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公开(公告)号：US20050009707A1
公开(公告)日：2005-01-13
申请号：US10860175
申请日：2004-06-03
摘要： Granulated solids containing at least (A) a compound of the general formula RO-[G]p, in which R represents an alkyl and/or alkenyl radical with 4 to 22 carbon atoms, G represents a sugar radical with 5 or 6 carbon atoms, and p represents numbers from 1 to 10, and (B) water-soluble, nonionic, homopolymeric and/or copolymeric compounds, wherein the monomers are selected from compounds of the formula R1R2C═CR3X, in which R1, R2, and R3 each independently represent a hydrogen atom or an aliphatic alkyl radical with 1 to 4 C atoms or an acryl radical possibly containing N or O atoms and X represents a group OR4, OCOH, OCOY, OCOR5, CONR6, CN, NR72, NH—CO—R8, wherein the radicals R4 to R8 independently represent a hydrogen atom or saturated or unsaturated, branched or unbranched aliphatic or aromatic organic radicals with 1 to 22 C atoms, and Y represents a cation, unsaturated dicarboxylic acids, preferably maleic acid or aspartic acid and derivatives thereof, isocyanates, polyols, amino acids, and sugars, and also represents at least one agrochemical active ingredient and optionally auxiliaries and fillers.
摘要翻译： 含有至少（A）通式为RO- [G] p的化合物的颗粒状固体，其中R表示具有4至22个碳原子的烷基和/或烯基，G表示具有5或6个碳原子的糖基 ，和p表示1至10的数字，和（B）水溶性，非离子，均聚和/或共聚的化合物，其中所述单体选自式R 1 R 2 C = CR 3的化合物 >其中R 1，R 2和R 3各自独立地表示氢原子或具有1至4个C原子的脂族烷基或可能含有N或O原子的丙烯酰基，X表示 OR 4，OCOH，OCOY，OCOR 5，CONR 6，CN，NR 7，NH-CO-R 8，其中基团R 4至R 8， 独立地表示氢原子或具有1至22个C原子的饱和或不饱和，支链或非支链的脂族或芳族有机基团，Y表示阳离子，不饱和二羧酸，优选马来酸或天冬氨酸及其衍生物，isocya 胺，多元醇，氨基酸和糖，并且还代表至少一种农药活性成分和任选的助剂和填料。
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公开(公告)号：US20120245070A1
公开(公告)日：2012-09-27
申请号：US13513762
申请日：2010-11-26
申请人： Rainer Eskuchen , Sabine Both , Arnold Benert , Ditmar Kischkel
发明人： Rainer Eskuchen , Sabine Both , Arnold Benert , Ditmar Kischkel
CPC分类号： C11D1/662
摘要： Disclosed is the use of alkyl(oligo)glycosides based on selected branched fatty alcohols as hydrotropic agents, preferably for use in cleaning agents, in particular agents for automatic dish washing.
摘要翻译： 公开了使用基于所选择的支链脂肪醇的烷基（寡糖）糖苷作为水溶助长剂，优选用于清洁剂，特别是用于自动洗碗的药剂。
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3.发明申请公开(公告)号：US20070082836A1
公开(公告)日：2007-04-12
申请号：US11531320
申请日：2006-09-13
IPC分类号： C11D1/72
CPC分类号： C11D1/825 , C11D1/40 , C11D1/44 , C11D1/662 , C11D1/72 , C11D1/721 , C11D1/722 , C11D1/74 , C11D1/835 , C11D1/90 , C11D1/94
摘要： The disclosed invention relates to mixtures of at least two structurally different surface-active compounds, one surface-active compound a) being selected from an hydroxyl mixed ether compound of formula (I): R1O[CH2CH2O]xCH2CH(OM)R2 (I) in which R1 is a linear or branched alkyl and/or alkenyl group containing 4 to 22 carbon atoms or an R2—CH(OH)CH2 group, where R2 is a linear or branched alkyl and/or alkenyl group containing 8 to 16 carbon atoms, x is a number from 40 to 80 and M is a hydrogen atom or a saturated alkyl group containing 1 to 18 carbon atoms. The second surface-active compound b) is preferably selected from a structurally different hydroxy mixed ether compound of formula (II): R3O[CH2CH2O]y[CH2CHCH3O]zCH2CH(OH)R4 (II) These mixtures are capable of improving the drying of hard surfaces after washing and, at the same time, also positively influence clear-rinse performance.
