwell ,  Max Allen Weaver ,  James John Krutak, Sr. ,  William Whitfield Parham ,  Gerry Foust Rhodes ,  Jean Carroll Fleischer

发明人： Brian Edison Maxwell ,  Max Allen Weaver ,  James John Krutak, Sr. ,  William Whitfield Parham ,  Gerry Foust Rhodes ,  Jean Carroll Fleischer

IPC分类号： C08K534

CPC分类号： C08K5/0041 ,  B29C35/02 ,  B29C49/00 ,  B29K2067/00 ,  B29K2105/253 ,  C08L67/02

摘要： The present invention relates to a container preform comprising: a polymer suitable for the production of a stretch blow molded bottle and at least one organic or metallated organic near infrared absorbing compound which absorbs at least twice as much light between about 700 nm and about 1200 nm as between about 400 mn and about 700 nm wherein said near infrared absorbing compound is present in an amount sufficient to improve reheat rate of said preform. Suitable near infrared absorbing compounds include phthalocyanines, 2,3-napthalocyanines, squaraines (squaric acid derivatives), croconic acid derivatives, substituted indanthrones and certain highly substituted anthraquinones. A process for improving the reheat rate of a container preform is also disclosed.

摘要翻译： 本发明涉及一种容器预制件，其包括：适于制造拉伸吹塑成型瓶子的聚合物和至少吸收约700nm至约1200nm光的至少两倍的有机或金属化有机近红外吸收化合物的聚合物 约400nm至约700nm，其中所述近红外吸收化合物的存在量足以提高所述预型件的再加热速率。 合适的近红外吸收化合物包括酞菁，2,3-萘酞菁，方酸（方酸衍生物），克罗酸衍生物，取代的茚满酮和某些高度取代的蒽醌。 还公开了一种用于改善容器预制件的再加热速率的方法。

公开(公告)号：US07138539B2

公开(公告)日：2006-11-21

申请号：US11249793

申请日：2005-10-13

申请人： Michael John Cyr ,  Max Allen Weaver ,  Gerry Foust Rhodes ,  Jason Clay Pearson ,  Phillip Michael Cook

发明人： Michael John Cyr ,  Max Allen Weaver ,  Gerry Foust Rhodes ,  Jason Clay Pearson ,  Phillip Michael Cook

IPC分类号： C07C229/48 ,  C07D207/40

CPC分类号： C09B69/109 ,  C08F246/00 ,  C08F290/06 ,  C08F290/14 ,  C09B69/101 ,  C09B69/105 ,  C09B69/106

摘要： Disclosed are novel colorant compounds which contain one or more ethylenically-unsaturated (vinyl), photopolymerizable radicals which may be copolymewrized (or cured) with ethylenically-unsaturated monomers to produce colored compositions such as colored acrylic coatings and polymers, e.g., coatings and polymers produced from acrylate and methacrylate esters, colored polystyrenes, and similar colored polymeric materials derived from other ethylenically-unsaturated monomers. The present invention also pertains to processes for the preparation of certain of the photopolymerizable colorant compounds.

公开(公告)号：US06689828B2

公开(公告)日：2004-02-10

申请号：US09911789

申请日：2001-07-24

申请人： Michael John Cyr ,  Max Allen Weaver ,  Gerry Foust Rhodes ,  Jason Clay Pearson ,  Phillip Michael Cook ,  Jos Simon De Wit ,  Larry Keith Johnson

发明人： Michael John Cyr ,  Max Allen Weaver ,  Gerry Foust Rhodes ,  Jason Clay Pearson ,  Phillip Michael Cook ,  Jos Simon De Wit ,  Larry Keith Johnson

IPC分类号： C09B100

CPC分类号： C08F290/06 ,  C08F246/00 ,  C08F283/00 ,  C08F283/008 ,  C08F290/061 ,  C08F290/14 ,  C08F290/141 ,  C09B69/101 ,  C09D4/00 ,  C09D4/06

摘要： Disclosed are thermally-stable, anthraquinone colorant compounds (dyes) which contain one or more vinyl groups which render the compounds copolymerizable with reactive vinyl monomers to produce colored, polymeric compositions such as acrylate and methacrylate polymeric materials. The compounds possess good fastness (stability) to ultraviolet (UV) light, good solubility in vinyl monomers, good color strength and excellent thermal stability. Also disclosed are (1) coating composition comprising (i) one or more polymerizable vinyl compounds, (ii) one or more of the dye compounds described above, and (iii) a photoinitiator and (2) polymeric materials, i.e., polymers derived from one or more acrylic acid esters, one or more methacrylic acid esters, one or more other polymerizable vinyl compounds or mixtures of any two or more thereof, having copolymerized therein one or more of the anthraquinone colorant compounds.

