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公开(公告)号：US4167412A
公开(公告)日：1979-09-11
申请号：US885927
申请日：1978-03-13
CPC分类号： G03G5/0637
摘要： Sensitizers for photoconductive compositions and elements are disclosed. The sensitizers are 2,4,6 tri substituted pyrylium dye salts wherein at least one of said substituents is a 5 or 6 membered heterocyclic ring having at least one atom selected from the group consisting of N, O and S.
摘要翻译： 公开了用于感光组合物和元件的敏化剂。 敏化剂是2,4,6-三取代的吡喃鎓染料盐，其中至少一个所述取代基是具有至少一个选自N，O和S的原子的5或6元杂环。
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公开(公告)号：US4341894A
公开(公告)日：1982-07-27
申请号：US33614
申请日：1979-04-26
IPC分类号： G03G5/06 , C07D309/32 , C07D335/00
CPC分类号： G03G5/0661
摘要： Sensitizers for photoconductive compositions and elements are disclosed. The sensitizers are 2,4,6 tri substituted pyrylium dye salts wherein at least one of said substituents is a 5 or 6 membered heterocyclic ring having at least one atom selected from the group consisting of N, O and S.
摘要翻译： 公开了用于感光组合物和元件的敏化剂。 敏化剂是2,4,6-三取代的吡喃鎓染料盐，其中至少一个所述取代基是具有至少一个选自N，O和S的原子的5或6元杂环。
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3.发明授权Negative working photoresists responsive to longer wavelengths and novel coated articles 失效负性工作的光致抗蚀剂响应更长的波长和新颖的涂层制品
公开(公告)号：US4743530A
公开(公告)日：1988-05-10
申请号：US933660
申请日：1986-11-21
CPC分类号： G03F7/031 , Y10S430/115 , Y10S430/121
摘要： A negative working photoresist is disclosed responsive to imaging radiation of a wavelength longer than 550 nm comprised of an organic film forming component containing ethylenic unsaturation and capable of selective immobilization by addition at the site of ethylenic unsaturation and activator and photosensitizer coinitiators for ethylenic addition. The activator is an azinium salt activator, and the photosensitizer is a dye having its principal absorption peak at a wavelength longer than 550 nm and having a reduction potential which in relation to that of said azinium salt activator is at most 0.1 volt more positive.
摘要翻译： 公开了一种负光致抗蚀剂，其响应于包含含有烯属不饱和键的有机成膜组分的波长超过550nm的成像辐射，并且能够通过在烯属不饱和位置加入而选择性地固定，并且用于乙烯添加的活化剂和光敏剂共引发剂。 活化剂是吖嗪盐活化剂，并且光敏剂是其波长比550nm长的主要吸收峰并且具有与所述氮鎓盐活化剂相关的还原电位至多为0.1伏更多正电荷的还原电位的染料。
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公开(公告)号：US4366228A
公开(公告)日：1982-12-28
申请号：US262675
申请日：1981-05-11
CPC分类号： G03F7/031 , C08F2/50 , Y10S430/114 , Y10S430/117 , Y10S430/121
摘要： A photopolymerizable composition, element and method of photopolymerizing the composition or element are disclosed wherein the composition comprises an addition polymerizable compound containing ethylenic unsaturation and a co-initiator including a photopolymerization activator and photosensitizer.In one aspect of the invention, the photosensitizer is selected to be a coumarin having an absorption maximum between about 250 and about 550 nm, and a ##STR1## substituent in the 3-position wherein R.sup.1 is alkyl or alkenyl having 1-12 carbon atoms, or a carboxylic or heterocyclic group having 5-20 nuclear carbon and hetero atoms, the coumarin and the activator being present in an amount sufficient to provide, when the compound is coated, dried and exposed to a medium-pressure mercury light source, a speed which is at least about one-fifth that of the same composition coated, dried and exposed identically except with a co-initiator consisting of Michler's ketone and benzophenone.In another aspect of the invention, the activator is selected to have the structure: ##STR2## wherein: J is --O--, --S-- or a carbon-to-carbon bond;J.sup.1, J.sup.2, and J.sup.3 are each independently hydrogen; alkyl, alkoxy, or alkylthio having from 1 to 5 carbon atoms; aryloxy having from 6 to 10 carbon atoms; halogen; or any two of J.sup.1, J.sup.2, and J.sup.3 taken together comprise the atoms necessary to complete a 5- or 6-membered fused heterocyclic or aromatic ring; andZ is the number of atoms necessary to complete a heterocyclic or aromatic ring of from 4 to 6 ring atoms. This application is a division of Ser. No. 184,606 filed 9/5/80, now U.S. Pat. No. 4,289,844, which is a continuation-in-part of Ser. No. 49,661, filed 6/18/79, now abandoned.
