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公开(公告)号：US4654376A
公开(公告)日：1987-03-31
申请号：US791015
申请日：1985-10-24
CPC分类号： C08G18/5033 , C08G18/546 , C08G2101/0025 , C08G2101/005 , C08G2105/02 , Y10S521/902
摘要： An improved method for preparing amino polyols is disclosed. The method is the Mannich condensation of phenol, formaldehyde and diethanolamine in a molar ratio of (1:1:1), and then alkoxylation with a mixture of ethylene oxide and propylene oxide in a weight ratio of about 5:95 to 20:80 to form an amino polyol of hydroxyl number 440 to 515.The method gives higher yields of aromatic amino polyols of lower viscosity than those of the comparative example.
摘要翻译： 公开了改进的制备氨基多元醇的方法。 该方法是苯酚，甲醛和二乙醇胺的摩尔比为（1:1:1）的曼尼希缩合，然后用环氧乙烷和环氧丙烷的混合物以约5:95至20:80的重量比进行烷氧基化 以形成羟基数为440至515的氨基多元醇。该方法提供比比较例的更低的粘度的芳族氨基多元醇的较高产率。
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2.发明授权Urea catalyst for preparation of sucrose polyols useful for rigid polyurethane foams 失效用于制备用于硬质聚氨酯泡沫的蔗糖多元醇的尿素催化剂
公开(公告)号：US4820810A
公开(公告)日：1989-04-11
申请号：US924660
申请日：1986-10-30
CPC分类号： C07H15/08 , C08G18/4804 , C08G18/4883 , C08G18/5021 , C08G65/2606 , C08G65/2672 , C08G2101/0025 , C08G2101/005
摘要： Catalytic quantities of urea are used in the alkoxylation of aqueous sucrose to prepare low color polyols useful in rigid polyurethane foams.
摘要翻译： 在水性蔗糖的烷氧基化中使用催化量的尿素以制备用于硬质聚氨酯泡沫体的低色多元醇。
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公开(公告)号：US4469823A
公开(公告)日：1984-09-04
申请号：US518171
申请日：1983-07-28
CPC分类号： C08G18/4009 , C08G18/4216 , C08G2101/0008 , C08G2101/005 , C08G2101/0083
摘要： A method for producing a flexible polyurethane foam from reacting a polyol blend with a polyisocyanate in the presence of a polyurethane formation catalyst is described. The polyol blend contains from 0.5 to 10 wt. % of an aromatic polyester polyol extender typically used in rigid foams. The polyol extender is made from dibasic acids, alkylene glycols and recycled polyethylene terephthalate. Commercial extenders cause flexible foams to shrink, a problem not found in the foams of this invention.
摘要翻译： 描述了在聚氨酯形成催化剂存在下使多元醇共混物与多异氰酸酯反应制备柔性聚氨酯泡沫的方法。 多元醇共混物含有0.5至10wt。 通常用于硬质泡沫的芳族聚酯多元醇增量剂的％。 多元醇增量剂由二元酸，亚烷基二醇和再生聚对苯二甲酸乙二醇酯制成。 商业增长剂导致柔性泡沫收缩，这在本发明的泡沫中没有发现。
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4.发明授权Preparation of linear polyethylenepolyamines with an aluminum phosphate catalyst 失效用磷酸铝催化剂制备线性聚亚乙基多胺
公开(公告)号：US4448997A
公开(公告)日：1984-05-15
申请号：US453841
申请日：1982-12-27
申请人： Michael E. Brennan
发明人： Michael E. Brennan
IPC分类号： C07C85/06
CPC分类号： C07C209/16
摘要： A method of preparing predominantly linear polyethylenepolyamines from ethylenediamine and monoethanolamine reactants with an aluminum phosphate catalyst prepared from alumina, phosphoric acid, ammonium hydroxide and water is disclosed.
摘要翻译： 公开了一种由乙二胺和单乙醇胺反应物与由氧化铝，磷酸，氢氧化铵和水制备的磷酸铝催化剂制备主要线型聚亚乙基多胺的方法。
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公开(公告)号：US4299956A
公开(公告)日：1981-11-10
申请号：US188164
申请日：1980-09-17
申请人： Michael E. Brennan
发明人： Michael E. Brennan
IPC分类号： C07D295/08 , B01J21/00 , B01J27/00 , C07B61/00 , C07D295/088
CPC分类号： C07D295/088
摘要： Covers a process of making N-(2-methoxyethyl)morpholine by reacting N-(2-hydroxyethyl)morpholine with an excess of methanol in presence of a phosphorus-containing catalyst.
摘要翻译： 在含磷催化剂的存在下，通过使N-（2-羟乙基）吗啉与过量的甲醇反应来制备N-（2-甲氧基乙基）吗啉的方法。
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公开(公告)号：US4117227A
公开(公告)日：1978-09-26
申请号：US583015
申请日：1975-06-02
申请人： Michael E. Brennan
发明人： Michael E. Brennan
IPC分类号： C07D295/088 , C08G18/20 , C07D295/02
CPC分类号： C07D295/088 , C08G18/2018
摘要： An improved process is disclosed for selectively producing an N-(substituted) morpholine compound from the corresponding N-(substituted) diethanolamine compound. The improved process includes contacting the N-(substituted) diethanolamine compound with a catalytically effective amount of a silica-alumina or certain phosphorus-containing substances at temperatures of from about 190.degree. C to about 260.degree. C under a pressure sufficient to maintain the mixture substantially in liquid phase and recovering from the reaction mixture the formed N-(substituted) morpholine.According to a preferred embodiment, triethanolamine is heated in the presence of a catalytically effective amount of a silica-alumina catalyst having an aluminum content of from about 5 to about 50 wt. % at temperatures of from about 240.degree. C to about 260.degree. C in liquid phase to selectively produce the corresponding N-(hydroxyethyl)morpholine (HEM).
