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1.发明授权Process for restoring permeance of an oxygen-permeable ion transport membrane utilized to recover oxygen from an oxygen-containing gaseous mixture 失效用于恢复用于从含氧气体混合物中回收氧气的透氧离子转运膜的渗透性的方法
公开(公告)号：US5240473A
公开(公告)日：1993-08-31
申请号：US937766
申请日：1992-09-01
CPC分类号： B01D53/22 , B01D53/228 , B01D71/024 , C01B13/0255 , B01D2325/26 , C01B2210/0051 , C01B2210/0062 , C01B2210/007 , Y10S505/701 , Y10S505/778 , Y10S505/785
摘要： This invention relates to a process for restoring permeance of an oxygen-permeable ion transport membrane utilized to recover oxygen from an oxygen-containing gaseous mixture which contains water, carbon dioxide or volatile hydrocarbons. The process utilizes a class of ion transport membranes formed from multicomponent metallic oxides wherein permeance of such membranes had been believed to be permanently degraded by water and the like under conventional process operating temperatures. This invention provides a continuous process for restoring oxygen permeance of such membranes caused by deleterious interaction between the membrane and components such as carbon dioxide, water or hydrocarbons at elevated process temperatures.
摘要翻译： 本发明涉及一种用于恢复用于从含有水，二氧化碳或挥发性烃的含氧气体混合物中回收氧的透氧离子迁移膜的渗透性的方法。 该方法利用由多组分金属氧化物形成的一类离子迁移膜，其中这种膜的渗透被认为在常规工艺操作温度下被水等永久性降解。 本发明提供了一种连续的方法，用于恢复由膜和组分如二氧化碳，水或烃在升高的工艺温度下的有害相互作用而导致的这种膜的氧渗透性。
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2.发明授权Process for recovering oxygen from gaseous mixtures containing water or carbon dioxide which process employs barium-containing ion transport membranes 失效从含有水或二氧化碳的气态混合物中回收氧气的方法，该方法采用含钡离子迁移膜
公开(公告)号：US5269822A
公开(公告)日：1993-12-14
申请号：US937768
申请日：1992-09-01
申请人： Michael F. Carolan , Paul N. Dyer , Stephen M. Fine , James M. LaBar, Sr. , Robert M. Thorogood
发明人： Michael F. Carolan , Paul N. Dyer , Stephen M. Fine , James M. LaBar, Sr. , Robert M. Thorogood
CPC分类号： B01D53/326 , B01D71/024 , C01B13/0255 , B01D2325/26 , C01B2210/0046 , C01B2210/0051 , C01B2210/0062 , Y10S505/701 , Y10S505/778 , Y10S505/785
摘要： The invention is a process for recovering oxygen from an oxygen-containing gaseous mixture containing one or more components selected from water, carbon dioxide or a volatile hydrocarbon which process utilizes ion transport membranes comprising a multicomponent metallic oxide containing barium. The process utilizes a temperature regime which overcomes problems associated with degradation of barium-containing multicomponent oxides caused by carbon dioxide.
摘要翻译： 本发明是从含有一种或多种选自水，二氧化碳或挥发性烃的组分的含氧气体混合物中回收氧的方法，该方法利用了包含含钡的多组分金属氧化物的离子迁移膜。 该方法利用克服由二氧化碳引起的含钡多组分氧化物降解相关问题的温度状态。
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3.发明授权Process for recovering oxygen from gaseous mixtures containing water or carbon dioxide which process employs ion transport membranes 失效从含有水或二氧化碳的气态混合物中回收氧气的方法，该方法采用离子迁移膜
公开(公告)号：US5261932A
公开(公告)日：1993-11-16
申请号：US937767
申请日：1992-09-01
CPC分类号： C01B13/0255 , B01D53/326 , B01D71/024 , C01B2210/0051 , C01B2210/0062 , C01B2210/007 , Y10S505/701 , Y10S505/778 , Y10S505/785
摘要： The invention is a process for recovering oxygen from an oxygen-containing gaseous mixture containing one or more components selected from water, carbon dioxide or a volatile hydrocarbon which process utilizes ion transport membranes comprising a multicomponent metallic oxide containing strontium, calcium or magnesium. The process utilizes a temperature regime which overcomes problems associated with degradation of strontium-, calcium- and magnesium-containing multicomponent oxides caused by carbon dioxide.
