摘要:
In metal complexes of the formula I ##STR1## the substituents have the following meanings: M is a metal of transition group III, IV, V or VI of the Periodic Table of the Elements or a metal of the lanthanide series,Y is a negative leaving atom or a negative leaving group,X and X.sup.1 are negatively charged or uncharged atoms of main group IV, V or VI of the Periodic Table of the Elements,Z is hydrogen, C.sub.1 -C.sub.10 -alkyl, C.sub.3 -C.sub.10 -cycloalkyl, C.sub.1 -C.sub.10 -alkoxy, C.sub.1 -C.sub.10 -alkylthio or dialkylamido having from 1 to 4 carbon atoms in each alkyl radical,R.sup.1 to R.sup.11 are hydrogen, carboorganic or organosilicon radicals,n is 0, 1 or 2 andthe valence of M is 2+n.
摘要:
A catalyst system containing as active constituentsA) metal complexes of the formula I ##STR1## wherein the substituents have the meanings set forth in the specification andB) a compound capable of forming metallocenium ions.
摘要:
Continuous process for preparation of polyalkylene arylates A) comprising highly branched or hyperbranched polymers B) and, if appropriate, comprising lubricants C), by esterifying or transesterifying an aromatic dicarboxylic acid or its ester or ester-forming derivatives, with a molar excess of an aliphatic dihydroxy compound, and polycondensing the resultant transesterification or esterification product, which comprises, on achievement of at least 80% of the desired viscosity number, adding component B) and also, if appropriate, C) to the polymer melt, and, if appropriate, post-condensing the melt and then discharging, cooling, and pelletizing it, and also using, as component B), at least one highly branched or hyperbranched polycarbonate B1) with an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, Part 2), or at least one highly branched or hyperbranched polyester B2) of AxBy type, where x is at least 1.1 and y is at least 2.1, or a mixture of these.
摘要:
The invention relates to thermoplastic molding compositions comprising A) from 10 to 89.9% by weight of a thermoplastic polyester with a viscosity number (VN) of at least 145 ml/g B) from 10 to 89.99% by weight of a thermoplastic polyester with a viscosity number (VN) of not more than 135 ml/g C) from 0.01 to 5% by weight of at least one nucleating agent D) from 0 to 5% by weight of at least one lubricant E) from 0 to 70% by weight of other additives, the total of the percentages by weight of components A) to E) being 100%.
摘要:
The invention relates to thermoplastic moulded masses, comprising A) 10 to 97 wt. % of at least one thermoplastic polyester, B) 1 to 30 wt. % of a flame-resistant agent combination with, based on 100 wt. % B), b1) 20 to 99 wt. % of a halogenated flame resistant agent, b2) 1 to 80 wt. % of a antimony oxide, C) 0.01 to 3 wt. % of at least one polyamide, D) 0.01 to 2 wt. % of at least one nigrosin, E) 0.01 to 3 wt. % of at least one anti-dripping agent and F) 0 to 70 wt. % of further adjuncts, whereby the sum of components A) to F) is 100 %.
摘要:
Linear, alternating .alpha.-olefin-CO copolymers are obtainable by polymerization of a monomer mixture comprisinga) carbon monoxide,b) 1-alkenes which are functionalized by a covalently bonded crown ether unit or cryptand unit A containing at least 5 heteroatoms selected from the group consisting of nitrogen, oxygen, sulfur and/or selenium in the polyheteroatom framework, and, if desired,c) C.sub.2 -C.sub.24 -1-alkenes.