摘要翻译： 所公开的发明涉及至少两种结构不同的表面活性化合物的混合物，一种表面活性化合物a）选自式（I）的羟基混合醚化合物：<β在线式描述=“In- 线式“end =”lead“？> R 1 O 2 CH 2 CH 2 O 2 CH 2 CH 2 （I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中R < SUP> 1是含有4至22个碳原子的直链或支链烷基和/或烯基或R 2 -CH（OH）CH 2 - 基团 其中R 2是含有8至16个碳原子的直链或支链烷基和/或烯基，x是40至80的数，M是氢原子或含有1的饱和烷基 至18个碳原子。 第二表面活性化合物b）优选选自结构不同的式（II）的羟基混合醚化合物：<？in-line-formula description =“In-line formula”end =“lead”？> R SUP > 3 O 2 CH 2 CH 2 CH 2 CH 2 CH 2 CH 2 CH 2 CH 2 CH 2 （O）CH 2 CH 2 OH（CH 2）2（2） 在线配方“end =”tail“？>这些混合物能够改善洗涤后硬表面的干燥，同时也对清洗性能有积极的影响。
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4.发明授权Alkyl and/or alkenyloligoglycoside preparations having reduced magnesium salt concentrations 有权具有降低的镁盐浓度的烷基和/或烯醇降糖苷制剂公开(公告)号：US07045494B2
公开(公告)日：2006-05-16
申请号：US10481841
申请日：2002-06-12
摘要： A process for making an alkyl and/or alkenyl oligoglycoside preparation having a magnesium salt concentration of less than about 10 ppm involving the steps of: (a) providing an alkyl and/or alkenyl oligoglycoside preparation having an active substance content of from about 10 to 70% by weight, based on the weight of the preparation; (b) providing an acid component; (c) adjusting the pH of the alkyl and/or alkenyl oligoglycoside preparation to from about 4 to 9.5 by combining the acid component with the alkyl and/or alkenyl oligoglycoside preparation to form a pH-modified alkyl and/or alkenyl oligoglycoside preparation; (d) providing a column charged with an ion exchange resin; and (e) purifying the pH-modified alkyl and/or alkenyl oligoglycoside preparation by passing it through the column of step (d) at a viscosity of from about 20 to 6,000 mPas, and at a temperature of from about 20 to 90° C. to form the alkyl and/or alkenyl oligoglycoside preparation having a magnesium salt concentration of less than about 10 ppm.
摘要翻译： 制备镁盐浓度小于约10ppm的烷基和/或烯基低聚糖苷制剂的方法，包括以下步骤：（a）提供活性物质含量为约10至10重量％的烷基和/或烯基低聚糖苷制剂， 70重量％，基于制剂的重量; （b）提供酸组分; （c）通过将酸组分与烷基和/或链烯基低聚糖苷制剂组合以形成pH-改性的烷基和/或烯基低聚糖苷制剂，将烷基和/或链烯基低聚糖苷制剂的pH调节至约4至9.5; （d）提供带有离子交换树脂的柱; 和（e）通过使pH值为约20至6,000mPa·s的粘度和约20至90℃的温度通过步骤（d）的柱来纯化pH-改性的烷基和/或烯基低聚糖苷制剂 形成镁盐浓度小于约10ppm的烷基和/或烯基低聚糖苷制剂。
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公开(公告)号：US5569752A
公开(公告)日：1996-10-29
申请号：US244647
申请日：1994-06-06
申请人： Paul Schulz , Herbert Esser , Rainer Eskuchen
发明人： Paul Schulz , Herbert Esser , Rainer Eskuchen
CPC分类号： C07H15/04
摘要： Light-colored lower alkyl oligoglucosides having a low polyglucose content can be obtained in short reaction times by a process in whicha) aqueous glucose sirup is added to a mixture of a lower alcohol and an acidic catalyst at elevated temperatures via an inline mixer,b) the water present in the reaction mixture and the water released are azeotropically distilled off continuously andc) after the addition of glucose sirup, the reaction mixture is subjected to heating until at least 99% of the glucose is reacted.
