公开(公告)号：US07686855B2

公开(公告)日：2010-03-30

申请号：US11220140

申请日：2005-09-06

申请人： Ronald Sills ,  Theo H. Fleisch ,  Taras Y. Makogon ,  Michael D. Briscoe

发明人： Ronald Sills ,  Theo H. Fleisch ,  Taras Y. Makogon ,  Michael D. Briscoe

IPC分类号： C10L1/185 ,  F17C11/00

CPC分类号： F17D1/005 ,  C10L3/00 ,  F17D1/16

摘要： Disclosed are methods for transporting one or more synthetic products produced from a carbonaceous source, such as coal, natural gas, or biomass, which may be located in a location that is remote from markets for such products. The synthetic products may include lower molecular weight alcohols such as methanol, lower molecular weight ethers such as dimethyl ether, olefins and/or the products of a Fischer-Tropsch or other hydrocarbon synthesis. The methods include transport of such synthetic products via a pipeline in the dense phase state, either neat or blended with light hydrocarbons, such as natural gas.

摘要翻译： 公开了用于运输一种或多种由碳质源（例如煤，天然气或生物质）生产的合成产品的方法，其可以位于远离这种产品的市场的位置。 合成产物可以包括较低分子量的醇如甲醇，低分子量醚如二甲醚，烯烃和/或费 - 托或其他烃合成产物。 这些方法包括通过密相状态的管线输送这些合成产物，纯的或与轻烃例如天然气混合。

公开(公告)号：US07084180B2

公开(公告)日：2006-08-01

申请号：US10766297

申请日：2004-01-28

申请人： Yong Wang ,  Anna Lee Tonkovich ,  Terry Mazanec ,  Francis P. Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Shari Li ,  Michael D. Briscoe ,  Nathan Gano ,  Ya-Huei Chin

发明人： Yong Wang ,  Anna Lee Tonkovich ,  Terry Mazanec ,  Francis P. Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Shari Li ,  Michael D. Briscoe ,  Nathan Gano ,  Ya-Huei Chin

IPC分类号： C07C27/00

CPC分类号： C10G2/332 ,  B01J19/0093 ,  B01J21/04 ,  B01J23/75 ,  B01J23/8896 ,  B01J23/8913 ,  B01J35/0066 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0205 ,  B01J2219/00783 ,  B01J2219/00822 ,  B01J2219/00824 ,  B01J2219/00826 ,  B01J2219/00831 ,  B01J2219/00835 ,  B01J2219/00844 ,  B01J2219/0086 ,  B01J2219/00873 ,  C10G2/341 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2300/4025 ,  C10G2300/70 ,  C10G2400/04 ,  C10G2400/10 ,  Y02P20/582

摘要： The disclosed invention relates to a process for converting a reactant composition comprising H2 and CO to a product comprising at least one aliphatic hydrocarbon having at least about 5 carbon atoms, the process comprising: flowing the reactant composition through a microchannel reactor in contact with a Fischer-Tropsch catalyst to convert the reactant composition to the product, the microchannel reactor comprising a plurality of process microchannels containing the catalyst; transferring heat from the process microchannels to a heat exchanger; and removing the product from the microchannel reactor; the process producing at least about 0.5 gram of aliphatic hydrocarbon having at least about 5 carbon atoms per gram of catalyst per hour; the selectivity to methane in the product being less than about 25%. The disclosed invention also relates to a supported catalyst comprising Co, and a microchannel reactor comprising at least one process microchannel and at least one adjacent heat exchange zone.

摘要翻译： 所公开的发明涉及将包含H 2 CO和CO的反应物组合物转化为包含至少一种具有至少约5个碳原子的脂族烃的产物的方法，该方法包括：使反应物组合物通过 与费 - 托催化剂接触以将反应物组合物转化成产物的微通道反应器，该微通道反应器包含多个含有该催化剂的工艺微通道; 将热量从工艺微通道传递到热交换器; 并从微通道反应器中除去产物; 该方法每小时产生至少约0.5克具有至少约5个碳原子的每克催化剂的脂族烃; 产品中甲烷的选择性小于约25％。 所公开的发明还涉及包含Co的载体催化剂和包含至少一个工艺微通道和至少一个相邻的热交换区的微通道反应器。

公开(公告)号：US06749829B2

公开(公告)日：2004-06-15

申请号：US10201339

申请日：2002-07-23

申请人： Michael D. Briscoe

发明人： Michael D. Briscoe

IPC分类号： C01B300

CPC分类号： C01B5/00 ,  C01B3/323 ,  C01B3/38 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/062 ,  C01B2203/1264 ,  C01B2203/142

摘要： The present invention is directed to a process for producing synthesis gas comprising the steps of reacting a hydrogen-containing stream with an oxygen-containing stream and producing an oxidized stream comprising water; contacting a feedstream comprising hydrocarbon or hydrocarbon comprising at least one atom of oxygen with the oxidized stream comprising water and forming a reforming feedstream; and passing the reforming feedstream into a reforming reaction zone at reforming reaction conditions and producing a synthesis gas product.