摘要翻译： 公开了热稳定的蒽醌着色剂化合物（染料），其含有一个或多个乙烯基，使得化合物与反应性乙烯基单体共聚以产生着色的聚合物组合物，例如丙烯酸酯和甲基丙烯酸酯聚合物材料。 该化合物对紫外线（UV）光具有良好的牢度（稳定性），在乙烯基单体中的良好溶解性，良好的着色强度和优异的热稳定性。 还公开了（1）涂料组合物，其包含（i）一种或多种可聚合乙烯基化合物，（ii）一种或多种上述染料化合物，和（iii）光引发剂和（2）聚合物材料，即衍生自 一种或多种丙烯酸酯，一种或多种甲基丙烯酸酯，一种或多种其它可聚合乙烯基化合物或其任何两种或多种的混合物，其中共聚有一种或多种蒽醌着色剂化合物。

公开(公告)号：US06620858B2

公开(公告)日：2003-09-16

申请号：US09920151

申请日：2001-08-01

申请人： Michael John Cyr ,  Max Allen Weaver ,  Gerry Foust Rhodes ,  Jason Clay Pearson ,  Phillip Michael Cook ,  Jos Simon De Wit ,  Larry Keith Johnson

发明人： Michael John Cyr ,  Max Allen Weaver ,  Gerry Foust Rhodes ,  Jason Clay Pearson ,  Phillip Michael Cook ,  Jos Simon De Wit ,  Larry Keith Johnson

IPC分类号： C08F246

CPC分类号： C09D4/00 ,  C08F20/38 ,  C08F22/24 ,  C08F290/06 ,  C08F290/14 ,  C09B69/10 ,  C08F222/24 ,  C08F220/38

摘要： Disclosed are thermally-stable, colored, photopolymerizable compounds containing a vinyl group which are capable of being copolymerized with reactive vinyl monomers to produce colored compositions such as polyacrylates, polymethacrylates, polystyrene, etc. The compounds exhibit good thermal stability, fastness (stability) to UV-light, good solubility in the reactive monomers and good color strength.

公开(公告)号：US07030244B2

公开(公告)日：2006-04-18

申请号：US10654103

申请日：2003-09-03

申请人： Michael John Cyr ,  Max Allen Weaver ,  Gerry Foust Rhodes ,  Jason Clay Pearson ,  Phillip Michael Cook

发明人： Michael John Cyr ,  Max Allen Weaver ,  Gerry Foust Rhodes ,  Jason Clay Pearson ,  Phillip Michael Cook

IPC分类号： C07D221/18 ,  C07D221/04

CPC分类号： C09B69/109 ,  C08F246/00 ,  C08F290/06 ,  C08F290/14 ,  C09B69/101 ,  C09B69/105 ,  C09B69/106

摘要： Disclosed are novel colorant compounds which contain one or more ethylenically-unsaturated (vinyl), photopolymerizable radicals which may be copolymewrized (or cured) with ethylenically-unsaturated monomers to produce colored compositions such as colored acrylic coatings and polymers, e.g., coatings and polymers produced from acrylate and methacrylate esters, colored polystyrenes, and similar colored polymeric materials derived from other ethylenically-unsaturated monomers. The present invention also pertains to processes for the preparation of certain of the photopolymerizable colorant compounds.

公开(公告)号：US06713641B2

公开(公告)日：2004-03-30

申请号：US10046679

申请日：2001-10-19

申请人： Max Allen Weaver ,  Gerry Foust Rhodes ,  Jason Clay Pearson ,  Sara Stanley Wells ,  Michael John Cyr

发明人： Max Allen Weaver ,  Gerry Foust Rhodes ,  Jason Clay Pearson ,  Sara Stanley Wells ,  Michael John Cyr

IPC分类号： C09B62004

CPC分类号： C08K5/0041 ,  C07C225/34 ,  C07C271/12 ,  C08G18/38 ,  C08G18/3819 ,  C08G18/8108 ,  C08G63/6856 ,  C09B1/325 ,  C09B62/80 ,  C09B69/101 ,  C09D167/07 ,  G03C1/7954 ,  G03C1/83 ,  G03C5/16 ,  G03C2005/168 ,  G03C2200/22

摘要： Disclosed are blue, diol anthraquinone blue colorant compounds having excellent thermal stability and which can be reacted into or copolymerized with polyester thus providing a blue-colored polyesters useful for manufacturing a variety of shaped articles such as photographic film base, particularly roentgenographic (X-ray) film. Also disclosed are blue anthraquinone colorant compounds which contain two ethylenically-unsaturated (vinyl), photopolymerizable radicals which may be derived from the aforesaid diol anthraquinone compounds. The anthraquinone colorant compounds containing two ethylenically-unsaturated may be reacted into or copolymerized (or cured) with ethylenically-unsaturated monomers to produce colored vinyl polymers.

