摘要:
A liquid-crystalline polymer phase having an induced cholesteric structure comprises a component having a chiral structure and a component having a nematic structure and contains a polymer with nematogenic units of the formula ##STR1## wherein R.sub.1 is hydrogen or methyl, n is an integer from 1 to 6 and R.sub.3 represents specific structural elements containing at least two phenylene groups. Preferred is a copolymer comprising a component of the above formula and an additional chiral component of similar structure, prepared by copolymerization of the nematogenic monomer with the chiral monomer.The liquid-crystalline polymer phase permits variation of the wavelength of the reflected light .lambda..sub.R, and its cholesteric structure can be converted to the glassy polymer state and remains preserved in the solid state. Such liquid-crystalline polymer phases can be used in integrated optics, opto-electronics and information storage, e.g. for the manufacture of polarization filters or selective reflectors.
摘要:
The polymer chain comprises(a) one or more monomers possessing a nematogenic, chiral or smectogenic group, or a mixture of monomers possessing a nematogenic group with those possessing a chiral group, and(b) one or more monomers possessing a radical of a pleochroic dye, and the nematogenic, the chiral and the smectogenic groups are bonded to the polymerizable group either directly or, like the dye radicals, via a spacer.The polymers can be used, together with low molecular weight liquid crystals or liquid crystal mixtures, in electrooptical displays.
摘要:
An aqueous polymer dispersion with a solids volume concentration of at least 50% by volume is obtainable by polymerizing monomers by the method of free radical aqueous emulsion polymerization with the addition of at least one fine and at least one coarse aqueous starting polymer dispersion.
摘要:
UV-crosslinkable materials based on (meth)acrylate copolymers and containing from 0.01 to 10% by weight, based on the copolymer, of copolymerized monomers of the formula I ##STR1## where x is alkyl of 1 to 3 carbon atoms or is phenyl which is unsubstituted or substituted by n Y groups, Y is --H, --CF.sub.3, --O-- alkyl and/or alkyl-COO--, where alkyl in each case is of 1 to 4 carbon atoms, halogen, --CH, --COOH or a non-ortho --OH group, n is from 0 to 4 and Z is a group of the formula ##STR2## where R is H or C.sub.1 -C.sub.4 -alkyl and A is an alkylene, oxaalkylene or polyoxaalkylene radical of 2 to 12 carbon atoms are used as hotmelt adhesives, for coating sheet-like mineral substrates and as surface coatings.
摘要:
Lightweight building board based on mineral fibers A and thermoplastic binders contains, based on A,from 1 to 25% by weight of a copolymer B having a glass transition temperature of from 70.degree. to 105.degree. C., composed essentially offrom 50 to 98% by weight of methyl methacrylate I,from 2 to 50% by weight of one or more acrylic esters II of C.sub.1 -C.sub.8 -alkanols, andfrom 0 to 2.5% by weight of one or more crosslinking monomers III as binder,from 0 to 150% by weight of filler C,and, based on B,from 0.2 to 15% by weight of one or more amines F of the formula ##STR1## where R is C.sub.8 -C.sub.18 -alkyl or C.sub.8 -C.sub.18 -alkenyl,U and V are each C.sub.2 -C.sub.4 -alkylene,X and Y are each hydrogen, C.sub.1 -C.sub.18 -alkyl or C.sub.2 -C.sub.18 -alkenyl, andn and m are each an integer from 0 to 10, or an acid addition salt thereof.
摘要:
Wholly aromatic mesomorphic polyether ester imides which form a liquid-crystalline fiber-forming melt below 320.degree. C. and are composed of(a) from 5 to 35 mol % of repeat units of the formula I ##STR1## (b) from 5 to 35 mol % of repeat units of the formula II ##STR2## where X is a chemical bond, --O--, --S--, --SO.sub.2 --, --CO--, --Ch.sub.2 -- or .dbd.C(CH.sub.3).sub.2, and n is 0 or 1,(c) from 15 to 30 mol % of repeat units of the formula III ##STR3## (d) a molar amount corresponding to the total amount of (b) plus (c) minus (a) of repeat units of the formulae IV and/or V ##STR4## (e) repeat units of the formula VI ##STR5## the mole percentages of components a, b, c, d and e adding up to a 100 mol % in each case,the preparation thereof and fibers, films and molding prepared therefrom.
摘要翻译:全芳族介晶聚醚酯酰亚胺,其在320℃以下形成液晶纤维形成熔体,并由(a)5-35摩尔%的式I(b)的重复单元组成, 5至35摩尔%的式II的重复单元其中X是化学键,-O - , - S - , - SO 2 - , - CO - , - C 2-或= C(CH 3)2,n为0或1,(c)15至30摩尔%的式III的重复单元(III)(d)相当于(b) (IV)的重复单元加(c) - (a)(Ⅴ)(ⅴ)式Ⅵ的重复单元Ⅵ(VI)的重复单元 在各种情况下,组分a,b,c,d和e加起来为100mol%,其制备和由其制备的纤维,薄膜和模制品。
摘要:
Wholly aromatic polyesters which form a liquid-crystalline fiber-forming melt below 300.degree. C. and are composed of(a) from 10 to 25 mol % of repeat units of the formula I ##STR1## (b) from 5 to 15 mol % of repeat units of the formula II ##STR2## (c) from 5 to 15 mol % of repeat units of the formula III ##STR3## (d) not less than 10 mol % of repeat units of the formula IV ##STR4## and (e) a molar amount corresponding to the total amount of (a), (b) and (c) of repeat units of the formula V ##STR5## the molar proportions of components a, b, c, d and e adding up to 100 mol % in each case, the preparation thereof and fibers, films, moldings and surface coatings prepared therefrom.
摘要:
An aqueous polymer dispersion with a final solids volume concentration of at least 50% by volume is obtainable by polymerizing at least one radical polymerizable monomer by the method of free radical aqueous emulsion polymerization with the addition of an aqueous dispersion of a starting polymer.
摘要:
An aqueous polymer dispersion with a solids volume concentration of at least 50% by volume is obtainable by polymerizing monomers by the method of free radical aqueous emulsion polymerization with the addition of at least two starting polymer dispersions, of which one contains not only particularly finely divided but also coarsely divided polymer particles.
摘要:
An aqueous polymer dispersion with a solids volume concentration of at least 50% by volume is obtainable by polymerizing monomers by the method of free radical aqueous emulsion polymerization with the addition of at least one fine and at least one coarse aqueous starting polymer dispersion.