摘要翻译： 本发明涉及一种生产合成气的方法，包括以下步骤：使含氢物流与含氧物流反应并产生包含水的氧化物流; 将包含烃或包含至少一个氧原子的烃的进料流与包含水的氧化流接触并形成重整进料流; 并在重整反应条件下使重整原料流进入重整反应区，生成合成气产物。

公开(公告)号：US08188153B2

公开(公告)日：2012-05-29

申请号：US12718356

申请日：2010-03-05

申请人： Yong Wang ,  Anna Lee Tonkovich ,  Terry Mazanec ,  Francis P. Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Shari Li ,  Michael D. Briscoe ,  Nathan Gano ,  Ya-Huei Chin

发明人： Yong Wang ,  Anna Lee Tonkovich ,  Terry Mazanec ,  Francis P. Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Shari Li ,  Michael D. Briscoe ,  Nathan Gano ,  Ya-Huei Chin

IPC分类号： C07C27/00 ,  B01J8/00

CPC分类号： C10G2/332 ,  B01J19/0093 ,  B01J21/04 ,  B01J23/75 ,  B01J23/8896 ,  B01J23/8913 ,  B01J35/0066 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0205 ,  B01J2219/00783 ,  B01J2219/00822 ,  B01J2219/00824 ,  B01J2219/00826 ,  B01J2219/00831 ,  B01J2219/00835 ,  B01J2219/00844 ,  B01J2219/0086 ,  B01J2219/00873 ,  C10G2/341 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2300/4025 ,  C10G2300/70 ,  C10G2400/04 ,  C10G2400/10 ,  Y02P20/582

摘要： The disclosed invention relates to a process for converting a reactant composition comprising H2 and CO to a product comprising at least one aliphatic hydrocarbon having at least about 5 carbon atoms, the process comprising: flowing the reactant composition through a microchannel reactor in contact with a Fischer-Tropsch catalyst to convert the reactant composition to the product, the microchannel reactor comprising a plurality of process microchannels containing the catalyst; transferring heat from the process microchannels to a heat exchanger; and removing the product from the microchannel reactor; the process producing at least about 0.5 gram of aliphatic hydrocarbon having at least about 5 carbon atoms per gram of catalyst per hour; the selectivity to methane in the product being less than about 25%. The disclosed invention also relates to a supported catalyst comprising Co, and a microchannel reactor comprising at least one process microchannel and at least one adjacent heat exchange zone.

摘要翻译： 所公开的发明涉及将包含H 2和CO的反应物组合物转化为包含至少一种具有至少约5个碳原子的脂族烃的产物的方法，该方法包括：使反应物组合物流过与Fischer接触的微通道反应器 - 催化剂将反应物组合物转化成产物，微通道反应器包含多个含有催化剂的工艺微通道; 将热量从工艺微通道传递到热交换器; 并从微通道反应器中除去产物; 该方法每小时产生至少约0.5克具有至少约5个碳原子的每克催化剂的脂族烃; 产品中甲烷的选择性小于约25％。 所公开的发明还涉及包含Co的载体催化剂和包含至少一个工艺微通道和至少一个相邻的热交换区的微通道反应器。

公开(公告)号：US20100160463A1

公开(公告)日：2010-06-24

申请号：US12718356

申请日：2010-03-05

申请人： Yong Wang ,  Anna Lee Tonkovich ,  Terry Mazanec ,  Francis P. Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Shari Li ,  Michael D. Briscoe ,  Nathan Gano ,  Ya-Huei Chin

发明人： Yong Wang ,  Anna Lee Tonkovich ,  Terry Mazanec ,  Francis P. Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Shari Li ,  Michael D. Briscoe ,  Nathan Gano ,  Ya-Huei Chin