摘要翻译： PCT No.PCT / EP92 / 02748 Sec。 371日期：1994年6月6日 102（e）日期1994年6月6日PCT提交1992年11月27日PCT公布。 公开号WO93 / 11142 日期：1993年7月10日可以在短的反应时间内通过以下方法获得具有低聚葡萄糖含量的低色低级烷基寡葡糖苷：其中a）将水性葡萄糖sirup在升高的温度下通过下列方法加入到低级醇和酸性催化剂的混合物中： 在线混合器，b）反应混合物中存在的水和释放的水被连续共沸蒸馏，c）在加入葡萄糖sirup后，将反应混合物加热至至少99％的葡萄糖反应。
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公开(公告)号：US5559219A
公开(公告)日：1996-09-24
申请号：US952535
申请日：1992-02-09
申请人： Willi Wuest , Joseph Wollmann , Rainer Eskuchen
发明人： Willi Wuest , Joseph Wollmann , Rainer Eskuchen
CPC分类号： C07H15/04
摘要： Alkyl glycosides are produced by direct synthesis from higher monofunctional alcohols and powder-form glycoses, particularly anhydrous glucose and/or glucose monohydrate, in the presence of acidic catalysts at elevated temperatures, the interior of the reactor being kept under reduced pressure and the glycose being introduced with delay into the alcohol reactants present in excess therein, the alcohol reactants containing the acidic catalyst and being heated to the reaction temperature, while water released in the reaction mixture is removed from the reaction zone via the gas phase. A partial stream is run off from the liquid reaction mixture and delivered to a premixing zone into which the powder-form reactant is simultaneously introduced and is converted with the liquid partial stream into a paste which is delivered to the interior of the reactor via a following intensive mixer. The premixing zone is in direct pressure equalization with the reduced pressure of the reactor interior via the intensive mixer on the one hand and, at the same time, with the ambient pressure via the feed unit used for the powder-form glycose on the other hand, the consistency of the paste formed in the premixing zone being selected so that the paste serves as a pressure-equalizing sealing compound and, hence, as a so-called "living seal".
摘要翻译： PCT No.PCT / EP91 / 01010 Sec。 371日期1992年2月9日 102（e）1992年2月9日PCT PCT 1991年5月31日PCT公布。 出版物WO91 / 19722 日期1991年12月26日烷基糖苷通过在高温下在酸性催化剂存在下由高级单官能醇和粉末形糖糖，特别是无水葡萄糖和/或葡萄糖一水合物进行直接合成来制备，反应器内部保持减少 压力，并且将糖类延迟引入其中存在的醇反应物中，醇反应物含有酸性催化剂并被加热至反应温度，同时通过气相将反应混合物中释放的水从反应区除去。 部分物流从液体反应混合物中流出并且被输送到预混合区，粉末形式的反应物同时被引入到该预混合区中，并且用液体部分流转化成糊状物，该浆料经由下列物质被输送到反应器的内部 密集搅拌机 一方面，预混合区域通过强化混合器在反应器内部的压力下进行直接均压，另一方面，通过用于粉末形式的糖的进料单元的环境压力 选择在预混合区中形成的糊状物的稠度，使得糊状物用作均压密封剂，因此作为所谓的“活性密封”。
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公开(公告)号：US5538669A
公开(公告)日：1996-07-23
申请号：US424230
申请日：1995-04-19
申请人： Paul Schulz , Rainer Eskuchen , Manfred Weuthen
发明人： Paul Schulz , Rainer Eskuchen , Manfred Weuthen
CPC分类号： C11D1/662 , C11D17/003
摘要： Water-based surfactant pastes, more particularly those containing nonionic surfactants of the alkyl glycoside type, are effectively stabilized against microbial infestation if, after oxidative bleaching to eliminate alkali-sensitive color bodies, they are adjusted to a pH value of at least 11 by addition of alkaline substances.