摘要翻译： 公开了可光聚合的组合物，组合物或元素的光聚合组分，元素和方法，其中组合物包含含有烯属不饱和的加成聚合化合物和包含光聚合活化剂和光敏剂的共引发剂。 在本发明的一个方面，光敏剂选择为吸收最大值在约250至约550nm之间的香豆素，以及3-位上的取代基，其中R1是具有1-12个碳原子的烷基或烯基 或具有5-20个核碳原子和杂原子的羧基或杂环基团时，香豆素和活化剂的存在量足以提供当化合物被涂覆干燥并暴露于中压水银光源时， 除了使用由米ler酮和二苯甲酮组成的共引发剂之外，相同组合物的涂覆，干燥和曝光相同的速度至少约为五分之一。 在本发明的另一方面，活化剂被选择为具有以下结构：其中：J为-O-，-S-或碳 - 碳键; J1，J2和J3各自独立地为氢; 具有1至5个碳原子的烷基，烷氧基或烷硫基; 具有6至10个碳原子的芳氧基; 卤素; 或J1，J2和J3中的任何两个一起包含完成5或6元稠合杂环或芳环所必需的原子; Z是完成4至6个环原子的杂环或芳环所必需的原子数。 这个应用程序是Ser的一个部门。 现在的美国专利申请第184,606号。 第4,289,844号是Ser的继续部分。 第49,661号，于6/18/79提交，现已放弃。
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5.发明授权Light-sensitive compositions with 3-substituted coumarin compounds as spectral sensitizers 失效具有3-取代香豆素化合物作为光敏剂的感光组合物
公开(公告)号：US4147552A
公开(公告)日：1979-04-03
申请号：US769621
申请日：1977-02-17
申请人： Donald P. Specht , Samir Y. Farid
发明人： Donald P. Specht , Samir Y. Farid
CPC分类号： G03C1/695 , C07D311/16 , C08F2/50 , G03C5/60 , G03F7/0085 , G03F7/031 , Y10S430/114
摘要： 3-Substituted coumarins are efficient sensitizers for light-sensitive unsaturated materials such as unsaturated vesiculators which release a gas upon exposure to radiation, unsaturated monomers and photocrosslinkable unsaturated polymers, and azides such as photocrosslinkable polymeric azides used in photomechanical resists and lithographic plates. Water soluble derivatives can be used for aqueous coatable or aqueous processable systems.
摘要翻译： 3-取代的香豆素是用于光敏不饱和材料的有效敏化剂，例如在暴露于辐射时释放气体的不饱和泡沫剂，不饱和单体和可光致交联的不饱和聚合物，以及用于光机械抗蚀剂和平版印刷板的叠氮化物如光可交联的聚合叠氮化物。 水溶性衍生物可用于水性可涂覆或水性可加工体系。
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6.发明授权
公开(公告)号：US5635343A
公开(公告)日：1997-06-03
申请号：US520153
申请日：1995-08-28
申请人： Donald P. Specht , Donald R. Diehl
发明人： Donald P. Specht , Donald R. Diehl
IPC分类号： C07D403/04 , C07D413/04 , G03C1/815
CPC分类号： C07D403/04 , C07D413/04 , G03C1/8155 , Y10S430/132
摘要： A substantially inert ultraviolet absorbing compound, and photographic elements containing them, which compound has a peak absorption at less than 400 nm and being of formula (I): ##STR1## wherein: X is O or NR.sub.8, Z represents the atoms necessary to complete a 5-membered or 6-membered heterocyclic ring which includes X and N, and the 3-position of the pyrazolone ring may independently be substituted or unsubstituted;R.sub.5 is alkyl, alkenyl, or arylalkyl any of which may be substituted or unsubstituted, or R.sub.5 may form a ring with a 3-position substituent on the pyrazolone ring or a 4-position substituent on the benzo ring;R.sub.7 is alkyl, alkenyl, aryl, or heterocycle, any of which may be substituted or unsubstituted, or H; andR.sub.8 is alkyl, alkenyl, or arylalkyl any of which may be substituted or unsubstituted, or H.