IPC分类号： C07C1/04 ,  B01J8/02

CPC分类号： C10G2/332 ,  B01J19/0093 ,  B01J21/04 ,  B01J23/75 ,  B01J23/8896 ,  B01J23/8913 ,  B01J35/0066 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0205 ,  B01J2219/00783 ,  B01J2219/00822 ,  B01J2219/00824 ,  B01J2219/00826 ,  B01J2219/00831 ,  B01J2219/00835 ,  B01J2219/00844 ,  B01J2219/0086 ,  B01J2219/00873 ,  C10G2/341 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2300/4025 ,  C10G2300/70 ,  C10G2400/04 ,  C10G2400/10 ,  Y02P20/582

摘要： The disclosed invention relates to a process for converting a reactant composition comprising H2 and CO to a product comprising at least one aliphatic hydrocarbon having at least about 5 carbon atoms, the process comprising: flowing the reactant composition through a microchannel reactor in contact with a Fischer-Tropsch catalyst to convert the reactant composition to the product, the microchannel reactor comprising a plurality of process microchannels containing the catalyst; transferring heat from the process microchannels to a heat exchanger; and removing the product from the microchannel reactor; the process producing at least about 0.5 gram of aliphatic hydrocarbon having at least about 5 carbon atoms per gram of catalyst per hour; the selectivity to methane in the product being less than about 25%. The disclosed invention also relates to a supported catalyst comprising Co, and a microchannel reactor comprising at least one process microchannel and at least one adjacent heat exchange zone.

摘要翻译： 所公开的发明涉及将包含H 2和CO的反应物组合物转化为包含至少一种具有至少约5个碳原子的脂族烃的产物的方法，该方法包括：使反应物组合物流过与Fischer接触的微通道反应器 - 催化剂将反应物组合物转化成产物，微通道反应器包含多个含有催化剂的工艺微通道; 将热量从工艺微通道传递到热交换器; 并从微通道反应器中除去产物; 该方法每小时产生至少约0.5克具有至少约5个碳原子的每克催化剂的脂族烃; 产品中甲烷的选择性小于约25％。 所公开的发明还涉及包含Co的载体催化剂和包含至少一个工艺微通道和至少一个相邻的热交换区的微通道反应器。

公开(公告)号：US09023900B2

公开(公告)日：2015-05-05

申请号：US13397942

申请日：2012-02-16

申请人： Yong Wang ,  Anna Lee Tonkovich ,  Terry Mazanec ,  Francis P. Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Li ,  Michael D. Briscoe ,  Nathan Gano ,  Ya-Huei Chin

发明人： Yong Wang ,  Anna Lee Tonkovich ,  Terry Mazanec ,  Francis P. Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Li ,  Michael D. Briscoe ,  Nathan Gano ,  Ya-Huei Chin

IPC分类号： C10G2/00 ,  C07C1/04 ,  B01J19/00 ,  B01J37/03 ,  B01J38/48 ,  B01J23/94 ,  B01J37/02 ,  B01J23/755 ,  B01J23/83 ,  B01J23/889 ,  B01J23/89 ,  B01J35/00 ,  B01J35/04 ,  B01J35/10 ,  C10G45/58 ,  C10G47/00 ,  B01J23/75 ,  B01J21/04 ,  B01J38/58

CPC分类号： C10G2/332 ,  B01J19/0093 ,  B01J23/75 ,  B01J23/755 ,  B01J23/83 ,  B01J23/8896 ,  B01J23/8913 ,  B01J23/892 ,  B01J23/894 ,  B01J23/8986 ,  B01J23/94 ,  B01J35/0066 ,  B01J35/04 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/0201 ,  B01J37/0205 ,  B01J37/038 ,  B01J38/48 ,  B01J38/58 ,  B01J2219/00783 ,  B01J2219/00822 ,  B01J2219/00824 ,  B01J2219/00831 ,  B01J2219/00835 ,  B01J2219/00855 ,  B01J2219/0086 ,  B01J2219/00873 ,  C10G2/331 ,  C10G2/334 ,  C10G2/34 ,  C10G2/341 ,  C10G21/00 ,  C10G45/58 ,  C10G47/00 ,  C10G2300/1022 ,  C10G2400/04 ,  C10G2400/10 ,  C10L1/08 ,  C10L2200/0492 ,  C10L2270/026 ,  C10L2290/42 ,  C10L2290/544 ,  C10M105/04 ,  Y02P20/582

摘要： Disclosed is a process for converting a reactant composition comprising H2 and CO to a product comprising at least one aliphatic hydrocarbon having at least about 5 carbon atoms, the process comprising: flowing the reactant composition through a microchannel reactor in contact with a Fischer-Tropsch catalyst to convert the reactant composition to the product, the microchannel reactor comprising a plurality of process microchannels containing the catalyst; transferring heat from the process microchannels to a heat exchanger; and removing the product from the microchannel reactor; the process producing at least about 0.5 gram of aliphatic hydrocarbon having at least about 5 carbon atoms per gram of catalyst per hour; the selectivity to methane in the product being less than about 25%. Also disclosed is a supported catalyst comprising Co, and a microchannel reactor comprising at least one process microchannel and at least one adjacent heat exchange zone.