摘要翻译： 水性表面活性剂糊剂，更特别是含有烷基糖苷类非离子表面活性剂的那些，如果在氧化漂白以消除碱敏感的着色体之后，通过加入将它们调节至至少11的pH值， 的碱性物质。
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公开(公告)号：US08399042B2
公开(公告)日：2013-03-19
申请号：US12746626
申请日：2008-11-28
IPC分类号： A23D7/00
CPC分类号： A23L2/00 , A23L29/10 , A23L33/10 , A23L33/11 , A23L33/12 , A23P10/47 , A23V2002/00 , A23V2200/222 , A23V2250/2136
摘要： The invention relates to aqueous dispersions containing (a) 5 to 50% by weight of sterols and/or stanols; and (b) 0.5 to 20% by weight of citric acid esters of mono- and/or diglycerides, based on the total weight of the dispersion, wherein the citric acid esters of mono- and/or diglycerides are partially neutralised; and to a process for the production of an aqueous sterol/stanol-containing dispersion, which process comprises (a) dissolving citric acid esters of mono- and/or diglycerides that are partly neutralised, in water; (b) dispersing sterols and/or stanols in the emulsifier solution to form a pre-dispersion; and (c) grinding the pre-dispersion in a ball-mill until the dispersion has a particle mass diameter, d90, of less than 5 μm. Optionally, this dispersion is spray-dried.
摘要翻译： 本发明涉及含有（a）5至50重量％的甾醇和/或甾醇的水分散体; 和（b）基于分散体总重量的0.5至20重量％的甘油单酯和/或甘油二酯的柠檬酸酯，其中甘油单酯和/或甘油二酯的柠檬酸酯部分中和; 以及生产含水甾醇/含Stanol的分散体的方法，该方法包括（a）将部分中和的甘油单酯和/或甘油二酯的柠檬酸酯溶解在水中; （b）将甾醇和/或甾醇分散在乳化剂溶液中以形成预分散体; 和（c）在球磨机中研磨预分散体，直到分散体具有小于5μm的颗粒质量直径d 90。 任选地，将该分散体喷雾干燥。
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9.发明申请公开(公告)号：US20080076694A1
公开(公告)日：2008-03-27
申请号：US11820951
申请日：2007-06-21
摘要： Surfactant granules, of which the grain size distribution as determined by RRSB graph to DIN 66145 possess the following parameters: dm is in the range from 0.5 to 1.5 mm; d63.3 is in the range from 0.5 to 1.5 mm; and n is in the range from 1 to 10, show advantageous performance properties, for example in the production of detergents, for example, automatic dish and laundry detergents.
摘要翻译： 通过根据DIN 66145的RRSB图确定的颗粒尺寸分布的表面活性剂颗粒具有以下参数：d> m <0.5;在0.5至1.5mm的范围内; 63.3 在0.5至1.5mm的范围内; 并且n在1至10的范围内，显示出有利的性能，例如在洗涤剂的生产中，例如自动洗涤剂和衣物洗涤剂。
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10.发明申请Mixtures of fatty alcohol(s) and alk(en)yl polyglycoside ether carboxylate(s), methods for their production and uses thereof 有权脂肪醇和烷基（en）基多糖苷羧酸酯的混合物，其制备方法及其用途公开(公告)号：US20050215454A1
公开(公告)日：2005-09-29
申请号：US11088088
申请日：2005-03-23
申请人： Ansgar Behler , Karl Schmid , Michael Neuss , Rainer Eskuchen
发明人： Ansgar Behler , Karl Schmid , Michael Neuss , Rainer Eskuchen
CPC分类号： C07H15/04
摘要： Mixtures comprising at least one alk(en)yl polyglycoside ether carboxylate, and one or more fatty alcohols are described along with methods for preparing the same, wherein a starting mixture comprising (i) at least one alk(en)yl polyglycoside, and (ii) one or more fatty alcohols is provided, and the starting mixture is reacted with a compound selected from the group consisting of ω-halocarboxylic acids, ω-halocarboxylic acid salts, ω-halocarboxylic acid esters, and mixtures thereof.
摘要翻译： 包含至少一种烷基（en）基多糖苷醚羧酸酯和一种或多种脂肪醇的混合物与其制备方法一起描述，其中起始混合物包含（i）至少一种烷基（en）基多糖苷和（ ii）提供一种或多种脂肪醇，并使起始混合物与选自ω-卤代羧酸，ω-卤代羧酸盐，ω-卤代羧酸酯及其混合物的化合物反应。
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