摘要翻译： 公开了具有优异的热稳定性并且可以与聚酯反应或与聚酯共聚的蓝色二醇蒽醌蓝色着色剂化合物，从而提供可用于制造各种成型制品如摄影底片，特别是摄影胶片（X射线）的蓝色聚酯 ）电影。 还公开了蓝色蒽醌着色剂化合物，其包含可以衍生自上述二醇蒽醌化合物的两个烯键式不饱和（乙烯基）可光聚合基团。 含有两个烯键式不饱和基团的蒽醌着色剂化合物可以与烯属不饱和单体反应或共聚（或固化）以产生着色的乙烯基聚合物。

公开(公告)号：US06630521B2

公开(公告)日：2003-10-07

申请号：US10054285

申请日：2001-11-13

申请人： Michael John Cyr ,  Max Allen Weaver ,  Gerry Foust Rhodes ,  Jason Clay Pearson ,  Jean Carroll Fleischer

发明人： Michael John Cyr ,  Max Allen Weaver ,  Gerry Foust Rhodes ,  Jason Clay Pearson ,  Jean Carroll Fleischer

IPC分类号： C07C22534

CPC分类号： C09B69/101 ,  C08F246/00

摘要： Disclosed are thermally-stable, red, anthraquinone colorants which contain one or more ethylenically-unsaturated, photopolymerizable radicals and which may be copolymerized with ethylenically-unsaturated monomers to produce colored compositions such as colored acrylic polymers, colored polystyrenes, and similar colored polymeric materials derived from other ethylenically-unsaturated monomers. The compounds possess good stability to ultraviolet light, good solubility in vinyl monomers, good color strength and thermal stability. Also disclosed are acrylic polymeric materials, i.e., polymers derived from acrylic acid esters, methacrylic acid esters and/or other copolymerizable vinyl compounds, having copolymerized therein one or more of the colorant compounds of the present invention.

摘要翻译： 公开了含有一个或多个烯键式不饱和的光聚合基团的热稳定的红色蒽醌着色剂，其可以与烯键式不饱和单体共聚以产生着色的组合物，例如着色的丙烯酸聚合物，着色的聚苯乙烯和类似的着色的聚合物材料 来自其它烯属不饱和单体。 该化合物对紫外线具有良好的稳定性，在乙烯基单体中的良好溶解性，良好的着色强度和热稳定性。 还公开了丙烯酸聚合物材料，即衍生自丙烯酸酯，甲基丙烯酸酯和/或其它可共聚的乙烯基化合物的聚合物，其中共聚有一种或多种本发明的着色剂化合物。

公开(公告)号：US06197223B1

公开(公告)日：2001-03-06

申请号：US09320002

申请日：1999-05-26

申请人： Max Allen Weaver ,  James John Krutak, Sr. ,  Brian Edison Maxwell ,  Gerry Foust Rhodes ,  Samuel David Hilbert ,  Jean Carroll Fleischer ,  William Whitfield Parham

发明人： Max Allen Weaver ,  James John Krutak, Sr. ,  Brian Edison Maxwell ,  Gerry Foust Rhodes ,  Samuel David Hilbert ,  Jean Carroll Fleischer ,  William Whitfield Parham

IPC分类号： F21V900

CPC分类号： C09B31/02 ,  C09B1/32 ,  C09B1/585 ,  C09B1/62 ,  C09B5/14 ,  C09B29/0007 ,  C09B29/0025 ,  C09B29/08 ,  C09B29/36 ,  C09B69/101 ,  C09B69/106 ,  C09B69/109

摘要： The present invention recites a method comprising reacting in a solvent in the presence of a base a) at least one diacidic monomer comprising about 1 to 100 mole % of at least one light-absorbing monomer having a light absorption maximum between about 300 nm and about 1200 nm and 99-0 mole % of a non-light absorbing monomer which does not absorb significant light at wavelengths above 300 nm or has a light absorption maximum below 300 nm, with b) an organic compound of Formula II X—B—X1 wherein B is a divalent organic radical to form a light absorbing composition comprising a mixture of a polymer having the formula and a cyclic compound having the general formula wherein B is as defined above; n is at least 2, m is 1, 2, 3 or 4 and A comprises the residue of a diacidic monomer comprising about 1 to 100 mole % of at least one light-absorbing monomer having a light absorption maximum between about 300 nm and about 1000 nm and wherein the remaining portion of A comprises the residue of a non-light absorbing monomer which does not absorb significant light at wavelengths above 300 nm or has a light absorption maximum below 300 nm.

摘要翻译： 本发明描述了一种方法，包括在碱的存在下在溶剂中反应至少一种二酸单体，其包含约1至100摩尔％的至少一种光吸收单体，其光吸收最大值在约300nm至约1200 nm和99-0摩尔％的非光吸收单体，其不吸收波长高于300nm的显着光或具有300nm以下的光吸收最大值，b）式II的有机化合物，其中B是二价有机基团， 形成包含具有下式的聚合物和具有通式化合物B的环状化合物的混合物的光吸收组合物如上所定义; n至少为2，m为1,2,3或4，A包含二酸单体的残基，该二酸单体包含约1至100摩尔％的至少一种光吸收单体的光吸收最大值在约300nm至约 1000nm，并且其中A的剩余部分包含不吸收波长高于300nm或在300nm以下的光吸收最大值的不吸收光的非光吸收单体的残基。