摘要翻译： 公开了一种将包含H 2和CO的反应物组合物转化为包含至少一种具有至少约5个碳原子的脂族烃的产物的方法，该方法包括：使反应物组合物流过与费 - 托催化剂接触的微通道反应器 将反应物组合物转化成产物，微通道反应器包含多个含有催化剂的工艺微通道; 将热量从工艺微通道传递到热交换器; 并从微通道反应器中除去产物; 该方法每小时产生至少约0.5克具有至少约5个碳原子的每克催化剂的脂族烃; 产品中甲烷的选择性小于约25％。 还公开了包含Co的载体催化剂和包含至少一个工艺微通道和至少一个相邻的热交换区的微通道反应器。

公开(公告)号：US20130217793A1

公开(公告)日：2013-08-22

申请号：US13397942

申请日：2012-02-16

申请人： Yong Wang ,  Anna Lee Tonkovich ,  Terry Mazanec ,  Francis P. Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Li ,  Michael D. Briscoe ,  Nathan Gano ,  Ya-Huei Chin

发明人： Yong Wang ,  Anna Lee Tonkovich ,  Terry Mazanec ,  Francis P. Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Li ,  Michael D. Briscoe ,  Nathan Gano ,  Ya-Huei Chin

IPC分类号： C07C1/04 ,  B01J23/75 ,  B01J21/04

CPC分类号： C10G2/332 ,  B01J19/0093 ,  B01J23/75 ,  B01J23/755 ,  B01J23/83 ,  B01J23/8896 ,  B01J23/8913 ,  B01J23/892 ,  B01J23/894 ,  B01J23/8986 ,  B01J23/94 ,  B01J35/0066 ,  B01J35/04 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/0201 ,  B01J37/0205 ,  B01J37/038 ,  B01J38/48 ,  B01J38/58 ,  B01J2219/00783 ,  B01J2219/00822 ,  B01J2219/00824 ,  B01J2219/00831 ,  B01J2219/00835 ,  B01J2219/00855 ,  B01J2219/0086 ,  B01J2219/00873 ,  C10G2/331 ,  C10G2/334 ,  C10G2/34 ,  C10G2/341 ,  C10G21/00 ,  C10G45/58 ,  C10G47/00 ,  C10G2300/1022 ,  C10G2400/04 ,  C10G2400/10 ,  C10L1/08 ,  C10L2200/0492 ,  C10L2270/026 ,  C10L2290/42 ,  C10L2290/544 ,  C10M105/04 ,  Y02P20/582

摘要： The disclosed invention relates to a process for converting a reactant composition comprising H2 and CO to a product comprising at least one aliphatic hydrocarbon having at least about 5 carbon atoms, the process comprising: flowing the reactant composition through a microchannel reactor in contact with a Fischer-Tropsch catalyst to convert the reactant composition to the product, the microchannel reactor comprising a plurality of process microchannels containing the catalyst; transferring heat from the process microchannels to a heat exchanger; and removing the product from the microchannel reactor; the process producing at least about 0.5 gram of aliphatic hydrocarbon having at least about 5 carbon atoms per gram of catalyst per hour; the selectivity to methane in the product being less than about 25%. The disclosed invention also relates to a supported catalyst comprising Co, and a microchannel reactor comprising at least one process microchannel and at least one adjacent heat exchange zone.

公开(公告)号：US06239184B1

公开(公告)日：2001-05-29

申请号：US09401420

申请日：1999-09-22

申请人： Gary L. Beer ,  James F. Leahy ,  Greg A. Lisewsky ,  Kernan J. McHugh ,  Michael D. Briscoe

发明人： Gary L. Beer ,  James F. Leahy ,  Greg A. Lisewsky ,  Kernan J. McHugh ,  Michael D. Briscoe

IPC分类号： C07C2700

CPC分类号： C07C1/066 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2523/10 ,  C07C2523/12 ,  C07C2523/36 ,  C07C2523/46 ,  C07C2523/75

摘要： A process for extending the life of a Fisher-Tropsch catalyst in a process for converting synthesis gas produced in an autothermal reactor by the substoichiometric oxidation of a light hydrocarbon gas by removing ammonia from the synthesis gas prior to passing the synthesis gas to a Fischer-Tropsch reactor.