摘要翻译： 本发明是从含有一种或多种选自水，二氧化碳或挥发性烃的组分的含氧气体混合物中回收氧气的方法，该方法利用了包含含锶，钙或镁的多组分金属氧化物的离子迁移膜。 该方法利用了克服由二氧化碳引起的含锶，钙和镁的多组分氧化物降解相关问题的温度状态。
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公开(公告)号：US5516359A
公开(公告)日：1996-05-14
申请号：US428611
申请日：1995-04-25
CPC分类号： B01D53/22 , B01D53/326 , C01B13/0251 , F01K23/064 , C01B2210/0046 , Y02E20/18 , Y02P20/123 , Y02P20/131 , Y02P20/57
摘要： Oxygen is separated from air by a high temperature ion transport membrane which is integrated with a gas turbine system for energy recovery from the membrane nonpermeate stream. Air is compressed, heated in a first heating step, and passed through the feed side of a mixed conductor membrane zone to produce a high purity oxygen product on the permeate side of the membrane zone. Nonpermeate gas from the membrane zone is heated in a second heating step and passed through a hot gas turbine for power recovery. The operating temperatures of the membrane zone and the expansion turbine are independently maintained by controlling the rate of heat addition in the first and second heating steps, whereby the membrane zone and expansion turbine are thermally delinked for maximum oxygen recovery efficiency.
摘要翻译： 氧气通过与气体涡轮机系统集成的高温离子传输膜与空气分离，以从膜非渗透流中回收能量。 将空气压缩，在第一加热步骤中加热，并通过混合导体膜区域的进料侧，以在膜区域的渗透侧产生高纯度氧产物。 来自膜区的非渗透气体在第二加热步骤中被加热，并通过热燃气轮机进行动力回收。 通过控制第一和第二加热步骤中的加热速率来独立地维持膜区和膨胀涡轮机的操作温度，由此膜区域和膨胀涡轮机被热脱胶以获得最大的氧气回收效率。
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公开(公告)号：US4422411A
公开(公告)日：1983-12-27
申请号：US268450
申请日：1981-05-29
申请人： Robert M. Thorogood
发明人： Robert M. Thorogood
摘要： A convective heater for heating fluids such as a coal slurry is constructed of a tube circuit arrangement which obtains an optimum temperature distribution to give a relatively constant slurry film temperature. The heater is constructed to divide the heating gas flow into two equal paths and the tube circuit for the slurry is arranged to provide a mixed flow configuration whereby the slurry passes through the two heating gas paths in successive co-current, counter-current and co-current flow relative to the heating gas flow. This arrangement permits the utilization of minimum surface area for a given maximum film temperature of the slurry consistent with the prevention of coke formation.
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公开(公告)号：US5565017A
公开(公告)日：1996-10-15
申请号：US428610
申请日：1995-04-25
CPC分类号： C01B13/0251 , B01D53/22 , B01D53/326 , F01K23/064 , C01B2210/0046 , Y02E20/18 , Y02P20/123 , Y02P20/131 , Y02P20/57
摘要： Oxygen is separated from air by a high temperature ion transport membrane which is integrated with a gas turbine system for energy recovery from the membrane nonpermeate stream. Air is compressed, heated in a first heating step, and passed through the feed side of a mixed conductor membrane zone to produce a high purity oxygen product on the permeate side of the membrane zone. Nonpermeate gas from the membrane zone is heated in a second heating step and passed through a hot gas turbine for power recovery. Water is added to the nonpermeate gas prior to the hot gas turbine to increase mass flow to the turbine and thus balance the mass flows of the air feed compressor and the expansion turbine. The operating temperatures of the membrane zone and the expansion turbine are independently maintained by controlling the rate of heat addition in the first and second heating steps and by controlling the rate of water addition, whereby the membrane zone and expansion turbine are thermally delinked for maximum oxygen recovery efficiency.
摘要翻译： 氧气通过与气体涡轮机系统集成的高温离子传输膜与空气分离，以从膜非渗透流中回收能量。 将空气压缩，在第一加热步骤中加热，并通过混合导体膜区域的进料侧，以在膜区域的渗透侧产生高纯度氧产物。 来自膜区的非渗透气体在第二加热步骤中被加热，并通过热燃气轮机进行动力回收。 在热燃气涡轮机之前将水加入到非渗透气体中，以增加到涡轮机的质量流量，从而平衡供气压缩机和膨胀涡轮机的质量流量。 通过控制第一和第二加热步骤中的加热速率并通过控制加水速率来独立地维持膜区和膨胀涡轮机的操作温度，由此膜区域和膨胀涡轮机对于最大氧气进行热脱水 恢复效率。
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公开(公告)号：US5240480A
公开(公告)日：1993-08-31
申请号：US945320
申请日：1992-09-15
CPC分类号： C01B13/0255 , B01D71/024 , B01D2325/26 , C01B2210/0046 , Y10S505/701 , Y10S505/778 , Y10S505/785
摘要： The present invention relates to novel multi-layer composite solid state membranes which are capable of separating oxygen from oxygen-containing gaseous mixtures at elevated temperatures. The membranes comprise a multicomponent metallic oxide porous layer having an average pore radius of less than about 10 micrometers and a multicomponent metallic oxide dense layer having no connected through porosity wherein the porous and dense layers are contiguous and such layers conduct electrons and oxygen ions at operating temperatures.