摘要翻译： 基本惰性的紫外线吸收化合物和含有它们的照相元件，该化合物在小于400nm具有峰值吸收，并且具有式（I）：其中：X为O或NR8，Z表示原子 必要的是完成包括X和N的5元或6元杂环，吡唑啉酮环的3位可以独立地被取代或未取代; R5是烷基，烯基或芳基烷基，其中任何一个可以是取代的或未取代的，或者R5可以与吡唑啉酮环上的3位取代基或苯并环上的4位取代基形成环; R 7是烷基，烯基，芳基或杂环，其中任何一个可以是取代或未取代的，或H; 并且R 8是烷基，烯基或芳烷基，其中任何一个可以是取代或未取代的，或H.
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7.发明授权Optical article containing a transmission medium exhibiting a high level of second order polarization susceptibility 失效含有表现出高水平二阶极化敏感性的传输介质的光学制品
公开(公告)号：US4886339A
公开(公告)日：1989-12-12
申请号：US101897
申请日：1987-09-28
CPC分类号： G02F1/377 , G02F1/065 , G02F1/3615
摘要： An optical article is disclosed containing, for the transmission of electromagnetic radiation, a medium exhibiting a second order polarization susceptibility greater than 10.sup.-9 electrostatic units comprised of polar aligned noncentrosymmetric molecular dipoles having an electron donor moiety linked through a conjugated .pi. bonding system to an electron acceptor moiety to permit oscillation of the molecular dipole between a ground state exhibiting a first dipole moment and an excited state exhibiting a differing dipole moment. The molecular dipoles are held in polar alignment by a crosslinked polymeric binder.
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8.发明授权Photopolymerization co-initiator compositions comprising amine-substituted ketocoumarins and certain acetic acid derivative activators 失效包含胺取代的酮香豆素和某些乙酸衍生物活化剂的光聚合共引发剂组合物
公开(公告)号：US4278751A
公开(公告)日：1981-07-14
申请号：US95171
申请日：1979-11-16
CPC分类号： C08F2/50 , G03F7/031 , Y10S430/116 , Y10S430/12 , Y10S430/121 , Y10S430/124
摘要： A co-initiator for use in an improved photopolymerization composition, element and method is disclosed. The photopolymerizaton composition comprises an addition-polymerizable compound containing ethylenic unsaturation and the co-initiator which includes a photopolymerization activator and an amine-substituted ketocoumarin sensitizer having an absorption maximum between about 350 and about 550 nm; said activator having the structure ##STR1## wherein Q.sup.1 and Q.sup.2 are each independently hydrogen; alkyl, thioalkyl or alkoxy containing from 1 to about 5 carbon atoms; aryl or aryloxy or benzoyloxy containing from about 6 to 10 carbon atoms; hydroxy; or halogen; or together Q.sup.1 or Q.sup.2 are the necessary atoms to complete a fused heterocyclic or aromatic ring containing from about 4 to 6 ring atoms; and Q.sup.3 is hydrogen or alkyl containing from 1 to about 5 carbon atoms.