摘要翻译： 一种在将合成气通过合成气之前通过从合成气中除去氨而在轻质烃气体的亚化学计量氧化转化合成气的方法中延长费 - 托催化剂寿命的方法， 托反应堆。

公开(公告)号：US07722833B2

公开(公告)日：2010-05-25

申请号：US11484069

申请日：2006-07-11

申请人： Yong Wang ,  Anna Lee Tonkovich ,  Terry Mazanec ,  Francis P. Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Shari Li ,  Michael D. Briscoe ,  Nathan Gano ,  Ya-Huei Chin

发明人： Yong Wang ,  Anna Lee Tonkovich ,  Terry Mazanec ,  Francis P. Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Shari Li ,  Michael D. Briscoe ,  Nathan Gano ,  Ya-Huei Chin

IPC分类号： B01J19/00

CPC分类号： C10G2/332 ,  B01J19/0093 ,  B01J21/04 ,  B01J23/75 ,  B01J23/8896 ,  B01J23/8913 ,  B01J35/0066 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0205 ,  B01J2219/00783 ,  B01J2219/00822 ,  B01J2219/00824 ,  B01J2219/00826 ,  B01J2219/00831 ,  B01J2219/00835 ,  B01J2219/00844 ,  B01J2219/0086 ,  B01J2219/00873 ,  C10G2/341 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2300/4025 ,  C10G2300/70 ,  C10G2400/04 ,  C10G2400/10 ,  Y02P20/582

摘要： A microchannel reactor is described which has at least one process microchannel and at least one heat exchange zone. The microchannel reactor may be used for conducting a Fischer-Tropsch synthesis reaction.

摘要翻译： 描述了具有至少一个工艺微通道和至少一个热交换区的微通道反应器。 微通道反应器可用于进行费 - 托合成反应。

公开(公告)号：US07168265B2

公开(公告)日：2007-01-30

申请号：US10805982

申请日：2004-03-22

申请人： Michael D. Briscoe ,  Theo H. Fleisch ,  Michael J. Gradassi ,  Jeffrey H. Sawchuk ,  Pedro Ernesto Fischer-Calderon

发明人： Michael D. Briscoe ,  Theo H. Fleisch ,  Michael J. Gradassi ,  Jeffrey H. Sawchuk ,  Pedro Ernesto Fischer-Calderon

IPC分类号： F25J1/00 ,  C07C27/00 ,  C07C27/06

CPC分类号： F25J3/0233 ,  C01B3/384 ,  C01B3/48 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/0283 ,  C01B2203/0475 ,  C01B2203/061 ,  C01B2203/062 ,  C01B2203/065 ,  C01B2203/0883 ,  C01B2203/0894 ,  C01B2203/1058 ,  C01B2203/142 ,  C01B2203/148 ,  C07C29/1518 ,  F25J1/0022 ,  F25J1/0035 ,  F25J1/004 ,  F25J1/0042 ,  F25J1/0205 ,  F25J1/021 ,  F25J1/0229 ,  F25J3/0209 ,  F25J3/0257 ,  F25J3/029 ,  F25J3/061 ,  F25J3/0635 ,  F25J3/066 ,  F25J3/069 ,  F25J3/0695 ,  F25J2200/02 ,  F25J2200/04 ,  F25J2200/08 ,  F25J2205/02 ,  F25J2205/04 ,  F25J2215/04 ,  F25J2220/62 ,  F25J2220/66 ,  F25J2230/60 ,  F25J2240/02 ,  F25J2240/30 ,  F25J2240/40 ,  F25J2245/02 ,  F25J2260/60 ,  F25J2260/80 ,  F25J2270/60 ,  F25J2280/02 ,  Y02P20/125 ,  C07C31/04

摘要： An integrated process for producing LNG and GTL products is provided, wherein a CO2-containing natural gas feed to an LNG production zone is first pre-treated to separate at least a portion of the CO2 therefrom, and the resulting CO2 stream obtained thereby is then directed to a GTL production zone and utilized to make GTL products that include methanol and/or methanol derivatives.

摘要翻译： 提供了一种用于生产LNG和GTL产品的综合方法，其中首先对LNG生产区域的含CO 2的天然气进料进行预处理，以将至少一部分CO 2，然后将由此获得的所得CO 2流导向GTL生产区，并用于制备包括甲醇和/或甲醇衍生物的GTL产物。