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公开(公告)号：US4699209A
公开(公告)日：1987-10-13
申请号：US844917
申请日：1986-03-27
申请人： Robert M. Thorogood
发明人： Robert M. Thorogood
CPC分类号： F25J5/002 , F25J3/04412 , F28D9/0068 , F25J2250/02 , F25J2290/32 , F25J2290/44 , F28D2021/0033
摘要： The present invention is directed to a heat exchanger for reboiler or condenser service in a cryogenic distillation column (e.g. air separation) or other service in which small temperature differences between clean fluids are a primary objective. The exchanger comprises a stack of corrugated sheets having corrugations generally parallel to the diagonal between opposite corners of a sheet assembled with each sheet on an opposed diagonal to that of its neighbor, which provides for alternating condensing and boiling passages. These passages because of their configuration have increased primary heat transfer surfaces resulting in reduced temperature differences in the exchanger. Special edge configurations control boiling and condensing fluid flow patterns to maximize the heat transfer performance. Optionally, the heat exchanger can have an enhanced boiling surface applied to the boiling channel surface.
摘要翻译： 本发明涉及一种用于在低温蒸馏塔（例如空气分离）中的再沸器或冷凝器服务的热交换器或其中清洁流体之间的小温差是主要目的的其它服务。 交换器包括一叠波纹片，其波纹通常平行于与每个片组成的片的相对角之间的对角线，该片与相邻的相对的对角线组装，其提供交替的冷凝和沸腾通道。 这些通道由于其构型而增加了一次传热表面，导致交换器中的温度差降低。 特殊边缘配置控制沸腾和冷凝流体流动模式，以最大限度地提高传热性能。 任选地，热交换器可以具有施加到沸腾通道表面的增强的沸腾表面。
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公开(公告)号：US4414094A
公开(公告)日：1983-11-08
申请号：US474926
申请日：1983-03-14
申请人： Robert M. Thorogood
发明人： Robert M. Thorogood
CPC分类号： C10G1/065
摘要： There is described an improved SRC reactor quench system using a condensed product which is recycled to the reactor and provides cooling by evaporation. In the process, the second and subsequent reactors of a series of reactors are cooled by the addition of a light oil fraction which provides cooling by evaporation in the reactor. The vaporized quench liquid is recondensed from the reactor outlet vapor stream.
摘要翻译： 描述了使用冷凝产物的改进的SRC反应器骤冷系统，其被循环到反应器并通过蒸发提供冷却。 在该过程中，通过加入通过在反应器中蒸发提供冷却的轻质油馏分来冷却一系列反应器的第二和随后的反应器。 蒸发的骤冷液体从反应器出口蒸气流重新凝结。
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公开(公告)号：US6128922A
公开(公告)日：2000-10-10
申请号：US316820
申请日：1999-05-21
CPC分类号： F25J3/04672 , B01J19/32 , F25J3/04921 , B01J2219/3306 , B01J2219/3325 , Y10S62/906
摘要： A distillation method and column in which a gaseous mixture is introduced into a bottom region of a packed column having a plurality packed beds using structured packing. The gaseous mixture comprises higher and lower volatility components. The packed column is operated so that the higher and lower volatility components have a relative volatility within the column in a range of between 1.05 and 1.8. In order to alleviate the effect of liquid maldistribution in the lowermost bed of such a column, the lowermost bed is sized to be between about 50% and about 80% of the height of the next overlying bed, with 80% being preferred and the total height of the packing within the column is at least about six meters.
摘要翻译： 蒸馏方法和塔，其中使用规整填料将气态混合物引入具有多个填充床的填充塔的底部区域。 气体混合物包含较高和较低挥发性成分。 操作填充柱使得较高和较低挥发性组分在柱内的相对挥发度在1.05和1.8之间的范围内。 为了减轻液体在这种塔的最低床中的分布不均匀的影响，最下层的尺寸设定在下一个覆盖床的高度的约50％至约80％之间，其中80％是优选的， 柱内的包装高度至少约六米。
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