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公开(公告)号：US4095022A
公开(公告)日：1978-06-13
申请号：US679590
申请日：1976-04-23
IPC分类号： C07D295/023 , C07D295/088 , C08G18/20 , C07D265/28
CPC分类号： C07D295/023 , C07D295/088 , C08G18/2018 , C08G18/2081
摘要： An improved process is disclosed for selectively producing a bis-(morpholino-N-alkyl) ether directly from the corresponding N-(hydroxyalkyl)morpholine compound. The improved process includes contacting the N-(hydroxyalkyl)morpholine compound with a catalytically effective amount of a silica-alumina or certain phosphorus containing substances at a temperature of about 200.degree. C to 300.degree. C under a pressure sufficient to maintain the mixture substantially in liquid phase and recovering from the resultant reaction mixture the bis-(morpholino-N-alkyl) ether.According to the preferred embodiment, N-(2-hydroxyethyl)morpholine is heated in the presence of a catalytic amount of a silica-alumina catalyst having an alumina content of from about 5 to about 50 wt. % at temperatures of from about 240.degree. C to about 290.degree. C in liquid phase to selectively produce the corresponding N,N',2,2'-dimorpholinodiethyl ether (DMDEE).
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公开(公告)号：US3943162A
公开(公告)日：1976-03-09
申请号：US568794
申请日：1975-04-16
IPC分类号： C07B61/00 , B01J21/00 , B01J21/12 , C07C67/00 , C07C253/00 , C07C255/24 , C07C255/32 , C07C255/66 , C07C121/78
CPC分类号： C07C253/30
摘要： An improved process is disclosed for the production of cyanoethylated aromatic amines comprising contacting an aromatic amine with acrylonitrile in the presence of a silica-alumina catalyst in a liquid phase reaction at elevated temperature. Aromatic polyamines are cyanoethylated according to the process of this invention to form a reaction product comprising poly-(N-monocyanoethylated) aromatic amines and poly-(N-monocyanoethylated) aromatic amines additionally having at least one cyanoethyl group attached to the nucleus of the aromatic ring.
摘要翻译： 公开了用于制备氰乙基化芳族胺的改进方法，包括在二氧化硅 - 氧化铝催化剂存在下，在高温下在液相反应中使芳族胺与丙烯腈接触。 根据本发明的方法，芳族多胺是氰基乙基化的，以形成包含聚（N-单 - 亚乙基化的）芳族胺和聚（N-单 - 亚乙基化）芳族胺的反应产物，另外具有至少一个氰基乙基连接到芳香族核上 环。
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9.发明授权Alkoxylated ethylene glycol diamine bottoms products for rigid urethane foams 失效用于刚性聚氨酯泡沫的烷氧基化乙二醇二胺底产物
公开(公告)号：US4885390A
公开(公告)日：1989-12-05
申请号：US117559
申请日：1987-10-30
IPC分类号： C07C217/50 , C08G18/50 , C07C89/02
CPC分类号： C08G18/5021 , C07C217/50 , C08G2101/0025
摘要： Novel amino polyols made by alkoxylating ethylene glycol diamine bottoms products, such as triethylene glycol diamine bottoms products, and tetraethylene glycol diamine bottoms products are described. For example, these bottoms products, alone or together, maybe propoxylated in a non-catalytic reaction to give amino polyols that are useful in producing rigid polyurethane foams. The resultant foams have better K-factors and a higher percentage of closed cells than comparable foams made with conventional amino polyols.
摘要翻译： 描述了通过乙二醇二胺塔底产物烷氧化制备的新型氨基多元醇，例如三甘醇二胺塔底产物和四甘醇二胺塔底产物。 例如，单独或一起的这些底部产物可在非催化反应中进行丙氧基化，得到可用于生产刚性聚氨酯泡沫的氨基多元醇。 与常规氨基多元醇制成的可比泡沫相比，所得泡沫具有更好的K-因子和更高百分比的闭孔。
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10.发明授权Preparation of linear polyethylenepolyamines with silica-alumina catalysts 失效用二氧化硅 - 氧化铝催化剂制备线性聚亚乙基多胺
公开(公告)号：US4547591A
公开(公告)日：1985-10-15
申请号：US562122
申请日：1983-12-16
IPC分类号： C07B61/00 , B01J21/12 , B01J27/16 , B01J29/00 , C07C67/00 , C07C209/00 , C07C209/16 , C07C211/10 , C07C211/14 , C07C85/06
CPC分类号： C07C209/16
摘要： Disclosed is a process for preparing predominantly linear polyethylenepolyamines from the catalyzed reaction of (1) an ethyleneamine and an alkanolamine, (2) ethyleneamines or (3) an alkanolamine and ammonia. The catalyst employed is a silica-alumina catalyst. An acidic phosphorus cocatalyst may be used in conjunction with the silica-alumina catalyst.
摘要翻译： 公开了从（1）乙烯胺和链烷醇胺，（2）亚乙基胺或（3）链烷醇胺和氨的催化反应中主要制备线性聚亚乙基多胺的方法。 所使用的催化剂是二氧化硅 - 氧化铝催化剂。 酸性磷助催化剂可与二氧化硅 - 氧化铝催化剂结合使用。
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