摘要翻译： 公开了用于改进的光聚合组合物，元素和方法的共引发剂。 光聚合组合物包含含有烯属不饱和度的加成聚合化合物和包含光聚合活化剂的共引发剂和吸收最大值在约350至约550nm之间的胺取代的酮香豆素敏化剂; 所述活化剂具有以下结构：其中Q1和Q2各自独立地为氢; 烷基，硫代烷基或含有1至约5个碳原子的烷氧基; 含有约6至10个碳原子的芳基或芳氧基或苯甲酰氧基; 羟基; 或卤素; 或者Q1或Q2一起是完成含有约4至6个环原子的稠合杂环或芳环的必要原子; 并且Q3是氢或含有1至约5个碳原子的烷基。
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公开(公告)号：US5316902A
公开(公告)日：1994-05-31
申请号：US49
申请日：1993-01-04
CPC分类号： C08H1/06 , G03C1/047 , G03C1/30 , Y10S430/136 , Y10T428/31728
摘要： Hydrophilic organic colloids such as collagen or gelatin are modified for use in photographic elements such as film or paper, or for use as reagents in automated dry chemical analyzers. The modification comprises reaction of some of the carboxy groups attached to the polypeptide with (i) a amide bond forming agent, e.g. 1-pyrrolidinylcarbonylpyridinium chloride, and (ii) a di- or triamine, such as piperazine, diethylenetriamine or ethylenediamine. Such modification enables that colloid to react faster with a gelatin hardener such as bis(vinylsulfonyl)methane (BVSM). When coated over an equal amount of unmodified gelatin, and both layers imbibed with BVSM, a modified gelatin layer showed an enzyme resistance greater than that of the unmodified gelatin. This demonstrates that the modified gelatin hardened preferentially. This discovery of a method for differential hardening can be utilized to prepare multilayer photographic elements or multilayer reagents for chemical analyzers that contain one or more layers which are hardened preferentially, i.e. to a greater degree than other layers.
摘要翻译： 亲水性有机胶体如胶原或明胶被修饰用于照相材料如薄膜或纸张，或用作自动干化学分析仪中的试剂。 修饰包括与多肽连接的一些羧基与（i）酰胺键形成剂，例如， 1-吡咯烷基羰基吡啶鎓氯化物，和（ii）二胺或三胺如哌嗪，二亚乙基三胺或乙二胺。 这种改性使得胶体与明胶固化剂如双（乙烯基磺酰基）甲烷（BVSM）反应更快。 当涂覆在等量的未改性明胶上，并且两层都被BVSM吸收时，改性明胶层显示出比未改性明胶更大的酶电阻。 这表明改性明胶优先硬化。 这种用于差分硬化的方法的发现可以用于制备用于化学分析仪的多层照相元件或多层试剂，所述多层照相元件或多层试剂含有一个或多个优先硬化的层，即比其它层更大的硬化层。
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10.发明授权Use of 1-(1-pyrrolidinylcarbonyl)pyridinium salts to attach compounds to carboxylated particles and a kit containing same 失效使用1-（1-吡咯烷基亚苄基）吡啶鎓盐将化合物与羧甲基化的颗粒和包含其的试剂盒
公开(公告)号：US5155166A
公开(公告)日：1992-10-13
申请号：US539680
申请日：1990-06-18
IPC分类号： C08F8/32 , C12N11/08 , G01N33/543 , G01N33/545 , G01N33/547
CPC分类号： C12N11/08 , G01N33/54353 , G01N33/545 , Y10S530/812 , Y10S530/815 , Y10S530/816
摘要： Useful materials for diagnostic tests, affinity chromatography, enzymatic reactions and immunoassays are prepared by covalently attaching reactive compounds containing reactive amino or sulfhydryl groups to polymeric particles having pendant carboxyl groups on the outer surfaces. Such reactive compounds include biologically reactive species, including enzymes, polypeptides and proteins. This attachment is carried out using specific carbamoylonium compounds, namely certain 1-(1-pyrrolidinylcarbonyl)pyridinium salts. These compounds react with the carboxyl groups on the particles to form intermediate reactive groups which then react with the amino or sulfhydryl groups to form a covalent linkage between particle and reactive compound. A kit comprises polymeric particles having carboxyl groups on the outer surfaces, and a 1-(1-pyrrolidinylcarbonyl)pyridinium salt.
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